Eureka!

Chem

. [.]

2558

PAT 2
2558
2559

. 1

2558
50 = 13 37
2 (
)

--

10

classic

58

, , Colligative,
, ,
, ,

!1

Eureka! Chem

. [.]

59

1. ( 27Ni)
1. Ni Ni2+
2. Ni2+ [Ar] 4s2 3d6
3. Ni2+ 7
4. NiCl2 MgCl2 Cl
5. KMnO4 Mn

2. 16A 17B 19C 20D 35E

1. C
2. B2 E-
3. C > D > E > A > B
4. A
5. C E

!2

Eureka! Chem

. [.]

3. A B
A = [Ar] 4s2

B = [Ar] 3d10 4s2 4p3

1. A B
2. A B
3. A B
4. A IE1 B
5. A B
4.
1. : F > O > S > Se
2. : P3- > S2- > K+ > Mg2+
3. : Br > Kr > Rb > K
4. : Ni(C2O4)34- > MoS2 > Na3P > NiCO3
5. Mg Si
5.
1. Co(NH3)6SO3
2. Co(NH3)6(SO4)3
3. [Co(NH3)6]3 (SO4)2
4. [Co(NH3)6]2 (SO4)3
5. [Co(NH3)6](SO4)

!3

Eureka! Chem

. [.]

6. 3 NH3 PH3 NCl3

1. NH3 > PH3

2. PH3 > NH3

3. NCl3 > NH3

4. CO2 > HCN

5. HCHO > CH3COCH3

7

7. 3 N2O XeO3 SO3

1. B E D

2. A E D

3. A D C

4. B D C

5. C D E
8.
Na (s) + 1/2 Br2 (l) NaBr (s)
2Na (s) + 1/2 O2 (g) Na2O (s)

(1)
(2)

1. O- (g) + e- O2- (g)

2. -
3. 1
4. 2
5.

!4

Eureka! Chem

. [.]

9. Na2O Pb(NO3)2
. Pb2+ (aq) + O2- (aq) PbO (s)
.
.
.
1.
2.
3.
4.
5.
10.
450

150

1. 1.25

2. 3.5

3. 4.5

4. 5.0

5. 5.25
11.
. NaOH 2% / x cm3
. Na2CO3 53 g/dm3 225 cm3
400 cm3 [Na+] 0.75
mol/dm3 ( Na = 23, C = 12, O = 16, H = 1)
1. 175 cm3
2. 150 cm3
3. 100 cm3
4. 50 cm3
5. 25 cm3
!5

Eureka! Chem

. [.]

12. A 1.5 g B 100 cm3

5.021 OC B

=
0.900 g/cm3

=
5.533 OC
Kf
=
5.12 OC / m
A
=
300
B
=
500
1. 0.20
2. 2.00
3. 0.40
4. 4.00
5. 4.50
13. IA Mx(CO3)y

Mx(CO3)y (s) MxOy (s) + CO2 (g)

Mx(CO3)y 3.45 750 cm3 0.82 atm 27 OC
Mx(CO3)y
1. 74
2. 80
3. 106
4. 138
5. 231

!6

Eureka! Chem

. [.]

14. CaCO3 80 CaCO3 8

1 M. 500 CO2
896 STP CaCO3
1. 0.5
2. 1.0
3. 2.5
4. 3.0
5. 4.5
15. KI 0.1 mol/dm3 100 cm3 KI
Pb(NO3)2 AgNO3 PbI2 2 AgI
1. 80 , 20
2. 20 , 80
3. 60 , 40
4. 50 , 50
5. 30 , 70
16. CxHy 38 cm3 O2 171 cm3 CO2
114 cm3
CxHy
1. C3H4
2. C3H6
3. C3H8
4. C6H12
5. C6H14

!7

Eureka! Chem

. [.]

17.
1.
2.

3.

4.

5.
18. 600 cm3 4560 mmHg
760 mmHg 0.1 cm3
5
( )
1. 1

2. 2

3. 3

4. 4

5. 5
19. A 120 1 10-5 / B

2.4 10-5 / B
1. 20.8
2. 41.6
3. 62.4
4. 83.2
5. 95.3
!8

Eureka! Chem

. [.]

20. A B C D -115, -5.5, 27 100 OC

1. A
2. -37 OC
3. C D 25 OC
4. D
5. C D
21. Mg (s) + 2HCl (aq)

MgCl2 (aq) + H2 (g)

H2 X

(s)

8.0

16.1

26.6

12

40.7

15

1. 40.8
2. 48.7
3. 50.7
4. 54.7
5. 60.8

!9

Eureka! Chem

. [.]

22. NO2 CO NO CO2

R = k[NO2]2

NO2 + NO2 NO + NO3

NO3 + CO NO2 + CO2

1.
2.
3. NO2
4. NO3
5.
23. X 3X 5Y +6Z X

()
0.0
5.0
10.0
15.0
20.0

[X] (mol/dm3)
1.00
0.85
0.75
0.70
0.67

5 Y /
1. 0.15
2. 0.25
3. 0.85
4. 1.42
5. 2.45

!10

Eureka! Chem

. [.]

24. A
B

1.
2.
3.
4.
5.
25. S (g) + 2T (g)

ST2 (g) = 10-3

70 OC
.
.
. S ST2
.
1.
2.
3.
4.
5.
!11

AB3

A2 + B2
Eureka! Chem

A2 + B2

26.

A2 + B2

AB3

A2 + B2

AB

. [.
3 ]

AB3

A + B

2 2
1.
AB
3

2.
3. AB3

4. B2

23.

( ..57)
5.

AB3
.
27.
CO

Cl2 0.06

500 cm3 300 K
.

0.05

2 3.96
.

COCl

. CO
(g)

+ Cl2 (g)
COCl2(g)
.

1. = 0.14 mol
2. 5.412 atm
3. = 200
4. COCl2 = 0.08 mol/dm3
5. 1

!1 2

Eureka! Chem

. [.]

28.
A(g) + 3B(g)

C (g)

K = 30

3D (g) + 2E (g)

2C (g)

K = 20

2A (g) + 6B (g)

3D (g) + 2E (g)

K=x

X
1. 10
2. 25
3. 40
4. 45
5. 50
29. B(OH)3
B(OH)3 (aq) + H2O (l)
B(OH)4- (aq) + H+ (aq)

1.
B(OH)3
2.
B(OH)3
3.
B(OH)3
4.
B(OH)3 -
5.
B(OH)3
30.

(mol/dm3)

HCOOH

0.25

4.0 10-6

C6H5COOH

0.25

6.5 10-5

C6H5COOH

0.40

6.5 10-5

C2H5NH2

0.40

7.5 10-5

(H3C)2NH

0.40

7.5 10-7
!13

Eureka! Chem

. [.]

31. A B
X. H3PO4 0.01 mol/dm3 100 cm3 (H3PO4 Ka1 = 10-5 , Ka2 = 10-9 , Ka3 = 10-12 )
Y. Ca(OH)2 0.1 mol/dm3 100 cm3 HBr 0.2 mol/dm3 100 cm3

pH

5.5 - 6.0

6.5 - 7.5

. A X Y
. A B Y
. B X A Y

1.

2.

3.

4.

5.
32. H2SO4 NaOH H2SO4
H2SO4 NaOH

NaOH pH = 13 H2SO4 mol/dm3

1. 0.025

2. 0.05

3. 0.25

4. 0.40

5. 0.50
!14

Eureka! Chem

. [.]

33. CaCO3 1.0 g

H2SO4 0.1 mol/l 60 cm3
NaOH 0.5 mol/l 20 cm3 CaCO3

1. 0.1 %
2. 0.5 %
3. 1.0 %
4. 10.0 %
5. 50.0 %
34.
HF (Ka = 6.8 10-4)

HCN (Ka = 4.9 10-10)

C6H5COOH (Ka = 6.6 10-5)

HCNO (Ka = 3.5 10-4)

) ) ) ) A B
A

) HF 0.10 mol/dm3 100 cm3

NaF 1.0 mol/dm3 100 cm3

) HCN 0.20 mol/dm3 10 cm3

KOH 0.10 mol/dm3 100 cm3

) C6H5COOH 0.10 mol/dm3 10 cm3

HCl 0.10 mol/dm3 50 cm3

) HCNO 0.20 mol/dm3 100 cm3

NaOH 0.10 mol/dm3 100 cm3

1. ) pH =6.77
2. )
3. ) pH = 5.7
4. )
5. ) pH )
!15

Eureka! Chem

. [.]

35. (H2C2O4) KMnO4 H2SO4

()
aH2C2O4 + bMnO4- + cH+ dMn2+ + eH2O + fCO2

1. CO2 8 mol H2C2O4 1 mol

2. H2C2O4 : MnO4- = 1:2
3. CO2 4.4 H2C2O4 4.5
4. H2SO4 MnO4- Mn2+
5.
36. Cl2 ClO3- + Cl-
1. 5
2. H2O
3. OH-
4. = -10
5.

37. E0
A+ (aq) + e- A (s)

E0 = -0.10 V

B+ (aq) + e- B (s)

E0 = -0.40 V

C2+ (aq) + 2e- C (s)

E0 = -0.70 V

D2+ (aq) + 2e- D (s)

E0 = -1.10 V

!16

Eureka! Chem

. [.]

1. D
2. C B+ (aq)
3. B A+
4. D(s) + 2A+ (aq) D2+ (aq) + 2A (s)
5. C(s) / C2+ (aq) // B+ (aq) / B (s)
38. X Y
X

H2

E0

E0 (v) X+ (aq) + e- X (s)

E0 (v) Y+ (aq) + e- Y(s)

-0.50

-1.00

-1.00

-0.50

+050

-0.50

+050

+1.00

-0.10

+1.00

!17

Eureka! Chem

. [.]

39.
)
e-

)
e-

D
CuSO4 (aq)

ZnSO4 (aq)

A C
A

)
B

)
B

40.
1. 2,3--2-
2. 3,4--1-
3. 3,4--3-
4. 3--2-
5.

!18

Eureka! Chem

. [.]

Taxol 41 - 42

41.
1.

2.

3.

4.

5.
42.
1. 1 3
2.
3. 1 1
4. 2
5. Na

!19

Eureka! Chem

. [.]

43. X KMnO4 (aq) (Y) Na

NaOH Y 1 Na 3 H2 1.5

1. X 2
2. X
3. Y
4. X Na
5. Y NaHCO3 CO2
44. 3

30

20

50

70

10

20

20

30

50

1. 3
2. A
3. B
4. A C
5. B A C
45. 4
1.
2.
3. 4
4. 4
5.
!20

 .
CH3COOH
. HaHCO3
. [.]
Eureka! Chem

.
46.
46. polynucleotide DNA

1.
1. polynucleotide

2.
2.

3.
polynucleotide

3.

4.



4. nucleotide

C
: H :O1:2:1
5.

5.

1

(...57)
. 1 2 3
. 2 3 4
. 3 4 5
. 1 2 5 . 1 3 4
47.

47. X
X

O
C

O
C-O-CH2

CH2O
n

1.
.

2.

.
3.

4.
.


X (...57)
.
.
1
X

. 2 4
1.
. 1 3 4
2.

. 2
. 3 4

19

3.
4.
5.

!21

Eureka! Chem

. [.]

48.
1. LPG
2.
3. NGV NGV
4.
5.
49.
1.

2.

3.
4.

5.

50.
1.

2.
3.
4.
5.
___ ___ ___ __

!22

Eureka! Chem

. [.]

59
1. 1

2. 4

3. 5

4. 2

5. 2

6. 1

7. 2

8. 3

9. 4

10. 2

11. 5

12. 2

13. 4

14. 4

15. 1

16. 2

17. 3

18. 2

19. 1

20. 1

21. 5

22. 4

23. 2

24. 2

25. 1

26. 5

27. 4

28. 4

29. 2

30. 2

31. 3

32. 1

33. 4

34. 5

35. 3

36. 3

37. 3

38. 1

39. 4

40. 3

41. 1

42. 4

43. 2

44. 3

45. 1

46. 3

47. 2

48. 5

49. 1

50. 3

___ ___ ___ __

!2 3