Hints & Solutions

Chemistry
Part A
1.
Sol.

B (Concept Code: C 110504)

CH3COOH NaOH
CH3COONa H2O
Initial
After reacn

2
1

pH pKa log

1
0

Salt pKa log 1 pKa

1
Acid

0
1

0
1

2.
Sol.

D (Concept Code: C 121210)

Tranquilizers are used for stress.

3.
Sol.

B (Concept Code: C 110803)

In NaO, the valency of Na is two, which is not possible.

4.
Sol.

C (Concept Code: C 111003)

Nascent hydrogen is formed in atomic state(H). Others are molecular hydrogen.

5.
Sol.

A (Concept Code: C 111302)

H

(display aromaticity)

The cyclopentadinide ion which is formed after the loss of H as H+, is an aromatic
compound. Hence it is most acidic.
6.
Sol.

A (Concept Code: C 111404)

Cyclic isomers having formula C5H10 are:

7.
Sol.

and
(optically active)

C (Concept Code: C 111804)

The major product is
CH3

CH 3CH 2

C - CH 2CH 3

CH3
It forms five monochloro products
8.
Sol.

D (Concept Code: C 111804)

X = CH3CH2CH2OH

Y = CH 3CHCH 3

OH
9.

B (Concept Code: C 121201)

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Sol.

Phenyl carbocation is unstable. The C Cl bond in (B) contains double bond character
due to +R effect of chlorine.

10.
Sol.

C (Concept Code: C 111403, 111404)

(C) can display geometrical and optical isomerism whereas the other compounds have
only geometrical isomerism. All the compounds can display same no. of structural
isomerism.

11.
Sol.

ABCD (Concept Code: C 110502)

2

M OH2 aq
M aq 2OH aq
S

2S

Ksp = s (2s)2 = 4s3 = 4 1012 s = 104 mol/L

[OH] = 2 104 pOH = log(2 104) = 3.7 pH = 10.3
NH4 removes OH from the system and increases solubility
pH = 6 [OH] = 108
Ksp = [M2+][OH]2 = [M2+][108]2 = 4 1012 [M2+] = 4 104 M

12.
Sol.

ACD (Concept Code: C 110808)

Nitrates of Li(only in gr-I) and the group-2 metals form. Metal oxide, NO2 and O2 on
heating.

13.
Sol.

AC (Concept Code: C 111303)

The no. of hyperconjugation structure depends on the no. of alpha H atoms.
Not all the carbon atoms are sp2 hybridized. CH3 group exert inductive effect not +R.

14.
Sol.

ABCD (Concept Code: C 111403)

Geometrical isomerism is due to the two CH3 groups of the ring.

15.
Sol.

BCD (Concept Code: C 111804)

CH3

CH3

CH3

CH3

Cl
Cl2

Fe

Cl
Cl

CH3

CH2Cl
Cl2 /h

Part C
1.
Sol.

9 (Concept Code: C 111301)

For carbocation, 7, hyperconjugative structures are possible
For alkene, 4 hyperconjugative structures are possible
Two hyperconjugative structure are common to both carbocation and alkene. Hence,
total no. of structures = 9.

2.
Sol.

4 (Concept Code: C 111403)

The isomers are: E E
Z Z
Z E (Two optical isomers)

3.

8 (Concept Code: C 110503)

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Sol.

4.
Sol.

CH3COO H2O
CH3COOH OH
1
pH pK w pKa logC
2
1
14 5 log10 3 8
2

5 (Concept Code: C 121201)

OH

Cl

CH3 C CH2 CCl3

Cl

H2O

CH3

OH

C CH2 C

OH

OH

OH

CH3 C CH2COOH

H O
2

5.
Sol.

4 (Concept Code: C 111401)

The isomers are
CH3CH2CH = CH2, CH3 CH = CH CH3(cis and trans) and CH3 - C = CH 2
CH3

Mathematics
PART A
1.
1.

B
M120602
dy
dy
2e2x 2x 2eo 0 2
dx
dx x 0
1
Slope of normal , at x = 0, y = 1
2
1
Equation of normal, y 1 x 0
2

x 2y 2 0 . Its distance from (0, 0) =

2.
2.

2
5

M120803
x9 3x5 7x3 x
f(x)
sec2 x
2
cos x
2
9
sec x x 3x5 7x3 x sec2 x

/ 4

/ 4
/ 4
0

f(x)dx

/ 4

/ 4

sec2 x dx

sec2 x dx
/4

2.tan x 0 2

Hence (C) is the correct answer.

3.
3.

A
M120809
Given limit is of 0/0 form so applying Leibnitz rule, required value is 8f ' 1 .

4.

M120702

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4.

dx
x tan1 x
1
(1 x2 )3 / 2 dx . Let tan x t 1 x2 dt

5.
5.

x tan1 x
1 x

c now compare it with RHS k1 = 1, k2 = x hence max 1, xdx

0

A
M120603
1 sin x cos x 2

y sinx cos x 1
2 sin x cos x 2

sin x cos x

sin x cos x
1 sin 2x 1

Let P and Q be the points of intersection of given curves.

Now, solving y 1 and x2 y2 5

x2 1 5
x 2

P = (2, 1) and Q = (2, 1)

Clearly the slope of line y = 1 is zero
x2 y2 5

dy
0
dx
dy
x

dx
y

2x 2y

dy
dy
2 and
2
dx
2, 1
dx 2, 1
Thus, the angle of intersection is tan1 2 and tan1 2
6.
6.

M120904
dy 3x 2y 1
We have

dx 3x 2y 1
Put 3x 2y z
dy dz
32

dx dx
1 dz
z 1

3
2 dx
z 1
dz
2z 2 5z 1
3

dx
z 1
z 1
z 1
dz dx

5z 1
1 5z 1 4

dz dx
5 5z 1
1
4 1 5 dz
dz
dx c

5
5 5 5z 1
z 4

log 5z 1 x c

5 25
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2

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5 3x 2y 4log 5 3x 2y 1
25x constant
4log 15x 10y 1 10x 10y

= constant
5
log 15x 10y 1 x y c

2
(b) is the correct answer

7.
7.

M120702
x
x x2 1 dx

dx

x x x2 1

x2 x2 1

x 2dx

1
x 2 1.2 x dx

3/2

2
x3 1 x 1

.
c
3 2
3/2
3/2
x3 1 2

x 1 c
3 3

8.
8.

M120703
x

x3 x

x 1
x5
x 2 1dx
2

x
x 1
2

x 3 dx x dx

9.
9.

1 2x
dx
2 x2 1

x4 x2 1

log x 2 1 C
2
2 2

C
M120603
The curve ax2 by2 1

a' x2 b' y 2 1
1 1 1 1
' '
a a b b
1 1 1
1
But
5 18 13
1
a a' 1
5 18
1 1
1 1

5 8 13
b b' 5 1
8

2
cut orthogonally if

10.

M110707

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Sol.

One of the side of triangle is y = 1 and other two sides are represented by
x2 2y 2 7xy 0 x2 2 7x 0 x1 x 2 7
As one of the vertex is (0, 0)
x1 x 2 x 3 7
y y2 y3 2

y1 y 2 1 1

,
3
3
3
3
7 2
Centroid is ,
3 3

11.

AD

M120804
b

11.

Since f x dx b a f b ax adx ,

sin x dx sinx 1 dx sinx

2

1
4

2x 1 dx

cos x 2 dx 8 cos8x 4 dx

= 8 cos162x 12 dx

12.
12.

AC M110711
As one side of the right angled triangle
is parallel to y axis (x = k) other side
must be parallel to y axis. Also
triangle is isosceles angle made by
hypotenuse from coordinate axis must
be equal
m 1

1 k
k, m

x + my = 1

13.
13.

AD
M110715
Using parametric form of line we get slopes 3 and 1

14.

AC

14.

dy
3ax12 2bx1 c
Slope of the tangent to the curve at (x1, y1) is
dx
(x1 ,y1 )

M120601

The point Q is (0, 5).

Since the curve passes through (-2, 0),
-8a + 4b - 2c + 5 = 0
Since the slope of the tangent at (-2, 0) is 0,
12a - 4b +c =0
Since the slope of the tangent at (0, 5) is 3
c=3
1
3
From (1), (2) and (3), a = , b , c 3.
2
4
15.
15.

... (1)
... (2)
... (3)

BC
M110707
The triangle formed by the given three sides is an obtuse angled triangle, so
circumcentre and orthocentre lies outside the triangle.
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PART C
1.

M120804

1.

f(x) = cos t cos(x t)dt cos( t) cos(x t)dt cos t cos(x t)dt

2f(x) cos t 2cos x cos2 t dt

0

f(x) cos x cos2 tdt

0

cos x
f(x)
2
2.

M120803
/3

2.

I1

sec

f 2 sin 2 d

/6

f a b x dx

Apply property

/3

I1

sec

/6
/3

I1

2 f 2 sin 2 2 d

cos ec f 2 sin 2 d I
2

/6

3.
3.

4.

M120604
t3
16t
Given S =
3
dS 3t 2

16 t 2 16
dt
3
v = t2 16 (where v is the velocity at any time t)
dv
dv
2t acceleration is

= 2t
dt
dt
When v = 0, t2 16 = 0 i.e. t = 4
Thus velocity of the particle will be zero after 4 seconds.
Acceleration = 2 4 = 8 cm/sec2
3

M121002
0

4.

Area 2 x dy 2. k y dy
3

2y3/2
2 k .

3 3
4
. k .3 3 12
3
k 3 k 3
5.

M120803

5.

f (x) =

f x 2

2
f x f x dx dx

f x 3
3

=x+c

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2

Now f (2) =

f t

dt 3 6

6
= 2 + c c = 0 f (x) =
3

3 x f (9) =

27 = 3

Physics
Part A
1.
Sol.

A (Concept code: P110723)

I11 I22

45
36

I 2
I 0.02 (0.04)2 2

60
60

I 1.28 104 kg m2
2.
Sol.

3.
Sol.

B (Concept code: P110801)

JL 10 2 60
JL = I ;
=

15 rad/s
I
4
1 22
3
A (Concept code: P110610)
1
1
1
Since collision is elastic mv 2 mv12 mv 22
2
2
2
2
2
2
v1 v 2 v
(i)

and momentum conservation given mv mv1 mv 2

(ii)
v1 v 2 v
Equation (i) and (ii) shows that angle between the velocity of both bodes after collision is
900 thus angle made by another body = 90 15 = 750

4.
Sol.

A (Concept code: P110706)

From perpendicular axis theorem Iz Ix Iy 2I

5.
Sol.

B (Concept code: P110607 & P110610)

Impact takes place along the normal to the
inclined plane
u sin v cos

v utan

usin

vsin

ucos

v
vcos

v sin u tan sin

ucos
ucos
e tan2
e

6.
Sol.

D (Concept code: P110715 & P110807)

mg T 2ma

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T F ma

T F R I

T F ma
T ma
g
aring =
3

aparticle =
7.
Sol.

2a

F
mg

2g
3

D (Concept code: P110602 & P110715)

mA MA
A
mM
M 0 mR mR
(A CM )y

mM
mM
f (M m)A
(M m)g N (M m)(A CM )y

(A CM )x

mgR IA
A R
N = 70 N

(i)
(ii)
(iii)
(iv)

8.
Sol.

A (Concept code: P110807)

When c.m. moves a distance S, distance covered by the point of application of force F is
2S, therefore work done = F(2S).

9.

A (Concept code: P110610)

Initial momentum 2mu cos

2
Where is angle between initial velocities
By conservation of linear momentum,
u

2m 2mucos
2
2
1
cos 120
2 2

Sol.

2m

u
m

10.
Sol.

D (Concept code: P110609)

Collision will occur after 1 sec.
Just before collision velocity of each object will be 10 m/sec.
Just after collision velocity of combined system will be zero.
So, time taken to reach ground = ( 3 1) sec.

11.
Sol.

ACD (Concept code: P110603 & P110612)

As insect starts moving the tension in the string becomes more than Mg and so net
external force (2T 2Mg) is not zero and the centre of mass of the system accelerates.
When insect moves with constant velocity, net force on the system (insect + rod +
counter mass) is zero. Hence acceleration of the system (insect + rod + counter mass) is
zero.

12.
Sol.

CD (Concept code: P110723)

Linear velocity and angular velocity will be calculated by conservation of angular
momentum. So, they will be independent of coefficient of friction.
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13.
Sol.

AD (Concept code: P110601 & P110604)

At highest point, linear momentum
2 mv = mv1 mv
v1 = 3v
At highest point, velocity of other part after explosion = 3v
Centre of mass of particles will be at a distance R from initial point on ground.

14.
Sol.

BC (Concept code: P110721)

Ring will start pure rolling
a=

F
m

Velocity after time t,

v=at
v=

F
t
m

Angular momentum about point of contact,

L = m(2v)R = 2FRt
15
Sol.

AB (Concept code: P110806)

x2 + y2 = 2

dx
dy
2y
0
dt
dt
dy
x dx 4
vo
dt
y dt 3

4
Now, v + w v o cos 37o
2
3
and

w v = vo sin 37
2

2x

(i)
(ii)

From (i) and (ii)

w=

5v o
3L

PART-C
1.

4 (Concept code: P110603)

Sol.

R R
R R
R2 (O)
( )
2
2

2 2
Xcm =
2
2
R
R
R2 ( )
2
2

2.
Sol.

6 (Concept code: P110807)

F f = ma
(i)
2
(F +f)R = mR2
(ii)
3
6F
a

5m
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vo

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3.
Sol.

11

7 (Concept code: P110613)

Linear impulse of friction = F(dt)
= N(dt)
= 80 N sec

2
m /s
5
Horizontal velocity of ball just after impact = 1 m/s
2
So, x 2 1
5
Horizontal velocity of cart just after impact =

4.
Sol.

2 (Concept code: P110609 & P110604)

Equation of Newtons collision law
v
v1 2
v1 v 2 sin
2
,
e
v0
v0
(i)
2v1 v2 7
From momentum conservation
mv sin30 mv1 sin30 mv 2
v
5 1 2v 2
(ii)
2

v1
v2 cos

v2 sin

After collision

Solving v1 = 2 m/s
5.
Sol.

v2

2 (Concept code: P110709)

= 2
Time taken to reach ground = 2 sec.
So, number of rotations before hitting the ground = 2.

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