Methanol PDF
Methanol PDF
METHANOL
UNIVERSITY OF INDONESIA
Methanol
Introduction
Production
Uses
The Market
Capital Investment and Production Cost
Technology
Advantages
UNIVERSITY OF INDONESIA
Introduction
UNIVERSITY OF INDONESIA
Introduction
Methanol is a
UNIVERSITY OF INDONESIA
Introduction
UNIVERSITY OF INDONESIA
Introduction
UNIVERSITY OF INDONESIA
Introduction
Seperti
proses
amonia,
sintesis
methanol
juga
tergantung
pada
pengembangan katalis yang digunakan.
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Introduction
Tahun 1996 ICI memperkenalkan katalis
cooper/zinc
oxide/alumina
dengan
aktivitas yang lebih besar.
Dengan
katalis ini methanol dapat
bereaksi pada temperatur yang lebih
rendah (kurang dari 300oC) dan tekanan
yang lebih rendah (50-100 bar).
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Introduction
Hasilnya, jika dibandingkan dengan
proses sebelumnya yang memerlukan
tekanan tinggi.
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Introduction
UNIVERSITY OF INDONESIA
Introduction
chloromethanes,
methyl methacrylate,
methylamines,
dimethyl terephthalate,
solvents (such as glycol methyl ethers),
antifreeze, and
fuels.
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Introduction
UNIVERSITY OF INDONESIA
Introduction
UNIVERSITY OF INDONESIA
Introduction
UNIVERSITY OF INDONESIA
Introduction
In short,
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Production
UNIVERSITY OF INDONESIA
Production
UNIVERSITY OF INDONESIA
Production
UNIVERSITY OF INDONESIA
Production
UNIVERSITY OF INDONESIA
Production
UNIVERSITY OF INDONESIA
Production
UNIVERSITY OF INDONESIA
Production
UNIVERSITY OF INDONESIA
Production
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Production
UNIVERSITY OF INDONESIA
Production
(50
UNIVERSITY OF INDONESIA
Production
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Production
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Production
dalam
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Production
Steam Reforming
Oksidasi Parsial
Gasifikasi Batubara
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Production
CO + 2H2 CH3OH
kkal/mol
H298 = -21.684
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Production
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Production
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Production
Recycle
P-5
Flash colom
Heat Exchanger
Gas Sintesis
Crude Methanol
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Production
UNIVERSITY OF INDONESIA
Production
UNIVERSITY OF INDONESIA
Production
UNIVERSITY OF INDONESIA
Production
UNIVERSITY OF INDONESIA
Production
UNIVERSITY OF INDONESIA
Production
UNIVERSITY OF INDONESIA
Production
Proses
Proses
Proses
proses
Lurgi,
Kellog,
Nissui Topsoe dan
Mitsubishi Gas Company (MGC).
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Production
jenis katalis,
reaktor yang dipergunakan dan
kondisi operasi reaksi.
UNIVERSITY OF INDONESIA
Production
Perbandingan penggunaan proses sintesis methanol didunia
Kellogs
3% MGC
8%
ICI
61%
Lurgi
27%
Other
1%
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Production
Dari diagram
sebagian
besar
(61%)
proses
menggunakan teknologi ICI pada tekanan
rendah,
diikuti dengan proses tekanan rendah
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Production
UNIVERSITY OF INDONESIA
Campuran gas sintesis umpan segar ditekan dari 50100 atm melalui sebuah kompresssor dan diumpan
kedalam reaktor berpendingin (quench type converter)
yang beroperasi pada 270oC.
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Karena
dianggap
kurang menguntungkan
ICI
mengganti jenis reaktor yang digunakan dari quench
reactor menjadi tube berpendingin yang pada prinsipnya
sama dengan yang digunakan oleh Lurgi.
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UNIVERSITY OF INDONESIA
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boiling water.
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Pemlihan Teknologi
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Pemlihan Teknologi
Hidrogen
dalam
jumlah
banyak
dibutuhkan dalam sintesis metanol
sebab diperlukan rasio H2 : CO2 sebesar
3:1 dan rasio H2 : CO sebesar 2:1.
Oleh karena itu, proses steam
reforming
dipergunakan
untuk
memproduksi gas sintesis.
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Pemlihan Teknologi
keaktifan katalis,
jenis reaktor, dan
tekanan operasi yang dipergunakan.
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Pemlihan Teknologi
keaktifan
dan
selektifitas
katalis
memegang
peranan
penting
dalam
efisiensi proses,
sehingga proses tidak berlangsung pada
tekanan tinggi atau sedang.
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Pemlihan Teknologi
UNIVERSITY OF INDONESIA
Pemlihan Teknologi
Selektifitas
yang
tinggi
akan
menghasilkan
metanol
dengan
kemurnian yang tinggi dan produk
samping yang terjadi dapat dikurangi.
UNIVERSITY OF INDONESIA
Pemlihan Teknologi
UNIVERSITY OF INDONESIA
Pemlihan Teknologi
teknologi ICI,
Lurgi dan
Kellog.
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Pemlihan Teknologi
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Pemlihan Teknologi
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Pemlihan Teknologi
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Pemlihan Teknologi
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Pemlihan Teknologi
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Pemlihan Teknologi
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Uses
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Uses
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Uses
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Uses
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Uses
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Uses
UNIVERSITY OF INDONESIA
Uses
UNIVERSITY OF INDONESIA
Uses
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Uses
UNIVERSITY OF INDONESIA
Uses
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Uses
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Uses
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Uses
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Uses
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The Market
Methanol is
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The Market
formaldehyde,
methyl tertiary butyl ether (MTBE) and
acetic acid
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UNIVERSITY OF INDONESIA
The Market
UNIVERSITY OF INDONESIA
The Market
UNIVERSITY OF INDONESIA
The Market
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The Market
Hydrogen or
Feed material for power generating systems or
Use in integrated schemes combined with an
ammonia/urea complex, for example.
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The Market
UNIVERSITY OF INDONESIA
The Market
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The Market
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The Market
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Capital Investment
and Production
Cost
UNIVERSITY OF INDONESIA
UNIVERSITY OF INDONESIA
Capital
Investment and
Production Cost
The
double
capacity
of
the
MegaMethanol plant only requires
additional capital expenditure of about
50 % of the plant investment cost
based on the reforming technologies
mentioned above.
These
figures
demonstrate
the
superiority of Lurgi MegaMethanol
technology.
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Capital
Investment and
Production Cost
Since 1995
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Capital
Investment and
Production Cost
UNIVERSITY OF INDONESIA
UNIVERSITY OF INDONESIA
Capital
Investment and
Production Cost
UNIVERSITY OF INDONESIA
Capital
Investment and
Production Cost
UNIVERSITY OF INDONESIA
Capital
Investment and
Production Cost
UNIVERSITY OF INDONESIA
Capital
Investment and
Production Cost
UNIVERSITY OF INDONESIA
Capital
Investment and
Production Cost
UNIVERSITY OF INDONESIA
Capital
Investment and
Production Cost
UNIVERSITY OF INDONESIA
Capital
Investment and
Production Cost
UNIVERSITY OF INDONESIA
Capital
Investment and
Production Cost
UNIVERSITY OF INDONESIA
Capital
Investment and
Production Cost
UNIVERSITY OF INDONESIA
Capital
Investment and
Production Cost
UNIVERSITY OF INDONESIA
UNIVERSITY OF INDONESIA
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Advantages
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Tugas
Jelaskan
mengapa
pada
reaksi
pembuatan metanol yang eksotermis
lebih disukai pada tekanan tinggi dan
suhu rendah
CO + 2H2 CH3OH
kkal/mol
H298 = -21.684