PDF

SAFETY DATA SHEET
Issue Date 27-Jul-2016
Revision Date 27-Jul-2016
Version 2
1. IDENTIFICATION
Product identifier
Product Name
NitraVer 6 Nitrate Reagent
Other means of identification

Product Code(s)
1411999
Safety data sheet number
M00061
UN/ID no
UN3288
Component of Kits or Sets
1411928; 2245100
Recommended use of the chemical and restrictions on use

Determination of nitrate.
Recommended Use
None.
Uses advised against
None.
Restrictions on use
Details of the supplier of the safety data sheet
Manufacturer Address
Hach Company
P.O.Box 389 Loveland, CO 80539 USA
(970) 669-3050
Emergency telephone number
(303) 623-5716 - 24 Hour Service (515)232-2533 - 8am - 4pm CST
Product Information
Chemical Name
Formula
CAS No
Alternate CAS Number
NIOSH (RTECS) Number
Not applicable
Not applicable
Not applicable
Not applicable
None reported
2. HAZARDS IDENTIFICATION
Classification
Regulatory Status
This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200)
Acute toxicity - Inhalation (Dusts/Mists)
Skin corrosion/irritation
Serious eye damage/eye irritation
Germ cell mutagenicity
Carcinogenicity
Reproductive toxicity
Specific target organ toxicity (single exposure)
Category 3
Category 2
Category 1
Category 2
Category 1B
Category 2
Category 3
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Product Code(s) 1411999

Version 2
Product Name NitraVer 6 Nitrate Reagent

Page 2 / 19
Specific target organ toxicity (repeated exposure)
Category 1
Hazards not otherwise classified (HNOC)

Not applicable
Label elements
Signal word - Danger
Hazard statements
H331 - Toxic if inhaled
H315 - Causes skin irritation
H318 - Causes serious eye damage
H341 - Suspected of causing genetic defects
H350 - May cause cancer
H361 - Suspected of damaging fertility or the unborn child
H335 - May cause respiratory irritation
H372 - Causes damage to organs through prolonged or repeated exposure
Precautionary statements
P201 - Obtain special instructions before use
P202 - Do not handle until all safety precautions have been read and understood
P281 - Use personal protective equipment as required
P271 - Use only outdoors or in a well-ventilated area
P264 - Wash face, hands and any exposed skin thoroughly after handling
P260 - Do not breathe dust/fume/gas/mist/vapors/spray
P270 - Do not eat, drink or smoke when using this product
P308 + P313 - IF exposed or concerned: Get medical advice/attention
P304 + P340 - IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing
P311 - Call a POISON CENTER or doctor/physician
P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to
do. Continue rinsing
P310 - Immediately call a POISON CENTER or doctor/physician
P302 + P352 - IF ON SKIN: Wash with plenty of soap and water
P332 + P313 - If skin irritation occurs: Get medical advice/attention
P362 - Take off contaminated clothing and wash before reuse
P405 - Store locked up
P403 + P233 - Store in a well-ventilated place. Keep container tightly closed
P501 - Dispose of contents/ container to an approved waste disposal plant
Other Information
May be harmful if swallowed
Very toxic to aquatic life with long lasting effects
Very toxic to aquatic life
3. COMPOSITION/INFORMATION ON INGREDIENTS
Substance
Not applicable

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Mixture
This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200)
Chemical Name
Tartaric Acid
Sodium Sulfate
1,2-Cyclohexanediaminetetraacetic Acid Trisodium Salt
Cadmium
Copper Dihydrogen Cyclohexanediaminetetraacetic Acid
CAS No
87-69-4
7757-82-6
36679-96-6
7440-43-9
19332-78-6
Weight-%
30.6718
23.4022
9.4605
5.7759
0.3983
HMRIC #
-
4. FIRST AID MEASURES

Description of first aid measures
General advice
In case of accident or unwellness, seek medical advice immediately (show directions for
use or safety data sheet if possible).
Eye contact
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing. Call a physician immediately.
Skin contact
IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin
with water/shower. If symptoms persist, call a physician.
Inhalation
IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a
physician immediately.
Ingestion
IF SWALLOWED: Rinse Mouth. Call a physician immediately.
Self-protection of the first aider
Use personal protective equipment as required. Ensure that medical personnel are aware
of the material(s) involved and take precautions to protect themselves.
Most important symptoms and effects, both acute and delayed

Symptoms
See Section 11: TOXICOLOGICAL INFORMATION.
Indication of any immediate medical attention and special treatment needed

Note to physicians
Treat symptomatically.
5. FIRE-FIGHTING MEASURES
Suitable Extinguishing Media
Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.
Unsuitable extinguishing media Caution: Use of water spray when fighting fire may be inefficient.
Flammable properties
Substance does not burn.
Specific hazards arising from the chemical
None reported.
Hazardous combustion products
cadmium oxide. sulfur oxides. carbon monoxide, carbon dioxide.
Protective equipment and precautions for firefighters

As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full
protective gear.

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6. ACCIDENTAL RELEASE MEASURES

U.S. Notice
Only persons properly qualified to respond to an emergency involving hazardous

substances may respond to a spill according to federal regulations (OSHA 29 CFR
1910.120(a)(v)) and per your company's emergency response plan and
guidelines/procedures. See Section 13, Special Instructions for disposal assistance.
Outside of the US, only persons properly qualified according to state or local regulations
should respond to a spill involving chemicals.
EC Notice

substances should respond to a spill involving chemicals. See Section 13, Special
Instructions for disposal assistance.
WHMIS Notice

substances should respond to a spill involving chemicals. See Section 13, Special
Instructions for disposal assistance.
Personal precautions, protective equipment and emergency procedures

Personal precautions
Evacuate personnel to safe areas. Do not touch or walk through spilled material. Ventilate
affected area. Use personal protective equipment as required.
For emergency responders
Use personal protection recommended in Section 8.
Environmental precautions
Avoid release to the environment. See Section 12 for additional ecological information.
Environmental precautions
Methods and material for containment and cleaning up

Methods for containment
Prevent further leakage or spillage if safe to do so. Cover with plastic sheet to prevent
spreading.
Methods for cleaning up
Take up mechanically, placing in appropriate containers for disposal. Clean contaminated

surface thoroughly. Dispose of in accordance with local, state and federal regulations or
laws.
151
Emergency Response Guide Number
7. HANDLING AND STORAGE

Precautions for safe handling
Advice on safe handling
Use personal protective equipment as required. Avoid contact with skin, eyes or clothing.
Do not breathe dust/fume/gas/mist/vapors/spray.
Conditions for safe storage, including any incompatibilities

Storage Conditions
Keep container tightly closed in a dry and well-ventilated place. Keep out of the reach of
children.
Flammability class
Not applicable
Incompatible materials
Incompatible with:. Oxidizers. powdered metals. hydrazoic acid.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Control parameters
Exposure Guidelines

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Chemical Name
Cadmium
0 - 10%
ACGIH TLV
TWA: 0.01 mg/m3
TWA: 0.002 mg/m3
Copper Dihydrogen
Cyclohexanediaminetetraacetic Acid
0 - 10%
TWA: 1 mg/m3
Chemical Name
Alberta OEL
Cadmium
TWA: 0.01 mg/m3
0 - 10%
TWA: 0.002 mg/m3
Copper Dihydrogen
NDF
Cyclohexanediaminetetraa
cetic Acid
0 - 10%
Chemical Name
Cadmium
0 - 10%
Copper Dihydrogen
cetic Acid
0 - 10%
NIOSH IDLH
IDLH: 9 mg/m3 dust IDLH: 9
mg/m3 Cd dust and fume
IDLH: 100 mg/m3 Cu dust and

mist
TWA: 1 mg/m3 Cu dust and
mist
British Columbia
Manitoba OEL
New Brunswick New Foundland &
OEL
OEL
Labrador OEL
TWA: 0.01 mg/m3 TWA: 0.01 mg/m3 TWA: 0.01 mg/m3 TWA: 0.01 mg/m3
TWA: 0.002 mg/m3 TWA: 0.002 mg/m3 TWA: 0.002 mg/m3 TWA: 0.002 mg/m3
NDF
TWA: 1 mg/m3
NDF
TWA: 1 mg/m3
Northwest
Nova Scotia OEL
Territories OEL
TWA: 0.01 mg/m3 TWA: 0.01 mg/m3
TWA: 0.002 mg/m3 TWA: 0.002 mg/m3
STEL: 0.03 mg/m3
STEL: 0.006 mg/m3
NDF
TWA: 1 mg/m3
Chemical Name
Cadmium
0 - 10%
OSHA PEL
TWA: 0.1 mg/m3
TWA: 0.2 mg/m3
TWA: 5 g/m3
(vacated) STEL: 0.3 ppm
Ceiling: 0.3 mg/m3
Ceiling: 0.6 mg/m3
NDF
Quebec OEL
TWA: 0.025 mg/m3
Nunavut OEL
Ontario TWA
TWA: 0.05 mg/m3

STEL: 0.2 mg/m3
TWA: 0.01 mg/m3

TWA: 0.002 mg/m3
Prince Edward
Island OEL
TWA: 0.01 mg/m3
TWA: 0.002 mg/m3
NDF
NDF
TWA: 1 mg/m3
Saskatchewan OEL
TWA: 0.01 mg/m3
TWA: 0.002 mg/m3
STEL: 0.03 mg/m3
STEL: 0.006 mg/m3
Yukon OEL
STEL: 0.15 mg/m3
TWA: 0.05 mg/m3
Other Information
Vacated limits revoked by the Court of Appeals decision in AFL-CIO v. OSHA, 965 F.2d 962
(11th Cir., 1992).
Legend
See section 16 for terms and abbreviations
Appropriate engineering controls

Engineering Controls
Showers
Eyewash stations
Ventilation systems
Individual protection measures, such as personal protective equipment

Eye/face protection
Wear tight sealing safety goggles and/or face protection shield.
Skin and body protection
Wear protective gloves and protective clothing.
Respiratory protection
In case of insufficient ventilation, wear suitable respiratory equipment.
General Hygiene Considerations
Handle in accordance with good industrial hygiene and safety practice. Do not eat, drink or
smoke when using this product. Take off all contaminated clothing and wash it before
reuse. Wash hands thoroughly after handling. Regular cleaning of equipment, work area

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and clothing is recommended.
Environmental exposure controls

Local authorities should be advised if significant spillages cannot be contained. Do not allow into any sewer, on the ground or into
any body of water. Prevent product from entering drains. Avoid creating dust.
9. PHYSICAL AND CHEMICAL PROPERTIES

Information on basic physical and chemical properties
Physical state
Solid
Gas Under Pressure
Not classified according to GHS criteria
Appearance
powder
Color
blue
metallic
Odor
Odorless
Odor threshold
No data available
Remar
ks Met
hod
Property
Values
Molecular weight
No data available
pH
3.4
Melting point/freezing point
No data available
Boiling point / boiling range
No data available
Evaporation rate
Not applicable
Vapor pressure
Not applicable
Vapor density (air = 1)
Not applicable
Specific gravity (water = 1 / air = 1)
0.954
Partition Coefficient (n-octanol/water)
No data available
Soil Organic Carbon-Water Partition

Coefficient
Autoignition temperature
No data available
Decomposition temperature
No data available
Dynamic viscosity
Not applicable
Kinematic viscosity
Not applicable
5% Solution
No data available
Solubility(ies)
Water solubility
Water solubility classification
Soluble
Solubility in other solvents
Water solubility
> 1000 mg/L
Water Solubility Temperature

25 C / 77 F

Version 2
Chemical Name
None reported

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Solubility classification
No information available
Solubility
No data available
Solubility Temperature
Other Information
Not classified as corrosive to metal according to GHS criteria
Metal Corrosivity
Steel Corrosion Rate
Not applicable
Aluminum Corrosion Rate
Not applicable
Volatile Organic Compounds (VOC) Content
Not applicable.
Bulk density
No data available
Explosive properties
Not classified according to GHS criteria.
Explosion data
Can burn in fire, releasing toxic vapors.
Upper explosion limit
No data available
Lower explosion limit
No data available
Not classified as flammable according to GHS criteria.
Flammable properties
Flammability Limit in Air
Upper flammability limit:
No data available
Lower flammability limit:
No data available
Not applicable
Flash point
Method
Oxidizing properties
Not classified according to GHS criteria.
Reactivity propeties
Not classified as self-reactive, pyrophoric, self-heating or emitting

flammable gases in contact with water according to GHS criteria.
10. STABILITY AND REACTIVITY

Reactivity propeties
Not classified as self-reactive, pyrophoric, self-heating or emitting flammable gases in contact with water according to GHS criteria
Chemical stability
Stable under recommended storage conditions.
Special dangers of the product
None reported
Possibility of Hazardous Reactions
None under normal processing.
Hazardous polymerization
Hazardous polymerization does not occur.
Conditions to avoid
Excess moisture. Excessive heat. Extreme temperatures. Contact with acid or acid fumes. Contact with oxidizers. Incompatibles.

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Incompatible materials
Incompatible with:. Oxidizers. powdered metals. hydrazoic acid.
Hazardous Decomposition Products
Heating to decomposition releases toxic and/or corrosive fumes of:. cadmium oxide. Sulfur oxides. carbon dioxide. Carbon
monoxide.
Explosive properties
Not classified according to GHS criteria. Can burn in fire, releasing toxic vapors.
Upper explosion limit
No data available
Lower explosion limit
No data available
Autoignition temperature
No data available
Sensitivity to Static Discharge
None reported
Sensitivity to Mechanical Impact
None reported
11. TOXICOLOGICAL INFORMATION

Information on Likely Routes of Exposure
Product Information
Inhalation
Eye contact
Skin contact
Ingestion
Aggravated Medical Conditions
Toxicologically synergistic products
Toxicokinetics, metabolism and distribution
Toxic if inhaled. Corrosive to eyes. May cause respiratory

irritation. Causes skin irritation. May be harmful if swallowed.
Avoid breathing dust/fume/gas/mist/vapors/spray. Toxic by
inhalation. Immediate medical attention is required. Inhalation of
dust in high concentration may cause irritation of respiratory
system. May cause irritation of respiratory tract.
Corrosive to the eyes and may cause severe damage including
blindness.
Causes skin irritation.
May be harmful if swallowed. Ingestion may cause irritation to
mucous membranes.
Skin disorders. Eye disorders. Respiratory disorders.
None known.
No information available.
Product Acute Toxicity Data

Oral Exposure Route
No data available
Dermal Exposure Route
No data available
Inhalation (Dust/Mist) Exposure Route
No data available
Inhalation (Vapor) Exposure Route
No data available
Inhalation (Gas) Exposure Route
No data available

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The following values are calculated based on chapter 3.1 of the GHS document
3,570.00 mg/kg
0.87 mg/L
ATEmix (oral)
ATEmix (inhalation-dust/mist)
Ingredient Acute Toxicity Data
Oral Exposure Route
Chemical Name
Endpoint
type
Cadmium
Rat
(0 - 10%)
LD50
CAS#: 7440-43-9
Reported
dose
225 mg/kg
Exposure
time
None
reported
Toxicological effects
None reported
Key literature references and

sources for data
GESTIS (Information System
on Hazardous Substances of
the German Social Accident
Insurance)
No data available

Chemical Name
Endpoint
Reported
type
dose
Cadmium
Rat
0.0125 mg/L
(0 - 10%)
LC50
CAS#: 7440-43-9
Exposure
time
4 hours
None reported
No data available
No data available

sources for data
ERMA (New Zealands
Environmental Risk
Management Authority)
Product Skin Corrosion/Irritation Data

No data available.
Ingredient Skin Corrosion/Irritation Data
Chemical Name
Test method
Species
Reported
dose
Exposure
time
Results
Tartaric Acid
(30 - 40%)
CAS#: 87-69-4
Existing human
experience
Human
None
reported
None
reported
Skin irritant
Key literature
references and
sources for data
Vendor SDS
Product Serious Eye Damage/Eye Irritation Data

No data available.
Ingredient Eye Damage/Eye Irritation Data
Chemical Name
Test method
Species
Reported
dose
Exposure
time
Results
Tartaric Acid
(30 - 40%)
CAS#: 87-69-4
Existing human
experience
Human
None
reported
None
reported
Corrosive to eyes
Sensitization Information
Product Sensitization Data
Skin Sensitization Exposure Route
No data available.
Key literature
references and
sources for data
Vendor SDS

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Respiratory Sensitization Exposure Route
No data available.
Ingredient Sensitization Data

Skin Sensitization Exposure Route
Toxicological data for ingredients is not indicative of likely harm.
Respiratory Sensitization Exposure Route
Toxicological data for ingredients is not indicative of likely harm.
Chronic Toxicity Information

Product Repeat Dose Toxicity Data
Oral Exposure Route
No data available.
No data available.
No data available.
No data available.
No data available.
Ingredient Repeat Dose Toxicity Data

Oral Exposure Route
Chemical Name
Endpoint
type
Cadmium
Rat
(0 - 10%)
TDLo
CAS#: 7440-43-9
Reported
dose
37.5 mg/kg
Exposure
time
30 days

sources for data
RTECS (Registry of Toxic
Biochemical
Enzyme inhibition, induction, or
Effects of Chemical
change in blood or tissue levels
Substances)
(other enzymes)
Blood
Other changes
Kidney, Ureter, or Bladder
Other changes in urine
composition
No data available

Chemical Name
Endpoint
Reported
type
dose
Cadmium
Man
0.000088
(0 - 10%)
TDLo
mg/L
CAS#: 7440-43-9
Exposure
time
3139 days
Kidney, Ureter, or Bladder
Proteinuria
No data available
No data available
Chemical Name
Tartaric Acid
Sodium Sulfate
Sodium Tartrate
1,2-Cyclohexanediaminete
traacetic Acid Trisodium
Salt
Magnesium Sulfate

sources for data
Effects of Chemical
Substances)
CAS No
87-69-4
7757-82-6
868-18-8
36679-96-6
ACGIH
-
IARC
-
NTP
-
OSHA
-
7487-88-9

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Cadmium
Copper Dihydrogen
cetic Acid
Cationic Acrylamide
Copolymer Salts
7440-43-9
19332-78-6
A2
-
Group 1
-
Known
-
X
-
35429-19-7
Legend
ACGIH (American Conference of Governmental Industrial Hygienists)
IARC (International Agency for Research on Cancer)
NTP (National Toxicology Program)
OSHA (Occupational Safety and Health Administration of the US Department of
Labor)
Product Carcinogenicity Data
No data available
Oral Exposure Route
No data available
No data available
No data available
No data available
No data available
A2 - Suspected Human Carcinogen

Group 1 - Carcinogenic to Humans
Known - Known Carcinogen
X - Present
Ingredient Carcinogenicity Data

Oral Exposure Route
No data available
No data available

Chemical Name
Endpoint
Reported
type
dose
Cadmium
Human
0.129 mg/L
(0 - 10%)
CAS#: 7440-43-9
Exposure
route
20 years

sources for data
Lungs, Thorax, or Respiration
Tumors
Effects of Chemical
Substances)
No data available
No data available
Product Germ Cell Mutagenicity invitro Data

No data available.
Ingredient Germ Cell Mutagenicity invitro Data
Chemical Name
Test
Cell Strain
Reported
dose
Exposure
time
Cadmium
(0 - 10%)
CAS#: 7440-43-9
DNA damage
Human
lymphocyte
0.25 mmol/L
1 hours
Chemical Name
Test
Cell Strain
Reported
dose
Exposure
time
Cadmium
Micronucleus test
Mouse embryo
0.006 mmol/L
None
Results
Key literature
references and
sources for data
Positive test result for RTECS (Registry
mutagenicity
of Toxic Effects of
Chemical
Substances)
Results
Key literature
references and
sources for data
Positive test result for RTECS (Registry

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reported
(0 - 10%)
CAS#: 7440-43-9
Oral Exposure Route
No data available
No data available
No data available
No data available
No data available
mutagenicity
of Toxic Effects of
Chemical
Substances)
Ingredient Germ Cell Mutagenicity invivo Data

Oral Exposure Route
No data available
No data available
No data available
No data available
No data available
Oral Exposure Route
No data available
No data available
No data available
No data available
No data available
Ingredient Reproductive Toxicity Data

Oral Exposure Route
Chemical Name
Endpoint
type
Sodium Sulfate
Mouse
(20 - 30%)
TDLo
CAS#: 7757-82-6
Cadmium
Rat
(0 - 10%)
TDLo
CAS#: 7440-43-9
Reported
dose
14000 mg/kg
Exposure
time
4 days
23 mg/kg
22 days
Effects on Newborn
Other neonatal measures or
effects
Specific Developmental
Abnormalities
Blood and lymphatic systems
(including spleen and marrow)
No data available
No data available
No data available
No data available

sources for data
Effects of Chemical
Substances)
Effects of Chemical
Substances)
12. ECOLOGICAL INFORMATION

Ecotoxicity
Product Ecological Data
Very toxic to aquatic life with long lasting effects.

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Aquatic toxicity
Fish
No data available
Crustacea
No data available
Algae
No data available
Terrestrial toxicity
Soil
No data available
Vertebrates
No data available
Invertebrates
No data available
Ingredient Ecological Data

Aquatic toxicity
Fish
Chemical Name
Sodium Sulfate
(20 - 30%)
CAS#: 7757-82-6
Cadmium
(0 - 10%)
CAS#: 7440-43-9
Chemical Name
Sodium Sulfate
(20 - 30%)
CAS#: 7757-82-6
Cadmium
(0 - 10%)
CAS#: 7440-43-9
Crustacea
Chemical Name
Sodium Sulfate
(20 - 30%)
CAS#: 7757-82-6
Cadmium
(0 - 10%)
CAS#: 7440-43-9
Chemical Name
Cadmium
(0 - 10%)
CAS#: 7440-43-9
Algae
Chemical Name
Cadmium
(0 - 10%)
CAS#: 7440-43-9
Exposure
time
96 hours
None reported
Endpoint
type
LC50
Reported
dose
56 mg/L
96 hours
Morone saxatilis
LC50
0.019 mg/L
Exposure
time
96 hours
Species
Pimephales promelas
Endpoint
type
LC50
Reported
dose
7960 mg/L
96 hours
None reported
LC50
7.8 mg/L
Exposure
time
48 Hours
Species
Daphnia magna
Endpoint
type
EC50
Reported
dose
3150 mg/L
48 Hours
None reported
EC50
0.58 mg/L
Exposure
time
96 hours
Species
Endpoint
type
LC50
Reported
dose
sources for data
0.0016 mg/L PEEN (Pan European Ecological
Network)
Endpoint
type
EC50
Reported
dose
0.132 mg/L
Exposure
time
72 Hours
Species
Mysidopsis bahia
Species
None reported

sources for data
IUCLID (The International
Uniform Chemical Information
Database)
PEEN (Pan European Ecological
Network)
sources for data
Database)
Network)

sources for data
Database)
Network)

sources for data
Network)

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Terrestrial toxicity
Soil
No data available
Vertebrates
No data available
Invertebrates
No data available
Other Information
Canadian Environmental Protection Act (CEPA) - Domestic Substances List (DSL):
Environmentally Hazardous Substances Categorizations
Chemical Name
Cationic Acrylamide Copolymer

Salts
(0 - 10%)
CAS#: 35429-19-7
Category
Persistent
Yes
Bioaccumulation Inherently Toxic

to Aquatic
Organisms
No
Yes
Persistence and degradability

None known.
Product Biodegradability Data
If available, see ingredient data below.
Ingredient Biodegradability Data
Test data reported below
Chemical Name
Test method
1,2-Cyclohexanediam
inetetraacetic Acid
Trisodium Salt
(0 - 10%)
CAS#: 36679-96-6
None reported
Biodegradation Exposure
time
None reported
None
reported
Results
Not readily
biodegradable
Bioaccumulation
None known.
Product Bioaccumulation Data
No data available.
Ingredient Bioaccumulation Data
No data available
Additional information
Product Information
No data available
Partition Coefficient (n-octanol/water)
No data available
Ingredient Information
Chemical Name
Tartaric Acid
(30 - 40%)
CAS#: 87-69-4
Partition Coefficient
(n-octanol/water)
log Kow = -1
Method
Estimation through KOWWIN v1.68 part
of the Estimation Programs Interface
(EPI) Suite

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Sodium Sulfate
(20 - 30%)
CAS#: 7757-82-6
Sodium Tartrate
(20 - 30%)
CAS#: 868-18-8
1,2-Cyclohexanediaminetetraacetic Acid
Trisodium Salt
(0 - 10%)
CAS#: 36679-96-6
log Kow = -3
log Kow = -4.28
log Kow = -11
Estimation through KOWWIN v1.68 part

(EPI) Suite
Mobility
Mobility in soil: Moderate to high mobility. If available, see ingredient data below.
Product Information
No data available
Soil Organic Carbon-Water Partition Coefficient
No data available
Chemical Name
Sodium Sulfate
(20 - 30%)
CAS#: 7757-82-6
Sodium Tartrate
(20 - 30%)
CAS#: 868-18-8
1,2-Cyclohexanediaminetetraacetic Acid
Trisodium Salt
(0 - 10%)
CAS#: 36679-96-6
Soil Organic Carbon-Water Partition

Method
Coefficient
log Koc = -1.4
Estimation through KOCWIN v2.00 part
(EPI) Suite
log Koc = -1.33
log Koc = 2.24
Estimation through KOCWIN v2.00 part

(EPI) Suite
Additional information
Water solubility
Product Information
Water solubility classification
Water solubility
Water Solubility Temperature
Soluble
> 1000 mg/L
25 C / 77 F
Chemical Name
Water solubility Water solubility

classification
Completely soluble 1390000 mg/L
Tartaric Acid
(30 - 40%)
CAS#: 87-69-4
Sodium Sulfate
Completely soluble
(20 - 30%)
CAS#: 7757-82-6
Sodium Tartrate
Completely soluble
(20 - 30%)
CAS#: 868-18-8
1,2-Cyclohexanediaminetetraacetic Acid Trisodium
Soluble
Salt
(0 - 10%)
CAS#: 36679-96-6
Cadmium
Insoluble
Water solubility
temperature C
20 C
Water solubility
temperature F
68 F
160000 mg/L
20 C
68 F
100000 mg/L
20 C
68 F
> 1000 mg/L
50 C
122 F
< 0.1 mg/L
25 C
77 F

Version 2

Page 16 / 19
(0 - 10%)
CAS#: 7440-43-9
Copper Dihydrogen Cyclohexanediaminetetraacetic
Acid
(0 - 10%)
CAS#: 19332-78-6
Soluble
> 1000 mg/L
25 C
77 F
Other adverse effects

Contains a substance with an endocrine-disrupting potential.
13. DISPOSAL CONSIDERATIONS

Waste treatment methods
Disposal of wastes
Disposal should be in accordance with applicable regional, national and local laws and
regulations.
Contaminated packaging
Working in a well-ventilated area,. Rinse three times with an appropriate solvent. Collect
rinsate and dispose of according to local, state or federal regulations. Dispose of empty
container as normal trash. In the US, rinsate from empty containers is classified as
hazardous waste and should be disposed of at an E.P. A. approved facility. Rinsate from
empty containers may contain sufficient product to require disposal as hazardous waste in
countries other than the US. Improper disposal or reuse of this container may be dangerous
and illegal. Disposal should be in accordance with applicable regional, national and local
laws and regulations.
Chemical Name
RCRA
Cadmium
7440-43-9
Special instructions for disposal
RCRA - Basis for

Listing
Included in waste
streams: F006, F039,
K061, K069, K100
RCRA - D Series
Wastes
1.0 mg/L regulatory level
RCRA - U Series
Wastes
-
Dispose of material in an E.P.A. approved hazardous waste facility. Otherwise, Check with
local municipal and state authorities and waste contractors for pertinent local information
regarding the proper disposal of chemicals.
14. TRANSPORT INFORMATION

DOT
UN/ID no
Proper shipping name
DOT Technical Name
Hazard Class
Packing Group
Marine pollutant
Emergency Response Guide
Number
TDG
UN/ID no
Hazard Class
Packing Group
Marine pollutant
IATA
UN3288
Toxic Solid, Inorganic, N.O.S.
(Cadmium mixture)
6.1
III
This product contains a chemical which is listed as a severe marine pollutant according to
DOT.
151
UN3288
6.1
III
This product contains a chemical which is listed as a severe marine pollutant according to
TDG. Lead compounds.

Version 2
UN/ID no
Hazard Class
Packing Group
ERG Code

Page 17 / 19
UN3288
6.1
III
151
IMDG
UN/ID no
Hazard Class
Packing Group
Marine pollutant
UN3288
6.1
III
This material meets the definition of a marine pollutant
Note:
No special precautions necessary.
15. REGULATORY INFORMATION

National Inventories
TSCA
DSL/NDSL
Complies
Complies
TSCA - United States Toxic Substances Control Act Section 8(b) Inventory
DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List
International Inventories
EINECS/ELINCS
ENCS
IECSC
KECL
PICCS
TCSI
AICS
NZIoC
Complies
Complies
Complies
Complies
Does not comply
Complies
Does not comply
Does not comply
EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances
ENCS - Japan Existing and New Chemical Substances
IECSC - China Inventory of Existing Chemical Substances
KECL - Korean Existing and Evaluated Chemical Substances
PICCS - Philippines Inventory of Chemicals and Chemical Substances
TCSI - Taiwan Chemical Substances Inventory
AICS - Australian Inventory of Chemical Substances
NZIoC - New Zealand Inventory of Chemicals
US Federal Regulations
SARA 313
2
Chemical Name
Cadmium (CAS #: 7440-43-9)
SARA 311/312 Hazard Categories
Acute health hazard
Chronic Health Hazard
Fire hazard
Sudden release of pressure hazard
Reactive Hazard
SARA 313 - Threshold Values %

0.1
No
Yes
No
No
No
CWA (Clean Water Act)

This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40
CFR 122.42)

Version 2
Chemical Name
Cadmium
7440-43-9
Copper Dihydrogen
Cyclohexanediaminetetra
acetic Acid
19332-78-6

Page 18 / 19
CWA - Reportable
Quantities
-
CWA - Toxic Pollutants

X
CWA - Priority
Pollutants
X
CWA - Hazardous
Substances
-
CERCLA
As supplied, this material does not contain any hazardous substances as regulated under the Comprehensive Environmental
Response Compensation and Liability Act (CERCLA) (40 CFR 302)or the Superfund Amendments and Reauthorization Act
(SARA) (40 CFR 355). T
Chemical Name
Hazardous Substances RQs

10 lb
Cadmium
7440-43-9
CERCLA/SARA RQ
-
Reportable Quantity (RQ)

RQ 10 lb final RQ
RQ 4.54 kg final RQ
US State Regulations
California Proposition 65
This product contains the following Proposition 65 chemicals
Chemical Name
Cadmium (CAS #: 7440-43-9)
California Proposition 65
Carcinogen
Developmental
Male Reproductive
U.S. State Right-to-Know Regulations

Chemical Name
Cadmium
7440-43-9
Copper Dihydrogen
Cyclohexanediaminetetraacetic
Acid
19332-78-6
New Jersey
X
Massachusetts
X
Pennsylvania
X
U.S. EPA Label Information

EPA Pesticide Registration Number Not applicable
16. OTHER INFORMATION, INCLUDING DATE OF PREPARATION OF THE LAST REVISION

NFPA and HMIS Classifications
NFPA
Health hazards - 3
Flammability - 0
Instability - 0
HMIS
Health hazards - 3
Flammability - 0
Physical hazards - 0
Key or legend to abbreviations and acronyms used in the safety data sheet
NIOSH IDLH
Immediately Dangerous to Life or Health
Physical and Chemical

Properties Personal protection - X
- See section 8 for more
information

Version 2
ACGIH
NDF

Page 19 / 19
ACGIH (American Conference of Governmental Industrial Hygienists)
no data
Legend - Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION

TWA
TWA (time-weighted average)
STEL
STEL (Short Term Exposure Limit)
MAC
Maximum Allowable Concentration
Ceiling
Ceiling Limit Value
Listed
Vacated
These values have no official status. The only

binding levels of contaminants are those
listed in the final OSHA PEL. These lists are
for reference purposes only. Please note that
some reference state regulations of these ''
liberated '' exposure limits i
SKN*
RSP+
C
M
Skin designation
Respiratory sensitization
Carcinogen
mutagen
SKN+
**
R
Skin sensitization
Hazard Designation
Reproductive toxicant
Prepared By
Hach Product Compliance Department
Issue Date
27-Jul-2016
Revision Date
27-Jul-2016
Revision Note
None
Disclaimer
USER RESPONSIBILITY: Each user should read and understand this information and incorporate it in individual site
safety programs in accordance with applicable hazard communication standards and regulations.
THE INFORMATION CONTAINED HEREIN IS BASED ON DATA CONSIDERED TO BE ACCURATE. HOWEVER, NO
WARRANTY IS EXPRESSED OR IMPLIED REGARDING THE ACCURACY OF THESE DATA OR THE RESULTS TO BE
OBTAINED FROM THE USE THEREOF.
HACH COMPANY 2016
End of Safety Data Sheet

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SAFETY DATA SHEET

Issue Date 27-Jul-2016

Revision Date 27-Jul-2016

NitraVer 6 Nitrate Reagent

Other means of identification

Component of Kits or Sets

Recommended use of the chemical and restrictions on use

Product Code(s) 1411999

Product Name NitraVer 6 Nitrate Reagent

Specific target organ toxicity (repeated exposure)

Hazards not otherwise classified (HNOC)

Product Code(s) 1411999

Product Name NitraVer 6 Nitrate Reagent

4. FIRST AID MEASURES

IF SWALLOWED: Rinse Mouth. Call a physician immediately.

Self-protection of the first aider

Most important symptoms and effects, both acute and delayed

See Section 11: TOXICOLOGICAL INFORMATION.

Indication of any immediate medical attention and special treatment needed

cadmium oxide. sulfur oxides. carbon monoxide, carbon dioxide.

Protective equipment and precautions for firefighters

Product Code(s) 1411999

Product Name NitraVer 6 Nitrate Reagent

6. ACCIDENTAL RELEASE MEASURES

Only persons properly qualified to respond to an emergency involving hazardous

Only persons properly qualified to respond to an emergency involving hazardous

Only persons properly qualified to respond to an emergency involving hazardous

Personal precautions, protective equipment and emergency procedures

For emergency responders

Use personal protection recommended in Section 8.

Methods and material for containment and cleaning up

Methods for cleaning up

Take up mechanically, placing in appropriate containers for disposal. Clean contaminated

Emergency Response Guide Number

7. HANDLING AND STORAGE

Conditions for safe storage, including any incompatibilities

Incompatible with:. Oxidizers. powdered metals. hydrazoic acid.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Product Code(s) 1411999

Product Name NitraVer 6 Nitrate Reagent

IDLH: 100 mg/m3 Cu dust and

TWA: 0.05 mg/m3

TWA: 0.01 mg/m3

See section 16 for terms and abbreviations

Appropriate engineering controls

Individual protection measures, such as personal protective equipment

Wear tight sealing safety goggles and/or face protection shield.

Skin and body protection

Wear protective gloves and protective clothing.

In case of insufficient ventilation, wear suitable respiratory equipment.

General Hygiene Considerations

Product Code(s) 1411999

Product Name NitraVer 6 Nitrate Reagent

Environmental exposure controls

9. PHYSICAL AND CHEMICAL PROPERTIES

Gas Under Pressure

Not classified according to GHS criteria

Melting point/freezing point

Boiling point / boiling range

Vapor density (air = 1)

Specific gravity (water = 1 / air = 1)

Partition Coefficient (n-octanol/water)

Soil Organic Carbon-Water Partition