Calculas las composiciones de vapor y liquido y graficas los diagramas de fase para

1) propano
2) n-butano
a)
Temperatura constante de 240K
b)
A presin constante de 1 bar
Parmetros de Antoine
A
B
C
P=bar
log()=/(+
propano
n-butano
propano
n-butano

3.98292
3.85002

819.296
909.65

-24.417
-36.146

T=K

Presiones de vapor
1.522460838 bar
0.244206822 bar
T
240 K
x1
P
y1
0
0.244206822
0
0.05
0.308119523 0.24705686
0.1
0.372032224 0.409228217
0.15
0.435944925 0.523848571
0.2
0.499857625 0.609157792
0.25
0.563770326 0.675124588
0.3
0.627683027 0.727657483
0.35
0.691595728 0.770480892
0.4
0.755508429 0.806058956
0.45
0.819421129 0.836087028
0.5
0.88333383 0.861769801
0.55
0.947246531 0.883986833
0.6
1.011159232 0.903395305
0.65
1.075071932 0.920496122
0.7
1.138984633 0.935677757
0.75
1.202897334 0.949246121
0.8
1.266810035 0.961445392
0.85
1.330722735 0.972472836
0.9
1.394635436 0.982489558
0.95
1.458548137 0.991628428
1
1.522460838
1

T
1.6
1.4
1.2
1
P

0.8
0.6
0.4
0.2
0
0

c)

0.1

cuando:
y1
x1=
P

0.2

0.3

0.4

gramas de fase para

c)
d)

Calcular la presin de roco para mezcla equimolar a T=240K

Calcular la temperatura de roco para mezcla equimolar a P=1 bar

log()=/(+)

Para calcular T, usar T-x-y.ees

=11+(11)2
1=11/

T=240K
burbuja

X
Y

roco

0.2

0.3

0.4

0.5

0.6

0.7

x,y

0.5
0.1382
0.4209 bar
calculado con EES
dew_P.ees

0.8

0.9

1.1

x1
0
0.05
0.1
0.15
0.2
0.25
0.3
0.35
0.4
0.45
0.5
0.55
0.6
0.65
0.7
0.75
0.8
0.85
0.9
0.95
1

1=.5=11/(11+(11)

calcular T, usar T-x-y.ees

P
T
272.4
267.7
263.6
260
256.8
253.9
251.3
249
246.8
244.8
243
241.3
239.7
238.3
236.9
235.6
234.4
233.2
232.1
231.1
230.1

1=.5=11/
1 bar

Pvap1
4.776179321
4.123381684
3.610156715
3.200234428
2.866104689
2.586653946
2.3541021
2.161938534
1.989543753
1.842125768
1.716743307
1.604447936
1.504008372
1.420168022
1.339988114
1.268718583
1.205576079
1.144904039
1.091401861
1.044474404
0.999137636

y1
0
0.206169084
0.361015671
0.480035164
0.573220938
0.646663487
0.70623063
0.756678487
0.795817501
0.828956596
0.858371654
0.882446365
0.902405023
0.923109214
0.93799168
0.951538937
0.964460863
0.973168433
0.982261675
0.992250684
0.999137636

P=1 b
280
270
260
250
240
230
220
210
200

burbuja

x,y

d)

cuando:
y1
x1
T
calculado con EES

1/(11+(11)2)

de aqu se saca x1
para luego:

11/

se despeja P

P=1 bar
roco

X
Y

x,y

0.5
0.1598
259.3 K

ulado con EES

dew_T.ees