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BITSAT SAMPLE PAPER

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BITSAT SAMPLE PAPER

BITSAT Sample Papers - 1

- 1

1.

Question
From the given sets of quantum numbers the one that is inconsistent with the theory is :
Possible Answer

2.

Question
Calculate the momentum of a particle which has a de-Broglies wavelength of

Possible Answer
None

3.

Question
The total number of electrons present in all the p-orbitals of bromine are :
Possible Answer
Seventeen
Five
Thirty five
Eighteen

4.

Question

BITSAT SAMPLE PAPER

When an electron revolves in a stationary orbit then:

Possible Answer
Its energy remains constant
It gains kinetic energy
It emits radiation
absorbs energy
5.

Question
The

total

number

of

valence

electrons
in
4.2
gm
of
ion is (
is the Avogadros number) :

Possible Answer

6.

Question
If

, then the value of

which is incorrect :

Possible Answer
3
0
1
2
7.

Question
Chlorine atom differs from chloride ion in the number of :
Possible Answer
Neutron
Proton
Electrons

BITSAT SAMPLE PAPER

Protons and electrons

8.

Question
The uncertainty in the position of an electron (
) moving with a velocity of
accurate upto 0.001% will be (use
in the uncertainty
expression, where
erg-s
Possible Answer
1.92 cm
5.76 cm
3.84 cm
7.68 cm

9.

Question
A 3p orbital has :
Possible Answer
Two non-spherical nodes
One spherical and two non-spherical nodes
Two spherical nodes
One spherical and one non-spherical nodes

10.

Question
Zeeman effect refers to the :
Possible Answer
Emission of electrons from metals when light falls upon them
Random scattering of light by colloidal particles
Splitting up of the lines in an emission spectrum in a magnetic field
Splitting up to the lines in an emission spectrum in the presence of an external
electrostatic field

11.

Question
For n = 3 energy level, the number of possible orbitals are :

BITSAT SAMPLE PAPER

Possible Answer
4
9
3
1
12.

Question
The orbital angular momentum of an electron in 2s orbital is :
Possible Answer

zero
13.

Question
Which statement is not correct for n = 5, m = 3 :
Possible Answer
l = 0, 1, 2, 3 ; s = + 1/2
l=3
l=4
All are correct

14.

Question
shows configuration of :
Possible Answer
All are correct
in ground state
in excited stated
Ne in excited state

15.

Question
4

BITSAT SAMPLE PAPER

In a Bohrs model of atom when an electron jumps from n = 1 to n = 3, how much energy
will be emitted or absorbed :
Possible Answer
ergs
ergs
ergs
ergs
16.

Question
Which of the following metal ions will have maximum number of unpaired electrons :
Possible Answer

17.

Question
The maximum probability of finding an electron in the

orbital is :

Possible Answer
At an angle of 90 from the x and y-axes
Along the x-axis
At an angle of 45 from the x and y-axes
Along the y-axis
18.

Question
CO has same electrons as or the ion that is isoelectronic with CO is :
Possible Answer

BITSAT SAMPLE PAPER

19.

Question
The total number of orbital in an energy level designated by principal quantum number n,
is equal to :
Possible Answer

20.

Question
Which electronic level would allow the hydrogen atom to absorb a photon but not to emit
a photon :
Possible Answer
1s
2p
2s
3s

21.

Question
An electron has principal quantum number
(i) subshells and (ii) orbitals would be respectively
Possible Answer
3 and 7
3 and 9
2 and 5
3 and 5

22.

Question
Aufbau principle is not satisfied by :

3.

The

number

of

its

BITSAT SAMPLE PAPER

Possible Answer
Cu and Ag
Cr and Mg
Cr and Cl
Cu and Na
23.

Question
The first use of quantum theory to explain the structure of atom was made by :
Possible Answer
Planck
Heisenberg
Bohr
Einstein

24.

Question
Five valence electrons of
are labelled as
If the spin quantum number of B
and Z is + 1/ 2, the group of electrons with three of the quantum number same are :
Possible Answer
XYZ, AZ
AB
AB, XYZ
Ab, XYZ, BY

25.

Question
In an element going away from nucleus, the energy of particle :
Possible Answer
None of these
Decreases
Increases
Unchanged

BITSAT SAMPLE PAPER

26.

Question
In neutral atom, which particles are equivalent :
Possible Answer

27.

Question
If

, then total possible number of subshells would be :

Possible Answer
3
5
2
4

28.

Question
The configuration

shows

Possible Answer
Excited state of ion
Excited state of fluorine atom
Excited state of neon atom
Ground state of fluorine atom
29.

Question
The electron configuration of gadolinium (atomic no. 64) is :
Possible Answer

BITSAT SAMPLE PAPER

30.

Question
If electron falls from n = 3 to n = 2, then emitted energy is :
Possible Answer
1.9 eV
0.65 eV
12.09 eV
10.2 eV

31.

Question
Number of protons, neutrons and electrons in the element

is :

Possible Answer
89, 71, 89
89, 142, 89
89, 89, 242
89, 231, 89
32.

Question
In the ground state configuration of
and unpaired electrons

how many orbitals are present having paired

Possible Answer
16
10
12
15
33.

Question
Discoverer of positron :

BITSAT SAMPLE PAPER

Possible Answer
Paulling
Segre
Anderson
Yukawa
34.

Question
Which of the following species not contains neutrons :
Possible Answer
O
C
H

35.

Question
The energy of an electron in the first Bohr orbit of H atom is
. The possible energy
value of the first excited state for electrons in Bohr orbits to hydrogen is (are) :
Possible Answer

36.

Question
The energy of an electron in the first orbit of He+ is
electron in the first orbit of hydrogen would be
Possible Answer

10

. The energy of the

BITSAT SAMPLE PAPER

37.

Question
The position of both an electron and a helium atom is known within 1.0 nm and the
momentum of the electron is known within
. The minimum
uncertainty in the measurement of the momentum of the helium atom is :
Possible Answer

38.

Question
The Bohr orbit radius for the hydrogen atom (n = 1) is approximately 0.530 A. The radius
for the first excited state (n = 2) orbit is :
Possible Answer

39.

Question
Which of the following explain the sequence of filling the electrons in different orbitals :
Possible Answer
All of these
Octet rule
Aufbau principle
Hunds rule

40.

Question
Number of orbitals having paired electrons for gaseous Fe are :
Possible Answer

11

BITSAT SAMPLE PAPER

19
4
15
11
41.

Question
is the configuration of the following ion :
Possible Answer

42.

Question
Which triad of quantum number

is not applicable for 3d-electron :

Possible Answer
3, 1, 1
3, 2, 0
3, 2, +1
3, 2, 2
43.

Question
Which of the following configuration follows the Hunds rule :
Possible Answer

12

BITSAT SAMPLE PAPER

44.

Question
The ratio of radii of 3rd and 2nd Bohrs orbit of hydrogen atom is :
Possible Answer
3:2
9:1
4:9
9:4

45.

Question
The four quantum number for the valence shell electron or last electron of sodium is :
Possible Answer

46.

Question
Heaviest particle is :
Possible Answer
Proton
Meson
Electron
Neutron

47.

Question
Which is correct statement about proton :
Possible Answer
Proton is ionized hydrogen atom
Proton is ionized hydrogen molecule

13

BITSAT SAMPLE PAPER

Proton is -particle
Proton is nucleus of deuterium
48.

Question
The energy of an electron in nth orbit of hydrogen atom is :
Possible Answer

49.

Question
If wavelength of photon is

, then momentum of photon is :

Possible Answer

50.

Question
The electrons identified by quantum number

and

can be placed in order of increasing energy from the lowest to highest, as :

Possible Answer
(iv) < (ii) < (iii) < (i)
(ii) < (iv) < (i) < (iii)
(i) < (iii) < (ii) < (iv)
(iii) < (i) < (iv) < (ii)

14

BITSAT SAMPLE PAPER

51.

Question
Ground state electron configuration of nitrogen atom can be represent by :
Possible Answer
None of these

52.

Question
Which of the following has more unpaired d-electron :
Possible Answer

53.

Question
The uncertainty in momentum of an electron is
position will be :

. The uncertainty in its

Possible Answer

54.

Question
The de-Broglie wavelength of a particle with mass 1g and velocity 100 m/s is :
Possible Answer

15

BITSAT SAMPLE PAPER

55.

Question
Which of the following set of quantum numbers belong to highest energy :
Possible Answer

56.

Question
Which of the following are isoelectronic species :

Possible Answer
I, II, IV
I and II
I, II, III
II, III, IV
57.

Question
Which quantum number will determine the shape of the subshell :
Possible Answer
Spin quantum number
Magnetic quantum number
Principal quantum number
Azimuthal quantum number

16

BITSAT SAMPLE PAPER

58.

Question
A metal in its di positive state has the electronic configuration 2, 8, 14 and has the atomic
weight equal to 56. Number of neutrons in its nucleus would be :
Possible Answer
30
34
28
32

59.

Question
Which set of quantum number for an electron of an atom is not possible :
Possible Answer

60.

Question
Outer electronic configuration of the element of atomic number 24 is :
Possible Answer
None

61.

Question
The basis of three unpaired electrons in the configuration of nitrogen is :
Possible Answer
Aufbau principle
Hunds principle

17

BITSAT SAMPLE PAPER

Paulis principle
Uncertainty principle
62.

Question
Correct order of size is :
Possible Answer

63.

Question
Which is not electromagnetic radiation :
Possible Answer
Xray
Infrared rays
Cathode rays
Gamma rays

64.

Question
Which of the following pair of orbitals posses two nodal planes :
Possible Answer

65.

Question
The mass of a neutron is of the order of :
Possible Answer
18

BITSAT SAMPLE PAPER

66.

Question
Smallest cation is :
Possible Answer

67.

Question
Electron enters the sub-shell for which
This is enunciated as :

value is minimum.

Possible Answer
Aufbau principle
Paulis exclusion principle
Hunds rule
Heisenberg uncertainty principle
68.

Question
The minimum real charge on any particle which can exist is :
Possible Answer
Zero

19

BITSAT SAMPLE PAPER

69.

Question
Which sub-shell is not permissible :
Possible Answer
4f
2d
3s
6p

70.

Question
Sub-shell designated by azimuthal quantum number
electrons :

can have maximum number of

Possible Answer
0
14
10
6
71.

Question
Quantum number

shows how many orbitals :

Possible Answer
2
3
4
1
72.

Question
Which is isoelectronic with sulphide ion :
Possible Answer
Ne
Ar

20

BITSAT SAMPLE PAPER

Kr
Cl
73.

Question
Ground state electronic configuration of nitrogen is :
Possible Answer

74.

Question
In the Bohrs orbit, what is the ratio of total kinetic energy and total energy of electron :
Possible Answer
+2
1
1
2

75.

Question
Rutherford -particle dispersion experiment concludes :
Possible Answer
All positive ions are deposited at small part
Protons moves around the electrons
All negative ions are deposited at small part
Neutrons are charged particles

76.

Question
Which of the following element outermost orbits last electron has magnetic quantum
number m = 0 ?

21

BITSAT SAMPLE PAPER

Possible Answer
Na
O
N
Cl
77.

Question
The value of Plancks constant is
Js. The velocity of light is
.
Which value is closest to the wavelength in nanometers of a quantum of light with
frequency of
?
Possible Answer

78.

Question
The orbital angular momentum for an electron revolving in an orbit is given by
for an s-electron will be given by :
Possible Answer

Zero
79.

Question
The number of d-electrons retained in

(At. no. of Fe = 26) ion is :

Possible Answer
5
4
6

22

BITSAT SAMPLE PAPER

3
80.

Question
The de Broglie wavelength of a tennis ball of mass 60 g moving with a velocity of 10
metres per second is approximately :
Possible Answer

81.

Question
In Bohr series of lines of hydrogen spectrum, the third line from the red end corresponds
to which one of the following inter-orbit jumps of the electron for Bohr orbits in an atom
of hydrogen ?
Possible Answer
25
41
52
32

82.

Question
Which of the following sets of quantum number is correct for an electron in 4f orbital ?
Possible Answer

83.

Question

23

BITSAT SAMPLE PAPER

consider the ground state of Cr atom

. The numbers of electrons with the
azimuthal quantum numbers,
and are, respectively :
Possible Answer
12 and 4
12 and 5
16 and 5
16 and 4
84.

Question
The wavelength of the radiation emitted, when in a hydrogen atom electron falls from
infinity to stationary state 1, would be (
):
Possible Answer

85.

Question
Which one of the following sets of ions represents the collection of isoelectronic species?
Possible Answer

86.

Question
Consider the following nuclear relations :

The number of neutrons in the element L is :

24

BITSAT SAMPLE PAPER

Possible Answer
144
140
142
146
87.

Question
Which of the following have same radius as hydrogen n = 1 :
Possible Answer

88.

Question
In a multi-electron atom, which of the following orbitals described by the three quantum
members will have the same energy in the absence of magnetic and electric fields ?

Possible Answer

89.

Question
Of the following sets which one does contain isoelectronic species ?
Possible Answer

25

BITSAT SAMPLE PAPER

90.

Question
Which of the following statements in relation to the hydrogen atom is correct ?
Possible Answer
3s orbitals is lower in energy than 3p orbital
3p orbital is lower in energy than 3d orbital
3s, 3p and 3d orbitals all have the same energy
3s and 3p orbitals are of lower energy than 3d orbitals

91.

Question
Which of the following factors may be regarded as the main cause of lanthanide
contraction ?
Possible Answer
Poorer shielding of 5d electron by 4f electrons
Greater shielding of 5d electron by 4f electrons
Effective shielding of one of 4f electrons by another in the subshell
Poor shielding of one of 4f electron by another in the subshell

92.

Question
Which of the following molecules/ions does not contain unpaired electrons ?
Possible Answer

26

BITSAT SAMPLE PAPER

93.

Question
Uncertainty in the position of an electron
velocity 300
, accurate upto 0.001%, will be

moving with a

Possible Answer

94.

Question
Which one of the following sets of ions represents a collection of isoelectronic species ?
Possible Answer

95.

Question
Lanthanoid contraction is caused due to
Possible Answer
the same effective nuclear charge from Ce to Lu
the appreciable shielding on outer electrons by 5d electrons from the nuclear charge
the appreciable shielding on outer electrons by 4f electrons from the nuclear charge
the imperfect shielding on outer electrons by 4f electrons from the nuclear charge

96.

Question
Atomic radius is of the order of
cm and nuclear radius is of the order of
Calculate what fraction of atom is occupied by nucleus ?
Possible Answer

27

cm.

BITSAT SAMPLE PAPER

97.

Question
The atomic masses of two isotopes of O are 15.9936 and 17.0036. Calculate in No. of
neutrons atom
Possible Answer
8 and 9
16 and 17
8 and 8
None of these

98.

Question
The mass charge ratio for

ion is

kg

. Calculate the mass of A atom.

Possible Answer

99.

Question
service on Vividh Bharati is transmitted on 219 m band. What is its transmission
frequency in Hertz ?
Possible Answer

28

BITSAT SAMPLE PAPER

100. Question
Calculate the number of proton emitted in 10 hours by a 60 W sodium lamp (

or photon

)
Possible Answer

101. Question
Calculate momentum of radiations of wavelength 0.33 nm.
Possible Answer

102. Question
The ionization energy of
stationary state of
will be :

. The energy of the first

Possible Answer

103. Question
Which of the following set of quantum numbers are permitted
Possible Answer

29

BITSAT SAMPLE PAPER

104. Question
Find out the energy of H atom in first excitation state.The value of permittivity factor

Possible Answer

105. Question
The shortest wave length in H spectrum of Lymen series when

is

Possible Answer

106. Question
Electromagnetic radiations of wavelength 242 nm is just sufficient to ionise sodium atom.
Calculate the ionisation energy of sodium in
Possible Answer

30

BITSAT SAMPLE PAPER

107. Question
On the basis of Heisenbergs uncertainty principle, show that the electron cannot exist
within the nucleus.
Possible Answer

108. Question
Naturally occurring boron consists of two isotopes whose atomic weights are 10.01 and
11.01. The atomic weight of natural boron is 10.81. Calculate the percentage of each
isotope in natural boron
Possible Answer
40 & 85
20 & 60
30 & 50
20 & 80
109. Question
The shape of an orbital is given by the quantum number :
Possible Answer

31

BITSAT SAMPLE PAPER

110. Question
Write down the numerical value of h and its unit
Possible Answer

111. Question
Calculate the longest wavelength which can remove the electron from I Bohrs orbit.
Given
Possible Answer

112. Question
The ionization energy of H-atom is 13.6 eV. The ionization energy of
Possible Answer

32

ion will be

BITSAT SAMPLE PAPER

113. Question
How many electrons in a given atom can have the following quantum numbers

Possible Answer
6
4
1
2
114. Question
According to Bohrs theory, the angular momentum of an electron in 5th orbit is
Possible Answer

33