Overview
Part I
Part III
History
Worldwide production today
Applications
Basic definitions
Magnet types
Fabrication technologies
Measurement of macroscopic properties
Part II
Metallurgic aspects of permanent magnets
Magnetic domains
Observation techniques of magnetic domains
New materials
Aging / damage of magnets
Simulation methods
PPM quadrupoles
Johannes Bahrdt, HZB fr Materialien und Energie, CERN Accelerator School Magnets, June 16th-25th, Bruges, Belgium, 2009
Permanent Magnets
Including Wigglers and Undulators
Part I
Johannes Bahrdt
June 20th-22nd, 2009
Overview
Part I
History
Worldwide production today
Applications
Basic definitions
Magnet types
Fabrication technologies
Measurement of macroscopic properties
Johannes Bahrdt, HZB fr Materialien und Energie, CERN Accelerator School Magnets, June 16th-25th, Bruges, Belgium, 2009
Scaling of an electromagnet:
The current density has to be inctreased linearly
with the scaling parameter to maintain the
magnetic field
technical limits for small structures
appr. 500A / cm2 (water cooled)
Permanent Magnets
The development of magnetic materials was / is driven by the demand for:
- high remanence
- stability with respect to reverse fields, temperature
- cost effective fabrication procedure
- availibility of material
Ferromagnetic materials:
- Fe, Co, Ni: Curie temperature several 100C
- a few Lanthanides: Eu, Gd, Tb, Dy,Ho, Er, Tm
Curie temperature below room temperature
- many alloys
Johannes Bahrdt, HZB fr Materialien und Energie, CERN Accelerator School Magnets, June 16th-25th, Bruges, Belgium, 2009
History I
600 b.C.: Thales von Milet believed that magnets have a soul since they attract iron
Stones of magnetite Fe II ( Fe III ) 2 O4 were found in the area Magnesia, Greece
200 b.C.: Si Nan (pointing South):
first chinese compass??
1200: Europe: first compass with a Fe-needle magnetized by a lodestone
swimming on a wooden pice in a bowl of water
independent European invention or copy of Chinese compass?
1600: description of Gilbert how to magnetize iron:
- forging or drawing of iron in North - South direction
- cooling down a red hot iron bar in the earth magnetic field
1750: fabrication of ferrites by Knight (first sintering process)
1819: Oersted discovers the magnetic field of a current carrying wire
1825: invention of electromagnet by Sturgeon: easy way to magnetize steel
1867: handbooks recording magnetic alloys made from non magnetic components
and non magnetic alloys made from magnetic components
Johannes Bahrdt, HZB fr Materialien und Energie, CERN Accelerator School Magnets, June 16th-25th, Bruges, Belgium, 2009
History II
Johannes Bahrdt, HZB fr Materialien und Energie, CERN Accelerator School Magnets, June 16th-25th, Bruges, Belgium, 2009
production [to]
10 4
10
10
bonded
NdFeB:
0.7%
sintered
SmCo: 0.2%
Alnico: 1,4%
bonded
hard ferrites:
5.3%
1990
1995
2000
-1
1985
sintered
hard ferrites:
89.1%
VAC
10
10
sintered NdFeB:
3.3%
production of sintered
NdFeB magets
2005
year
300
250
100%
price of sintered
NdFeB magnets
200
80%
150
60%
100
40%
50
20%
0
1980
0%
1985
1990
1995
2000
Miscellaneous
Communications
Acoustics
Motors
MRI
VCM
2005
2010
year
2000
2001
2002
2003
year
Johannes Bahrdt, HZB fr Materialien und Energie, CERN Accelerator School Magnets, June 16th-25th, Bruges, Belgium, 2009
MRI
1800
Loud speaker
11280
VCM
1300
Separator
3610
CD-pickup
2515
magnetizer
900
DVD / CD-ROM
4060
Mobile phone
3160
Coreless tool
3160
5860
Y. Luo, REPM, Krete, Greece, 2008
Johannes Bahrdt, HZB fr Materialien und Energie, CERN Accelerator School Magnets, June 16th-25th, Bruges, Belgium, 2009
Faradays law
dynamo, generators
using wind / water energy
microphone
eddy current based speedometer
Johannes Bahrdt, HZB fr Materialien und Energie, CERN Accelerator School Magnets, June 16th-25th, Bruges, Belgium, 2009
magnetron for
sputter systems
MRI magnets
Johannes Bahrdt, HZB fr Materialien und Energie, CERN Accelerator School Magnets, June 16th-25th, Bruges, Belgium, 2009
Br
Hs
-Hcj
-Hc
H / kOe
or
0H / 0,1T
location of the knee of B:
- 2nd quadrant for ferrites
- 3rd quadrant for RE magnets
Johannes Bahrdt, HZB fr Materialien und Energie, CERN Accelerator School Magnets, June 16th-25th, Bruges, Belgium, 2009
B / kG
i
H / kOe
i initial permeability
d differential or maximum permeability
r reversal or recoil permeability
Johannes Bahrdt, HZB fr Materialien und Energie, CERN Accelerator School Magnets, June 16th-25th, Bruges, Belgium, 2009
Br
BHmax
BHmax
Johannes Bahrdt, HZB fr Materialien und Energie, CERN Accelerator School Magnets, June 16th-25th, Bruges, Belgium, 2009
C
A
lines of magnetizing
force: H
surfaces of equal
magnetic potential
permeance of volume
defined by ABC =
flux through B /
potential difference
between A and C
r r
B ds
P= r r
H dl
Johannes Bahrdt, HZB fr Materialien und Energie, CERN Accelerator School Magnets, June 16th-25th, Bruges, Belgium, 2009
r r
r
B = H + 4 M
r
r
H d = D M
r
r
4 v
Bd = H d
Hd
D
r
Bd
4
r = 1
D
Hd
M = magnetization
Hd = demagnetization field
D = demagnetization factor
Bd
Hd
load line
H
in reality: demagnetization factor and thus permeance varies over the volume
Johannes Bahrdt, HZB fr Materialien und Energie, CERN Accelerator School Magnets, June 16th-25th, Bruges, Belgium, 2009
permanent magnet in
closed and open circuit
yoke permeance
P = A/L
A = cross section
area of yoke
L = length of yoke
PL/A >> 1
open circuit with air gap
PL/A 1
PL/A << 1
Johannes Bahrdt, HZB fr Materialien und Energie, CERN Accelerator School Magnets, June 16th-25th, Bruges, Belgium, 2009
- 20
Z
- 30
-- 40
40
- 30
- 20
X
- 10
- 20
0
20
40
B, H, 4 pi M [10kG]
small
demagnetization
1.5
1.25 20mm x 40mm x 40mm
1
0.75
0.5
0.25
0
-0.25
-0.5
-0.75
-1
-60
-40
-20
0
20
x [mm]
B, H, 4 pi M [10kG]
- 40
1.5
1.25 80mm x 40mm x 40mm
1
0.75
0.5
0.25
0
-0.25
magnetic induction
-0.5
magnetic field
magnetization
-0.75
-1
-60
-40
-20
0
20
x [mm]
B, H, 4 pi M [10kG]
0
- 10
B, H, 4 pi M [10kG]
large
demagnetization
- 10
X
- 20
0
0
- 10
- 20
Z
- 30
- -405
- 2.50
Y 2.5 5
Johannes Bahrdt, HZB fr Materialien und Energie, CERN Accelerator School Magnets, June 16th-25th, Bruges, Belgium, 2009
- 30
- 40
Dx + D y + Dz = 4
analytic evaluation
is possible only in specific cases, e.g.:
generalized ellipsoid
rectangular prism
x
y
z
x
Johannes Bahrdt, HZB fr Materialien und Energie, CERN Accelerator School Magnets, June 16th-25th, Bruges, Belgium, 2009
4 cos( ) cos( )
sin 2 ( ) sin( ) cos( )
2
E (k , ) F (k , ) cos ( )
Dy =
sin 3 ( ) sin 2 ( ) cos 2 ( )
cos( )
Dz =
(
,
)
E
k
3
2
cos( ) = c / a
cos( ) = b / a
sin( ) = sin( ) / sin( ) = k
Special cases:
sphere: Dx=Dy=Dz=4/3
infinite long circular cylinder:
Dpar=0, Dperp=2
infinite wide plane:
Din-plane=0, Dperp-plane=4
prolate / oblate spheroid etc
+
+
2bc
2
2
sabc
a
ac
sabc
b
c
sab
a
2c sab b
3
3
3
c sbc b c sac a
ab a + b 2c
+
ln
+ ln
+ 2 arctan
+
2a sbc + b 2b sac + a
3abc
c sabc
Note:
c
sab 3 + sbc 3 + sac 3
a 2 + b 2 2c 2
+
sabc + (sac + sbc )
3abc
ab
3abc
sabc = a 2 + b 2 + c 2
sab = a 2 + b 2
sac = a 2 + c 2
sbc = b 2 + c 2
Special cases:
cube:
Dx = Dy = Dz = 4 / 3
These expresisons
are averaged values
over the prism.
Except for an ellipsoid
the D-factors vary
over the magnet volume.
D par = 0
1 p2
D perp / 4 =
ln(1 + p 2 ) + p ln( p) + 2 arctan(1 / p )
2p
p =c/a
Johannes Bahrdt, HZB fr Materialien und Energie, CERN Accelerator School Magnets, June 16th-25th, Bruges, Belgium, 2009
Magnet type II
Hcj > Br
e.g. hard ferrites, RE-magnet
1
low leakage flux
Br
Br
-Hcj
-Hc
-Hcj
-Hc
leakage flux
Johannes Bahrdt, HZB fr Materialien und Energie, CERN Accelerator School Magnets, June 16th-25th, Bruges, Belgium, 2009
Common Materials I
12
CoFe
35wt. % Co
B / kGauss
6wt. % Co
-200
H / Oersted
Johannes Bahrdt, HZB fr Materialien und Energie, CERN Accelerator School Magnets, June 16th-25th, Bruges, Belgium, 2009
Common Materials II
Alnico:
remanence
12,4 kG
11,2 kG
10,5 kG
7,6 kG
coercivity (Hc)
0,64 kOe
1,5 kOe
0,60 kOe
1,5 kOe
energy product
5,5 MGOe
11,5 MGOe
3,0 MGOe
4,5 MGOe
force
Johannes Bahrdt, HZB fr Materialien und Energie, CERN Accelerator School Magnets, June 16th-25th, Bruges, Belgium, 2009
Common Materials IV
Hard Ferrites: MO 6(F2O3) (or MFe12O19) with M = Ba, Sr or Pb, sintered
low Br, high Hcj, isotropic and anisotropic
Temperature coefficients: -0.2%(Br) +0.1 to 0.5%(Hc), TC 450C
grade
remanence
coercivity (Hc ) energy product
typical:
4,1 kG
2,9 (3,0) kOe
4,2 MGOe
value in bracket refers to Hcj
Hc and Hcj are very similar
knee is in the second quadrant
Johannes Bahrdt, HZB fr Materialien und Energie, CERN Accelerator School Magnets, June 16th-25th, Bruges, Belgium, 2009
Common Materials V
Sintered SmCo magnets (brittle)
High coercivity
SmCo5
Br=1.01 T (typical)
Hcj=12.5 kOe (minimum)
TK (Br) =-0,04
TK (Hcj)=-0,21
High remanence
Sm2Co17
Br=1.12 T (typical)
Hcj=8.0 kOe (minimum)
TK (Br) =-0,03
TK (Hcj)=-0,15
Common Materials VI
Sintered or melt spun NdFeB magnets
High remanence
Nd2Fe17B
Br=1.47 T (typical)
Hcj=11 kOe (minimum)
TK (Br) =-0,115
TK (Hcj)=-0,77
Curie Temperature
Material
Curie temperature
(C)
Iron
770
Cobalt
1130
Nickel
358
Nd2Fe14B
310
SmCo5, Sm2Co17
700-800
35% Co Steel
890
CrFeCo
630
Alnico
850
Hard ferrites
400
Courtesy of Vacuumschmelze
Johannes Bahrdt, HZB fr Materialien und Energie, CERN Accelerator School Magnets, June 16th-25th, Bruges, Belgium, 2009
Magnet Stability
Modification of magnetic properties:
1)
2)
Reversible demagnetization
- heating above Curie temperature
- applying high reverse fields H < Hcj
- exposure to radiation (local demagnetization)
3)
Irreversible demagnetization
- modification of crystal structure
- modification of specific phases of alloy
- oxidation
Aging of magnets for critical applications:
- heating well above final operation temperature for a few hours
- applying reverse fields higher than maximum expected reverse fields
Johannes Bahrdt, HZB fr Materialien und Energie, CERN Accelerator School Magnets, June 16th-25th, Bruges, Belgium, 2009
Johannes Bahrdt, HZB fr Materialien und Energie, CERN Accelerator School Magnets, June 16th-25th, Bruges, Belgium, 2009
Crushing
Milling
Aligning
P
H
Courtesy of Vacuumschmelze
Johannes Bahrdt, HZB fr Materialien und Energie, CERN Accelerator School Magnets, June 16th-25th, Bruges, Belgium, 2009
die-
Pressing pressing
P
T
Sintering /Annealing
t
Machining/
Surface-Treatment
Magnetizing
H
Courtesy of Vacuumschmelze
Johannes Bahrdt, HZB fr Materialien und Energie, CERN Accelerator School Magnets, June 16th-25th, Bruges, Belgium, 2009
Pressing Technologies
Die pressed magnets
transverse pressing
axial pressing
near net-shape
production is
cost effective
Properties:
Remanence:
isostatic > transverse > axial
2%
4%
Dipole errors:
isostatic > transverse, axial
Higher order multipoles:
transverse, axial > isostatic
Johannes Bahrdt, HZB fr Materialien und Energie, CERN Accelerator School Magnets, June 16th-25th, Bruges, Belgium, 2009
Sintering
15 - 20% shrinking
has to be regarded when
- designing the pressing die
- aiming for easy axis
orientatiopns not equal
0 or 90
after
before sintering
Courtesy of Vacuumschmelze
Johannes Bahrdt, HZB fr Materialien und Energie, CERN Accelerator School Magnets, June 16th-25th, Bruges, Belgium, 2009
300m ribbon:
microcrystalline
structure with
high anisotropy
water cooled
spinning wheel
Three types,
based on ribbon material:
Magnequench I:
matrix or bonded version
isotropic
Magnequench II:
hot pressed dense magnet
isotropic
Magnequench III:
hot deformation of
Magnequench II
anisotropic;
this material has the
highest energy product
Johannes Bahrdt, HZB fr Materialien und Energie, CERN Accelerator School Magnets, June 16th-25th, Bruges, Belgium, 2009
Johannes Bahrdt, HZB fr Materialien und Energie, CERN Accelerator School Magnets, June 16th-25th, Bruges, Belgium, 2009
(d / 2 x) 2 1.5 (d / 2 + x 2 ) 1.5
+ 1 +
1 +
2
2
a
a
d = distance of coils
a = radius of coils
quadratic terms disapperas if d = a
Helmholtz coil arrangement
measurement of dipole with high accuracy
insensitive on
- displacement of magnet block in the coil
- size of magnet block
APPLE II
reproducibilities
A-magnets
B-magnets
Mz
< 0.07 %
< 0.04 deg.
My
< 0.04 deg.
< 0.08 deg.
Mx
< 0.04 deg.
< 0.07 %
Data are important but not sufficient for prediction of field integrals
Johannes Bahrdt, HZB fr Materialien und Energie, CERN Accelerator School Magnets, June 16th-25th, Bruges, Belgium, 2009
Mz
My
Mx
AN
122.73
0.25
-0.36
0.17
0.26
0.17
AS
-122.75
0.27
0.30
0.22
-0.33
0.23
BN
-0.44
0.13
-0.88
0.36
-118.66
0.4
BS
0.53
0.14
0.63
0.26
118.78
0.39
My
Mx
Johannes Bahrdt, HZB fr Materialien und Energie, CERN Accelerator School Magnets, June 16th-25th, Bruges, Belgium, 2009
angle of magnetization [ ]
3,0
2,5
2,0
1,5
1,0
0,5
0,0
0
-0,5
10
15
20
25
30
35
40
-1,0
slices measured
in Helmholtz coil
-1,5
-2,0
-2,5
Courtesy of Vacuumschmelze
-3,0
example of an
inhomogenious
magnet block
BN BS
2( BN + BS )
10
5
0
0
-5
N/S-effect [ % ]
-10
10
15
20
25
30
45
50
-25
N/S 10%
-30
N/S 25%
-35
40
-15
-20
35
N/S 50%
N/S 100%
-40
-45
N/S25%extrapol.
100% = 80mm distance to surface
-50
Courtesy of Vacuumschmelze
Johannes Bahrdt, HZB fr Materialien und Energie, CERN Accelerator School Magnets, June 16th-25th, Bruges, Belgium, 2009
By dx / Tmm
B-magnets:
type B magnet
type A magnet
By dx / Tmm
reproducibility:
A-magnets:
x 100
A-magnet
-50
50
8
6
4
2
0
-2
-4
-6
-8
x 1000
B-magnet
Temperature dominated
-50
z / mm
Johannes Bahrdt, HZB fr Materialien und Energie, CERN Accelerator School Magnets, June 16th-25th, Bruges, Belgium, 2009
50
z / mm
0.02
0.015
0.01
Bry-SW [T-mm]
AN
AS
0.005
1.44
1.435
0.04
0.02
BN
-0.02
1.43
-0.04
1.425
-0.005
-40
Magnet AN 53
-0.01
1.42
-0.015
-0.02
-0.02
gap = 12mm
BS
-0.01
0.01
0.02
Bry-HHS [T-mm]
1.415
1.32
1.33
1.34
Bry-HHS [T-mm]
Bry-SW [T-mm]
0.01
-20
20
40
60
20
40
60
20
40
gap = 39mm
0
-0.01
-40
0.005
-20
gap = 79mm
0
-0.005
-40
-20
60
z [mm]
Johannes Bahrdt, HZB fr Materialien und Energie, CERN Accelerator School Magnets, June 16th-25th, Bruges, Belgium, 2009
0.03
inhomogeneity [T-mm]
inhomogeneity [T-mm]
AN side 1
AN side 2
0.02
AS side 1
0.01
AS side 2
0
-0.01
0.1
0.08
BN side 1
0.06
BN side 2
0.04
BS side 1
0.02
BS side 2
0
-0.02
-0.04
Magnet AN 53
-0.02
-0.06
-0.08
-0.03
0.03
0.02
-20
-10
10
20
-0.1
30
z [mm]
AN ffy*bryy
AS ffz*brzz
AN ffz*brzy
AS ffy*bryz
0.01
0
-0.01
-30
BN (ffy-ffymean)*bryy
0.02
BN (ffz-ffzmean)*brzy
10
20
30
z [mm]
10
20
30
z [mm]
Statistics of
1200 magnets:
averaged field
integrals and
two sigma values
-0.03
0
-0.01
-0.02
-10
-10
0.01
-0.03
-20
-20
0.03
-0.02
-30
-30
BS (ffy-ffymean)*brzz
BS (ffz-ffzmean)*bryz
-30
-20
-10
10
20
30
z [mm]
Johannes Bahrdt, HZB fr Materialien und Energie, CERN Accelerator School Magnets, June 16th-25th, Bruges, Belgium, 2009
powder 2
powder 3
powder B
powder C
powder 4
starting powder
in large container
distribution of
starting powder to
smaller containers
mixing of final
powder from
content of smaller
containers
powder A
powder D
Johannes Bahrdt, HZB fr Materialien und Energie, CERN Accelerator School Magnets, June 16th-25th, Bruges, Belgium, 2009