org
doi:10.14355/mwe.2016.05.002
MineralIndustryinEgyptPartII
NonMetallicCommoditiesSilicaOres
EzzElDin,M.1;Abouzeid,A.M.2;Elmaadawy,Kh.3;Khalid,A.M.4;andElSherif.,R.E.5
1EgyptianMineralResourceAuthorityEMRA
2CairoUniversity,FacultyofEngineering,Dept.ofMining.
3MinofiyaUniversity,FacultyofSciences,Drpt.OfGeology.
4ExEgyptianMineralResourceAuthorityEMRA
5Geologistfreehand
Abstract
Silicon, nowadays, is involved in many advanced and high technology industries due to its unique property. The silica ores
existintheformofquartz,quartzite,andwhitesand.InEgypt,quartzisconfinedtoigneousandmetamorphicorigins,while
white sand exists in the form of sedimentary deposits. Quartz and quartzite are found in association with basement rocks in
Eastern Desert and Western Desert. While white sand deposits are widely distributed in Sinai, Eastern Desert, and Western
Desert,withthemostcommercialdepositsinSinaiandEasternDesert.
Estimationofthegeologicalandeconomicreservesindicatehugetonnagesofalltypesofsilicaores.Quartzreservessumupto
20milliontons,andsilicasandssumuptomorethan3billiontons.Evaluationofthechemicalandphysicalcharacteristicsof
the silica in Egypt showed high quality silica with low contaminations. The major part of these reserves is available through
openpitminingwithverylowcostsduetominimaloverburden.Someofthesilicasanddepositscontainahighpercentageof
whitekaolin,uptoabout11percent,whichisseparatedasavaluableeconomicbyproduct.Thebasicprocessingoperationsof
thewhitesandarewashing,screening,attritionscrubbing,desliminganddewatering.Insomelocationsmagneticseparationis
usedfortheremovalofmagneticimpurities.Academicresearchworkshowedthatthequalityofthewhitesandproductcanbe
improvedwhenfrothflotationoperationisused.
Keywords
SilicaOresinEgypt,Quartz,Quartzite,GlassSands,ProcessingofWhiteSands
Introduction
Thesilicaoccurrencesencompassbasicallyquartz,quartziteandwhitesand.Silica,nowadays,isessentialinhigh
technologyindustriesduetoitsabilitytoactasmetallicand/ornonmetallicsubstance.Itsuniquepropertymakes
itoneofthemostusefulnaturalsubstances.Itiscomposedofsiliconandoxygen,thetwomostabundantelements
in the Earths crust, in the form of SiO2. It is composed of silica tetrahedral, and belongs to the rhombohedral
crystaltype,hexagonalsystem.Thesiliconelementrepresents28.1%oftheconstituentsoftheEarthscrust(Wills,
2006).Silicaoccursmostlyinacrystallineformandrarelyasanoncrystalline(amorphous)form.Initspureform,
itisacolorless,odorless,noncombustiblesolid.Crystallinesilicahasthreemaincrystallinevarieties:quartz(byfar
themostabundantspecies),tridymite,andcristobalite.Theworldannualproductionofsilicain2013ismorethan
140 billion tons of industrial silica sands (Dolley, 2013). Figure 1 presents the world production of silica in the
period20072013.Theworldproductionraterangedfrom118milliontonsin2009to142milliontonsin2013.
Silicaoresoccurintwoformsquartzandwhitesand.Theydiffermainlyintheoriginwherequartzispresentin
igneousrocksasaresidualofmagmaticactivitiesorhydrothermalsolutions,andmetamorphicrocks,whilewhite
sandisaweatheredproductofoldsedimentary,metamorphic,origneousorigin.
Duetothisoriginwhitesandcouldbecontaminatedwithclaymineralsindifferentratios.Asamatteroffact,the
strategicimportanceofsilicasandsattractedmanyscientistsaroundtheworldtoinvestigatetheoriginofthesilica
oredeposits,characterizethem,andworkforimprovingtheirgradeinpracticalandeconomicmanners(Abdallah
etal.,1992;Awadh,2010;Bandeletal.,1987;Blattetal.,1980;Carver,1971;ElBokletal.,1993;EzzElDin,2007;
Issawi et al., 1999; Khalid, 1993; Klitzsch et al., 1990; Madanat et al., 2006; Norton, 1957; Mustafa et al., 2011;
www.mwejournal.orgJournalofMiningWorldExpress(MWE)Volume5,2016
Ramadan,2014;Sundararajanetal.,2009;KrinsleyandBoornkamp,1973).Thenaturalsilicacycleandsandtexture
areshowninFigures2and3(BarrettandBeskeen,1986).Whitequartzsand,asdefinedbytheBritishGeological
Surveyissandusedforapplicationsotherthanconstructionaggregatesandwhicharevaluedfortheirphysical
andchemicalproperties(Platiasetal.,2014).
FIGURE1:WORLDPRODUCTIONOFSILICAINTHEPERIOD2009T2013(DOLLEY,2010,2011,2012,2013)
FIGURE2:NATURALCYCLEOFSILICAFIGURE3:CYCLEOFFORMATIONOF
(QUARTZANDSILICASAND)FORMATIONSROUNDEDSANDFROMMOTHERROCK.
(BARRETTANDBESKEEN,1986).(BARRETTANDBESKEEN,1986).
Silicasandisaweatheredderivativeofquartz,asseeninFigure3.Itoccursasloosesand(sanddunes)and/oras
consolidatedrock,asseeninFigures4and5.Sanddunesareformedbymovingwind,flowingwater,orglaciers.
Thegrainsizerangesandsizedistributionsofthesilicasandsdependonthemodeofformation.Thedesertsandis
verycloselysized,whereastheglacialsandisverycoarseandhasawidesizedistribution.Themodeofformation
affectsgreatlythesizedistributionofthesand.Figure6showsthedifferentdistributionsaccordingtotheprocessit
wasformedwith(BarrettandBeskeen,1986).
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UsesofQuartzandSilicaSand
Electronicgradequartzcrystalissinglecrystalsilicawithpropertiesthatmakeituniquelyusefulinaccuratefilters,
frequency controls, and timers used in electronic circuits. These devices are used for a variety of electronic
applications in aerospace hardware, commercial and military navigational instruments, communications
equipment, computers, and consumer goods. Such high technology uses generate practically all the demand for
electronicgradequartzcrystals.Alesseramountofopticalgradequartzcrystalisusedforlensesandwindowsin
specializeddevices.Naturalelectronicgradequartzcrystalhasbeenreplacedbyculturedquartzcrystalsince1971.
Theuseofnaturalcrystalforcarvingandothergemstoneapplicationsisstillgoingon(Dolley,2004).
Silicasandsareusedinmanycommercialprocessesandproducts,andtherefore,arecommonlyclassifiedonthe
bases of their industrial applications. This classification depends on the mineralogical, chemical, and physical
properties such as size, size distribution, surface area, melting point, and particle shape (Platias et al., 2014). In
general, the specificationsof the silica sand dependon the intended useand the purity level of thequartz sand.
Figure7showsthedistributionoftheusesofwhitesilicasandintheworldin2013(Zarad,2014).
FIGURE4:CONSOLIDATEDSILICASAND.
FIGURE5:WHITESILICASANDDUNES.
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FIGURE6:THEDIFFERENTMODESOFSANDFORMATION:A)DESERTSAND,B)BEACHSAND,C)LAKECLAY,D)GLACIAL
WASHOUT(BARRETTANDBESKEEN,1986).
Silicasandisusedmainlyformakingglass(opticalglassessuchascameras,opticalinstruments,microscopes,in
opticalfibers,andothertypesofglass).Forthispurpose,theBritishStandardBS2975includesrecommendedlimits
forthecompositionofquartzsandforsevendifferentgradesofglass,asseeninTable1.Industrialsilicasandsare
alsousedforabrasives,grouts,andextenders.Here,particlesizeandsurfaceareaofthequartzsandaretwoofthe
mostimportantattributes.Quartzsandisalsousedtomakemouldsandcoresformetalcastings.Thisuserequires
sandconsistingofuniformsizedroundedgrainsofquartz(Platiasetal.,2014;Moldenke,1930).Therearemany
other uses of silica sand such as electronics, renewable energy sources (solar energy), the manufacture of silicon
carbide,sodiumsilicate,Portlandcement,siliconalloyswithmetals,siliconmetal(chipsandwafers),filtermedia
in water treatment, hydraulic fracturing in oil reservoirs, sand blasting, rubber, paints, plastics, polymers, and a
host of other applications (Platias et al., 2014; Sundararajan et al., 2009). Table 2 summarizes the chemical
composition limits of the silica sand for various products as specified by the American Ceramics Society and
NationalBureauofStandardsfordifferentglassproducts(Norton,1957).Sincesizedistributionofglasssandsisan
essentialattributefortheglassrawmaterials,Table3providesthesizerangesofthesandasrecommendedbyboth
the American and British standards. Table 4 summarizes the required chemical compositions of quartz
recommendedforvariousindustries.
TABLE1:BS2975SPECSFORTHEGRADESOFSILICASANDFORTHEDIFFERENTTYPESOFGLASSPRODUCTS(BRITISHSTANDARDINSTITUTION,1988).
12
Composition
Grade
Product
SiO2%
Fe2O3%
Al2O3%
Cr2O3%
Opticalglass
99.7
0.013
o.2
0.00015
Tablewareglass
99.6
0.01
0.2
0.0002
Borosilicateglass
99.6
0.01
0.2
0.0002
Colorlesscontainerglass
98.8
0.03
0.1
0.0005
Flatglass
99.0
0.1
0.5
Coloredcontainerglass
97.0
0.25
0.1
Insulatingfibers
94.5
0.3
3.0
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TABLE.2:RECOMMENDEDSPECIFICATIONSPROPOSEDBYTHEAMERICANCERAMICSOCIETYANDNATIONALBUREAU
OFSTANDARDSFORCHEMICALCOMPOSITIONOFGLASSSANDUSEDFORTHEPRODUCTIONOFDIFFERENTGLASSPRODUCTS(NORTON,1957).
S/N
Product/glass
Min.SiO2%
Max.Al2O3%
Max.Fe2O3%
Max.CaO+MgO%
Qualityopticalglass
99.8
0.1
0.02
0.1
Qualityflintcontainers
&tableware
98.5
0.5
0.035
0.2
Qualityflintglass
95
0.035
0.5
98
0.5
0.06
0.5
95
0.06
0.5
98
0.5
0.3
0.5
3
4
5
6
Qualitysheet&plate
glass
Qualitysheet&plate
glass
Qualitygreencontainer
&windowglass
Qualitygreenglass
95
0.3
0.5
QualityAmberglass
container
98.5
0.5
1.0
0.5
QualityAmber
95
4.0
10
0.5
Pure white sands are used mainly in glass making, silicon chips and wafers, glass fibers, and other industries
(Arrifin, 2004). Figure 7 shows that the main uses of silica sands worldwide are distributed as follows: 62% for
makingglass,14%forsiliconchips,6%forglassfibers,and18%forotherpurposes(Zarad,2006).
TABLE3:GRADINGOFSILICASANDSFORGLASSMANUFACTUREASSPECIFIEDBYTHEAMERICANANDBRITISHSTANDARDS.
ParticleSize,microns
Weight,percent
+1000
0.0
1000+600
2to6
600+420
10to15
420+150
80Minimum
150+125
10Maximum
125
5Maximum
TABLE4:RANGEOFTHECHEMICALCOMPOSITIONSOFQUARTZREQUIREDFORDIFFERENTINDUSTRIES.
Industry
SiO2,%
Al2O3,%
Fe,%
CaO,%
Na2O,%
Militaryproduction
9396
0.251.5
Electricpoles
9699.5
0.5
Ceramics
97.799.5
0.02
0.010.19
0.010.05
Ferrosilicon
9899
0.20.26
0.02
0.2
Chemicals
96
0.4
Siliconcarbide
99.599.75
0.04
0.01
0.01
Opticalandcrystals
99.799.8
0.01
0.014
0.02
Silicaglass(sodiumsilicate)
99
0.075
0.92
Spaceindustries
99.9
0.02
0.01
0.01
Foundry
72.591.11
0.081.0
6.224.7
Rubber
98
0.1
Bricks
9599
0.12.8
0.31.3
0.22.4
0.21.5
Tomeettherequiredspecificationsforaspecificproduct,thesandoftenhastobesubjectedtoextensivephysical
and chemical processing. This involves crushing, screening and further adjusting the grainsize distribution,
togetherwithremovingthecontaminatedimpuritiesinthesandbulkandfromthesurfaceoftheindividualsand
grains.Presenceofmetallicoxidesintheglassmakingsandsusuallyproducescoloredglass.Ifironispresent,the
resultingglassiscoloredgreenorbrown.Theironlevelisconsequentlythemostcriticalparameterindetermining
whetherparticularsandcanbeusedtomakeclearglass.Sandsusedtomanufacturecolorlessglassaretherefore
likelytobeprocessedfurtherbycertainmethodssuchasgravityseparation,magneticseparation,acidleaching,or
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even froth flotation. Figure 8 presents the general layout for extracting and processing of white sand for the
differentindustrialuses(BGS,2009).
FIGURE7:DISTRIBUTIONOFTHEWORLDUSESOFWHITESILICASANDS(ZARAD,2014)
FIGURE8:GENERALLAYOUTOFQUARTZSANDPROCESSING(BGS,2009)
ModeofQuartzOccurrences
Quartz occurs in nature in many forms, but the commercial quantities generally crops out in the following
forms:
1Quartzcapsofplutonsareformedasaresultofmagmaticdifferentiationandaftergraniticplutoncooledand
solidified.Someremainingmagmagetsmoreconcentrationinwaterandsilicawhichaccumulateattheroofof
graniticbodiesorassociatewithpegmatites.Thesequartzcapsdifferinsizeandpurityfromoneplacetothe
other.Themainganguemineralsaremicaandrarelyfeldspars,asseeninFigure9(EzzElDin,2007).
2Quartzveins:thequartwhichwasformedascapsleavesresidualsolutionsthatpenetratedthroughthecracks
andalongfissurestoformveins,andsometimesformlensoidalbodieswithdifferentdimensions.Figures1013
showsomequartsbodiesintheEasternDesert.
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FIGURE9:MARWASEWEQATQUARTZ(EZZELDIN,2007)
FIGURE10SHOWSQUARTZOVERGRANITOIDROCKS;(A)APHOTOGRAPHSHOWINGTRACHYTICDYKECUTTINGTHROUGH
THEBASICDYKE,WHICHCUTSBOTHQUARTZANDFOLIATEDTONALITEATWADIFANAT,AND(B)APHOTOGRAPH
SHOWINGABASICDYKECUTTINGAFOLIATEDTONALITEATWADIFANATBOTHPHOTOSAANDBARETAKENLOOKING
WEST(EZZELDIN,2007).
FIGURE11:WADIMUBARKQUARTZ(EZZELDIN,2007)
FIGURE12:QUARTZPLUGOFWADIUMMJURUF(LOOKINGNORTH)(EZZELDIN,2007).
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FIGURE13:ABUFANANIQUARTZ(EZZELDIN,2007)
3Quartziteispresentinbothsedimentaryandmetamorphicrocks.Itisoriginatedfromthemetamorphismof
sandstoneand,generally,formsheetsandlenses.QuartziteinAluwaynatareaSouthWestofEgyptformlarge
extendedsheetsoccasionallyassociatedwithmicaandfeldspars(Naimet1998;Khalidetal.2002;Khattabetal
2002).Table5andFigure14showthelocationsofthemostimportantquartzdepositsinEgypt.
The annual production and export quantities of quartz are shown in Figure 15. The production is relatively
more than the exported amount, because the difference is used locally. The production of the quartz has
significantlydecreasedintheyear2012/2013asaresultoftemporallylocalreasons.
TABLE5:LOCATIONSANDGEOLOGICALRESERVESOFQUARTZINEGYPT
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Composition
Location
Reserves,103tons
SiO2,%
Fe2O3,%
Al2O3,%
AbuFanani
100
96.4
0.17
0.27
UmGhanam
40
ND
ND
ND
RodAshab
ND
ND
ND
ND
Hamri
15
98.52
0.19
0.2
UmRashed
40
ND
ND
ND
GabalElTaweela
20
ND
ND
ND
SweigetElBeda
500
97.93
0.33
0.25
WadiEssel
ND
ND
ND
ND
WadiAbuShabah,Qussierarea
130
99.28
0.04
0.15
UmEshElHamra,Fawakheir
4,340
99.01
0.24
0.04
WadiKarim,BirKarim
7,456
98.28
0).29
0.17
HamraDome
1,354
99.34
0.12
0.02
WadiAtalla
269
ND
ND
ND
GabalShayiab
250
99.6
0.19
0.02
WadiFanat
800
99.45
0.14
0.02
WadiWarbeit1
405
99.22
0.27
0.03
WadiWarbeit2
81
99.44
0.28
0.02
WadiBoyia
697
99.09
ND
0.06
SouthSorukA
211
98.74
ND
0.06
SouthSorukB
26
98.98
ND
0.06
MansourDiabA
1,325
ND
NDD
ND
MarwatKlimkanW.ElBeida
10,000
ND
ND
ND
W.AnterRoadAbid
400
ND
ND
ND
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W.KhedahG.UmAthli
450
ND
ND
ND
G.Sorasr
35
ND
ND
ND
W.Kharit
1,300
ND
ND
ND
G.ElNikhairah
50
ND
ND
ND
G.HumrAlKarim
130
ND
ND
ND
W.ElGararah
2,300
ND
ND
ND
G.ElKahfa
940
ND
ND
ND
FIGURE14:MAPOFEGYPTSHOWINGTHEQUARTZOCCURRENCESINTHEEASTERNDESERT,ASSOCIATEDWITHTHERED
SEAGEOLOGICALSTRUCTURE.
FIGURE15:PRODUCTIONANDEXPORTOFQUARTZINEGYPTINTHEPERIOD2010/2013(ZARAD,2014)
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WhiteSand(GlassSand)
Silica sands are the most widely used among all the nonmetallic commodities for their physical and chemical
characteristics such as color, hardness, heat resistance, high melting point (1760C) as well as their low price.
Geologically,whitesandsinmanyplacesaroundtheworldareformedinthePaleozoicFormation.
TheimportantlocationsofwhitesandsinEgyptarewidelydistributedinSinai,NorthernpartofEasternDesert,
andintheWesternDesert.Forthelastfewdecades,theEgyptianglassandcrystalfactorieshavebeenusingthe
white sand for their firstclass international products. The demand for this high purity sand is continually
increasing (Kamel et al.,1997). The high qualityand the potential value of theEgyptian white sands(silicasand
deposits) attracted the attention of many researchers (Khalid, 1993; ElBokle and Hasanein, 1993; ElFawal, 1994;
Fathi, 2002; Bayat et al., 2007; Mustafa et al., 2011; and Ramadan, 2014; Weissbrod, 2004). About 16 localities
containinghighgradesilicasandshavebeenidentifiedinEgypt.ThemostimportantoftheseareWadiQenaand
Wadi ElDakhl (ElZaafarana) located in the Northern part of the Eastern Desert and El Maadi, and Gebel El
GunnahinSinai,asseeninFigure16(ElWekeilandGaafar,2014).Thereservesatthementionedareasexceed3
billionsoftonsofthehighqualitysilicasand,whichfulfillthespecificationsoftheglassindustry,paints,foundry,
chemicals,andceramicsrawmaterials.
FIGURE16:LOCATIONMAPOFGLASSSANDSINTHEMAINOCCURRENCESOFEGYPT(ELWEKEILANDGAAFAR,2014).
2)
Geology
1EasternDesert:
The largest deposit of white sand in the Eastern Desert lies at Wadi Qena. The white sand in Wadi Qena
constitutesmostofthelowerPaleozoicNaqusFormation(450km2)NorthEastofQena.TheNorthernpartof
Wadi Qena consists of the exposed lower Paleozoic rock units which are represented by Araba and Naqus
Formation (Wanas 2011). The Naqus Formation rests unconformably on the peneplained Precambrian
crystalline rocks of ArabaNubian shield and form scattered outcrops in a series of hills and mesas. The
thicknessoftheNaqusFormationrangesfrom22mto120m(AbouElAnwarandElWekeil,2013).
Two stratigraphic sections have been investigated in the study area by Abou ElAnwar and ElWekeil, 2013.
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These sections compriseamajor part of the Naqus Formation(Figure17). The first section(A) isabout106 m
thick and the second section (B) measures around 120 m. The Naqus sandstones have a similar lithological
characteristic in both sections. They are commonly, white, finetomedium grained, moderatetowellsorted,
subangulartosubrounded,consolidatedtolooselyconsolidatedmaterials,andoccasionallycontaincoarsesand
and granules. The sandstones are characterized by the presence of different primary sedimentary structures
such as planar and trough crossbedding and flat bedding. Kaolinitic lenses are randomly distributed
throughoutthewholesequenceespeciallyattheupperpartofthesediment.TheupperboundaryoftheNaqus
sandstones is absent in section (A), while section (B) is unconformably overlain by the shallow marine
sedimentsoftheCenomanianGalalaFormation.Thelaterformationismadeupofabout15mthickgreenish
yellowshaleandsandymarlintercalatedwithclaystone.
FIGURE17:LITHOSTRATIGRAPHICCOLUMNARSECTIONSOFTHEMEASUREDNAQUSSANDSTONESEQUENCESMODIFIED
AFTER(ABOUELANWARANDELWEKEIL,2013).
2Sinai
The white sand deposits in Sinai belong to the Naqus Formation of Early Paleozoic age. The Early Paleozoic
sectioninAbuDurbainSinaiwasclassified,frombasetotop,asArabaFormationandNaqusFormation(Early
Paleozoic age), unconformably overlain by Malha Formation of Lower Cretaceous (Hassan,1967; Said,1971;
Omara, 1972; Issawi and Jux, 1982). The term Naqus Formation was introduced by Hassan (1967) and was
adoptedbySaid(1971)describingathicksiliciclasticsequence.ItunconformablyoverliestheArabaFormation
andisoverlainedunconformablybytheMalhaFormation.
NaqusFormationattheSaintKatherineNewbieconsistsmainlyofathicksandstonesequencemeasuringabout
200m thick (Figure 18). Generally, the lower 30 m are white massive sandstone beds with minor ferruginous
clayeyandkaoliniticinterbeds.Therestofthesequenceisformedofcrossbeddedandvaricoloredsandstone
ranging in color from white to pale brownish and contains abundant quartz pebbles (Figure 18). It is almost
devoid of organic remnants. Termites (Awadh, 2010) could borrow and penetrate the sand glass giving the
appearancewhichiscalledMashrabiaorFenestrastructure(AbdelRahman,2002)asshowninFigure19.Fathi
2002studiedthephysicalandchemicalcharacteristicsofsilicasanddepositsofWadiWatirSinaiandcameto
theconclusionthatitissuitableforartanddomesticglassmanufacturewithsimplescreeningfortheremoval
ofcoarseandfinefractions.
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FIGURE18:COMPOSITELITHOSTRATIGRAPHICCOLUMNARSECTIONOFNAQUSFORMATIONINSAINTKATHERINENEWBIE
AREA(ABDELRAHMAN,2002).
FIGURE19:NAQUSFORMATIONATSAINTKATHERINENEWBIEAREASHOWINGMASHRABIA(FENESTRA)STRUCTURE.
ARROWSPOINTTOTHEREMNANTSOFTERMITETRENCHES(RAMADAN2014).
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TABLE6:LOCATIONSANDSPECIFICATIONSOFTHEMOSTIMPORTANTWHITESANDDEPOSITSINEGYPT.
Location
Reserves,
Mton
WadiElNatron
1.7
NewValley1
SiO2,%
Fe2O3,%
Al2O3,%
CaO+MgO,%
92.495.4
0.30.54
1.242.6
1.42.1
ND
93.996.0
0.281.02
0.012.01
0.61.2
NewValley2
ND
93.996.1
0.301.3
0.012.1
0.81.2
NorthFayoum
Unlimited
90.598.0
0.252.24
0.032.24
0.71
WesternDesert
EasternDesert0.86
WadiQena
258
94.8
0.33
4.0
WadiElDakhl
10
98.599.6
0.010.02
0.0360.19
0.030.2
EastEdfu
Unlimited
ND
ND
ND
ND
EastMaadi
Medium
95.097.0
0.270.42
0.61.44
0.120.2
0.030.07
0.231.43
0.221.07
Sinai
AbuElDarag
4.1
97.298.6
GabalElMenshereh
98.1
0.080.093
0.0260.32
0.060.28
WadiFilly
1.3
91.499.6
0.0270.26
0.0160.37
0.11.23
AbuZneima
1.25
97.599.7
0.011.34
0.211.35
0.0040.2
ElGunna
2,500
90.396.5
0.0260.08
1.856.0
0.010.35
WadiWatir
ND
ND
ND
ND
ND
KathrineNewbieRoad
ND
ND
ND
ND
ND
Ramadan (2014) studied the Physicochemical properties of the white sandstone deposits along the Nuweiba
Saint Katherine road,in Southern Sinai region for probableutilizationin industrialapplications suchassolar
cells,sheetglass,andoilproductionprocesses.Inhisstudy,Ramadanfoundthatthephysicalcharacteristicsof
thesesandsarefinetomediuminsize,wellsorted,andabout90%ofthegrainsfallintherangeof1.0mmto
0.125 mm. Mineralogically, the sandstones are quartz arenite (more than 85%). Chemically, the ranges of
compositionsare:from0.551.67%,Al2O3,from0.411.66%Fe2O3,andfrom91.1795.99%SiO2.Theauthorcame
totheconclusionthatthewhitesanddepositsofNuweibaSaintKatherineregionshowsthattheyareofwell
sortedgrainsizes,considerablepurity,withqualityrangescompatiblewithgrades(E,FandG)ontheBritish
Standard(Table1),andSerialNumbers(S/N)7to9accordingtoU.Sspecifications(Table2).
Theproductionandexportedglasssandsintheperiod2010to2013areshowninFigure20.Itisclearthatmost
of the produced white sand was exported in the year 2010/2011, whereas in the period 2011/2013, both the
produced and exported glass sands were significantly lower than before. This trend is probably due to local
reasons.
FIGURE20:THERATEOFPRODUCTIONANDEXPORTOFTHEWHITESANDSINEGYPTINTHEPERIOD2010TO2013(ZARAD,
2014).
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For economic reasons, more than 80% of the exported white sand is sold to Mediterranean and Middle East
countries.Thisismainlyduetotheeasytransportationbyseaatlowcost.Thisisunderstandablebecausethe
priceofthesandisrelativelylow.Figure21showsthemainimportingcountriesforthewhitesandfromEgypt,
and the percentages imported by each country. The countries importing the Egyptian white sand in the year
2012/2013,arrangedinadescendingorder,areTurkey(32%),Lebanon(22.8%),Italy(9.3%),UAE(8.9%),and
Greece(6.7%).
FIGURE21:THEMAINCOUNTRIESIMPORTEDTHEEGYPTIANWHITESANDSINTHEYEAR2012/2014(ZARAD,2014).
To meet the tight specifications of silica sands, the sand often has to be subjected to extensive physical and
chemical processing. This involves crushing, screening and further adjusting the grainsize distribution,
togetherwithremovingthecontaminatingimpuritiesinthebulkandfromthesurfaceoftheindividualquartz
grains. Sands used for manufacturing colorless glass are therefore likely to be processed further by certain
methodssuchasacidleaching,magneticseparation,frothflotation,and/orgravityseparation.
3)
Mining
Mining methods of industrial sands depend on the type of sand deposit. Unconsolidated deposits are mined
using frontend loaders, scrapers, or bulldozers. Material is dug, excavated, and then loaded onto trucks to
stockpiles or to the processing plant. Other unconsolidated deposits are mined with dredges or draglines. A
hydraulic dredge uses a suction pipe to excavate the sand, which is pumped to surge piles or directly to the
plant.Looselyconsolidatedmaterialcanbeminedusingahighpressurehydraulicmonitor.Sandwashedfrom
theworkingfaceiscollectedinasump,andthenpumpedtoadewatering/surgepile,andsenttotheplant.In
the case of wellconsolidated deposits, conventional drillandblast methods are used, where the sandstone is
mucked, haul, and transported to the crushing section of the processing plant. Due to the low price of the
sand,undergroundminingmayonlybeusedforextractingcompetent,welllithifiedsandstoneorquartziteby
usingconventionaldrillandblastmethods,thematerialisthenhauledorconveyedtotheprocessingplantor
surgepiles(Kogeletal.,2006).
In Egypt, surface mining is usually used for mining of silica sands as a result of the presence of little or no
overburden,about115m,inalmostallthewhitesanddeposits.TheoreisdrilledandblastedusingAnfoand
gelatin in the ratio of 3:1. The boreholes are drilled using pits of 3 inch diameter to a depth of 1012 meters,
filled with explosive mixture, stamped. About 100 bore holes are designed in a specific pattern, tied together
withcraftin,anddetonatedwithadetonatingcapsule.Thebrokenrockistransportedtoasizereductionand
screeningsection,tobepreparedforwashingandprocessing(Zarad,2014).
4)
Processing
Thetypeofprocessingorbeneficiationofsilicasandisdirectlyrelatedtotherelativenatureofthesanddeposit
and the purity of the required product. Regardless of markets, sands are, at a minimum, washed, dried, and
screened.Atypicalprocessingcircuitwouldincludewashingtoremoveclaysandotherdeleteriousmaterial.
Someprocessesmayrequirethatthematerialreporttoarodoraballmillforwetgrinding.Theslurryfromthe
washandmillcircuitispumpedtoadeslimingcircuitinwhichhydrocyclonesremovetheslimes.Thewashed
sandisthensubjectedtoacoarseseparationcutbyhydrosizingorwetscreening.Thesandisfurtherdewatered
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byreportingtosurgepilesorcyclones.Oncethesandcontainsapproximately70%solids,itreportstoattrition
scrubbingintanksequippedwithpropellertypeblades.Insomecases,thewaterisacidifiedwithaninorganic
acid.Attritionscrubbingremovesclays,ironoxides,andothermaterialsthatmaybeonthesurfaceofthesand
grains.Inaddition,attritionscrubbingcreatesafreshsurfaceonthequartzandnonquartzmineralstoenhance
reagentattachment,ifflotationistobeused.Flotation,cationicoranionic,isusedonlywhenhighpurityquartz
isrequiredforthemarket(Bayatetal.,2007).Oncewashingandflotation(ifrequired)iscompleted,thesandis
driedtomeetthemarketspecifications(Kogeletal.,20106;Sundararajanetal.,2009;AlMaghrabi,2004).Table
7presentstheironoxidecontentinsilicasandGradeIfromEuropeandUSAwhenpurifiedusinggravityand
magneticseparationtechniques(GWPConsultantsLLP,2010).
For the Egyptian white sands, usually, processing does not require complicated flowsheets. Basically only
washing and screening are carried out to remove coarse and fine fractions. For high purity sands, attrition
scrubbingwithacidifiedwaterremovesadheredfineclaysandironstains.Fortheremovalofheavyminerals,
low or high intensity magnetic separation, dry or wet, and /or flotation may be used (Zarad, 2014). For the
separation of kaolin as a byproduct in some ores, hydrocyclons are used efficiently to give a coarse sand
productandafinekaolinproduct.However,becauseflotationisanexpensiveprocess,itsusewilldependon
thepaybackfromthepurifiedproduct.
TABLE7:TYPICALRESULTSOFTHEGRAVITYANDMAGNETICSEPARATIONONSILICASANDSFROMEUROPEANDUSA.
Stageofprocessing
SilicaSandI(Europe)
SilicaSandI(USA)
Feed,Fe2O3%
0.085
0.089
Gravityspirals1pass,Fe2O3%
0.038
0.066
Gravityspirals2passes,Fe2O3%
0.033
0.049
Magneticseparationatleast2passes,Fe2O3%
0.014
0.039
SomeAcademicresearchworkwascarriedouttopurifytheEgyptianwhitesands.ElWekeilandGaafar(2014)
beneficiatedsilicasandfromElNaqusformationinWadiQena,EasternDesert.Theyusedattritionscrubbing
to loosen sands from kaolin and clean the sand surface from the contaminating elements such as iron,
chromium, and titanium using water acidified with 10 % HCl. The attritted sample was screened to remove
coarse grits (+2.0 mm). The 2 mm material was subjected to classification using different hydrocyclones to
separatethefeedintocoarsesandproduct,sandkaolinproduct,andwhitekaolinproduct.Forthefinefraction,
theauthorsusedamagneticfiltertoremovemagneticandparamagneticcontaminants.Forcleaningthecoarse
product,theyusedinducedrollmagneticseparatorandWilfleytabletoremoveheavyminerals.Theyobtained
quartz sand product containing 98.6 % SiO2 with less than 0.025 % Fe2 O3 and less than 0.045 % TiO2 after
attritionscrubbingandthefirststageofhydrocycloning.Inthesecondandthirdstagesofhydrocycloning,they
obtainedwhitekaolincontaining46.6%silicaand37.1%Al2O3representingabout11%ofthetotalfeed.They
alsocleanedtwosizefractionsofthesand:afinefraction,0.250.125mm,andaveryfinefraction,0.1250.063
mm. These fractions were treated by attrition scrubbing using acidified water containing 10 % HCl. The
scrubbed material was deslimed, washed and dried. The dried material wassubjected to sinkfloat test using
bromoform liquid (sp. gr. 2.85), where the sink fraction was collected, washed, dried and weighed. The float
fractions were collected, washed, dried, and passed through a magnetic filter to remove the coloring
contaminants.AbouElAnwar(2007)showedthatthebeneficiationofElMasaidsilicasands,WestofElArish,
Sinaicanbedonebywashingwithseawaterfollowedbyfreshwater.Thesandisthentreatedwithacidified
watercontaining10%HFor10%HClatroomtemperatureforlongtime.Hereportedthatthissandcanbe
furtherpurifiedbyflotationtoremovethedeterioratingmaterialsuchasiron,manganeseandheavyminerals.
Healsostatedthatwashingthesandwithwatercontaining10%HClpriortoflotationimprovedtheproduct.
Hagras(2013)showedthatgravityseparationissuitableforpurifyingsilicasandsasaresultoftheremovalof
heavyminerals.Ibrahimetal.2013)purifiedawhitesandsamplefromAbuZeneimaarea,Sinai.Theoriginal
samplecontained99.44SiO2,0.046%Fe2O3,0.044%Al2O3,0.03%TiO2,0.11%MnO,and0.02MgO.Bydry
screening,theyremovedthe+0.6mmandthe0.106mmfractions.Thesizedfractionwassubjectedtoattrition
scrubbing, deslimed andwashed with water. Theattritted material was treated on Wilfleytable. Theauthors
reported that screening the sample reduced the iron oxide content down to 0.04 %, attrition scrubbing and
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desliming reduced theiron oxide content to 0.025 %, and tablingreduced it to 0.02%. Thefinal sand product
contained0.018%Fe2O3and0.09%Al2O3.OfcoursetheauthorsdidnotreporttheSiO2percentinthefinal
product,becauseitwillnotdiffermuchfromitspercentageinthefeed.
Summary
White sands in all its forms: quartz, sandstone, and silica sand are essential commodities for various high
technology industries. Electronicgrade quartz is used in accurate filters, frequency controls, and timers in
electroniccircuits.Thesedevicesareusedforavarietyofelectronicapplicationsinaerospacehardware,military
navigationinstruments,communicationsequipment,andcomputers.
White sand is the final product of rock weathering of any quartzbearing rock which creates sand: igneous,
sedimentary, or metamorphic (Shaffer, 2006). It is called industrial silica sand, and defined by the BGS as sand
used for applications other than construction aggregates and which are valued for their physical and chemical
properties. It is used for glassmaking, water filtration, foundry industries, manufacture of electronic chips and
wafers,grouts,paints,andfillersforplastics,polymers,rubberandotherapplications.
In Egypt, there are a large number of highquality quartz deposits. All of them are spread in the Eastern Desert
alongtheRedSeaCoast.Theirmodesofoccurrenceareasquartzcapsofplutonsformedasaresultofmagmatic
differentiation and after granitic pluton cooled and solidified. Quartz veins were formed from the residual
solutionsafterformingthecaps,andthesesolutionspenetratedthroughthecracksandalongfissurestoformveins
and/orlensoidalbodies.Quartziteispresentinbothsedimentaryandmetamorphicrocks.Itisoriginatedfromthe
metamorphismofsandstone.ThequartsreservesinEgyptexceed20milliontonsinmorethan30localities.
The white sands in Egypt exist in Sinai, North part of Eastern Desert, and in the Western Desert. The most
importantsandstonedepositsinEgypt,quantityandquality,areinWadiQenaintheEasternDesertandGebelEl
Gunna in Sinai. The white sand in Wadi Qena constitutes most of the early lower Paleozoic Naqus Formation,
NorthEastofQena.TheNorthernpartofWadiQenaconsistsoftheexposedlowerPaleozoicrockunitswhichare
represented by Araba and Naqus Formation. At the Saint KatherineNeuwiba, the Naqus Formation consists
mainly of a thick sandstone sequence. Generally, the lower 30 m are white massive sandstone beds with minor
ferruginousclayeyandkaoliniticinterbeds.GebelElGunnahhasthelargestsandstonereservesinSinai.Thereare
morethan3billiontonsofhighqualitysilicasandsinmorethan16localitiesinEgypt.
Miningofunconsolidatedsanddepositsisdonebyusingfrontendloaders,scrapers,orbulldozers.Materialisdug,
excavatedandtheloadedintotruckstotheprocessingplant.Insomecaseshydraulicdredgeswithasuctionpump
excavatethesandandpumpthematerialtotheplant.Inthecaseofwellconsolidateddeposits,conventionaldrill
and blast methods are used, where the stone is mucked, hauled, and transported to the crushing section in the
processingplant.
InEgypt,surfaceminingtechniqueisusedforminingsilicasand.TheoreisdrilledandblastedusingAnfoand
gelatinforblasting.Benchheightisaround1012m.Thebrokenrocktransportedtoasizereductionandscreening
sectiontobepreparedforwashingandprocessing.
Theappliedmineralprocessingunitsarearrangedinsimpleflowsheets.Theyconsistofscreening,washing,and
classification.Sometimestheclassifiedproductisleachedusingdilutedinorganicacids.Mostoftheworkingsites
useseawaterfollowedbyfreshwaterduetothescarcityofthefreshwaterintheseareas.Insomesites,magnetic
separationisused.Academicresearchworkinvestigatedtheuseofgravityseparationand/orfrothflotation.The
grade of the final sand product depends on the purity of the feed and the mineral processing steps taken for
cleaningtheore.
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