A.K.

VIDYAMANDIR

ELECTROCHEMISTRY
WEEKEND (+2)

S.C.O. 214, SEC 36-D, CHD, PH:- 615071,899073

1.

2.

3.
4.
5.

6.

7.

8.

9.

CH3 COOH = 20 ohm1 cm2eq1 and CH COOH = 400 ohm1 cm2 equiv1 calculate the pH of this
3
solution
(a) 1.3
(b) 0
(c) 1.7
(d) 4
Equivalent conductance at infinite dilution of BaCl 2,H2SO4 and HCl aq. Solutions are x 1, x2, and x3
respectively. Equivalent conductance of BaSO4 solution is
(a) x1 + x2 x3
(b) x1 x2 x3
(c) x1 + x2 2x3
(d) x1 2x2 + x3
Which has maximum conductivity
(a) [Cr (NH3)3 Cl3]
(b) [Cr (NH3)4Cl2]Cl
(c) [Cr (NH3)5 Cl] Cl2
(d) [Cr (NH3)6] Cl3
Which of the following solutions of NaCl will have the highest specific conductance ?
(a) 0.001 N
(b) 0.1 N
(c) 0.01 N
(d) 1.0 N
For Al2(SO4)3 ;
1
(a) m =
eq
(b) m = 6 + eq
6
(c) m = 6 eq
(d) m = 6 eq
Equivalent conductance of NaCl, HCl and C2H5 COONa at infinite dilution are 126.45, 426.16 and 91
ohm1 cm2 respectively. The equivalent conductance of C2H5COOH is:
(a) 201.28 ohm 1 cm2
(b) 390.71 ohm 1 cm2
1
2
(c) 698.28 ohm cm
(d) 540.48 ohm1 cm2
o
For the cell given below Ecell E cell = 0.118 V
Zn | Zn2+| | Cu2+ | Cu
What is the ratio of [Zn2+] / [Cu2+]
(a) 104
(b) 104
2
(c) 10
(d) 102
The e.m.f of the cell
Tl |Tl+ (0.001 M) || Cu2+ (0.01 M) | Cu is 0.83 V. The emf of this cell could be increased by
(a) increasing the concentration of TI+ ions
(b) increasing the concentration of Cu2+ ions
(c) increasing the concentration of both
(d) none of the above.
Which graph correctly correlates Ecell as a function of concentrations for the cell (for different values of M
and M) :
Zn(s) + Cu2+(M) Zn2+ (M) + Cu(s) ,
Eo
cell = 1.10 V

X-axis : log10

[Zn 2 ]
[Cu 2 ]

y-axis : Ecell

1.10 V
1.10 V

(a)

(b)
0

1.0

1.0

+1.0

+1.0

1.10 V

(c)

(d)
1.0

10.

Cu+ + e

Cu,

1.0

+1.0

+1.0

E = X1 volt,

/var/www/apps/conversion/tmp/scratch_3/328009613.doc

A.K.VIDYAMANDIR

ELECTROCHEMISTRY
WEEKEND (+2)

S.C.O. 214, SEC 36-D, CHD, PH:- 615071,899073

11.

12.

13.
14.

15.

Cu2+ + 2e Cu,
E = X2 volt,
For Cu2+ + e Cu+ , E, will be :
(a) X 2X2
(b) X1 + 2X2
(c) X1 X2
(d) 2X2 X1
Which of the following statements about a reaction occurring in a galvanic cell is true
(a) If Eocell > 0, G < 0
(b) If Eocell < 0, G < 0
o
(c) If E cell < 0, Keq > 1
(d) If Eocell < 0, Keq < 1
0
The standard reduction potential at 25 C of the reaction. 2H 2O + 2e
H2 + 2OH is 0.8277 volt.

+
o
The equilibrium constant for the reaction 2H2O
H3O + OH at 25 C is
(a) 1012
(b) 1014
(c) 1011
(d) 108
The zinc acts as a sacrifician for cathodic protection to prevent rusting of iron because
(a) Eoop of Zn < Eoop of Fe
(b) Eoop of Zn > Eoop of Fe
o
o
(c) E op of Zn = E op of Fe
(d) Zn is cheaper than Fe
The reduction potential values are given below
Al+3/Al = 1.67 volt.
Mg+2/Mg = 2.34 volt

+2
Cu /Cu = + 0.34 volt, I2/2 I = +0.53 volt. Which one is the best reducing agent ?
(a) Al
(b) Mg
(c) I2
(d) Cu
Based on the data given below, the correct order of reducing power is :
Fe3+(aq) + e Fe2+ (aq) ; E = + 0.77 V
Al3+(aq) + 3e Al(s) ;
E = 1.66 V
Br2(aq) + 2e 2Br(aq) ;E = + 1.08 V
(a) Br < Fe2+ < Al
(b) Fe2+ < Al < Br

2+
(c) Al < Br < Fe
(d) Al < Fe2+ < Br
ANSWERS
1
2
3
4
5

A
C
D
D
C

/var/www/apps/conversion/tmp/scratch_3/328009613.doc

6
7
8
9
10

B
A
C
B
D

11
12
13
14
15

A
B
B
B
A