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Natural Science Department, Community College of Riyadh, King Saud University, kingdom of Saudi Arabia
emabdelrazek@yahoo.com; a,c*mabdelaziz62@yahoo.com
Abstract
Polymeric films of pure poly (vinyl pyrrolidone) (PVP) and
PVP/gelatin blend (60/40) containing various amounts of
MgCl2 were prepared using a casting technique. The
structural and related physical properties of the prepared
films were studied using different techniques. The obtained
data revealed that the addition of gelatin and magnesium
chloride causes structural variation in the PVP network. The
X-Ray diffraction (XRD) patterns reveal that the amorphous
nature of the blend increases with the concentration of
magnesium chloride. Complex formation was confirmed by
XRD and FT-IR analysis. The DSC results indicate that the
addition of both gelatin and magnesium chloride to PVP
changes the thermal behavior, such as the glass transition
temperature and thermal stability. The analysis of the UVvisible optical absorption shows the decrease in the optical
band gap (Eg) as dopant concentration increase. The reduced
values of the optical gap improve their optical response,
which can be used as optical sensors. The direct current (DC)
electrical resistivity studies revealed a linear temperature
dependence of the hopping distance (Ro) for all doped films.
The conduction mechanism discussed based on the phononassisted charge carrier inter-polaron hopping model.
Moreover, the addition of both gelatin and MgCl2 gives rise
to improve the electrical properties of PVP film. The optical
and electrical results suggested the applicability of these
materials in optical and/or electrical sensors.
Keywords
Blends; XRD; FT-IR; DSC; Optical; Electrical Properties
Introduction
Polymer science has shown a tendency in the last
decade to create blends of different polymers rather
than to develop new polymers. Blending of polymers
is one of the simplest means to obtain a variety of
physical and chemical properties from the constituent
polymers. The gain in newer properties depends on
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Sample preparation
Poly (vinyl pyrrolidone) (PVP) from Aldrich chemical
co. Ltd England were used as received. The quantity of
PVP and gelatin (60/40) by weight to weight (wt %)
was added to doubly distilled water with stirring the
solution at 343K to complete dissolution. Required
quantity (0.0, 2, 6, 8,10,15 and 20 wt%) of MgCl2 was
also dissolved in doubly distilled water and added to
the polymeric solution with continuous stirring. Then
the solution was left for 24 hour to eliminate bubbles.
The solution was poured onto cleaned Petri dishes and
dried in oven at 333 K for 4 days to ensure removal of
the solvent traces. After drying, the films were peeled
from Petri dishes and kept in vacuum desiccators until
use. The thickness of the obtained films was in the
range of 80-90 m for the FT-IR measurement and
100150 m for other measurements.
Measuring techniques
The X-Ray diffraction (XRD) scans were obtained
using a Seimens type F diffractometer with CuKa
radiation and LiF monochromator. FT-IR absorption
spectra were carried out using the single beam Fourier
transform-infrared spectrometer (FT-IR-430, JASCO,
Japan). FT-IR spectra of the samples were obtained in
the spectral range of 4000-400 cm-1. The differential
scanning calorimetry (DSC) measurements were
performed by using a Shimadzu DSC-50 apparatus in
the temperature range 303873 K with a heating rate of
10 K/min. Ultraviolet and visible (UV-VIS) absorption
spectra were measured in the wavelength region of
200 - 900 nm using spectrophotometer (V-570
UV/VIS/NIR, JASCO, Japan). The direct current
electrical resistivity was measured using an auto-range
multimeter (Keithley 175) with an accuracy of 2%.
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h = B op (h E g
(1)
3
2
allowed,
allowed,
direct
E g = 0 . 049 W + 5 . 31
(2)
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h
= 0 exp
Er
(3)
DC electrical resistivity
In polymeric films, the change of electrical resistivity
( ) with temperature is due to the segmental motion,
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RS
d
(4)
2
Ro2 ( y p + ybp )
2BRo
=
exp
2
2
y p ybp
Ae ( T )
kT
(5)
Ro = [3 /(4Cimp)]3
is
T
(T ) = o
300 K
11
(6)
Ea
= o exp
kT
(7)
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Conclusion
FIG. 9 TEMPERATURE DEPENDENCEOF THE LOGARITHM OF
ELETRICAL RESISTVITY () FOR VARIOUS DOPED WITH
DIFFERENT CONTENTS OF OF MGCL2
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