PHENOMENON OF GASES
Introduction
In electrical power system, all three medias, solid, liquid and gas are used for
insulating purpose.
Out of them, solids have highest breakdown strength and gases have lowest.
To study the breakdown mechanism of gases, a detailed study of ionization process
and various proposed mechanism is required.
Collision process
Elastic collision
Inelastic collision
Ionization by collision
Fig.1
Photo-ionization
It occurs when the amount of radiation energy absorbed by an atom or
molecule exceeds its ionization potential.
Radiation of wavelength 1250 angstrom is capable of causing photoionization of almost all gases.
Secondary ionization
Electron emission due to positive ion impact when positive ions produced by
ionization collisions travel to cathode, bombard the metal cathode and its kinetic
energy and ionization energy gives rise to production of secondary electron if the
sum of them is greater than twice the work function of the metal
Electron emission due to photons photons of UV ray of suitable frequency can
cause electrons to emit from cathode for the critical condition
..
Threshold Frequency is given by
Excess energy goes partly as kinetic energy of the emitted electron and partly to
heat the electrode surface, if frequency is greater than threshold.
Electron emission due to metastable and neutral atoms -
D = sparking distance
V = spark breakdown voltage, for given pressure.
Townsends mechanism explains breakdown phenomenon only at low pressure
corresponding to p * d values of 1000 torr-cm and below.
Streamers Theory
Growth of charge carriers in an avalanche in uniform field,
e^(d) as given by Townsend, is valid only when effect of
space charge is negligible compared to applied field.
When charge density is between 10^6 and 10^8, the field
due to space charge is weak, but beyond 10^8 there is a steep
rise in current leading to breakdown.
So, modifications to Townsends mechanism at both low
concentration and high concentration is marked by Streamer
theory.
Controversy
It is still undetermined which mechanism
operates in uniform field condition, though it
is assumed that :
At p*d < 1000 torr-cm and pressure
between 0.01 to 300 torr., Townsends
mechanism work, and above that pressure,
Streamers thoery is aplicable.
Paschens law
V = f(pd)
Penning effect
Corona discharge
For non-uniform fields, increase in voltage will first
cause discharge at points with highest electric field
intensity, namely at sharp points or on transmission
lines.
This form of discharge is called corona discharge,
observed as a bluish luminescence and hissing noise.
The surrounding air gets converted to ozone.
It causes considerable power loss in high voltage TL.
It leads to deterioration of insulation due to combined
action of bombardment of ions and chemical
compounds formed during discharge.
It gives rise to radio interference.
Post-breakdown phenomenon
Glow Discharge:
Arc Discharge:
SF6 as insulator
SF6 satisfies most of the above requirements.
It has very high dielectric strength, and can be used
over a wide range of operating conditions.
It has excellent arc quenching properties.
But it is a green house gas causing environmental
problems.
So alternate gas mixtures to replace pure SF6 are
experimented.