Ionic Equilibria
The equilibrium constant expression:
(Review)
by
HF(aq) H 2 O (l)
F - (aq) H 3O (aq)
AgCl (s)
Ag (aq) 2 Cl (aq)
Example 1
Kw = ion-product constant
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Example 2
Example 2
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Example
but
and therefore
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Since
, then:
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Example
Significant error has been introduced by the assumption that
[H3O+] << cC6H5NH3+ (just compare 7.09 x 10-5 with 2.0 x 10-4)
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Example
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Example
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Example
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A solution containing a weak acid, HA, and its conjugate base, A-,
may be acidic, neutral or basic, depending on the positions of two
competitive equilibria:
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Example
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Example
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Example
Example
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Example
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Preparation of Buffers
Buffer solution of any desired pH can be prepared by combining
calculated quantities of a suitable conjugate acid/base pair.
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Preparation of Buffers
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Sample Problems
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