Revision Date:
08.06.2016
SDS Number:
1598664-00006
Product code
000000000004047823
PO box
65091
Telephone
+91 22 66946868
+91 22 66946841
Telefax
+91 22 66946848
2. HAZARDS IDENTIFICATION
Manufacture, Storage and Import of Hazardous Chemicals Rules 1989
Classification
Not a hazardous substance or mixture.
GHS Classification
Skin corrosion/irritation
Category 2
Category 2
Signal word
Warning
Hazard statements
Precautionary statements
Prevention:
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Mixture
Chemical nature
Silicone emulsion
Hazardous components
Chemical name
CAS-No.
Triethoxy(octyl)silane
Dimethyl siloxane with aminoethylaminopropyl
silsesquioxane, hydroxy-term
Polyethylene oxide lauryl ether
Ethoxylated lauryl alcohol
Octamethylcyclotetrasiloxane
Hexadecyltrimethyl ammonium chloride
Hexadecyltrimethylammonium acetate
Hexadecyldimethylamine
2943-75-1
68554-54-1
Concentration (%
w/w)
>= 10 - < 20
>= 1 - < 5
9002-92-0
9002-92-0
556-67-2
112-02-7
51374-75-5
112-69-6
>= 1 - < 5
>= 0.1 - < 1
>= 0.1 - < 1
< 0.1
< 0.1
< 0.1
In the case of accident or if you feel unwell, seek medical advice immediately.
When symptoms persist or in all cases of doubt seek medical
advice.
If inhaled
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SDS Number:
1598664-00006
If swallowed
Protection of first-aiders
Notes to physician
Water spray
Alcohol-resistant foam
Carbon dioxide (CO2)
Dry chemical
Unsuitable extinguishing
media
None known.
5. FIREFIGHTING MEASURES
Carbon oxides
Silicon oxides
Formaldehyde
Nitrogen oxides (NOx)
Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.
Use water spray to cool unopened containers.
Remove undamaged containers from fire area if it is safe to do
so.
Evacuate area.
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Environmental precautions
Technical measures
Local/Total ventilation
Materials to avoid
CAS-No.
Octamethylcyclotetrasiloxane
556-67-2
Value type
(Form of
exposure)
TWA
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Basis
DCC OEL
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SDS Number:
1598664-00006
CAS-No.
Ethanol
64-17-5
Value type
(Form of
exposure)
TWA
STEL
Engineering measures
Basis
IN OEL
ACGIH
Hand protection
Material
Chemical-resistant gloves
Remarks
Eye protection
Select appropriate protective clothing based on chemical resistance data and an assessment of the local exposure potential.
Skin contact must be avoided by using impervious protective
clothing (gloves, aprons, boots, etc).
Hygiene measures
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liquid
Colour
white
Odour
not significant
Odour Threshold
No data available
pH
No data available
No data available
> 35 C
Flash point
> 100 C
Method: closed cup
Evaporation rate
No data available
Not applicable
No data available
No data available
Vapour pressure
No data available
No data available
Relative density
Solubility(ies)
Water solubility
No data available
No data available
Auto-ignition temperature
No data available
Decomposition temperature
No data available
Viscosity
Viscosity, dynamic
50 mPa.s
Explosive properties
Not explosive
Oxidizing properties
Molecular weight
No data available
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08.06.2016
SDS Number:
1598664-00006
Reactivity
Chemical stability
Conditions to avoid
Exposure to moisture
Incompatible materials
Oxidizing agents
Water
Formaldehyde
Inhalation
Skin contact
Ingestion
Eye contact
Acute toxicity
Not classified based on available information.
Components:
Triethoxy(octyl)silane:
Acute oral toxicity
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SDS Number:
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Octamethylcyclotetrasiloxane:
Acute oral toxicity
: LD50 (Rat): > 4,800 mg/kg
Assessment: The substance or mixture has no acute oral toxicity
Remarks: Based on test data
Acute inhalation toxicity
Hexadecyltrimethylammonium acetate:
Acute oral toxicity
: LD50 (Rat): 1,550 mg/kg
Remarks: Based on data from similar materials
Acute dermal toxicity
Hexadecyldimethylamine:
Acute oral toxicity
Skin corrosion/irritation
Causes skin irritation.
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Components:
Triethoxy(octyl)silane:
Species: Rabbit
Result: Skin irritation
Remarks: Based on test data
Dimethyl siloxane with aminoethylaminopropyl silsesquioxane, hydroxy-term:
Result: Skin irritation
Remarks: Based on data from similar materials
Polyethylene oxide lauryl ether:
Species: Rabbit
Method: Draize Test
Result: No skin irritation
Remarks: Based on data from similar materials
Ethoxylated lauryl alcohol:
Result: No skin irritation
Remarks: Based on data from similar materials
Octamethylcyclotetrasiloxane:
Species: Rabbit
Result: No skin irritation
Remarks: Based on test data
Hexadecyltrimethyl ammonium chloride:
Species: Rabbit
Result: Corrosive after 1 to 4 hours of exposure
Remarks: Based on data from similar materials
Hexadecyltrimethylammonium acetate:
Species: Rabbit
Result: Corrosive after 1 to 4 hours of exposure
Remarks: Based on data from similar materials
Hexadecyldimethylamine:
Species: Rabbit
Result: Corrosive after 3 minutes to 1 hour of exposure
Serious eye damage/eye irritation
Not classified based on available information.
Components:
Triethoxy(octyl)silane:
Species: Rabbit
Result: No eye irritation
Remarks: Based on test data
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Octamethylcyclotetrasiloxane:
Assessment: Does not cause skin sensitisation.
Test Type: Maximisation Test
Species: Guinea pig
Remarks: Based on test data
Hexadecyltrimethyl ammonium chloride:
Test Type: Buehler Test
Exposure routes: Skin contact
Species: Guinea pig
Method: OECD Test Guideline 406
Result: negative
Hexadecyltrimethylammonium acetate:
Test Type: Maximisation Test
Exposure routes: Skin contact
Species: Guinea pig
Result: negative
Remarks: Based on data from similar materials
Hexadecyldimethylamine:
Test Type: Maximisation Test
Exposure routes: Skin contact
Species: Guinea pig
Result: negative
Germ cell mutagenicity
Not classified based on available information.
Components:
Triethoxy(octyl)silane:
Genotoxicity in vitro
Octamethylcyclotetrasiloxane:
Genotoxicity in vitro
: Test Type: Bacterial reverse mutation assay (AMES)
Result: negative
Remarks: Based on test data
:
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Genotoxicity in vivo
SDS Number:
1598664-00006
Test Type: DNA damage and repair, unscheduled DNA synthesis in mammalian cells (in vitro)
Result: negative
Remarks: Based on test data
Carcinogenicity
Not classified based on available information.
Reproductive toxicity
Not classified based on available information.
Components:
Triethoxy(octyl)silane:
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Effects on fertility
Octamethylcyclotetrasiloxane:
Effects on fertility
: Test Type: Two-generation reproduction toxicity study
Species: Rat, male and female
Application Route: inhalation (vapour)
Symptoms: Effects on fertility
Remarks: Based on test data
Effects on foetal development
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SDS Number:
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Components:
Triethoxy(octyl)silane:
Exposure routes: Ingestion
Assessment: No significant health effects observed in animals at concentrations of 100 mg/kg
bw or less.
Octamethylcyclotetrasiloxane:
Exposure routes: Ingestion
Assessment: No significant health effects observed in animals at concentrations of 100 mg/kg
bw or less.
Exposure routes: inhalation (vapour)
Assessment: No significant health effects observed in animals at concentrations of 1 mg/l/6h/d or
less.
Exposure routes: Skin contact
Assessment: No significant health effects observed in animals at concentrations of 200 mg/kg
bw or less.
Repeated dose toxicity
Components:
Triethoxy(octyl)silane:
Species: Rat
Application Route: Ingestion
Remarks: Based on test data
Ethoxylated lauryl alcohol:
Species: Rat
NOAEL: >= 100 mg/kg
Application Route: Ingestion
Exposure time: 90 Days
Method: OECD Test Guideline 408
Remarks: Based on data from similar materials
Octamethylcyclotetrasiloxane:
Species: Rat
Application Route: Ingestion
Remarks: Based on test data
Species: Rat
Application Route: inhalation (vapour)
Remarks: Based on test data
Species: Rabbit
Application Route: Skin contact
Remarks: Based on test data
Hexadecyltrimethyl ammonium chloride:
Species: Rat
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Toxicity to algae
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Exposure time: 96 h
Toxicity to daphnia and other
aquatic invertebrates
Toxicity to algae
Octamethylcyclotetrasiloxane:
Toxicity to fish
: LC50 (Oncorhynchus mykiss (rainbow trout)): > 0.022 mg/l
Exposure time: 96 h
Remarks: No toxicity at the limit of solubility
Toxicity to daphnia and other
aquatic invertebrates
Ecotoxicology Assessment
Chronic aquatic toxicity
:
Revision Date:
08.06.2016
SDS Number:
1598664-00006
Toxicity to algae
10
Toxicity to bacteria
Hexadecyltrimethylammonium acetate:
Toxicity to fish
: LC50 (Danio rerio (zebra fish)): 0.19 mg/l
Exposure time: 96 h
Method: OECD Test Guideline 203
Remarks: Based on data from similar materials
Toxicity to daphnia and other
aquatic invertebrates
Toxicity to algae
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SDS Number:
1598664-00006
mg/l
Exposure time: 72 h
Method: OECD Test Guideline 201
Remarks: Based on data from similar materials
M-Factor (Acute aquatic toxicity)
10
Toxicity to algae
Hexadecyldimethylamine:
Toxicity to fish
100
10
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Octamethylcyclotetrasiloxane:
Biodegradability
: Result: Not readily biodegradable.
Biodegradation: 3.7 %
Exposure time: 28 d
Method: OECD Test Guideline 310
Stability in water
Bioaccumulative potential
Components:
Triethoxy(octyl)silane:
Partition coefficient: noctanol/water
Ethoxylated lauryl alcohol:
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Bioaccumulation
SDS Number:
1598664-00006
:
Octamethylcyclotetrasiloxane:
Partition coefficient: n: log Pow: 6.48 (25.1 C)
octanol/water
Hexadecyltrimethyl ammonium chloride:
Bioaccumulation
: Species: Lepomis macrochirus (Bluegill sunfish)
Bioconcentration factor (BCF): 33 - 160
Remarks: Based on data from similar materials
Hexadecyltrimethylammonium acetate:
Partition coefficient: n: log Pow: > 6.91
octanol/water
Remarks: Based on data from similar materials
Mobility in soil
No data available
Other adverse effects
Components:
Octamethylcyclotetrasiloxane:
Results of PBT and vPvB
: Remarks: Octamethylcyclotetrasiloxane (D4) meets the curassessment
rent REACh Annex XIII criteria for PBT and vPvB. In Canada,
D4 has been assessed and deemed to meet the PiT criteria.
However, D4 does not behave similarly to known PBT/vPvB
substances. The weight of scientific evidence from field studies shows that D4 is not biomagnifying in aquatic and terrestrial food webs. D4 in air will degrade by reaction with naturally
occurring hydroxyl radicals in the atmosphere. Any D4 in air
that does not degrade by reaction with hydroxyl radicals is not
expected to deposit from the air to water, to land, or to living
organisms.
13. DISPOSAL CONSIDERATIONS
Disposal methods
Waste from residues
Contaminated packaging
Empty containers should be taken to an approved waste handling site for recycling or disposal.
If not otherwise specified: Dispose of as unused product.
Revision Date:
08.06.2016
SDS Number:
1598664-00006
IECSC
ENCS/ISHL
PICCS
DSL
REACH
TSCA
KECI
TCSI
Items where changes have been made to the previous version are highlighted in the body of this
document by two vertical lines.
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Date format
SDS Number:
1598664-00006
:
dd.mm.yyyy
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information
and belief at the date of its publication. The information is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and shall not be considered a
warranty or quality specification of any type. The information provided relates only to the specific material identified at the top of this SDS and may not be valid when the SDS material is used in combination with any other materials or in any process, unless specified in the text. Material users should review the information and recommendations in the specific context of their intended manner of handling, use, processing and storage, including an assessment of the appropriateness of the SDS material in the users end product, if applicable.
IN / EN
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