Thermodynamics Practice Test Nam Note - this practice test does NOT contain questions from all sections of the chapters Ncho 1999 $2227. According to this information, and given the fact that for water, A= -286 kJ mol”, what is AH; for MgO(s)? Reaction aH [ata +2 HcH09) > Macon +H) | 167 mot Lago(s) + 2:1C(aq) -> MgCh(ag) +H200) | -151 kJ mol _| 2a (A) 904 id mot Mg lo) 240s Nigles + Sem Wt rn Ge Bal 2h -C1a) am 492) > “#20 = 200 (0) 3010 mol Bd tog MQ * 021g) —= Ugd(sy —-WOZ NChO 1998 C22. Carbon reacts with oxygen according to this equation. 2C(s)+O,(g) > 2CO(e) AH=-220 KI Which statements are true? 1. The reaction is exothermic. Tyg @y 2. The combustion of 0.50 mol of carbon produces 55 kJ of heat energy (A) 1 only 0.50 mol & y 220 = - roy ex Fm OS both 1 and 2 (D) neither 1 nor 2 C25. 4.1.0 gsample of substance A at 100 °C is added to 100 ml of H,O at 25 °C. Using separate 100 ml. portions of HO, the procedure is repeated with substance B and then with substance C, How will the final temperatures of the water re? Substance _ Specific Heat A 0.603 g'°C" conttuns mock energy te change tne VC | 0.40 I g7°C* _ 0.207 g'°C? Coninins Least dink. oF energy to Change temp re (AT.>T>T, @)%>T>T eErememioer veat fowS fom t 1 Y 5 Onnet ® Speafic hear means more ener (neat) @)T.=T=Te Wont wito the Guiestance to Change WS YnP5 th now has more hear to Awe to anornecud- P26. tow many grams of benzene, CzHy(), must be burned in a bomb calorimeter to raise its temperature by 1.5 °C? Given: The calorimeter constant is 12.59 kJ C™ and the AH? cbusion for CeH = -41.9 1 Ooase Coa = 12.00 ex Oran =— Coa « AT @)28 _ : oe Cc Grin= -(2aMpV(iSO (D) 84g 2Cyly #602 202+ bho Fren= -\0.9%2 uw ce 0.459 \ 29= ~\o.tob vx 8 aeNChO 1997 Y_19..30.0 ml. of water at 10, °C is mixed with 50.0 mL of water at 60. °C. What is the final temperature of the mixture? Qn = —O wid wire (0.09 (4.10%) oe . (B) 35°C 09) aO(te- WO) = (og \410%4C)e~Ip* Buc (200) (revo) = ape Ce NN OD ) 46°C 204 Tp -\ 2a Py 24, Whats the value of AH? for tis reaction? ‘Substance [an 0 me ) [ Fexoss) | recor. #00) Oe Atk = Athproa - Ati reace © ae =(2Cezo\-Eoun + 2-200) (D)-536 I = 3B. NChO 1996 _{D 22. The standard enthalpy of formation (AH®,) for sodium bromide is the enthalpy change for the reaction (A) Na'(g) + Br (g) —> NaBr(g) Muy = formaton of Compounds from (B) Na’(g) + Br (g) -> NaBr(s) elements @ Natural Swe (C)2.Na(s) + Brx(g) —> 2 NaBr(s) Oxo ¥%Brx(l) -> NaBr(s) Na(ss+4 Be) = NaBr Ncho 1994 £24. A student mixes 100 mL of 0.50 M NaOH with 100 mL of 0.50 M HCI in a styrofoam cup and observes a ‘temperature increase of AT). When she repeats this experiment using 200ml. of each solution, she observes-a temperature change of AT. If no heat is lost to the surroundings or absorbed by the styrofoam cup, what is true about AT; and 4 T;? equal quantthes and equal movaritres Generate equal ar! ()AT=4aT, NCho 1993 _C13. Which process or reaction has a positive AH? = @ndorwevwic (A)H0() > 1:06) 062 heat to freeve — Ad (B) 2CH,OH(D + 30,48) > 2COx(g) + 4,00) Combughon = - St coXs) > C02) dA neal tp Subime +AK aa (©) 2NaGs)* Cha) 2NECIO) loge. Weak when making lords Codd oat +0 oven voond>)Eis For the reaction Hig) + L(6) > 2 He) AHlnq = 53.0 KS at will be the value of AH, (in kJ) for this rxn ? HI(g) > 4 Hi(e) + 4 L(6) (A) 26s Feversed and holed = —L oe B73 4(620)= -20.9 26.5 (D) -53.0 Necno 1999 Levme move ordered _D 26. For which reaction do you expect AS to be negative? (A) 2C(s) + 0,(8) + 2008) S5O=% Qos part (B) BrAs) -> Br(l) S2Q = tee = 660 (C)H.0(1, 25 °C) > H,0(,, 50°C) 4emnp= re = AS e cre) + 211) > Hi) +2HCK®)Y Yo pares = ASO NChO 1997 _ D226. For which of these processes would AS* be expected to be the most positive? = MOSK A\sorderca (A) Oxg) + 2HL(@) > 280(@)_Y WE= 4°0 (B) Hr0() > 1,06) Dre e220 (C) N,Ox(g) > 2NO2(g) gas part. = 26 (c) amit as 4 QONUNOAS) > NIG) +220@) > qe = “ee greats stated OS 4848 ard Cece 2 Tare Wil Crewe a Greater charge in BS Avan NChO 1995 G24. For the process Ox(g) > 2 O(g), AH? = +498 KI, ‘What would be predicted for the sign of AS. and the conditions under which this reaction would be spontaneous? Spontaneous _ > at low temperatures onl AG] AW AS A670 at high temperatures onl es zs | _at high temperatures only 498 needed £9 get Gao eet e_|_at low temperatures on] jgronP « Lycomr ve negatwe --. T gas parhdes = o® 2. For the reaction NH,Cl(s) -» NHy(g) + HCI(g) [ARP = =176KT dnd AG" = F972 kijat{298 Ki What is the value of AG at 1000 K? @-1091%0 AG? = AW’-TAS? Do =BA-T AS B64 O\2 = nv - (200) OF = (1 Wid) (io (0.22%) (ast gage - 2aeat = 100 (D) +109 kr DAO 200 0,298> AFFree Response Question (1970) Consider the first ionization of sulfurous acid: H,SOs(aq) —> H’ (ag) + HSOs"(aq) Certain related thermodynamic data are provided below: _H2SOs(aq) H'(aq) HSOs(aq) Note - = these values are in calories (cal) or Hf kcal/mole -145.5 S‘cal/mole K 56 kilocalories (kcal) Use R = 1.9872 cal/mol-K (a) Calculate the value of AG" at 25°C for the ionization reaction. We [161-4 Keil - C1465 vcoil = ~.4 Kea BS [2ocais -[Svcai} = socal x Maal = -0.03 Kcal OG°= Od°- TAS? = C0 veal) — (25°42 721€) (0.08 teal) * =0.4 = (- 9.44) - [234 ca \ (b) Calculate the value of K at 25°C for the ionization reaction. AG* -Rr Ink (282) 2.544 veal = - (1.9972 ALN C5200) In K 250 ca, = — 692.182 (in ¥) oe ee k= e*= 0 pied = [.etxt0) Ue pecouprtortheigh ization fi and\orf\present,