Adva PII Sol PDF

FIITJEE
AITS-CRT-IV-(Paper-2)-PCM(S)-JEE(Advanced)/14
JEE(Advanced)-2014
ANSWERS, HINTS & SOLUTIONS
CRT IV
(Paper-2)
ALL INDIA TEST SERIES
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Q.
No.
1.
PHYSICS
CHEMISTRY
MATHEMATICS
A, B, C
2.
A, C
3.
4.
A, B, D
5.
B, C, D
A, C
6.
7.
8.
A, C
A, C, D
C
C
A, B
A, B, C
A, B, D
B, D
9.
10.
11.
12.
13.
14.
15.
16.
17.
18.
19.
20.
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website: www.fiitjee.com
Physics
2.
3.
PART I
T sin = mg/2
T = T cos
mg
mg
=
cot
2
2 tan
T cos
1
mv 2 pt (P = const)
2
2Pt
v=
m
a=
dv
dt
F = ma =
5.
T sin
2P 1
m 2 t
mP
1
2t
v

F F1 F2 F3 F4 F5
F2 F5 and F2 F4
F1 F3 2F2 cos 30 2F1 cos 60

Gm2
Gm2
Gm2
F3 =
;
F
=
;
F
=
2
1
4a2
3a2
a2
Gm2 5
1
2
F=

= m a
2
4
a
3
=
m
F3
F2
F4
F1
m
F5
Gm 5
1
3
a 4
3
T = 2
4 3a3
Gm 5 3 4
6.
g L x gL
7.
vp x 5 , v p y 5
d
xu
dt
5 2 = 7.1 m/s approx.

8.
1600 10 6
= 4 m/s
4 10 4
1600 106
vQ
= 8 m/s
2 104
1
PA PB A v Q2 vP2 gh
2
vP
11-12. Let the point of suspension is origin(O), then C.M. lies on

vertical line when it is in equilibrium position.
m(0) m(L / 2) m(L)
xcm =
= L/2 and
3m
m( L / 2) m( L) m( L / 2) 2L
ycm =
3m
3
L/2
tan =
= = tan-1 (3/4) or 370
2L / 3
2
2L L
2
d =
3 2
5L
d=
6
m
2/3
5/6
/2
x
/2
2 2 2 m 2
Moment of inertia I = Mk2 = 4m

= 3m2
12
4
2
3
(Assume full square and calculate moment of inertia about origin and subtract the moment of
inertia of fourth rod.)
I
6
Time period of a physical pendulum = 2
= 2
sec
mgd
5g
13-14. F = qvB sin = qvB ( = 90)

F
3.2 10 20
So, B =
=
= 5 10-7 T
19
3
qv
1.6 10 4 10
I
I
p q
Now, 0 5 10 7
2 5 2
I = 4 amp.
If the distance of point R from third current carrying current is X, then
BR = 0
0 2 2.5
5 107 0
4
so x = 1 m
16.
dv
dv
2(r+dr)
dr
dr
dv
P(2r)dr = 2 dr
dr
2v 0 r
P(2r) = 2
2
R
2v 0
P=
R2
P(2r)dr = 2r
Chemistry
PART II
SECTION A
8.
(D) is incorrect, since Gabriel method is used to prepare 1o aliphatic amines.
10.
Bottles 1, 2, 3, 4 have Pb(NO3)2, HCl, Na2CO3 and CuSO4.
When mixing:
Bottle 1 + Bottle 2 PbCl2
Bottle 1 + Bottle 3 PbCO3
Bottle 1 + Bottle 4 PbSO4
Bottle 2 + Bottle 3 CO2
Bottle 2 + Bottle 4 No visible reaction
Bottle 3 + Bottle 4 CuCO3
12.
Li N2
N2 O2
Li
Li2 O Li3N
H2 O
LiOH NH3
H2 O
LiOH
Solution for the Q. No. 15 & 16

OH
C 2H5 I
Sn HCl
NO 2
NO 2
B
OSO 2Ph
OC 2H5
Ac 2 OH AcOH
NH2
C
HN C
D O
Me
NaF/DMSO
NO 2
E
20.
OC 2H5
OC 2H5
NO 2
F
(P 2) oxalic acid dehydrate, loses H2O when treated at 105oC.

o
o
(Q 3) when heated at 200 C or when refluxed with H2SO4 at 90 C, it decomposes into CO2, CO,
HCOOH and H2O.
(R 4) malonic acid on heating with P2O5 loses H2O and forms carbon suboxide.
(S 1) oxalic acid is oxidised by KMnO4 to CO2.
Mathematics
PART III
HINTS AND SOLUTION
1.
Put x2 = t
2
1 t t2 t2
I
e te e 2t 2 et dt
2
a b
8
k and sec 2 A
2 3
5
5
cos2 A
8
5
c 2 10k 2 , k 2
2
2.
We have
4.
tan 1 2 3
tan tan
1 tan tan
1
7.
8.
a 1 b
1
1 b a
x if x [1, 2)
f x
if x (2, )
x
Clearly, A = (2 cos 60, 2 sin 60)

B = (2 cos 60, 2 sin 60)
Tangent at A is x(2 cos 60) + y(2 sin 60) = 4
and tangent at B is x(2 cos 60) + y(2 sin 60) = 4
P 3, 1
2
x
60
30
2
B
9.
Since, parabola is above xaxis

D = a2 4 0
Thus, amax = 2
10.
Equation of tangent at (0, 1) to the parabola is y 1 = a(x 0)
11.-12. az bz c 0
az bz c 0
Eliminating z from (1) and (2)
..... (1)
..... (2)
b 2 a 2 z ca bc
Adding (1) and (2) a b z a b z c c 0
This is of form Az Az B 0
2x
2x
1 e 1 e 1
2 e2x 1 e2x 1
So, f(x) = e2x + 1; g(x) = e2x 1
13.-14 Here, e A
/2
cos t f t dt sin x
15.-16. f x sin x
f(x) P sin x = sin x

or f(x) = (P + 1) sin x
/2
Where P
cos t f t dt
0
/2
cos t P 1 sin t dt
0
P 1
2
/ 2
sin2t dt
0
P 1
P
P
2
2

f x
1 sin x 2
2
sin x = 2
[1, 3]
/2
2
sin x dx 3
2

20.
4
3
(P) 2(F(x) f(x)) = f 2(x)

f(x) f(x) = f(x) f(x)
f x
1
f 'x
1
1 f x
1 f x
f(x) is an increasing function
(Q) 21 f(5) f(2) 28
x2
(R) y 2
2x 3x 6
1 1
y ,
13 3
x
(S) y = e cos x
x
x
x
y1 = e sin x e cos x = e sin x y
x
x
y2 = e cos x + e sin x y1
y4 + 4y = 0
k=2

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FIITJEE

ALL INDIA TEST SERIES

F1 F3 2F2 cos 30 2F1 cos 60

5 2 = 7.1 m/s approx.

11-12. Let the point of suspension is origin(O), then C.M. lies on

13-14. F = qvB sin = qvB ( = 90)

Solution for the Q. No. 15 & 16

(P 2) oxalic acid dehydrate, loses H2O when treated at 105oC.

Clearly, A = (2 cos 60, 2 sin 60)

Since, parabola is above xaxis

Equation of tangent at (0, 1) to the parabola is y 1 = a(x 0)

f(x) P sin x = sin x

(P) 2(F(x) f(x)) = f 2(x)

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