OF HIGH-PERFORMANCE
FIBRE
GUIDED BY:
SUBMITTED BY:
SOUMYA
SMARAK
CONTENTS:
1.
03
ABSTRACT
2.
04
INTRODUCTION
KEVLAR
AS
R E S I S TA N C E
CUT
INTRODUCTION:
Each year, millions of workers suffer workplace injuries that
could have been prevented. Some of the most common and
preventable injuries are cuts and lacerations. Although
statistical data differs from study to study; cuts and lacerations
often rank as the second or third most frequent workplace
injury. Approximately 30% of all workplace injuries involve cuts
or lacerations, and about 70% of those injuries are to the hands
or fngers which prompted development of protective gloves
and sleeves. The conventional means of protection were wire
mesh steel gloves, leather gloves and gloves made of some
alloys. Equipment for protection against fre, ballistic, chemical,
biological, nuclear, fall and cut injury. Higher strength to weight
ratios of these polymers is the major advantage over
conventional metals of steel, and alloys.
Most of these polymers are pliable, fexible and possess textile
characteristics making them easy to fabricate and ideal to
wear.
After the invention of high performance polymers and
materials, considerable research has focused on personal
safety equipment, carried out initially for the military and later
extended to occupational safety, has been done.
Characteristics,
applications
selection for cut resistance:
and
1960s by chemist Stephanie Kwolek, who earned a patent for her invention
with Paul Morgan in 1966.
STRUCTURE OF KEVLAR:
There are two main stages involved in making Kevlar.
First you have to produce the basic plastic from which Kevlar is
made
(a
chemical
called poly-para-phenylene
terephthalamideno wonder they call it Kevlar). Second, you
have to turn it into strong fbres. So the frst step is all about
chemistry; the second one is about turning your chemical
product into a more useful, practical material.
Polyamides like Kevlar are polymers (huge molecules made of
many identical parts joined together in long chains) made by
repeating amides over and over again. Amides are simply
chemical compounds in which part of an organic (carbonbased) acid replaces one of the hydrogen atoms in ammonia
(NH3). So the basic way of making a polyamide is to take an
ammonia-like chemical and react it with an organic acid. This is
Modulus,Gp
a
70
135
55
99
Tenacity
20-23
20-26
N/A
N/A
143
18
17
5.8
How Kevlar
fibres?
is
stronger
than
other
WHAT
MAKES
KEVLAR SUCH A
GOOD
ANTIBALLISTIC
MATERIAL?
Figure(6) which shows two
brave fighter fight with each
other
and
wearing
good
antiballistic cloth for their safety:
Isophthalamide)
(MPD-I),
poly
(para-phenylene
terephthalamide) (PPD-T), polybenZimidaZoles (PBI), polyphenylene benZobisoxaZole (PBO), and/or blends or mixtures of
those fbre. For improved abrasion resistance, the body
fabric yarn components can have in addition to the fre
resistant fbre up to 20 per cent by Weight nylon fbre,
preferably less than 10 percent by Weight. The body fabric yarn
components are preferably staple yarns containing 60 weight
per cent PPD-T fbre and 40 Weight per cent PBI fbre. The
preferred form and size of the body fabric yarn component is a
plied yarn of the above composition having a cotton count in
the range of 16/2 to 21/2.
The cut-resistant yarn component of the fabric is
useful in providing both cut resistance and tear strength to the
fabric. The cut resistant yarn component contains at least one
cut resistant ply-twisted yarn comprising a frst multiflament
yarn of continuous organic flaments having a twist in a frst
direction plied with a second yarn comprising 1 to 5 continuous
inorganic flament(s). The frst and second yarns are plied
together in a second direction which is opposite to the frst
direction. It is preferred that the cut resistant yarn component
contain flaments which are fre-resistant. Suitable fre-resistant
flaments include those made from aramids such as poly (paraphenylene terephthalamide) (PPDT), poly (meta-phenylene
isophthalamide) (MPD-I), and other high strength polymers such
as poly-phenylene benZobisoxaZole (PBO) and/or blends or
mixtures of those fbre. The preferred fre resistant and cut
resistant fbre is PPD-T fbre. The yarn can also include some
fbre of other materials to the extent that decreased cut
resistance, due to that other material, can be tolerated. The cut
resistant yarn component can also have, incorporated in the
multiflament continuous flament yarn, or in the plied yarn as a
separate entity, up to 10 Weight percent and as much as 20
percent by weight nylon fbre for improved abrasion resistance.
The total denier of the cut resistant yarn component may be in
the range of 320 denier to 1400 denier and the denier of
continuous organic multiflament yarns suitable for use in the
cut resistant yarn component may be in the range of
200-1000 denier. The continuous organic multiflament yarn is
plied with a yarn containing 1 to 5 continuous inorganic
flaments. Inorganic flaments useful in this invention include
glass flaments or flaments made from metal or metal alloys.
TEST METHOD:
CUT RESISTANCE(g)
TTP(cal/cm^2)
Graph(1)
fibres
GRAPH 2
469
42
715
39.3
GRAPH 3
WOVEN FABRICS
METHODS
FABRIC SAMPLES
Fabrics of different constructions are
set and made from 100% cotton yarn were selected for
determining the cut resistance, so as to fnd the effect of weave
pattern and fabric tightness on cut resistance. The type of
weaves selected were plain, 3/1 twill,2/2 matt and 8 end
honeycomb weave . Out of this, 3/1 twill weave was selected
and fabrics of different picks per inch were constructed so as to
observe the effect of fabric cover factor on cut resistance. To
study the effect of fbre material on cut resistance fabric woven
from Kevlar, HDPE, NYLON mono flament and multi flament
yarns were chosen.
TEST METHOD
Counting glass was used to count the end and pick densities
and an average of 10 reading were taken.
TABLE 5
The linear density of warp and weft yarns form fabric war
determined using the Beasley balance. An average of 5
readings was taken to determine the fabric weight per unit
area, the fabric sample of 10cmX10cm was weighed on an
GRAPH 4
GRAPH 5
KNITTED FABRICS:
FABRIC
PENETRATION ANGLE:
With the penetration angle changed, the knifes stab
met with different parts of stitches, some of which were
stretched and cut directly, playing an important role in resisting
the penetration. Other parts produced corresponding deformation and decided the yarns slippage ability.
When the knife penetrated at an angle of 0, the
slit extended along the length. Mostly underlaps between the
wales came into contact with the edge of the knife, stretched
and suffered a direct cut. The loops shrank at the same time.
When the knife stabbed at an angle of 90, the slit extended
transversally. The legs of the loops became the main part to
bear the force, becoming displaced and cut directly. When the
penetration angle was changed to 45, the underlaps of one
bar may be parallel to the knife and have little effect on the
stab resistance. In contrast the underlaps of the counter
lapping guide bar played an important role in resisting the
penetration.
CUT:
STRUCTUR
E2
(CREPE)
PES HT
PA HT
PP HT
UHMW-PE
p-AR
3
3
1
4
5
1
1
1
4
2
2.4
2.1
2.1
3.4
10.9
7.1
5.4
1.9
15.4
21.1
STRUCTUR
E3
(MOSS
TUCK
STICH)
4
10.5
2
3.4
2
4.5
5
33.4
5
48.4
ACKNOWLEDGEMENT
We would like to express our deep gratitude to Asst. Professor Dr. Rajesh Mishra
for their patient guidance, enthusiastic encouragement and useful critiques of this
project work.
We would like to thank our mentor Ing. Kasthuri Venkatesh for her advice and
CONCLUSION:
Kevlar is now being used in many high end
products, but still has a large usage and made very fast foray
into a vast range of products. This is all due to the virtue of the
properties it possesses. And in very near future Kevlar is going
to be used commonly in all work of life. From the above we
found that for the cut resistant, the count of the Kevlar should
be in between 150-170 Tex. i.e. count of Kevlar 29 found to be
167 Tex and count of Kevlar 49 is found to be 158 Tex. And also
we noticed that plied twisted yarn is more preferable than the
composite yarn as the plied gives more flexible and more
comfortable to fill.
The study on the effect of weave pattern on cut
resistance reveals that the plain weave has the maximum cut
resistance, while the minimum cut resistance is exhibited by
honeycomb weave. The study on the effect of fabric tightness
on cut resistance increases with increase in picks/inch of the
fabric. The study on the cut resistance of some high
performance fabrics shows a very high cut resistance of the
Kevlar fibre and the least cut resistance by nylon multi filament
along the warp direction and least cut resistance is shown by
HDPE fabric along the weft direction. So, from the above
observations we conclude that Kevlar has a very high cut
resistance and is the most appropriate fabric to be used for
protective clothing. warp knitted fabric was deformed,
stretched and cut during knife penetration. The primary
destruction of it was the breaking of yarns by cutting and
following stitch disassembly.
It was proved that the lapping, density of the take
down and the areal density were the factors which influenced
the stab resistance of warp knitted fabric. The fabric with
longer underlaps, regardless whether on front or back bar, had
better performance in resisting the stab. The fabrics with
longer underlaps on the front guide bar performed better than
those with the same length of underlaps on the back guide bar.
Although the tight structure was highly beneficial in resisting
the knifes puncture, appropriate stitch deformation of
moderate loop density led to the gathering of more yarns to
resist the knife cut, thereby restricting further knife
penetration. The specific maximum load and penetration
REFERENCES
Autex
Research
Journal,
4,
1418.
Retrieved
from
http://www.autexrj.org/No1-2004/0079.pdf
Flambard,
X.,
Ferreira, M., Vermeulen, B., & Bourbigot, S.(2003). Mechanical
and thermal behaviors of first choice, second choice and
recycled p-aramid fibre. Journal of
Textile and Apparel, Technology and Management, 3(2), 1
35. Retrieved from http://www.researchgate.net/publication/
228680152_Mechanical_and_thermal_behaviors_of_first_
choice_second_choice_and_recycled_p-aramid_fibre Fritzsche,
F. R., Dietel, M., Weichert, W., & Buckendahl, A. C.
36. Garcia V (2014) Sediment distribution patterns on the
Galicia-Minho continental shelf.
37. Xuhong M, Xiangyong K, Gaoming J (2013) The
experimental research on stab resistance of warp-knitted
spacer fabric. Journal of Industrial Textiles 43: 281-301.
38. Flambard X, Polo J (2004) Stab resistance of multi-layers
knitted structures. J Adv Mater 36: 30-35.
39. Xiaolin Y, Guanxiong O, Yaming J (2011) Research on the
stab resistant
mechanism of the weft knitted fabrics. TianJin University, China.
40. Lijuan L, Gaoming J, Xuhong M (2011) Structure and
properties of stab
resistant warp knitted fabric. J Text Res 32: 48-51.
41. Spencer DJ (2001) Knitting Technology: A Comprehensive
Handbook and
Practical Guide (3rd edn.). Woodhead Publishing Limited,
Cambridge,
England.
42. Triki E, Nguyen-Tri P, Gauvin C, Azaiez M, Vu-Khanh T, et al.
(2015) Combined puncture/cutting of elastomer membranes by
pointed blades: Characterisation of
mechanisms. Journal of Applied Polymer Science.
43. Miao X, Jiang G, Kong X, Zhao S (2014) Experimental
Investigation on the Stab Resistance of Warp Knitted Fabrics.
Fibres & textiles in Eastern Europe5 65-70.
44. El Messiry M (2014) Investigation of Puncture Behaviour of
Flexible Silk Fabric Composites for Soft Body Armour. Fibres &
textiles in Eastern Europe 5: 71-76.
45. Gong X, Xu Y, Zhu W, Xuan S, Jiang W, et al. (2014) Study of
the knife stab and puncture-resistant performance for shear
thickening fluid enhanced fabric.
Journal of Composite Materials 48: 641-657.