StuartShelf-AdelaideGeosynclineCopperProvince,SouthAustralia
IAN B. LAMBEBT,JANICEKNUTSON,T. H. DONNELLY,AND H. ETMINAN
BaasBeckingGeobiological
Laboratory,GPO Box378, Canberra,A.C.T.2601,Australia
Abstract
Coppermineralization
of severaldifferenttypesformedin the Stuartshelf-Adelaide
geosynclineregionfromthe middleProterozoic
to the earlyPaleozoic.
Hydrothermal,
unconformity-related,
andbeddeddeposits
havebeendistinguished
andthesearediscussed
in the
lightof the geologicevolutionof the province.
The basementrocksbeneaththe Stuartshelfwere metamorphosed
and deformedduring
theKimbanorogeny,
commencing
about1.82b.y.ago.Betweenapproximately
1.63and1.51
b.y.agotherewasmajorbimodalalkali-rich
igneous
activity,accumulation
of volcano-sedimentarygrabensequences,
andhydrothermal
activity.Duringthisperiodthelargestcopper
(gold,uranium)depositin the region,OlympicDam,formedfromhydrothermal
fluidsin a
grabensequence
andotherimportant
middleProterozoic
hydrothermal
copper(gold)mineralizationformedin fracturezonesin feldsparporphyryandschists
at MoontaandWallaroo.
In thelateProterozoic
(Adelaidean),
the Stuartshelfwasa stableplatformonwhichonlya
few hundredmetersof sedimentary
coveraccumulated.
Copper(lead,zinc)mineralization
formedin permeable
zonesandis associated
withthe unconformity
at the baseof the late
Proterozoic
sequence
at MountGunson
andelsewhere,
wheremetalliferous
fluidsfrommiddle
Proterozoicred bedsandigneousrocksencountered
biogenicH2Sandpyrite.
To the east,late Proterozoicsequences
locallymorethan 10 km thick accumulated
on
crystalline
basement
in theAdelaide
geosyncline,
whichwasa rift in the earlystages
of its
evolution.
Low-temperature,
beddedanddisseminated
mineralization
formedin thesestrata
wherecupriferous
fluidsreactedwith biogenicsulfide,but suchcoppermineralization
is not
of economic
importance.
The maincopperdepositsin the Adelaidegeosyncline
sequence
wereat Kanmantoo
andBurra,bothof whichareconsidered
to haveformedfromhydrothermal
fluidsduringthe earlyPaleozoic.
Uranium(copper)mineralization
in breccias
in the Mount
Painterinlieralsoappears
tohaveformedprimarilyasa resultofhydrothermal
activityduring
or afterthe earlyPaleozoicDelamerianorogeny.
The largestof the copperdeposits
in thisregion,regardless
of type or age,fall on two
alignments
subparallel
to themajorfaultzoneseparating
theStuartshelffromthevariably
metamorphosed
anddeformed
sequence
of theAdelaidegeosyncline.
Thisimpliesa general
regionaltectoniccontrolon ore formation.
(e.g.,Rowlands
et al., 1978),noneof whichhasbeen
Introduction
COPPER
miningin Australiacommencedin the Adelaidegeosyncline
in 1842, followingthe discovery
of
secondaryore in late Proterozoicrnetasediments
at
Kapunda(Fig. 1). Numerous
otherdeposits
werediscoveredin the Adelaidegeosyncline
andStuartshelf
regionsin the remainderof the nineteenthcentury
(Dickinson,1953a; Thomson,1965; Johns,1975).
Most of these were small,but there was protracted
mining at Kapunda, Burra, Blinman, Kanmantoo,
Moonta-Wallaroo,andMount Gunson(Fig. 1 andTable 1).
After a long period of little explorationthe late
1960ssawan upsurgeof interestin the potentialfor
buriedsediment-hosted
deposits
in thisregion,largely
becauseof increasing
recognitionof ageandlithological similaritieswith the Zambiancopperbelt (e.g.,
Rowlands,1974). The 1970s saw the discoveryof
Zambian-style primary mineralization at several
stratigraphic
levelswithin the late Proterozoicstrata
0361-0128/87/638/108-16$
2.50
geosyncline
provinceandto integratethesefeatures
into a metallogenicmodel.
RegionalGeology
10 8
STUART SHELF-ADELAIDE
GEOSYNCLINE Cu PROVINCE
138
...I",,x
Middle Proterozoicunmetamorphosed
sequences
-...
-..,/..'..':;;
''
l ate f-:.:-:-:-:.:-:-:.:.
:-:-:-:
'*'
,,
,.__.
,.^' ,,
'..'.'',
.
\- d,
E....
01
' 'ake '*
b---i-
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". -'.':
"'BI....
' ''"
In
::i.:'/2'"'"'"'"'"'""'""'"'""
l.:.?Frome.'.'.'.'.'.'.'.:.:.'.'.'.'.
"
,,z".
'-':"t-'T''*-'-'-C
]':':';':':':':':':':':431
I':-.":';'.'-;-:-:':-:-:':';';-;-:':':-;-:-:':l
Gunson
%'
STUART
'
;:'
.'
:.:
;-,"..
- L,.\
.
/
Q'd..', Ra '---Zr-f
'4
7,,-
GEOSYNCLINE
-.-:-:-.'::::::.:
................:..
/':-...'-.'-:-o'-''-'.....
-:
',,I
:-.-.:.'.:-..'
""; f
RadiumHdl'U,,
I"'.;,-*,
;.:'-.-','/.!
;X'/
The widespread
GawlerRangeVolcanics
andpostorogenic
granites
oftheGawlercraton(Fig.2) formed
around1.63 and 1.51 b.y. ago,respectively(Cooper
et al., 1985;Fanninget al., 1986).The volcanics
are
predominantly
daciticto rhyodacitic,
butbasaltic
units
are also found in someareas.Penecontemporaneous
or youngervolcano-sedimentary
graben sequences
cropoutlocallyandhavebeenencountered
in drilling
throughcoverrocksatOlympicDamandin theMount
: i.:.:.:.:.:.:.:.:.
'2.',
109
Burra
'-.'.-:-:.
'--.-' .'>:-:-..
Late Proterozoicsequences
.:-:-:-:-:.:.:-:-:-:-:.:.:-:-:-:.:.:.:.:-:-;
b".".'.'.'.'.".'.'-'.'-'.'.'-'-'-'-'.'.".".',
........
I
(/L--/.J
-' ....
e>Kanmantoo'-'.-'-'....:-'..:-:-:.'.-:-:-
/ ':'."'...'-'..'::::::
5
-' '"'"'"
h
"'"'""'"'
':"':''': :':
::..
::.
16/SA/22
::ZYounger
cover
- Late
Proterozoic
to
Metamorphic
basement
Cambrian
strata
ited sedimentaccumulation.The preservedAdelaideancoversequencevariesin thicknessup to a maximumof about800 m. In contrast,the Adelaidegeosynclinewasthe siteof a majorrift duringthisperiod
(Rutlandet al., 1980; von der Borch, 1980) and sequencesat least 10 km thick accumulatedin the
deeplysubsiding
basin.The Torrenshingezone(Figs.
1, 2) separates
the shelfandgeosyncline.
Featuresof
the lateProterozoicstrataof the Adelaidegeosyncline
andStuartshelfare the paucityof deep-watersedimentaryfacies,relativelyminorvolcanism,two major
tillites, and the occurrenceof strata-boundcopper
mineralization
at various levels.
toidsduringtheearlyProterozoic.
Laterin the early
Proterozoic,a predominantlysedimentarysequence
containing
iron-formations
wasdeposited,
andthiswas
metamorphosed
andintrudedby granitoids
duringthe
Kimbanorogeny,commencingabout 1.82 b.y. ago
(Webb et al., 1982). To the east,the Willyamainlier
(Fig.2) wasmetamorphosed
at ca.1.65 b.y. ago(Gulson, 1984).
b.y. ago,but Pageet al. (1984) reinterpretedthe RbSr data for the leastaltered samplesto indicatean
ageof around1.2 b.y. Over large areasof the Stuart
shelf,the PandurraFormationis cut by a swarmof
northwest-trendingdikes which probably formed
contemporaneously
with the BedaVolcanicsduring
crustal extension.
110
......
i-i.'-i-;-''-'-i-''"''-'-''''i
31
STUART
SHELF
/-/
ADELAIDE
Ill GEOSYNCLIN
I
1O0 km
16/SA/23
Younger
cover
Late
Proterozoic
toCambrian
strata
Mid
Proterozoic
Gawler
Range
Volcanics
Metamorphic
basement
Early
Palaeozoic
underformed
graniteiris
Mid
Proterozoic
uncleformed
graniteiris
Carbonatebreccia("diapirs'
Major faults
acterizedby fluvialanddeltaicclasticsandstones,
and
interspersedstromatoliticdolomitesandsedimentary
magnesiteare interpretedas havingformedin carbonate pansin pluvial environments(e.g., von der
sedimentation on the Stuart shelf or no strata of this Borch, 1976; Uppill, 1983).
In the Adelaide geosyncline,the Umberatana
cyclehavebeenpreserved.The BurraGroupis char-
STUART SHELF-ADELAIDE
GEOSYNCLINE Cu PROVINCE
111
SOUTHERNSTUARTSHELFNORTHERN
STUARTSHELF
(MOUNT
GUNSON) ADELAIDE
GEOSYNCLINE
zo
.....
./-
// / / 11
// // // o
EDIACARA
FAUNA-****
/
z
0
...................... . ..
'*'MARINOANGCIALS
.'.'.'.'.'.'.'.'.'.'.'.'.'.'.'.'.'.'.'.'.'.'.'
.....
:o.7
'','
._, '?'',',''-''
{
...
i'i'..,..
.....-
r U':'-?(. ,
GAWLE GEVOLC
15 b )-
'
SEDIMERRABEN
. .z..4.
J..4
. .
,,...".,:':L..'
16/SA/24
clasticsand
Group(thirdunit)isseparated
fromtheBurraGroup Group, comprisesquartzo-feldspathic
by a disconformity
or angularunconformity,
andit minor carbonatesdepositedunder shallow-waterto
hasglacialsequences
top andbottom.The ca. 0.75- emergentconditions.
Intrusive breccias are common in the Adelaide
b.y.-old(Webbet al., 1983) interglacial
TapleyHill
Formation is the first Adelaidean unit found exten- geosyncline
(Preiss,1985;Fig. 2). Manyof thesehave
sivelyon the Stuartshelf.It accumulated
in a variety been interpretedas havingformedby diapiric emofenvironments,
fromemergent
tobelow-wave
base. placementof evaporite-richCallannaGroup strata;
Betweenthe Tapley Hill Formationand the upper deformationof CallannaGroupandoverlyingstrata
glaciogenicstrata, mudstones,sandstones,
and car- in decollementprocesses
and sedimentationaround
tectonically
activebasement
highshavebeeninvolved
in some cases.
112
LAMBERT,KNUTSON,DONNELLY,AND ETMINAN
CopperMineralization
Hydrothermaldeposits
Size
Estimated ore: 450 million metric tons,
metric tons
Status
Closed 1923
Hydrothermal structurallycontrolleddeposits
in deformed early to middle Proterozoic
porphyry and schist
Almostmined
out
Unconformity-relatedmineralizationinfilling
brecciazone alongunconformitybetween
Cu (+ Au)
Cattle Grid
(Mt. Gunson)
(subeconomic
Pb, Zn)
Nature of mineralization
Closed 1982
Closed1976
Blinman
Closed 1918
dolomitic
Kapunda
Closed 1912
near uncon-
peripheralPb, Zn
Copper Claim
SubeconomicCu
STUART SHELF-ADELAIDE
GEOSYNCLINE Cu PROVINCE
113
indicatewiderangesof salinities
(from0.5-14.3 equiv
wt % NaC1,avg 7.5%) in both typesof ore. In view
of the hydrothermalalterationunderreasonablyoxidizingconditions,
the preliminarysulfurisotopedata
are consistent
with a magmaticsulfurcomponentin
theOlympicDammineralization.
The34Svfthle$
for
sulfidesfromboth ore typesconcentratein a narrow
negativerange(-5 to -11%0)andbariteiS4S
ValUeS
are positive(4.6-13%0).
absent.Mineralization
occursin a northwest-trending Moonta-Wallaroo:Poor outcropand complicated
grabenwhich containsthick middleProterozoicse- Proterozoicgeology have resulted in uncertainties
quencesof coarseclasticunitsand lessabundantal- aboutstratigraphic
correlations
andore genesis
in this
tered felsic volcanics and iron-formations. The coarse old miningarea (Dickinson,1953b; Johnson,1965),
clasticsrangefrom matrix-richpolymictbrecciasto the largestproducerof copperin the provinceto date.
brecciasdominatedby alkali feldspargranitefrag- The mainrock typesbeneaththe thin coverof Cainments;the uppermost
unitcontains
recycledbreccias. ozoicand Cambrianstrataare schists,amphibolites,
In structuralzonesthereare massivecrosscutting
he- and iron-formations
of early Proterozoicage, which
matite-richbodies,intrusivepolymictbreccias,anda havebeenintrudedby feldsparporphyriesandpostvariety of igneousdikes.Thesediscordantunitsex- orogenicgranitesand pegmatites.Most porphyries
hibit evidencefor multiplehydrothermal
eventsand arefoliatedandclearlywere emplacedbeforeor durhydraulicbrecciation.
Thereiswidespread
hematite, ing the Kimbanorogeny.
chlorite,sericite,andsilicaalterationofthe sequence The Moontaore shootswere largelyundeformed
andlocalpotashfeldsparandcarbonatealteration.
tabularto pipelikebodies.Theyformedmainlywithin
The coppermineralizationoccursas strata-bound arcuatefracturezonesin reddish(finely hematitic)
and transgressive
types,both of whichcontainrare feldsparporphyry.Theycomprised
chalcopyrite
and
disseminated
throughthe brecciamatrix, and clasts
of sulfidesup to severalcentimeters
across
alsooccur.
Texturesindicatea complexparagenesis
of sulfides
andhematite;replacement
andmicrocavity
fillingare
common,as are rock clastscontainingdisseminated
sulfides and sulfide rims. The strata-bound ore is
elsthanthestrata-bound
ore.It comprises
high-grade
zonesassociated
with irregulardiscordanthematite
and polymictbrecciabodies,and lower grademineralizationin relativelythin, discontinuous
veins.
Reconnaissance
fluid inclusionand sulfurisotope
studieshavebeenundertakenon OlympicDam mineralization(Robertsand Hudson,1984; D. Roberts,
oralcommun.,1984).Thefluidinclusion
datasuggest
involvement of fluids of different salinities and tem-
the majorregionalmetamorphism.
Mount Gunson area: In the Mount Gunson area,
the ca. 500-m-thick Pandurra Formation is underlain
unconformably
by some500 m of a hydrothermally
alteredsequenceof tuffs,siltstones,potassium-rich
mafic,intermediate,and felsicvolcanics-high-level
peraturesandpossible
boiling.Homogenization
temperaturesfor inclusions
in fluoriteand quartzasso- intrusions,and"calc-silicates"
(Knutsonet al., 1983a,
ciated with sulfides are variable in both strata-bound
and in prep.; Donnellyet al., 1983). At the baseof
114
115
ization(talc, chlorite,and mica at depth), moderate zone and decreases downward as the brecciation dies
faultsand
abundances
of feldspars,tourmalineandpyrite, and out. Prominentnorth-northwest-trending
minor chalcopyriteandbornitc (Wright, 1975). The jointsare mineralizedmoreintenselyandto greater
ore wassecondary,occurringmainlyin two irregular depthsthanadjacent
rocks.Sulfidemineralsalsoparenrichedzonesin a blockboundedby north-north- tially replacematrix claysand quartz and feldspar
west to northwest-trendingfaults.The main copper grainsin the brecciaclasts.
mineralsmined were malachite,cuprite, and chalMostof the copperminedfromthe unconformity
cociteandthe ganguemineralswere calcite,asbestos, has come from the Cattle Grid deposit(Gersteling
talc, andquartz.A smallquartzfeldsparintrusionand and Heape, 1975; Creelman1983; Knutsonet al.,
analteredrockresemblinganagglomeratehavebeen 1983b),a tabulardepositaveraging4.5 m thick.The
documentedfrom the vicinity of the mineralization. principalsulfidesin the Cattle Grid ore are minerals
The mineralizationhasbeenregardedassyngenetic- of the chalcocite-digenite-djurleite
series,bornitc,
remobilized (Thomson,1963; Johnson,1965) and chalcopyrite,and pyrite. Sphalerite,galena,marcaepigeneticrelatedto igneousactivity(Wright, 1975; site, covellite, bravoitc, and carrolite are minor comJ. Drexel, oral commun.1984).
ponents.
Thereistexturalevidencefor somereplacementof ironandcopper-ironsulfides
by progressively
Unconformity-related
deposits
morecopper-richphases(andsphalerite).Sequential
PandurraFormation-WhyallaSandstone:
Copper precipitationof the sulfidemineralsoccurredin fracmineralizationoccursin the uppermostPandurra turesandvugs,with the mostcopper-richminerals
FormationandbasalWhyaliaSandstone
in the Mount (andsphalerite-galena)
forminglate in the paragenGunson-Pernatty
lagoonareaof the Stuartshelf.Here esis.The mineraltexturesimplythattherewasa comnorth-northwest-trending
blocksof upfaultedPan- plex historyof deposition,dissolution,
redeposition,
durra Formation, in excessof 500 m thick, formed a andreplacement.
Smallquartzcrystalscoatedby suldepositional
highduringthe Adelaidean,the so-called fidesin the Cattle Grid deposithavebeen reported
Pernattyculmination(Figs.3 and4). The TapleyHill to containCaC12-richfluid inclusionswith homogeFormationislocallyabsentoverthisstructure,sothat nization temperaturesaround 120C (Busbridge,
Whyalia Sandstonedirectly overlies the Pandurra 1981). However, it is uncertainwhether suchfluids
Formation.Brecciation,silicification,and Liesegang were involvedin generationof part of the mineralbandingoccurto varyingdegreesin the uppermost ization;theymayhaveformedearlierduringintrusion
PandurraFormation of the culmination,reflecting of the regionaldolerite dike swarm.
prolongedexposurebeforedepositionof the Whyalia
Knutsonet al. (1983b)showed$34Svaluesfor the
Sandstone.Structuresindicativeof periglacialcon- Cattle Grid and other depositsalongthe Pandurra
ditions have been recognizedalong the Pandurra Formation-WhyallaSandstoneunconformityin this
Formation-Whyalla
Sandstone
unconformityby Wil- areato be predominantlynegative(-18 to 5%0;Fig.
liamsandTonkin (1985).
5), with no lateral or vertical isotopictrendsand no
A numberof depositshavebeen mined alongthis isotopic equilibrium between adjacent mineral
unconformity.The coppermineralizationmainlyfills phases.In the absenceof evidencefor high-temperin fracturesandvugsin the permeableunconformity aturemineralizingfluids,theseisotopecompositions
arebestinterpretedin termsof influxof groundwaters
carryingH2Sgeneratedby bacterialreductionof sulSW
CattleGrid
N_
Breccia
Pernatty
Lagoon
-.'
:';:,':.'.=,*.
,.,
:":.-,
.-..'-'..',-.'.,
--'.'.:.:
,.::';
v,
BasalTapleyHill Formation:Subeconomic
copper,
lead, andzinc sulfidesare concentratedin relatively
permeablelaminae in the basal few meters of the
Tapley Hill Formation at severallocalitieson the
' Altered
volcano
Copper
mineralization
Veicalexaggeration
ca 7 to I
'".
showed
CattleGridtocontainradiogenic
lead('apb/
4pbbetween20.5 and21.2; 7Pb/4pb
ca. 15.9)
whichplotsin themiddleof a colineararrayof isotopic
compositions
for rock lead from this area. They interpretedtheir datain termsof mixingof lead from
TentHillFm.
' Sandstone
Tapley
HillFm.
fate.
..:.
vv
. ......;
vvv
.,;
vv,
116
TAPLEY
(MT. GUNSON,
IMT GUNSON)
-3
-20
HILL
MYALL CREEK,
KAPUNDAetc.)
-10
10
20
6 34S(CDT)
%0
30
40
50
16/A/33
haveis4S
valuesin a widerangefrom0 to 45 permil
(Fig. 5). There are no significanttrendsrelated to
mineralogy,location,or form of the sulfides.The
concentration of is4Svalues for veinlet minerals be-
TheS7Sr/SSr
ratiosof dolomitefromunmineralized
TapleyHill Formationon the Stuartshelf(>0.710;
antanaGroups,they showno evidenceof hydrothermal alteration,and coppergradesin excessof I percent are very restrictedin occurrence.
Disseminatedcopper sulfides are particularly
commonin CallannaGroupstrata,whichare exposed
mainlyin the WillouranRangesandin the carbonate
breccias,or diapirs,scatteredthroughthe northern
half of the geosyncline(Fig. 2). However, as with
similarmineralizationin the youngerunits,noneof
the knownprimarydeposits
hasprovedto be of eco-
nomic importance.
occurlocallyalongtheunconformity
at the topof the
unit.
STUARTSHELF-ADELAIDE
GEOSYNCLINE
CuPROVINCE
117
pliesthatsomeformedbeforecleavage
development ized units, both of which showwide spreads(13 to
whereas
othersformedduringthelow-grade
regional 23%0for the mineralized,and 10 to 21%ofor the unA positive
3C/blso correlation
exists
metamorphism.
Thedisseminated
sulfides
havea34S mineralized).
dolostones
only.Theseisotope
data
range(-17.3 to 15.8%0)
consistent
withclosed-systemin thecupriferous
bacterial reduction of sulfate;veinlet sulfideshave a indicatethat low-temperatureisotopictrendshave
beenpreservedandthat they are consistent
with innarrowerrange(-12.2 to 9.3%0).
The
mineralized
and unmineralized
carbonate
steeplydippingquartzveins(Johnson,
1965). The
primary mineralizationin the underlyingvariably
carbonaceous
stratahasbeen describedby Lambert
et al. (1981). It occursnearthe top of the TapleyHill
Formationand has been metamorphosedto lowermiddle greenschistfacies.Chalcopyriteoccursas
millimeter-scale
grainsin two local albitic dolosilt-
118
TABLE2.
Region
Stuart shelf
Adelaide
geosync-
line
Middle Proterozoic
Late Proterozoic
Importanttransgressive
and strataboundhydrothermalCu (Au, U)
depositsformedin middleProterozoicvolcano-sedimentary
sequencesand crystallinebasement rocks.Extensionalregime
after Kimbanorogeny;bimodal
alkali-richigneousactivity. Regionalstructuralcontrol on igneousactivity, sedimentation,
and migrationof ore fluids.
Metals and sulfidefrom magmas
and rock leaching
Low-temperaturebeddedand
breccia infill Cu (Pb, Zn) depositsformedalongpermeable unconformityzonesin
stableplatformenvironments.
Mafic igneousactivity pre-
Low-temperature(subeconomic)
beddedCu depositsformedat
varioustimesduring deposition-diagenesis
of rift sequence;remobilization into
to east
ceded mineralization.
Early Paleozoic
Unmineralizedthin sedimentary
cover on stableplatform
Metals
leachedfrom underlyingred
bedsand igneousrocks. Biogenicsulfide,partly introducedin groundwaters.Regional structurecontrol
Largely transgressive
hydrothermal
Cu(U) depositsformedin Cambrian trough strata,late Proterozoic rift sequencesand crystalline
basement rocks. Mineralization
138
119
OE
MG
MC
400 km
16/SA/25
faultingformedthe Pernattyculmination
in the Mount
rich magmas.The altered,predominantlymaficvol- Gunsonarea and there wasextensionto the east,with
canits and intrusions studied in drill core from baseactivefaultingalongthe Torrenshingezoneandin
mentrocksin the MountGunsonareaprovideinsights the Adelaidegeosyncline.
into someof the generalprocesses
which are envisThe mineralizationalongthe PandurraFormationaged to have led to mineralizationand alteration at Whyalia Sandstoneunconformityon the Pernatty
OlympicDam and Moonta-Wallaroo.
Theseigneous culminationis considered
to havebeengeneratedin
rocksappearto havehad high primarycontentsof a numberof stages,noneof whichcanbe relatedto
iron and potassium,and hydrothermalactivity re- igneousactivity. Anoxic waters entering the upper
suitedin migrationof theseelements.Pyrite in this PandurraFormationduringdeposition
of the organicMount Gunsonbasementsequenceat least partly rich mudsof the Tapley Hill Formationwould have
preceded,andwasreplacedby,hematite.The paucity dissolved iron from the red beds. As these waters miof copperin thesealteredrockscouldbe a function gratedto the permeabilitywindowof the culmination,
of low levelsof copperprecipitationfromthe hydro- oxidationwouldhavecauseda build-upof ironoxides,
thermalfluidsbecauseof unfavorablephysicochem- in analogous
fashionto the generationof iron enrichical conditions(for example,low sulfurfugacity)in ments at zonesof emergenceof groundwaters in
the areassampled.Alternatively,there could have modern peritidal environments(Fergusonet al.,
been extensivesubsequent
leachingof copperfrom 1983). Sulfides along the Pandurra Formationthe sequence
to formthe mineralization
in younger WhyaliaSandstone
contact(mainlynegative6$4S
valstrata in this area.
ues)did not formby processes
relatedto pyrite forAlthoughthe mineralizationat OlympicDam is mationin the laterallyadjacentTapleyHill Formation
120
(rangeof positive34Svalues).The sandysediments strataimply that the metalliferousfluidswere domiwhich accumulatedabovethe Tapley Hill Formation
are consideredto have channelledreducingground
waterscontainingbiogenicH2S to the culmination,
wheretherewaspartialconversion
of the iron oxides
to iron
sulfides.
Metal-enriched
fluids
ascended
and enrich-
Pandurra Formation-WhyallaSandstonedepositsis
suggestedby spatial associations
and similar minor
metalcontents.The metalswere fixedin the Tapley
Hill Formationby reactionwith pyrite andH2Sgeneratedby bacterialsulfatereductionwithin thisunit.
The copper mineralsand pyrite in the Tapley Hill
bedsandthe underlyingmiddleProterozoicvolcanosedimentary
strata.The presenceof earlyAdelaidean
dolerite dikesraisestwo possibilitiesfor generation
of metal-enriched
121
122
LAMBERT,KNUTSON,DONNELLY,AND ETMINAN
The chances
for majormineralization
of thistypemust
decreasewith extensiveperiodsof exposureanderosion,during which there couldhave been considerable depletionof metalsfrom the sourcerocks.
Known bedded copper depositsin the Adelaide
geosynclineare of muchlower gradethan the main
Africancopperbelt deposits,whichoccurnear the
base of the late Proterozoicsequenceswhere evaporiticstrata,carbonaceous
shales,andsandstones
are
onlapsof basementhighs.Analogouspositivebasementstructures
havenotbeenprovenduringCallanna
Groupdeposition.The possibilitythat somebreccia
domesin the northernAdelaidegeosyncline
formed
as a result of sedimentationat structurallyactive
basementhighsdeservesdetailedassessment
because
such environments offer the best chance of bedded
mineralizationat mineabledepths.
isotopestudyof sandstones-hosted
copperdepositsof Pernatty
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troughcouldwell containburied
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rare earth elements)mineralizationat variousplaces
1953b, The copperand manganese
depositsof the Mount
alongthe easternmarginof the Adelaidegeosyncline. -lagoondistrict,in Edwards,A. B., ed, Geology
However, theseare unlikely to be as economically Gunson-Pernatty
of Australian
oredeposits:
Melbourne,Australasian
Inst.Mining
significantasthe olderhydrothermaldepositsof the
Metallurgy,p. 517-523.
Stuartshelf,whichformedduringa periodof greater Donnelly,T. H., Juodvalkis,A., Knutson,J., andEadington,P.,
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