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1. This experiment involves the titration of an unknown iron sample with potassium permanganate to determine the percentage of iron. Potassium permanganate is used as an oxidizing agent that reacts with iron(II) in acid solution, changing color from violet to colorless as it is reduced.
2. Students will weigh out samples of the unknown iron compound, dissolve it in sulfuric acid, and titrate with standardized potassium permanganate solution. The endpoint is reached when a light pink color persists, indicating that all iron has been oxidized.
3. By calculating the moles of permanganate used and the stoichiometry of the reaction, students can determine the mass percentage of iron
Deskripsi Asli:
Determination of Iron by Titration in the fundamental chemistry
1. This experiment involves the titration of an unknown iron sample with potassium permanganate to determine the percentage of iron. Potassium permanganate is used as an oxidizing agent that reacts with iron(II) in acid solution, changing color from violet to colorless as it is reduced.
2. Students will weigh out samples of the unknown iron compound, dissolve it in sulfuric acid, and titrate with standardized potassium permanganate solution. The endpoint is reached when a light pink color persists, indicating that all iron has been oxidized.
3. By calculating the moles of permanganate used and the stoichiometry of the reaction, students can determine the mass percentage of iron
1. This experiment involves the titration of an unknown iron sample with potassium permanganate to determine the percentage of iron. Potassium permanganate is used as an oxidizing agent that reacts with iron(II) in acid solution, changing color from violet to colorless as it is reduced.
2. Students will weigh out samples of the unknown iron compound, dissolve it in sulfuric acid, and titrate with standardized potassium permanganate solution. The endpoint is reached when a light pink color persists, indicating that all iron has been oxidized.
3. By calculating the moles of permanganate used and the stoichiometry of the reaction, students can determine the mass percentage of iron
Experiment #A: Determination of Iron by Reaction with
Permanganate
Experiment #A: Determination of Iron by Reaction with Permanganate
Health & safety You must follow all health and safety procedures for this experiment. Background Potassium permanganate, KMnO4, is widely used as an oxidizing agent in volumetric analysis. In acid solution, MnO4 ion undergoes reduction to Mn2+ as described by the following equation: MnO4(aq) + 8H+(aq) + 5e Mn2+(aq) + 4H2O Since the MnO4 ion is violet and the Mn2+ ion is nearly colorless, the end point in titrations using KMnO4 as the titrant can be taken as the first permanent pink color that appears in the solution. In this experiment, KMnO4 will be employed in order to determine the percentage of iron in an unknown sample containing iron(II) ammonium sulfate, Fe(NH4)2(SO4)2 6H2O. By determining the number of moles of potassium permanganate used in the titration, the amount of iron, and the stoichiometry of the reaction, you can work out the percentage by weight of iron in the solid sample. You should calculate the mean percentage of iron for your values, along with the standard deviation. Procedure Obtain a burette and an unknown iron(II) sample. Weigh out accurately on the analytical balance three samples of about 0.3 g of your unknown into clean 250 mL Erlenmeyer flasks. Clean your burette thoroughly. Draw about 100 mL of the standard KMnO4 solution (take a note of the concentration of solution written on the bottle) from the dispenser which will be located in a fume hood. Rinse the burette with a few milliliters of the KMnO4 solution three times. Drain and then fill the burette with the KMnO4 solution. Prepare 150 mL of 1 M H2SO4 by pouring 25 mL of 6 M H2SO4 into 125 mL of H2O, while stirring. Add 50 mL of this 1 M H2SO4 solution to one of the iron samples. The sample should dissolve completely. Make sure that you record the volume of KMnO4 in the burette. Then, without delay, titrate the iron solution with KMnO4. When a light-yellow color develops in the iron solution during the titration, add 3 mL of 85% H3PO4 (be careful with this reagent). Continue the titration until you obtain the first pink color that persists for 15 to 30 seconds. Record the final volume of KMnO4 solution left in the burette. This will allow you to work out what volume was required to react all of the iron in the sample. Repeat the same as above with the two more samples. Determine the percentage by weight of iron in the solid sample and deviation. When the experiments are finished, you must ensure you have cleaned all your apparatus and tidied your workspace. Noncompliance will result in penalties.
CHEM101E (Spring 2015)
Experiment #A: Determination of Iron by Reaction with
Permanganate
Post lab questions
1. Write a balanced equation for the reaction of iron (II) ammonium sulfate and potassium permanganate reaction; you do not need to include non-reacting species. (2 marks) 2. Explain why there is a color change in the reaction and why does a color change indicate the end point of the reaction? (2 marks) 3. Why is sulfuric acid used in this reaction? (1 mark) 4. Why is phosphoric acid used in this reaction? (1 mark) 5. What other methods can be used to monitor the progress of reaction (e.g. for automation purposes)? (2 marks) 6. If you wanted to assess the chemical kinetics of this reaction, describe how to modify the experiment and explain using titration in the analysis how to collect the necessary data. You must indicate any advantages or disadvantages. (4 marks) Report You must submit an electronic copy of your report through Moodle. Do not submit a scanned copy of a hand written report. Deadline will be 2 weeks from the day of your experiment. Late submissions will be penalized.