ii.
B. Fractional distillation
How can you separate a complex mixture of liquids by a
method of distillation? Simple distillation isn't good enough
to do an efficient job of separating liquids with boiling
points that may be relatively close together. The liquids
must all dissolve in each other i.e. they are all fully miscible.
Fractional distillation involves 2 main stages and both are
physical state changes. It can only work with liquids with
different boiling points but the boiling points can be quite
close together. However, this method only works if all the
liquids in the mixture are miscible (e.g. alcohol & water,
hydrocarbons in crude oil etc.) and do NOT separate out
into layers like oil & water (immiscible).
i.
ii.
The liquid or solution mixture is poured into the roundbottomed flask, heated and boiled to vaporize the most
volatile component in the mixture (liquid ==> gas). The antbumping granules give a smoother boiling action.
The vapour passes up through a fractionating column, where
the separation takes place. The fractionating column is
packed with glass beads or short rods/tubes to give a large
surface area for both evaporation and condensation. This
column is not used in the simple distillation described above.
When the temperature at the top of the column reaches
the boiling point of the lowest boiling component, that
component will then distil over into the condenser. The
higher boiling liquids, the most easily condensed liquids,
condense and separate out, running back into the flask
mixture, whereas the lower boiling liquid's vapour passes
through into the Liebig condenser. This is because the
iii.
C. Paper chromatography
This method of separation is used to see what colored
materials make up
Chromatography can be used to identify substances and
check on the purity of a substance.
i.
ii.
At the start
mark a baseline in
pencil - mark
won't dissolve or
run. Make sure it
is above the
surface of the
solvent, so as not
to dissolve the
spots directly.
The prepared
chromatogram
When the
solvent is near
paper is carefully
placed in the
solvent so the
baseline and
is removed and
allowed to dry
before
examination and
solvent is allowed
to move up the
measurement of
the RF values of
covered beaker
so the solvent
doesn't
evaporate into
the laboratory!
How do we
measure an Rf
value? Its
quite simple to
measure a
reference value
(Rf) value for a
dye colour. e.g.
for the green
dye spot, S
might be 7.2
cm, D might be
5.3 cm, so
Rf = D/S =
5.3/7.2 = 0.74
I.
Filtration
Filtration uses a filter paper or fine porous ceramic to
separate a solid from a liquid. It works because the tiny
dissolved particles are too small to be filtered BUT
any insoluble non-dissolved' solid particles are too big to go
through!
Filtration removes solid impurities from a solution
II.
II.
II.
II.
II.
II.
II.
II.
II.
Evaporation
Evaporation means a liquid changing to a vapour. In a
mixture separation procedure, it is the removal of most of
the liquid from a solution, usually to cause crystallization to
leave solid crystals in the evaporating dish - but you should
not heat some salts to complete dryness.
It is advisable to do filtration before evaporation to
remove insoluble impurities.
III.
Crystallization
Crystallization can mean a liquid substance changing to its
solid form. However, the term usually means what happens
when the liquid from a solution has evaporated to a point
IV.
DECANTATION
The solid-liquid mixture is allowed to stand e.g. in a beaker,
until all the solid settles out to the bottom of the
container.
Then the liquid is carefully poured off to leave the insoluble
solid behind.
Separating funnel
Used for 2 or more immiscible liquids
i. The mixture is put in the separating
funnel with the stopper on and the tap
closed and the layers left to settle out.
The denser liquid will always from the
lower layer
ii. The stopper is removed so no vacuum
forms as the liquid flows down, and the
tap is opened.
iii. As the less dense liquid goes out, close the tap.
II.
Magnet
IV.
Solvent Extraction
Solvent extraction involves sing a liquid to dissolve a
solid / another liquid to separate it from a mixture.
Centrifugation
Used to separate insoluble materials from a liquid, where
normal filtration does not work well e.g. a suspension of
very fine solid particles.
Involves rotating a test tube at high speed so particles
form layers according to their difference in density
Used to separate/purify: Blood, milk, edible oils, lubricants