97.5% of all water on Earth is salt water, and of the remaining 2.5%, more
than two thirds is inaccessible ice and permanent snow cover. Water is
acutely, unevenly distributed and large parts of the world are already
experiencing either water stress or water scarcity. According to the UN, by
2030 under a business as usual scenario, water demand will exceed supply
by 40%, with up to two thirds of the global population inhabiting areas that
are officially defined as water stressed.
Desalination
Production of drinking water from seawater is technologically achievable for several decades.
Until now, however, application of seawater desalination ("desal") on a large scale is primarily
limited to arid regions of the world that have a cheap supply of energy, such as in the Middle
East. Saudi Arabia uses this technology and produces 30% of the world's output of desalinated
seawater.
Desalination is a technology that is used to separates dissolved salts and
other minerals from seawater or other salty water. It provides clean drinking
water. The Desalination Plant uses reverse osmosis process, which removes
the salts and other minerals from the water as it passes through the layers of
extremely thin membranes under high pressure. The pure water is then
further mixed with other drinking water supplies and sends directly towards
the users.
In this process, Fresh water, which has a very small quantity of salt, is passed
through the membrane. After passing through the membrane, it leaves a
concentrated salt stream which is then discharged back to the ocean.
Approximately, 40 to 45 liters of drinking water is produced from 100 liters of
raw seawater. The advantage of the desalination process is that the raw water
source is independent of rainfall, so we are capable of providing water
throughout the year and produces drinking water.
Pretreatment processes
General description
The pre-treatment process improves the quality of the raw feedwater to ensure consistent
performance and the desired output volume of the desalination process. Almost all desalination
processes require pre-treatment of some kind. The level and type of pretreatment required
depends on the source and quality of the feedwater and the chosen desalination technology. For
source water of poor quality, pretreatment can be a very significant portion of the overall plant
infrastructure. The potential influences on public health and the environment from the
pretreatment process operations are associated with the chemical conditioning (addition of
biocides, coagulants, flocculants, antiscalants, etc.) of the source water prior to pre-treatment and
with the disposal of the residuals formed during the pre-treatment process. Pretreatment, when
required, normally involves a form of filtration and other physical-chemical processes whose
primary purpose is to remove the suspended solids (particles, silt, organics, algae, etc.) and oil
and grease contained in the source water when membrane desalination is used for salt separation.
For thermal desalination processes it protects downstream piping and equipment from corrosion
and from formation of excessive scale of hard deposits on their surface (scaling). Biofouling is
most often mitigated using an oxidant although non-oxidizing biocides are also utilized. Potential
public health effects associated with pre-treatment are typically associated with the by-products
formed during the chemical conditioning process and their potential propagation into the finished
fresh water.
Post-treatment
Product water from desalination plants is characteristically low in mineral content, alkalinity, and
pH. Therefore, desalinated water must be conditioned (post-treated) prior to final distribution and
use. Typically, post-treatment of product water includes one or more of the following processes:
Stabilization by addition of carbonate alkalinity;
Corrosion inhibition;
Re-mineralization by blending with high mineral content water;
Disinfection;
Water quality polishing for enhanced removal of specific compounds (i.e., boron, silica,
NDMA, etc.).
Post-treatment of permeate produced by the desalination system is needed for two key reasons:
to protect public health (by disinfection and mineral addition) and to safeguard the integrity of
the water distribution system. In some cases the same post-treatment process and conditioning
chemicals allow achievement of both goals. For example, addition of calcium and magnesium
salts to permeate provides not only essential minerals but also stabilizes the product water and
thereby protects the water distribution system against corrosion.
Usually, the ultimate application dosage of any multi-purpose chemical is determined by the
minimum dosage needed to achieve all purposes for which the conditioning chemical is added.
If the use of the same chemical is not found to be cost effective to achieve
both the public health and the corrosion protection goals, than a combination
of chemicals that yield the lowest overall cost of water production may be
used to meet all post-treatment goals. For example, typically calcium
hypochlorite addition for disinfection meets the public health goals for
pathogen inactivation and also adds some calcium. Therefore, calcium
hypochlorite addition is typically combined with the feed of corrosion
inhibitor to the desalination plant permeate, thereby achieving both public
health
and
corrosion
protection
goals
at
minimal
life-cycle
cost.
The abstraction
beach wells or through open seawater intake systems. Coast- and beach
wells provide better quality water with less turbidity, algae and total
dissolved solids than open seawater intakes but require more space. In
brackish water desalination, wells are used to abstract feed water. Pretreatment includes all activities to adjust the intake water in constitution and
pH-value. Particulate matter is removed from the feed-water and chemicals
are added to prevent scaling and fouling. The pumping system is required to
overcome height differences within the distribution chain and to apply the
necessary pressure to the feed. The membrane is capable of separating salt
from water with a rejection of 9899.5%, depending on the membranes in
use. The energy recovery system is responsible for the transfer of potential
energy from the concentrate to the feed. Current energy recovery systems
such as work exchangers operate with efficiencies of up to 96% [13]. In posttreatment (6) permeate is re-mineralized, re-hardened, disinfected by
chlorination and adjusted to drinking water standards. A control system
maintains a continuous and reliable production. Fig. shows a simplified
reverse osmosis scheme with energy recovery system and open seawater
intake.
OSMOTIC PRESSURE
The osmotic pressure, Posm, of a solution can be determined experimentally by
measuring the concentration of dissolved salts in solution:
Definitions
element, usually measured in gallons per minute (gpm). Concentrate flow is the
rate of flow of non-permeated feedwater that exits the membrane element. This
concentrate contains most of the dissolved constituents originally carried into
the element from the feed source. It is usually measured in gallons per minute
(gpm).
Flux: the rate of permeate transported per unit of membrane area, usually
feedwater.
Effect of pressure
Feed water pressure affects both the water flux and salt rejection of RO
membranes. Osmosis is the flow of water across a membrane from the dilute
side toward the concentrated solution side. Reverse osmosis technology
involves application of pressure to the feedwater stream to overcome the
Effect of temperature
As Figure demonstrates, membrane productivity is very sensitive to changes in
feedwater temperature. As water temperature increases, water flux increases
almost linearly, due primarily to the higher diffusion rate of water through the
membrane.
Increased feedwater temperature also results in lower salt rejection or higher salt passage.
This is due to a higher diffusion rate for salt through the membrane.
The ability of a membrane to tolerate elevated temperatures increases
operating latitude and is also important during cleaning operations
because it permits use of stronger, faster cleaning processes. This is
illustrated by the comparison of the pH and temperature ranges of thinfilm composite (TF) membrane and a cellulose acetate (CA) membrane in
Figure.
Effect of recovery
As shown in Figure, reverse osmosis occurs when the natural osmotic flow
between a dilute solution and a concentrated solution is reversed through
application of feedwater pressure. If percentage recovery is increased (and
feedwater pressure remains constant), the salts in the residual feed become
more concentrated and the natural osmotic pressure will increase until it is
as high as the applied feed pressure. This can negate the driving effect of
feed pressure, slowing or halting the reverse osmosis process and causing
permeate flux and salt rejection to decrease and even stop (please see
Figure).
The maximum percent recovery possible in any RO system usually depends not
on a limiting osmotic pressure, but on the concentration of salts present in the
feedwater and their tendency to precipitate on the membrane surface as
mineral scale. The most common sparingly soluble salts are calcium carbonate
(limestone), calcium sulfate (gypsum), and silica. Chemical treatment of
feedwater can be used to inhibit mineral scaling.
Effect of pH
The pH tolerance of various types of RO membranes can vary widely. Thinfilm composite (TF)membranes are typically stable over a broader pH range
than cellulose acetate (CA) membranes and, therefore, offer greater
operating latitude (please see Figure ).
Membrane salt rejection performance depends on pH. Water flux may also be
affected. Figure shows that water flux and salt rejection for Thin Film
membranes are essentially stable over a broad pH range.
c
At steady state, the solute diffusing through the membrane must equal
the amount of solute leaving in the downstream or product (permeate)
solution,
7. Flux
The total resistance at the end of filtration test (Rf) was calculated with the permeate flux and TMP at
the end of each permeate test. The resistance at the end of filtration test (Rf) includes the resistance
by concentration polarization, cake layer and adsorbed layer.
The membrane rinsed with deionized water was used for another pure water flux
(PWF) test to evaluate the resistance after hydraulic rinse (Rhy). The membrane
was operated for 3 minutes before the PWF test to stabilize the permeate flux
and pressure
Then, the third pure water flux test was performed to determine the
resistance after chemical cleaning (Rch).
The relationship between TMP and operating parameters (time or permeate
flux) were illustrated in Figure 5.
Theoretically, the relationship among the flux, the driving force and
resistances can be expressed by Darcys law as shown in Equation
membrane
resistance,
Rcp
is
the
resistance
by
concentration
8. Critical Flux
Critical flux has been proposed as a method for measuring the maximum
flux or TMP that can safely be applied and still keep the system running
effectively, i.e. with no or little fouling and with reduced frequency of
chemical cleaning.
Field et al. (1995) introduced the concept of critical flux, working on constant
flux filtration of yeast cells with MF. They defined the critical flux as the flux
below which an increase of TMP with time did not occur. Howell (1995)
defined the critical flux as the flux below which there is no deposition of
colloids on the membrane.
All the definitions of critical flux are related with fouling of the system. Based
on theoretical definitions of mass transport, the critical flux can be defined
more generally as the flux at which the hydrodynamic force transporting the
particle towards the membrane pore is exactly balanced by the opposing
back transport forces (Bowen et al. 1999). It should be recognized, however,
that diffusion is a statistical process and that not all particles in a population
will follow the same path. As a result, conditions that are believed to prevent
the average particle from depositing on a membrane surface will not
guarantee that all particles of a particular size and density will remain
detached from a surface. This also leads to the inference that there is no
such thing as a critical flux at which there will be zero fouling. Rather, critical
flux should be considered to be the operating condition that separates slow
fouling from rapid fouling.
Factors effecting the critical flux
Ionic strength
PH
Zeta potential
Particle concentration and size, and nature and concentration of organic
materials
strength
and
especially
multi-valent
ions
affect
electrostatic
membrane
due
to
sorption
of
the
organic
solutes
by
Bacchin et al. (1996) reported that crossflow was useless when filtering a
destabilized colloidal suspension.
has
shown
that
the
best
long-term
performance
of
an
first gel layer forms on the membrane surface. The best long-term
performance of an ultrafiltration/microfiltration fixed flux system is obtained
when the fixed flux is set below the critical flux.
Membrane fouling
Two fouling mechanisms are generally observed for membrane processes:
surface fouling and fouling in pores. However, RO membranes do not have
distinguishable pores and are considered to be essentially non-porous. Thus, the
main fouling mechanism for RO membranes is surface fouling. Surface fouling
can occur from a variety of contaminants, including suspended particulate
matter (inorganic or organic), dissolved organic matter, dissolved solids, and
biogenic material. [23] In addition, fouling can develop unevenly through a
membrane module or element and can occur between the membrane sheets of
a module, where spacers are located to create space for the concentrate
stream. [24] Overall, seawater RO plants, particularly those treating water from
an open water intake, are primarily fouled by organic and particulate material,
while brackish water RO plants are fouled by dissolved inorganic salts and
precipitation. However, both types of RO can experience both general groups of
contaminants. In addition, the types of problematic foulants are site-specific,
particularly for brackish water RO, and can depend on pretreatment processes.
The capacity of water to foul RO membranes is often described using the silt
density index, or SDI. The SDI of water is determined from the fouling rate of a
0.45 mm filter at a pressure of 207 kPa (30 psi) and is described in the AST
standard method D4189 [25]. The equation used to calculate SDI is as follows:
Where t is the total elapsed flow time, and t1 and t2 are the times (in seconds)
required to filter 500 mL of water initially and after t minutes, respectively. [25,
26] The experiment is setup as a dead-end filtration with continuous flow under
pressure, and the membrane is perpendicular to the permeate flow. The total
time t is chosen (the standard is 15 min), and the sample flows though the filter
during the entire 15 min. As water flows through the membrane, foulants will
continuously accumulate on and foul the membrane; therefore, t1 is expected to
be smaller than t2. Both conventional and membrane pretreatment lower the
SDI of feed water, but each pretreatment choice may have negative and positive
aspects (technologically and financially).
An SDI of 3 or less is preferred for RO influent. However, many plants tolerate
SDI values between 4 and 5, which is often the achievable range through
conventional pretreatment .
Kremen and Tanner (1998) showed the relationship between SDI and water
fouling propensity by relating the SDI to a total flow resistance. The total flow
resistance (Rt) is the combination of two resistances, the resistance of the filter
(RP) and the resistance of the foulant (on the filter) (RF). The theoretical
relationship between SDI and Rt, shown in Fig. 6, displays an exponential
relationship between increasing SDI and increasing foulant resistance (or
increasing foulant accumulation on the membrane).
Figure 21
This relationship indicates far greater fouling resistance between SDI values
of 4 and 5 than between SDI values of 1 and 4. Therefore, ideally, a
pretreatment scheme that can lower the SDI
Foulants
Rejected constituents by the RO membrane pose a general fouling risk to
plant operation.
Foulants can be classified into four categories [27]:
Chemical foulants, which cause scaling
Physical foulants or particulate matter, which is related to deposition of
particles on the membrane surface
silicate clays (0.31 m) and colloids of iron, e.g. iron oxide, aluminum oxide
and silica. The most problematic feeds are those containing colloidal
particles not easily removed by granular beds either because of their minute
size or because of electrostatic repulsion effects of the media. In such cases
it is necessary to add a coagulant or flocculating agent. The most frequently
used coagulants are ferric chloride, alum and cationic polymers. The
polymeric coagulants are effective in very small dosages but can cause
membrane fouling difficulties [43]. The presence of suspended solids can be
monitored by the silt density index (SDI) test, turbidity analysis, zeta
potential measurement and particle counting. For prevention of colloidal
fouling, membrane manufacturers require a turbidity NTU <0.2, zeta
potential > !30 mV and SDI <35 [43]. Waters from wells are much less
loaded with colloidal material and often no further reduction of colloid
content is needed.
Biofouling
All raw waters contain microorganisms such as bacteria, fungi, algae, viruses
and higher organisms such as protozoa, living or dead, or biotic debris such
as bacterial cell wall fragments.
At the large membrane surface dissolved organic nutrients of the water are
concentrated due to concentration polarisation. Microorganisms entering a
RO system therefore find ideal growth conditions resulting in possible
formation of a biofilm [28].
Biofilm formation consists of three stages:
Transport to the membrane surface
Attachment to the surface and
Biofilm growth
Biological fouling can influence the performance of an RO system, resulting
in increased pressure loss along the feed channel and significant flux decline.
Biofouling cannot be easily removed because microorganisms are protected
from shear forces and disinfectants by a gel like layer. If the gel layer is
partly removed by disinfection, e.g. chlorination, dead cellular matter serves
as additional nutrient leading to intensive biologic re-growth. It is therefore
essential for good RO performance to reduce biological fouling to a minimum
by effective pre-treatment [29].
The potential for biofouling is higher with open intake water than with well
water with its higher water quality. Pre-treatment is generally required for
surface water to prevent biofouling. For a bacterial count higher than 106
CFU/ml significant biofouling problems have to be expected
It was found that mainly the hydrophobic humic substances are deposited on
the membrane surface and that the adsorption process is favoured with
positively charged, high molecular mass compounds. Similarly, the most
hydrophilic membranes have been found less prone to fouling by organic
colloids, i.e. humic acids .
In RO operation it is recommended that humic acids are removed prior to
filter pre-treatment by flocculation, coagulation with hydroxide flocs,
ultrafiltration or adsorption on activated carbon. Other organic foulants in
natural waters are oil and grease droplets.
Key parameters
Scaling and fouling are the main problems in seawater and brackish water
desalination and the potential for scaling and fouling will strongly depend on
the water composition. The abundance of water constituents can never be
fully integrated in a process designing exercise. However, water quality can
be characterized by certain key parameters which are used to gain
information about the tendency of the feed water to cause scaling and
fouling.
Parameters that are commonly used to characterize the feed water are:
The SDI Index (Silt Density Index), which describes the fouling potential of
the feedwater and is determined in filtration tests with the feed or raw water
using porous microfiltration membranes.
The content of Ca2+ and Mg2+ in the feedwater gives information about
the hardness of the water, which causes calcinations of pipes. Total hardness
is defined by the content of calcium, magnesium, barium and strontium in
solution. However, in general only the amount of calcium and magnesium
are used to characterize the hardness of a feedwater.
The solubility product, which gives information about the limiting salts and
the potential for scaling.
The conductivity is directly proportional to the content of dissolved salts in
the water and is also used to determine the amount of dissolved salts in the
feed. Conductivity of sea water depends strongly on temperature. Therefore,
if salinity is to be calculated from conductivity, temperature must be
measured at the same time as conductivity, to eliminate the temperature
effect and obtain salinity.
The TDS (total dissolved solids) characterizes the content of dissolved
solids in the feed, butdoes not differentiate between different salts.
Algal can refer to either microscopic (seen only under a microscope) plant-like cells or larger aquatic
plants that can be seen with the unaided eye, such as sea lettuce. Both types of algae can be found
in seawater, brackish water, or fresh water. The term algal suggests plants that