10/9/2016

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ZetaPotentialisanelectrokinetic
parameterindirectlydeterminedbythe
surfacechargeofparticleswhensus
pendedinapolarmedia.The
magnitudeofzetapotentialbyitself
cannotguarantythestabilityof
suspensions
[1].However,throughitsmanipulation,
guidelinescanbetakentowards
stabilizationordestabilizationofce
ramicslurries.Thechargedparticlesin

ZetaPotensimerupakanparameter
elektrokinetiktidaklangsung
ditentukanolehmuatanpermukaan
partikelketikasuspendeddimedia
polar.Besarnyapotensizetadengan
sendirinyatidakbisamenjamin
stabilitassuspensi
[1].Namun,melaluimanipulasinya,
pedomandapatdiambilterhadap
stabilisasiataudestabilisasibuburce
ramic.partikelbermuatandisuspensi

suspensionscanbesetintomotion
undertheactionofanelectricfield[1]
[2].Themovementisinthedirectionof
theoppositelychargedelectrodeand

dapatdiaturkedalamgerakbawah
aksimedanlistrik[1]
[2].Gerakaninikearahelektroda
bermuatansebaliknyadandapat

canbedraggedofbytheviscous
hydrodynamicforcesofthesolution.At
equilibriumtheparticlescanmoveat
constantspeed.Theconstantvelocity

diseretdariolehkental
Pasukanhidrodinamikdarisolusi.Pada
kesetimbanganpartikeldapatbergerak
dengankecepatankonstan.Konstan

acquiredunderunitaryelectricfield
strengthiscalledunitary
electrophoreticmobility(e)[3].
Forconditionsoflowelectrolyte

velocitydiperolehdengankekuatan
medanlistrikkesatuandisebut
kesatuanmobilitaselektroforesis(e)
[3].

concentrationandparticlesizebigger
than0.2mtheHenrysfunctionturns
outtobe()1.5fka=.
Thezetapotentialindicatedin
Equation(1),isanindirectmeasureof
thenetchargecreatedintheparticles
of
thesuspension,eitherbyadsorptionof
contraionsordissociationofparticles
surfacegroups.Followingthe
DLVOtheorythelargerthezeta
potentialabsolutevalueis,morestable
thesuspensioncanbe.The
adjustment
ofthisparametermakesitpossibleto
controlthestabilityofcolloidal
ceramicsuspensions.Itisaccepted
that
zetapotentialvaluesof30mVare
enoughtopromotestablewater
suspensions.Thisoccursbecause
particles
likechargerepeleachother,
overcomingthetendencyto
aggregationcausedbytheactionof
theVanderWaals
forces[1][3].
Themeasurementofzetapotentialis
aninformation,frequentlyusedin
coagulation(aggregation)anddisper
sionprocessesinseveralapplications,

Untukkondisikonsentrasielektrolit
rendahdanukuranpartikelyanglebih
besardari0,2umfungsibergantian
yangHenry
menjadi()1.5fka=.
Potensizetaditunjukkandalam
Persamaan(1),merupakanukuran
tidaklangsungdaribiayabersihdibuat
dalampartikel
suspensi,baikolehadsorpsiionkontra
ataudisosiasipartikelpermukaan
kelompok.Mengikuti
DLVOteoribesarpotensizetanilai
mutlak,lebihstabilsuspensidapat.
penyesuaian
parameterinimemungkinkanuntuk
mengontrolstabilitassuspensikeramik
koloid.Haliniditerimabahwa
nilainilaipotensialzetadari30mV
cukupuntukmempromosikansuspensi
airyangstabil.Haliniterjadikarena
partikel
sepertibiayasalingtolak,mengatasi
kecenderunganuntukagregasiyang
disebabkanolehtindakandariVander
Waals
Pasukan[1][3].
Pengukuranpotensizetaadalah
informasi,seringdigunakandalam
koagulasi(agregasi)dandisper
prosessiondalambeberapaaplikasi,

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suchascolloidalprocessingofceramic
pastesandslurries,waterpurifi

sepertipengolahankoloidpasta
keramikdanlumpur,airpenjernihan

cation,paintsandcosmetics[4][7].

kation,catdankosmetik[4][7].

Ontheotherhand,thestabilityof

Disisilain,stabilitassuspensijuga

suspensionsisalsoaffectedbythe
sedimentationtendencyofparticles

dipengaruhiolehkecenderungan
sedimentasipartikelsus

sus

pendeddalamcairan.Dalamkondisi

pendedinaliquid.Underconditionsof

konsentrasipadatrendah,kecepatan

lowsolidconcentration,the
Edit
sedimentationvelocityisexpressedby

sedimentasidinyatakanoleh
hukumStokessepertidalam

StokeslawasinEquation(2).

Persamaan(2).

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