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+

Cu2+
m
r
s

0.3
0.15
0.15

2CuI2
m
r
s

0.3
0.3
-

Cu2I2

0.15
0.15

m
r
s

t(s)

50
y

(mol I2)
t(s)

30
y

[I-]0
log [I-]0

[CuSO4]

0.075
0.075

2I2O32-

0.075
0.01
0.065

(mol I2)

I2
0.075
0.075

I2

CuI2

2I-

2I0.02
0.02

0.02
0.02

0.000065
1.36
4.779E-005

log

-4.320626

log

-4.519525

Vki
0.3

Vtotal
1
10.25

0.1

VCuSO4 V total
3
10.25

0.000065
2.15
3.023E-005
0.0292683 M
-1.5336026
0.0292683 M

log [CuSO4] -1.5336026

6.2910E-005
sampel

Cu2+
m
r
s

0.3
0.3

2CuI2
m
r
s

1.2
0.6
0.6

0.3
0.3

0.15
0.01
0.014

(mol I2)
30 t(s)
y

[I-]0

0.15
0.15

2I2O32-

(mol I2)
50 t(s)

I2
0.15
0.15

m
r
s

0.3
0.3

Cu2I2

I2

CuI2

2I-

2I0.02
0.02

0.02
0.02

0.00014
1.23
0.0001138

log

-3.943777

log

-4.038563

0.00014
1.53
9.150E-005
0.1170732

Vki
0.3

log [I-]0

[CuSO4]

0.0292683

VCuSO4
0.1

log [CuSO4] -1.5336026

0.000159573

-0.9315426

sampel

Cu2+
m
r
s

CuI2

2I-

0.2
0.15
0.05

2CuI2

0.3
0.3

m
r
s

0.15
0.15

I2
m
r
s

0.075
0.01
0.065

(mol I2)
30 t(s)
y

[I-]0

Cu2I2

I2
0.075
0.075

(mol I2)
50 t(s)

0.15
0.15

0.075
0.075

2I2O32-

2I0.02
0.02

0.02
0.02

0.000065
1.85
3.514E-005

log

-4.454258

log

-4.572693

0.000065
2.43
2.675E-005
0.0292683

Vki
0.3

log [I-]0

[CuSO4]

-1.5336026

0.0195122

VCuSO4
0.1

log [CuSO4] -1.7096939


4.8510E-005

sampel

Cu2+
m
r
s

0.3
0.3

0.6
0.6
-

2CuI2
m
r
s

2I-

+
0.3
0.3

0.15
0.15

S4O62-

I2

m
0.01 r
0.01 s

0.15
0.01
0.014

(mol I2)
30

t(s)
y

(mol I2)
50

t(s)

Cu2I2

2I2O320.02
0.02

0.00014
2.27
6.17E-005
0.00014

1.23
0.0001138

[I-]0

0.0585366

log [I-]0

-1.232573

[CuSO4]

0.0292683

log [CuSO4]

-1.533603

0.000118585
Sampel

Cu2+
m
r
s

0.3
0.3

2CuI2
m
r
s

S4O62-

0.3
0.3

+
0.15
0.01
0.014

(mol I2)
50 t(s)
y

(mol I2)
30 t(s)

V total
10.25

Cu2I2
0.15
0.15

m
0.01 r
0.01 s

Vtotal
10.25

0.9
0.6
0.3

I2

2I-

2I2O320.02
0.02

0.00014
0.92
0.0001522
0.00014

1.38
0.0001014

[I-]0

0.0292683

log [I-]0

-1.533603

[CuSO4]

0.0487805

log [CuSO4]

-1.311754

0.000202899
sampel

sampe 1-4
log (mol I2)/t
log [I-]0
x
y
-1.53360261 -4.519525
-1.23257262 -4.209898
-1.05648136 -4.230449
-0.93154262 -4.038563
30 derajat
sampel 1,5,6 dan 7

log [CuSO4] log (mol I2)/t


x

S4O6

2-

-1.53360261 -4.519525
-1.31175386 -3.993751
-1.16562583 -4.40193
-1.70969387 -4.572693
30 derajat

0.01
0.01

Untuk T1 = 30
[CuSO4]
(mol I2)
No
[I- ]
1 6.2910E-005 0.0292683 0.02927
2 0.000118585 0.0585366 0.02927
3 9.6257E-005 0.0878049 0.02927
4 0.000159573 0.1170732 0.02927
5 0.000202899 0.0292683 0.04878
Vtotal
10.25

6 8.6144E-005 0.0292683 0.06829


7 4.8510E-005 0.0292683 0.01951
krata2
Untuk T2 = 50

V total
10.25

No

[CuSO4]
[I- ]
1 6.2910397E-005 0.029268293 0.0292683
(mol I2)

2 0.0001185846 0.058536585 0.0292683


3 9.6256684E-005 0.087804878 0.0292683
4 0.0001595728 0.117073171 0.0292683

5 0.0002028986 0.029268293 0.0487805


6 8.6143604E-005 0.029268293 0.0682927
7 4.8509621E-005 0.029268293 0.0195122
Krata2

Orde p
Orde q

T1 (30)
T2 (50)
4.49833
4.261
4.42704 4.272143

k(1/T)
lnk
0.00330033 21.707794
0.003095975 20.284321

slopnya
R
Ea

6965
8.314
57907.01 J/mol
57.907 KJ/mol

CuI2

Cu2+
m
r
s

0.3
0.3

I2

0.3
0.3

2CuI2
m
r
s

0.15
0.15

2I0.02
0.02

S4O62-

0.3
0.3
-

I2
m
0.01 r
0.01 s

0.15
0.01
0.014

(mol I2)
30
log

-4.209898

t(s)
y

(mol I2)
50

t(s)

log

-3.943777

Vki

[I-]0

0.3

Vtotal
2 10.25

log [I-]0
M

VCuSO4
0.1

V total
3 10.25

[CuSO4]
log [CuSO4]

9.6257E-005
2

CuI2

Cu2+
m
r
s

0.3
0.3

I2

0.7
0.15
0.55

2CuI2
m
r
s

0.15
0.15

2I0.02
0.02

S4O62-

0.15
0.075
0.075

I2
m
0.01 r
0.01 s

0.075
0.01
0.065

(mol I2)
50 t(s)
log

-3.81766

(mol I2)
30 t(s)
log

-3.993751

Vki

[I-]0

0.3

Vtotal
1 10.25

log [I-]0

VCuSO4
0.1

V total
5 10.25

[CuSO4]
log [CuSO4]

8.6144E-005
5

log [I-]0 log (mol I2)/t


x
y
-1.5336 4.320626
-1.23257 3.943777
-1.05648 4.125714
-0.93154 3.943777
50 derajat

log [CuSOlog
] (mol I2)/t
4
x

-1.5336 -4.320626
-1.31175 -3.81766
-1.16563 -4.178313
-1.70969 -4.454258
50 derajat

P
4.49833

Diperoleh nilai K
4.42704 k1
3066854392.29

4.49833

4.42704 k2

255780060.019

4.49833
4.49833
4.49833

4.42704 k3
4.42704 k4
4.42704 k5

33508329.5514
15228776.129
1030662297.92

4.49833
4.49833

4.42704 k6
4.42704 k7

98661070.186
14235137284.1
2676547458.59

Q
4.261

Diperoleh nilai K
4.272143 k1
767666883.509568

4.261
4.261
4.261

4.272143 k2
4.272143 k3
4.272143 k4

75472681.8720071
10885982.0594111
5297019.22213692

4.261
4.261
4.261

4.272143 k5
4.272143 k6
4.272143 k7

279228500.593211
28159437.2167537
3346303293.97301
644716256.920871

CuI2

2I0.9
0.6
0.3

0.3
0.3

Cu2I2

I2
0.15
0.15

0.15
0.15

2I2O32-

2I-

0.02
0.02

0.02
0.02

0.01
0.01

0.00014
2.38
5.882E-005

log

-4.2304489

1.87
7.487E-005

log

-4.1257136

0.08780488

Vki

0.00014

0.3

Vtotal
3
10.25

-1.0564814
0.02926829

VCuSO4
0.1

-1.5336026

sampel

S4O62-

V total
10.25

CuI2

2I0.3
0.3

0.15
0.15

Cu2I2

I2

0.075
0.075

0.075
0.075

2I2O32-

2I-

0.02
0.02

0.02
0.02

0.000065
0.98
6.633E-005

log

-4.1783127

1.64
3.963E-005

log

-4.4019305

0.02926829

Vki

Vtotal
1
10.25

VCuSO4

V total
7
10.25

0.000065

0.3
-1.5336026

0.06829268

M
0.1

-1.1656258

sampel

S4O620.01
0.01