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Reported values for the virial coefficient of isopropanol vapor at 200oC are :

B= -388 cm3mol-1
C= -26000 cm6mol-2
Calculate V and Z for isopropanol vapor at 200oC and 10 bar by equation
below:
eq 3.39 smith vanness
R
B
C

83.14 cm3.bar/mol.K
-338 cm3/mol
-26000 cm6/mol2

P
T

for ideal gas Z=1


V=RT/P= 3933.769 cm3
V0

3933.769 iterasi

Z=PV/RT= 0.902761

Vi+1
error
3933.769
0 3589.16 344.6094
1 3555.377 33.78285
2 3551.705 3.671605
3 3551.302 0.403335
4 3551.258 0.044359
5 3551.253 0.004879
6 3551.252 0.000537
7 3551.252 5.90E-005
8 3551.252 6.49E-006

10 bar
473.15 K

Reported values for the virial coefficient of isopropanol vapor at 200oC are :
B= -388 cm3mol-1
C= -26000 cm6mol-2
Calculate V and Z for isopropanol vapor at 200oC and 10 bar by equation
below:
eq 3.39 smith vanness
R
83.14 cm3.bar/mol.K
B
-338 cm3/mol
C
-26000 cm6/mol2
for ideal gas Z=1
V=RT/P= 3933.769 cm3

P
T

10/(83.14
(26000)/

10 bar
473.15 K

"0=0.000254" ^3

bisection
Iterasi
V1
V2
V3
f(V1)
f(V2)
f(V3)
error 1
1 3933.769
3500 3716.885 1355613.9558 -141784 520617.6 216.8846
2 3716.885
3500 3608.442 520617.60826 -141784 168815.1 108.4423
3 3608.442
3500 3554.221 168815.08782 -141784 8486.767 54.22114
4 3554.221
3500 3527.111 8486.7669153 -141784 -67890.53 27.11057
5 3554.221 3527.111 3540.666 8486.7669153 -67890.53 -30014.29 13.55528
6 3554.221 3540.666 3547.443 8486.7669153 -30014.29 -10842.1 6.777642
7 3554.221 3547.443 3550.832 8486.7669153 -10842.1 -1197.281 3.388821
8 3554.221 3550.832 3552.527 8486.7669153 -1197.281 3639.836 1.694411
9 3552.527 3550.832 3551.68 3639.8358018 -1197.281 1220.051 0.847205
10 3551.68 3550.832 3551.256 1220.051195 -1197.281 11.07872 0.423603
11 3551.256 3550.832 3551.044 11.07872333 -1197.281 -593.1776 0.211801
12 3551.256 3551.044 3551.15 11.07872333 -593.1776 -291.0686 0.105901
13 3551.256 3551.15 3551.203 11.07872333 -291.0686
-140 0.05295
14 3551.256 3551.203 3551.229 11.07872333
-140 -64.4617 0.026475
15 3551.256 3551.229 3551.243 11.07872333 -64.4617 -26.69179 0.013238
16 3551.256 3551.243 3551.249 11.07872333 -26.69179 -7.806607 0.006619
17 3551.256 3551.249 3551.253 11.07872333 -7.806607 1.63604 0.003309
18 3551.253 3551.249 3551.251 1.6360395437 -7.806607 -3.085288 0.001655
19 3551.253 3551.251 3551.252 1.6360395437 -3.085288 -0.724626 0.000827
20 3551.253 3551.252 3551.252 1.6360395437 -0.724626 0.455707 0.000414
21 3551.252 3551.252 3551.252 0.4557067053 -0.724626 -0.134459 0.000207
22 3551.252 3551.252 3551.252 0.4557067053 -0.134459 0.160624 0.000103
23 3551.252 3551.252 3551.252 0.1606235863 -0.134459 0.013082 5.17E-005
24 3551.252 3551.252 3551.252 0.0130820405 -0.134459 -0.060689 2.59E-005
25 3551.252 3551.252 3551.252 0.0130820405 -0.060689 -0.023803 1.29E-005

=/=1+/+/^2
10/(83.14 . 473.15)=1+(388)/+
(26000)/^2
0= "0.000254V-1+" "388" /"V" "+"
"26000" /"V" ^"2" dikali V^2
"0=0.000254" ^3^2+388+26000

error 2

Toleransi 1 Toleransi 2
lanjut
selesai
0.029176 lanjut
lanjut
0.015026 lanjut
lanjut
0.007628 lanjut
lanjut
0.003843 lanjut
lanjut
0.001914 lanjut
lanjut
0.000955 lanjut
lanjut
0.000477 lanjut
lanjut
0.000238 lanjut
lanjut
0.000119 lanjut
lanjut
5.96E-005 lanjut
selesai
2.98E-005 lanjut
selesai
1.49E-005 lanjut
selesai
7.46E-006 lanjut
selesai
3.73E-006 lanjut
selesai
1.86E-006 lanjut
selesai
9.32E-007 lanjut
selesai
4.66E-007 lanjut
selesai
2.33E-007 lanjut
selesai
1.16E-007 lanjut
selesai
5.82E-008 lanjut
selesai
2.91E-008 lanjut
selesai
1.46E-008 selesai
selesai
7.28E-009 selesai
selesai
3.64E-009 selesai
selesai

0.902761

interpolasi linier
Iterasi
V1
V2
V3
f(V1)
f(V2)
f(V3)
error 1
1 3933.769
3500 3541.072 1355614 -141784 -28869.24 216.8846
2 3933.769 3541.072 3549.261 1355614 -28869.24 -5675.038 196.3484
3 3933.769 3549.261 3550.864 1355614 -5675.038 -1107.829 192.2542
4 3933.769 3550.864 3551.176 1355614 -1107.829 -215.9656 191.4527
5 3933.769 3551.176 3551.237 1355614 -215.9656 -42.09017 191.2964
6 3933.769 3551.237 3551.249 1355614 -42.09017 -8.202654 191.2659
7 3933.769 3551.249 3551.251 1355614 -8.202654 -1.598541
191.26
8 3933.769 3551.251 3551.252 1355614 -1.598541 -0.311524 191.2588
9 3933.769 3551.252 3551.252 1355614 -0.311524 -0.06071 191.2586
10 3933.769 3551.252 3551.252 1355614 -0.06071 -0.011831 191.2585
11 3933.769 3551.252 3551.252 1355614 -0.011831 -0.002306 191.2585
12 3933.769 3551.252 3551.252 1355614 -0.002306 -0.000449 191.2585
13 3933.769 3551.252 3551.252 1355614 -0.000449 -8.8E-005 191.2585
14 3933.769 3551.252 3551.252 1355614 -8.8E-005 -1.7E-005 191.2585
15 3933.769 3551.252 3551.252 1355614 -1.7E-005 -3.3E-006 191.2585
16 3933.769 3551.252 3551.252 1355614 -3.3E-006 -6.5E-007 191.2585
17 3933.769 3551.252 3551.252 1355614 -6.5E-007 -1.3E-007 191.2585
18 3933.769 3551.252 3551.252 1355614 -1.3E-007 -2.3E-008 191.2585
19 3933.769 3551.252 3551.252 1355614 -2.3E-008 -5.8E-009 191.2585
20 3933.769 3551.252 3551.252 1355614 -5.8E-009 -1.4E-009 191.2585
21 3933.769 3551.252 3551.252 1355614 -1.4E-009 4.66E-010 191.2585
22 3551.252 3551.252 3551.252 4.66E-010 -1.4E-009 4.66E-010
0
23 3551.252 3551.252 3551.252 4.66E-010 -1.4E-009 4.66E-010
0
24 3551.252 3551.252 3551.252 4.66E-010 -1.4E-009 4.66E-010
0
25 3551.252 3551.252 3551.252 4.66E-010 -1.4E-009 4.66E-010
0

error 2

Toleransi 1 Toleransi 2
lanjut
selesai
0.002312 lanjut
lanjut
0.000452 lanjut
lanjut
8.81E-005 lanjut
selesai
1.72E-005 lanjut
selesai
3.34E-006 lanjut
selesai
6.52E-007 lanjut
selesai
1.27E-007 lanjut
selesai
2.48E-008 lanjut
selesai
4.82E-009 lanjut
selesai
9.40E-010 lanjut
selesai
1.83E-010 lanjut
selesai
3.57E-011 lanjut
selesai
6.96E-012 lanjut
selesai
1.36E-012 lanjut
selesai
2.64E-013 lanjut
selesai
5.15E-014 lanjut
selesai
1.01E-014 lanjut
selesai
0 lanjut
selesai
0 lanjut
selesai
0 lanjut
selesai
0 selesai
selesai
0 selesai
selesai
0 selesai
selesai
0 selesai
selesai

Z
0.902254
0.902662
0.902741
0.902757
0.90276
0.902761
0.902761
0.902761
0.902761
0.902761
0.902761
0.902761
0.902761
0.902761
0.902761
0.902761
0.902761
0.902761
0.902761
0.902761
0.902761
0.902761

R
83.14 cm3.bar/mol.K
B
-338 cm3/mol
C
-26000 cm6/mol2
for ideal gas Z=1
V=RT/P= 3933.769 cm3
secant
Iterasi

P
T

10 bar
473.15 K
"0=0.000254" ^3^2+388+26000

V1
V2
V3
f(V1)
f(V2)
f(V3)
1 3933.769
3500 3541.072 1355613.956 -141783.775 -28869.242
2
3500 3541.072 3551.573 -141783.775
-28869.242 916.7486312
3 3541.072 3551.573 3551.25 -28869.242 916.7486312 -5.61113118
4 3551.573 3551.25 3551.252 916.7486312 -5.611131179 -0.00107901
5 3551.25 3551.252 3551.252 -5.61113118 -0.001079006 6.9849E-010
6 3551.252 3551.252 3551.252 -0.00107901 6.98492E-010 4.6566E-010
7 3551.252 3551.252 3551.252 6.9849E-010 4.65661E-010 4.6566E-010
8 3551.252 3551.252
#DIV/0! 4.6566E-010 4.65661E-010
#DIV/0!

^3^2+388+26000

error 1
error 2
toleransi 1
toleransi 2
Z
28869.241999
lanjut
selesai
0.900173
916.74863122 0.002966 lanjut
lanjut
0.902842
5.6111311794 9.10E-005 lanjut
selesai
0.90276
0.0010790061 5.54E-007 lanjut
selesai
0.902761
6.98492E-010 1.06E-010 selesai
selesai
0.902761
4.65661E-010
0 selesai
selesai
0.902761
4.65661E-010
0 selesai
selesai
0.902761
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!

R
83.14 cm3.bar/mol.K
B
-338 cm3/mol
C
-26000 cm6/mol2
for ideal gas Z=1
V=RT/P= 3933.769 cm3

P
T

10 bar
473.15 K

"0=0.000254.3" ^

newton raphson
iterasi
Vn
f(Vn)
f'(Vn)
hn
Vn+1
error 1
1 3933.769 1355613.9558
4271.7691 317.3425 3616.427 0.080671
2 3616.427 193288.433148 3079.200395 62.77228 3553.654 0.017358
3 3553.654 6864.21867137 2861.499849 2.398818 3551.255 0.000675
4 3551.255 9.8370516191 2853.299731 0.003448 3551.252 9.71E-007
5 3551.252 2.030586E-005 2853.287952 7.12E-009 3551.252 2.00E-012
6 3551.252 -1.396984E-009 2853.287952 -4.9E-013 3551.252 1.28E-016

"0=0.000254" ^3^2+388+26000
"0=0.000254.3" ^22+388

error 2

toleransi 1
lanjut
0.017664 lanjut
0.000675 lanjut
9.71E-007 selesai
2.00E-012 selesai
0 selesai

toleransi 2
lanjut
lanjut
selesai
selesai
selesai

Z
0.919329
0.903371
0.902762
0.902761
0.902761
0.902761

R
83.14 cm3.bar/mol.K
B
-338 cm3/mol
C
-26000 cm6/mol2
for ideal gas Z=1
V=RT/P= 3933.769 cm3
Iterasi

P
T

10 bar
473.15 K

Xn-1
Xn=g(Xn-1) error 1
error 2
toleransi 1
1 3933.769 3589.15966 0.087603
lanjut
2 3589.16 3555.37682 0.009412 8.30711 lanjut
3 3555.377 3551.70521 0.001033 8.114507 lanjut
4 3551.705 3551.30188 0.000114 8.093721 lanjut
5 3551.302 3551.25752 1.25E-005 8.09144 selesai
6 3551.302 3551.25752 1.25E-005
0 selesai

toleransi 2
selesai
lanjut
lanjut
lanjut
lanjut
selesai

"0=0.000254" ^3^2+388+26000

g(Xn-1)="V=" / x
(1+/+/^2 )
Z

0.902762