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PHYSICS

Part 1
Straight Objective Type
This section contains 10 multiple choice questions numbered 1 to 10. Each ques
question
tion has 4 choices A, B,
C, D out of which only ONE is correct.
1. A toy is moving on a closed track whose curved portions are semicircles of radius 1 m. The
adjacent graph describes the variation of sped of the car with distance moved by it(starting from
point P). The time t required for the car to complete on lap is equ
equal
al to 6k second. Find k (take
ln2 2)

(A) 4
(B) 8
(C) 12
(D) 16
2. A particle P is to be projected from a fixed point A on the
ground with a fixed speed u. Another particle Q is also to
be projected from a point B which is directly above the
point A. The trajectory
rajectory of the particle Q touched all
possible trajectories (for different angle of projection) of
the particle P in the vertical xx-y plane. The equation of
trajectory of the particle Q is (take the point A as origin,
horizontal axis x-axis
axis and vertical axis y-axis. Consider the
figure)
(A) Y=

  

(B) Y=



 


 




(C) Y=



(D) Y=

 

 





3. A small coin is placed on a stationary horizontal disc at a


distance r from its centre. The disc starts rotating about a fixed
vertical axis through its centre with a constant angular acceleration
. Determine the number of revolution N, accomplished by the disc
before the coin starts slipping on the disc. The coefficient of static
friction between the coin and the disc is .

(A)





   






(B)



  


(C)



  


(D)



   












A wedge of mass M resting on a horizontal frictionless surface is


acted upon by a force F in the horizontal direction as shown in
figure. The net horizontal force acting on the shaded portion of
the wedge is
(A) F
(B) F/3
(C) F/6
(D) Zero

5. A person rolls a small ball with speed u along the


floor point A. If x=3R, determine the required speed u
so that the ball returns to A after rolling on the circular
surface in the vertical plane from B to C and becoming
a projectile at C.(neglect friction and radius of ball)
(A)
(B)
(C)











(D) 

6. In the figure shown when the massless spring is in relaxed state its free end is at point B. A very small
block is pressed against the spring by a distance and then released from rest. Except the portion BC
where coefficient of kinetic
netic friction is " , track is smooth everywhere. Determine the spring
compression so that the block enters a small hole at E. Consider all values shown in the figure.

(A) 
(B)

!
#"
"

$ 5&


!

#"

"

(C) 
(D) 

!
#"
"

$ 5&

$ 5&

 !
#"
"

$ 5&

7. The wheel of radius R rolls without slipping on


horizontal rough surface, and its centre O has an
horizontal acceleration '( in forward direction. A point
P on the wheel is a distance r from O and angular
position for which point P has no acceleratio
acceleration in this
position.
,

(A) cos ,

(B) tan ,

(C) sin -

(D) cos -

8. The two identical rectangular steel frames with the dimensions shown are fabricated from a bar of
the same material and are hinged. Rectangular at the mid points A and B of their sides (3m
(
X 1m). If the
frame is resting in the position shown on a horizontal surface with negligible friction, determine the
velocity v with which each of the upper ends of the frame hits the horizontal surface if the cord D is cut.
: 

: 

(take the value of dimensions shown in the figure c=1 m, b=3/2 m and =74( i.e., sin= and cos = &
g=10m/2  )

(A)
(B)
(C)
(D)

m/s
8 m/s
3 m/s
4 m/s

9. A car C of mass m is initially at rest on the boat A of mass M tied to


the identical boat B of same, mass M through a massless inextensible
string as shown in the figure. The car accelerates from rest to velocity
3( with respect to boat A in time 4( sec. At time t=4( the car applies
brake and comes to rest relative to boat in negligible time. Neglect
friction between boat and water find the velocity of boat A just after
applying brake.
(A)
(B)
(C)

5 67
#5 &#5 &
5 67
#5 &#5 &
5 67
#5 &#5 &

(D) Zero
10. In the figure shown a river of width 4km is flowing with the
speed of 5 km/h. A swimmer, whose swimming speed relative to
the water is 4km/h, starts swimming from point A on a bank. On the

other bank B is a point which is directly opposite to A. What minimum distance (in km) the swimmer will
have to walk on the other bank to reach the point B.
(A)
(B)
(C)
(D)

2
3
4
5

Multiple Correct Choice Types


This section contains 5 multiple choice questions. Each question has 4 choices A, B, C, D for its answer,
out which one or more is/are correct.
11. Under the action of force P, the constant acceleration of
block B is 6m/2;<  up the incline. For the instant when the
velocity of B is 3 m/sec up in the incline. Choose the correct
option(s)
(A) Velocity of B relative to A is 1m/s
(B) Acceleration of B relative to A is 2m/2 
(C) The velocity of point C of the cable (in ground frame) is
4m/s
(D) Velocity of B relative to A is 2m/s
12. In the adjacent figure there is a cube having a smooth groove at an
inclination of 30( with horizontal in its vertical face. A cylinder A of mass
2kg can slide freely inside the groove. The cube is moving with constant
horizontal acceleration '( parallel to the shown face, so that the slider
does not have acceleration along horizontal.
(A) The normal reaction acting on cube is zero.

(B) The value of '( is g3


(C) The value of '( is g
(D) Acceleration of the particle in ground frame is g

13. Two identical particles A and B of mass m each are connected together by a light and inextensible
string of length l. The particle are held at rest in air in same horizontal level at a separation l. Both
particles are released simultaneously nd one of them (say A) is given speed 3( vertically upward. Choose
the correct options. Ignore air resistance.

(A) the maximum height attained by the centre of mass of the system of A and B is

67 
@

(B) the kinetic energy of the system of A and B when the centre of mass is at its highest point, is
67 


(C) the maximum height attained by the centre of mss of the system of A and B is

67 


(D) the kinetic energy of the system of A and B when the centre of mass is at its highest point, is
67 


14. In the adjacent figure a uniform rof of length l and mass m is kept at
rest in horizontal position on an elevated edge. The value of x (consider
he figure) is such that rod will have maximum angular acceleration A, as
soon as it is set free.
(A) x is equal to

(B) A= B


B
B
x= 

(C) =
(D)

B
 

15. A block A is placed on a smooth horizontal surface and a particle


C is suspended with the help of light rod from point B of the block as
shown. Now both the block A and the particle C are given velocity 3(
towards left. The block A strikes a fixed wall and suddenly stops.
Then, (the rod BC if free to rotate about B)
(A) the smallest velocity 3( for which particle C will swing in full
circle about the point B is 4C.

(B) the smallest velocity 3( for which particle C will swing in full circle about the point B is C.
(C) velocity of point C at the highest point of the circle (for the smallest value of 3( ) is zero.

(D) velocity of point C at the highest point of the circle (for the smallest value of 3( ) is C.

Integer
nteger Answer Type

This section contains 5 questions. The answer to each of the questions is a single digit
integer, ranging from 0 to 9. The appropriate bubbles below the re
respective question
numbers in the ORS have to be darkened. For example, if the correct answers to
question numbers X,Y,Z and W (say) are 6,0,9 and 2 , respectively, then the correct
darkening of bubbles will look like as shown:

1. A disc A of mass M is placed at rest on the smooth incline surface of


inclination .. A ball B of mass m is suspended vertically from the centre
of the disc A by light inextensible string of length l as shown in the
figure. If the acceleration
on of the disc B immediately after the system is
released from rest is

#DEF
EF&I JK L
.Find
5 JK L

k.

2. A uniform rod AB of mass M and length 2R is moving in a vertical


plane inside a hollow sphere of radius R. The sphere is rolling on a
fixed horizontal surface without slipping with velocity of its centre of
mass 2v. When the end B is at the lowest position, its speed is found
to be v as shown in
n the figure. If the kinetic energy of the rof at this


instant is "M3  . Find k


3. A small particle is given an initial velocity 3( =10m/s along the
tangent to the brimof a fixed smooth hemisphere bowl of
radius G( = 152 mas shown in the figure. The par
particle slides
on the inner surface and reaches point B, a vertical distance
h=15 m below A and a distance r from the vertical centerline,
where its velocity v makes an angle with the horizontal
tangent to the bowl through B. If = 15 N ( . Find the value of k (take g=10 m/22 
4. A smooth disc of mass M and radius

is placed at rest horizontally on a

smooth horizontal surface. A massless pin is fixed at point P at a distance


l/2 from centre O of the disc as shown in the figure. Now a thin uniform

rod of mass M and length L is placed horizontally on the surface of the disc parallel to the line
OP such that its mid point and centre O of the disc just coincide as shown in figure. Now rod has
given angular velocity O( =24 rad/sec in counter clockwise direction as shown. As a result , the
end of the rod strikes the pin P and sticks to it rigidly. Calculate the angular velocity of disc just
after collision.

5. One end of the pile of chain falls vertically through a hole in its support and
pull the remaining links steadly. The links which are at rest acquire the
velocity of the hanging position suddenly and without having interaction with
the remaining stationary links and with the support. If the acceleration a of
the falling chain is g/k. find k, ignore any friction.

CHEMISTRY

Part 2
Section-A
Straight Objective Type

This section contains 10 multiple choice questions numbered 1 to 10. Each question has 4 choices
A,B,C,D out of which only one is correct.
1. In a small sample of H atoms in excited state n=5, transition to ground state releases all possible
lines except the ones in Paschen series. How many spectral lines are released in the emission
spectra:
(A) 6
(B) 7
(C) 8
(D) 9
2. The following equillibria is maintained in a closed vessel:
P #& + 3Q #& 2PQ3 #&
Moles @ equilibrium

Equillibrium is now disturbed by removing x moles of Q and simultaneously doubling the


volume of vessel. At new equilibrium, 17 gms of NQ is obtained. Find x.

(A) 1
(B) 1.3
(C) 1.9
(D) 2.5

3. A solid particle having spherical shape is assumed to react only on its surface. However the
amount of reactant contained in it is determined by it volume. Consider the following rate law
for a solid particle shrinking due to reaction.

ST
!U

= k S(S = surface area)

The order of the above reaction will be:


(A)
(B)
(C)
(D)

0
1
2/3
3/2

4. Pure SV (g) is heated in a solid vessel to create the following equilibrium:
2 SV (g) 2 SV (g) + V (g). The vapour density of the equilibrium mixture is:
(A) 16
(B) 26
(C) 36
(D) 46
5. The self ionization constant for pure formic acid K = [HCOOQ ][HCOV ] has been estimated as
10W at room temperature. The density of formic acid is 1.15 g/cX . What percentage of
formic acid molecules convert to formate anion:
(A) 0.001%
(B) 0.002%
(C) 0.004%
(D) 0.004%
6. Reactions at a very first instant of their life, i.e shortly after start, follow:
(A) Pseudo zero order kinetics
(B) Pseudo first order kinetics
(C) Pseudo second order kinetics
(D) Pseudo third order kinetics
7. If Aufbau rule is not obeyed and instead electronic filling occurs orbit by orbit till saturation is
reached, calculate the percentage change in total of (n + l) values for unpaired electronics in an
atom of manganese.
(A) 20

(B) 40
(C) 60
(D) 80
8. The pH at which a 0.01 M A
AC  solution is 99.99% precipitated is
(YZ Al(OH& = 1 X 10-18 at 25o C)
(A) 6.67
(B) 7.67
(C) 8.67
(D) 10
9. The styx number for B2H6 is:
(A) 2012
(B) 2222
(C) 2002
(D) 2102
10.

(A)
(B)
(C)
(D)

Decreasing order of shown angles will be:


[ > [ > [
[ > [ > [
[ > [ > [
[ = [ = [

MULTIPLE CORRECT CHOICE TYPE

This section contains 5 multiple choice questions. Each question has 4 choices A,B,C,D for its answer ,
out which ONE or MORE is/are correct.

11. Identify the correct statements w.r.t the titration curves shown below:

(A) Equivalence point with strong base is at pH=7


(B) Equivalence point with weak base is at pH=7
(C) Phenolphthalein (8 9.8) can be used as indicator in both titrations.
(D) Chlorophenol red (4.8 6.4) can be used as indicator in both titrations.
12. For solution of alkali metal (M) in liquid NH3, identify which of the following equillibria would
simultaneously exist:
(A) M + (x + y) NH3 M(NH3&
\ + e (NH3)y


(B) 2]#^

(C) 2;^

(D) ]#^

&

+ 2e-

M2 (am)


;#^
&


& + ; ]#^

&

13. Which of the following would be starved in the Lewis dot structure of N4O;
(A) Positive charge on N
(B) Negative charge on N
(C) Oxygen atom at the terminus
(D) Electronic delocalization
14. Which one of these statements correctly compare between SF4 and SF6;
(A) Both molecules have same hybridization for S atom.
(B) Both molecules have at least one linear F S F link
(C) SFW has higher boiling point than SF
(D) SF reacts vigorously with water whereas SFW is inert towards water
15. Inorganic benzene surpasses organic benzene in which property:
(A) Melting point

(B) Edge length of its hexagon


(C) Molar mass
(D) Total number of electrons in the molecule
SECTION C
INTEGER ANSWER TYPE

This section contains 5 questions. The answer to each of the questions is a single
digit integer, ranging from 0 to 9. The appropriate bubbles below the respective
question numbers in the ORS have to be darkened. For example, if the correct
answers to question numbers X,Y,Z and W (say) are 6,0,9 and 2 , respectively, then
the correct darkening of bubbles will look like as shown:
1. Ammonium carbonate is heated at 2270 C in a closed vessel of volume
8210 ml containing 0.2 mole of Argon gas. The manometer attached to the vessel shows a
pressure of 1 atom. Find K0 for NH2COONH4(s) 2NH3 (g) + CO2 (g)
2. Silver (I) ferrocyanide and Bismuth(III) sulphide are sparingly soluble salts with identical
^ 

water solubility. The ratio of their Ksp is


a  . Find (a+b).
3. On the Mohs hardness scale, what value is assigned to Gypsum mineral (CaSO4.2H2O)
4. How many gases/vapours are involved either as reactants or products in Serpecks process
used for concentration of bauxite.
@

5. The magnitude of potential energy of electron in nth excited of He+ ion is @ times the kinetic
energy of electron in the first excited state of Li+2 ion. Find n.

PART III
Section-A
Straight Objective Type
This section contains 10 multiple choice questions numbered 1 to 10. Each question has 4 choices
A,B,C,D out of which only one is correct.
1. Let f(x) = {(0.1)}3[x]}. (where [.] denotes greatest integer function and {.} denotes fractional part)
If f(x + T) = f(x) x 0, where T is fixed positive number then the least value of T, is

(A)
(B)
(C)
(D)

2
4
6
None of these

2. The minimum value of the function f(x) =


{}

- {x} occurs at x equals to (where {.} represents

part function)
(A) n +
(B) n
(C) n
(D) n

,n1



- ,n1


+ ,n1


+,n1

3. Consider the function f defined by

f (x) =

{ 0, when x = 0 or x is irrational,


K

, when x is non- zero rational number

, n > 0 and

is in

lowest term
which of the following statement(s) is (are) true?
(A) X = 0 is a point of discontinuity of f
(B) Any non-zero rational number is a point of continuity of f
(C) Any rational number is a point of continuity of f
(D) Any irrational number is a point of discontinuity of f
4. If co-domain is R, then which of the following functions is not a surjective (onto) function?
(A) f (x) = In |ln #i [i]m&|, (where [.] denotes the G.I.F)
(B) f (x) = x + cos (n[i]&, (where [.] denotes the G.I.F)
(C) f (x) = tan-1 x 

(D) f (x) =   




5. The value of o # #  - x + x In x ) sinx ) dx is

(A) Sin e cos 1


(B) cos e sin 1
(C) Sin e + cos 1
(D) cos e + sin 1
6. The differential equation of a family of curves whose angle of intersection with the family of


parabolas y2 = kx, (k = parameter), is  , is

(A)
(B)

!q
!
!q
!

q

= q
q

= q

(C)

!q
!

q

= q

(D) None of these


7. The value of x for which the function f(x) = sin-1 sin [x] is increasing can be given by
(A) X sin x <0
(B) X sin x >0
(C) X cos x <0
(D) X cos x >0
8. If |b| > |a + c | then atleast one root of the equation ax4 + bx3 + c = 0 lies in the interval
(A) (-2,0)
(B) (-1,1)
(C) (0,2)
(D) (1,3)


9. Let f(x) = o Cr1/2 (1 2-1 )dt then the value of f(2) + f(2 log23), is
(A)
(B)
(C)
(D)

 t    u  
dx
v 

  u
In ((t )v ) + c


  u
In ((t ) + c


  u
In (()v ) + c


  u
In (  ) + c


10.
(A)
(B)
(C)
(D)

0
1
2
3 2log23

is

MULTIPLE CORRECT CHOICE TYPE


This section contains 5 multiple choice questions. Each question has 4 choices A,B,C,D for its answer ,
out which ONE or MORE is/are correct.
11. Let f: RR, f(x) = x + In (1 + x2) then
(A) f is injective
(B) limy z(i) = +
(C) There is a point on the graph of y= f(x) where tangent is not possible is not parallel to any of
the chords
(D) F is bijective
12. If lim ( log3 (ax2 + 3x + 1))log(x-1)3 = l , where l is a finite real number then

(A)
(B)
(C)
(D)

a must be (-1)
a can have more than one values
L= e-2/3
L= e-1/3







13. Let a function f(x) , x 0 such that f(x) + f( ) = f(x). f( ) then f(x) can be
(A) 1 x2013

(B) |i| + 1
(C)
(D)


U^K} ||

" ~K ||

14. Let g be the inverse of the continuous function f. Let there be a point (, ), where  , is
such that is satisfies each of y = f(x) and y = g(x) then
(A) The equation f(x) = g(x) has infinite many solutions
(B) The equation f(x) = g(x) has atleast 3 solutions
(C) F must be a decreasing function of x
(D) G can be an increasing function of x
^  a

15. Let f(x) = !   p . If f(x) is not a constant function and both minimum and
maximum values of f(x) exist then
(A) F(x) must be a continuous function
(B) 4ac must be more than b2
(C) 4fd must be more than e2
(D) Ae must not be equal to bd

SECTION C
INTEGER ANSWER TYPE

This section contains 5 questions. The answer to each of the questions is a single digit integer, ranging
from 0 to 9. The appropriate bubbles below the respective question numbers in the ORS have to be
darkened. For example, if the correct answers to question numbers X,Y,Z and W (say) are 6,0,9 and 2 ,
respectively, then the correct darkening of bubbles will look like as shown:

1. The number of integers belonging to the interval [-3,30] but not belonging to the range of the
function
F(x) = x{x} x [-x], x R, is (where [.] and {.} denote the greatest integer function and functional
part respectively)


2. Find the maximum possible integral value of U^K}  U^K}  , where 0 < < <3 , is
:7

3. Let z([) = o <r2  sin([  ) i . If the value of



z  
 





z  is k then the value of

64 N , is
4. Consider a rectangle with vertical A = (0,0), B = (4,0), C = (4,6), D = (0,6). Let S be the region
consisting of all points P inside the rectangle such that
d(P, DC) < d(P,AB) < max.{d(P,BC);d(P,AD), where d(P,MN) denotes distance of the point P from
the line joining points M and N. the area of the region S in square units, is
5. If Rolles theorem is applicable to the function, z(i) =
+

I , then the value of a + b is

~K 


over the interval [a, b], where a, b

ANSWER KEY
Q. No.
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
1
2
3
4
5

Physics
B
A
B
B
C
D
C
B
A
B
A,B,C
A,B,D
A,D
A,C
A,C
1
3
3
6
3

Chemistry
A
C
C
C
D
A
B
D
C
B
A,D
A,B,C,D
A,B,C,D
D
B,C
0
7
2
5
5

Mathematics
B
B
C
C
A
C
D
B
D
C
A,C,D
A,D
A,B,C,D
B,C
A,C,D
8
3
3
1
6