Prepared by:
PO5 - Lime
Raymond A Li 44368991
22/3/2016
Executive Summary
P05-Lime had been assigned by the University of Queensland to design a solution for
waste water reuse in Mayukwayukwa. This study analysed prior work on urine waste water
treatment and reuse to design a cost-effective, portable, and modular system capable of
recovering a solid fertiliser, liquid household disinfectant, and irrigation water from urine.
The scope of this project deals solely with urine from pit latrine toilets. Faeces and flush
water or other waste are considered out of scope.
Constraints limiting this design include:
In order to overcome these constraints several past solutions were compared and
analysed. The most effective method was deemed to be an application of adsorption
through natural loess to produce a fertiliser, followed by a sequence of low-power electrooxidation and mixed-method filtration to produce a liquid disinfectant and irrigation water.
Research about the local culture found no reason to oppose or reject using the system.
The volume of urine treated daily had been approximated to 14L. First the urine will
undergo adsorption with natural loess, a widespread naturally occurring type of soil.
Research has demonstrated that this is capable of total recovery of the ammonia and
phosphate content of urine, producing up to 919 grams of solid fertiliser per day.
The ammonia and phosphate depleted urine will then be filtered by a 0.45 m membrane
filter to remove some of the total dissolved solids, and then undergo electro-oxidation to
produce active chlorine, which will allow the liquid to serve as disinfectant. Half of the
solution will be kept for this use, while another half will undergo filtration by reverse
osmosis to produce irrigation water free of contaminants.
The power of operating this system has been estimated to be very low at 0.87W/d. This
could easily be supplied by a solar panel which eliminates operating cost. In total the initial
capital cost has been estimated to be $4.64/L considering the commodity price ratio of
Zambia and Australia.
A method to dispose of the waste is not yet determined, and should be the primary subject
of future investigation. The estimations made in this investigation ultimately depend of the
actual final design.
TABLE OF CONTEN
Executive Summary.....................................................................................................................i
1.
Introduction.........................................................................................................................1
1.1
1.1.1
Fertilisers...............................................................................................................2
1.1.2
Irrigation...............................................................................................................2
1.1.3
Sanitation..............................................................................................................2
1.1.4
1.2
2.
2.1.1
2.2
3.
Ureolysis...............................................................................................................4
2.2.1
2.2.2
2.2.3
3.2
4.
3.1.1
3.1.2
Adsorption Method.............................................................................................10
3.3
3.4
3.5
3.6
System Wastes............................................................................................................11
3.7
Energy Requirement...................................................................................................11
3.8
Mass Balance..............................................................................................................11
3.9
Cost.............................................................................................................................11
3.10
References.................................................................................................................................14
Appendix A: Calculations.........................................................................................................16
Appendix B: Tables...................................................................................................................19
1. INTRODUCTION
Figure 1. UNHCRs mission in Zambia, with location of Mayukwayukwa marked. (UNHCR, 2015)
Means of sanitation, irrigation, and lack of fertilisers form a large problem for the ~11000
people living at the Mayukwayukwa refugee settlement located in the Kaoma district of
western Zambia (Figure 1). In a region where soil quality is subpar, these issues prove
crippling for a society primarily dependent on subsistence farming. A filtration and reuse
system would address these problems by filtering yellow water (urine waste) into water
capable of irrigation, while isolating materials that could function as solid fertilisers and a
household disinfectant. P05-Lime had been assigned by the University of Queensland and
the Engineers Without Borders to design a solution for waste water reuse in
Mayukwayukwa.
1.1 Background on the Mayukwayukwa Situation
The Mayukwayukwa refugee camp is located in the Kaoma District of Western Zambia,
jointly administrated by the Zambian government and the United Nations High Commission
for Refugees. It hosts around 11000 refugees and asylum seekers, of which over 6000 are
from neighbouring Angola. (UNHCR, 2015)
Currently, the community is facing three problems impacting their wellbeing: The lack of
fertilisers to improve soil quality, lack on household sanitation, and lack of water suitable
for irrigation.
1.1.1 Fertilisers
The community largely depend on subsistence farming, however the poor quality of the
land and lack of irrigation and effective fertilizers severely impede their efforts. The soil in
western Zambia, where the settlement is located, are largely ferrallic arenosols, which are
infertile, coarse sands. This is largely due to the lack of key elements and compounds in
the soil, namely nitrogen, phosphorus, and potassium. The problem would be mitigated by
the use of fertilisers containing such elements, however the residents are in no economic
condition to afford any commercial fertilisers. (UNHCR, 2015)
1.1.2 Irrigation
The farming in Mayukwayukwa is further hampered as previously reliable rainfall patterns
are becoming inconsistent, coupled by the fact that the mean annual rainfall over Zambia
has decreased by an average of 1.9mm per month per decade since 1960. The region in
which Mayukwayukwa is located experiences frequent mid-season dry spells. (UNHCR,
2015) This reduced precipitation is reducing yields in farming at the settlement, despite
efforts to raise drought resistance crops. In the Kaoma district where the settlement is
located, 45.8% people lack access to clean water. (UNHCR, 2015) The community largely
relies on using groundwater from bore holes drilled in the ground, for all purposes. This
divides the limited supply between drinking, irrigation, and sanitation. The extraction of
water is a lengthy and difficult process involving travelling to the holes and using hand
pumps. (UNHCR, 2015) The work is primarily done by women and children. A waste reuse
system could simplify the process, and reduce the use of groundwater for irrigation,
allowing more water to be diverted to other uses.
1.1.3 Sanitation
The community in Mayukwayukwa up to now uses pit latrine toilets, which are simply a
hole in the ground (Figure 4). In areas where these toilets are not available, open
defecation is practiced. Both these practices led to poor hygiene and environmental stress
by waste leaching into surrounding soils. Replacement of the pit latrines with urine
separating toilets have been suggested. (UNHCR, 2015) Assuming that project will be
implemented, the diverted urine provides the basis for the reuse system. As the toilets will
still not be sanitary, a portion of the reused urine could be utilised as a household
disinfectant.
1.1.4 Cultural and Social Considerations
Research did not encounter anything that would prevent the people from Angola and
Zambia from using this system. Zambians have a cultural taboo of mentioning toilet related
matters, but it is not an absolute taboo. Prior education and warning is required before
operating the system locally. (Holmes, 1998) (Kwintessential, 2016)
6
1.2 Project Objectives and Considerations
The design will need to satisfy the following three main objectives in order to address the
relevant problems faced by the Mayukwayukwa settlement:
Table 1. Project Definition
Objectives
Functions & Features
Ammonia (g N m3)
Urea (g N m3)
Phosphate (g P m3)
Calcium (g m3)
Magnesium (g m3)
Sodium (g m3)
Potassium (g m3)
Sulphate (g SO4 m3)
Chloride (g m3)
Carbonate (g C m3)
Total COD (g O2 m3)
pH (dimensionless)
Ureolysis in pipes
Literature
Fresh urine
Fresh urine
Urine
Mean
CV%
254
5810
367
129
77
2670
2170
748
3830
8150
7.2
4.5
0.9
1.4
2.7
0.6
Stored urine
1720
73
76
28
1
837
770
292
1400
966
1650b
9.0b
Mean
CV%
Mean
CV%
Data range
386
8750
559
168
121
3730
2250
1350
5230
<5
9700
6.0
2.5
3.1
4.6
1.7
1.7
3.2
2.3
0.8
1.6
4.9
0.3
480
7700
740
190
100
2800
2200
1500
3800
6.2
29
20
14
22
21
29
18005800
13003100
23007700
Content Removed
Organic
Particles
Inorganic
Particles
Bacteria
Power
Requirement
None
Advantages/Disadvantages
Centrifugation
(Maurer et al,
2006)
Distillation
(Fumasoli et al,
2016)
Reverse
Osmosis
(Voigt et al,
2012)
Electrodialysis
Inorganic
Particles
Bacteria
Requires high
electrical power
Inorganic
Particles
Dissolved
Solids
Bacteria
Dissolved
Solids
Dissolved
Gases
Requires
thermal energy
Ions (salts)
Requires
electrical power
(Jiang et al,
2015)
None
(Udert et al,
2015)
Adsorption
Organic
Particles
Bacteria
Dissolved
Gases
Dissolved
Solids
Bacteria
None
No power requirement
Simple to operate
Filters majority of
pollutants
Does not filter dissolved
material
Needs periodic
maintenance
High electrical power
required
Does not filter majority of
pollutants
Filters majority of
pollutants
High Energy requirement
No power requirement
Filters dissolved material
10
fault is that the process does not eliminate virus and bacteria, and while heating would
sterilise the struvite, studies show it is not stable above 55 C and would break down to
other compounds. (Udert et al, 2015)
Further studies have noted, however, that despite disadvantages mentioned above, during
field testing struvite performed equally to conventional fertilisers, suggesting that it did
possess a viable amount of phosphate and nitrogen, and the microorganism presence is
negligible. This could be further true given stored urine is known to be free of
microoganisms. (Bonvin, 2013) (Rmer, 2006)
Another mainstream option for treating urine is nitrification then distillation, which allows a
completely recovery of all nutrients and elimination all of all microorganisms. It has been
noted this that is the only option currently to achieve this. (Udert et al, 2015) The contrast
of the two methods could be seen in Table 5. However, this method is decisively
unfeasible in Mayukwayukwa due to the expense and sophistication of equipment
required, as well as the complexity of operation. This approach, as done by Fumasoli et al.
and Udert et al, involved a pilot-scale plant featuring moving-bed bio-reactors and
industrial grade stills. During the nitrification stage half of the total ammonia is biologically
converted to nitrate in a bio-reactor, then concentrated through distillation. (Fumasoli et al,
2016) (Udert et al, 2015) Udert et al. calculated the energy consumption of the overall
process to be 80 W Cap-1, while testing from Fumasoli et al. revealed a requirement of
71W Cap-1, which is noted by Mauer et al. to be more than two and a half times higher
than conventional wastewater treatment in first world countries. (Fumasoli et al, 2016)
(Udert et al, 2015) (Mauer et al, 2003) In a region of Zambia where grid power is not
dependable and economy is poor, supporting such an operation is highly unrealistic.
Jiang et al. pioneered a new method of obtaining both nitrogen and phosphorus from
urine, through adsorption of the nutrients by natural loess, which has an absorption
capacity of 23.24 and 4.01 mg/g for ammonia and phosphate respectively. The process,
which does not require electric power, recovered a compound with high concentrations of
N and P, which Jiang et al. believed would be a suitable and environmentally friendly
fertiliser. (Jiang et al, 2015) Graphs provided show that the adsorption rate is high for the
first 200 minutes (Jiang et al, 2015), which could allow fast and reliable fertiliser production
for Mayukwayukwa. Since the nutrients necessary are adsorbed onto the solid loess,
separation from urine should be simple using filters. Another distinct advantage is that the
adsorption process would function regardless of previous treatment steps to recover other
nutrients as long as nitrogen and phosphorus are present within the urine. This method
also ensures the total recovery of all ammonia and phosphate, as loess could be added
until all nutrients are adsorbed. Jiang et al. had taken advantage of the large amounts of
natural loess in China, where the experiment was conducted, however natural loess
formations are unknown in Zambia. To be used in Mayukwayukwa it may have to be
imported with cost unknown, however given that loess is a common type of soil found in
most continents it is not expected to be expensive. Jiang et al. had suggested loess to be
a cheap recovery solution for third world countries. (Jiang et al, 2015)
11
12
Average of Daily
Output (L)
0.8 - 2
1.4
Table 6. Daily Urine Processed
Min Volume
Required to
Treat Daily
(L)
8
Max Volume
Required to
Treat Daily (L)
Average Volume
Required to Treat
Daily (L)
20
14
Phosphate in
Stored Urine
Ammonia
Removed
(based on
Etter et al.)
Ammonia
Removed
(based on
Kabdasli
et al.)
Phosphate
Removed
Daily Struvite
Recovery
based on
Average
Volume Urine
Output (Based
on Etter et al.)
Daily
Struvite
Recovery
based on
Average
Volume
Urine
Output
(Based
on
Kabdasli
et al.)
1.72 g/L
0.076 g/L
0.0516 g/L
0.86 g/L
0.0722 g/L
0.00276
kg /d
0.03
kg/d
13
Phosphate in
Stored Urine
Ammonia
Adsorption
Capacity of
Loess
Phosphate
Adsorption
Capacity of
Loess
1720 mg/L
76 mg/L
23.24 mg/g
4.01 mg/g
Mass of
Loess after
Adsorption of
all Ammonia
and
Phosphate in
Daily Output
by 10 People
(Average)
0.919 kg/d
Daily
Ammonia
&
Phosphat
e
Recovery
(Average
Urine
Output)
0.0251
kg/d
14
Composition Data from Udert et al (2006)
Table 9. Daily Mass of Contaminants Removed
3.5 Chemical Requirements of System
The system requires several chemicals depending on the approach. The struvite
precipitation process requires magnesium salts, the cheapest being MgO. The adsorption
method requires natural loess. Loess requirement per day is 0.919 kg, as found during
3.2.1.
3.6 System Wastes
The waste generated by the system is composed of all the elements filtered from the urine
at various stages except the ones that are used: ammonia, phosphate, and chlorine. Using
data from the filtered mass daily, waste produced daily amounts to 0.0276 kg/d.
3.7 Energy Requirements
Based on the chemical equation of electro-oxidation (Li et al, 2014), and assuming half the
urine is diverted to disinfectant production, it could be calculated that the power required
for the process would be 0.87 W/d. Manual reactor for struvite precipitation and the loess
adsorption method require no electrical power.
3.8 Mass Balance
Volum
e (L)*
COD
(mg)
BOD
(mg)
Ammoni
a (mg)
TDS
(mg)
Sodiu
m
(mg)
Chlorid
e (mg)
Phosphat
e (mg)
Urine IN
14
8890
0
0
11718
19600
2476.5
5842
0
0
24080
Loess
Adsorptio
n
ElectroOxidation
9186
8
0
Micro
pollutant
s
(g)
1
-2476.5
-5
-370
2590
-9250
-14800
Filtration
-4800
-1
4140
8631
0
0
-2468
Irrigation
Water
OUT
9149
8
0
1702
0
0
-24080
Table 10. Mass Balance of System. Data from Udert et al, Li et al, Jiang et al, and CSIR
3.9 Cost
A rough estimate of the cost can be made based on some prices of equipment and
chemicals. Assuming loess can be locally acquired and the rest of the equipment
(containers, pipes) amount to $50, initial capital cost per litre is estimated to be $4.64/L,
while there is no running cost.
15
16
17
References
Adventec. (2016). Membrane Filters. Retrieved March 21, 2016, from Adventec:
http://www.advantecmfs.com/catalog/filt/membrane.pdf
Bonvin, C. (2013). Recycling of Phosphorus and Nitrogen from Human Urine: Evaluation
of two based fertilisers. Zurich: Swiss Federal Institute of Technology.
Etter, B., Tilley, E., Khadaka, R., & Udert, K. K. (2011). Low Cost Struvite Production Using
Source Separated Urine in Nepal. Water Research, 852-862.
Fumasoli, A., Etter, B., Sterkele, B., Morgenroth, E., & Udert, K. M. (2016). Operating a
pilot-scale nitrification/distillation plant for complete nutrient recovery from urine.
London: IWA Publishing.
Grau, M., Etter, B., Udert, K. M., Buckley, C. A., & Brouckert, C. J. (2012, May 6-10).
Development and operation of struvite reactors to recover phosphorus from source
separated urine in eThekwini. Proceedings of the WISA 2012 Biennial Conference
& Exhibition. Cape Town, South Africa.
Jiang, S., Wang, X. C., & Yang, S. (2015). Characteristics of Simultaneous Ammonium and
Phosphate Adsorption from Hydrolysis Urine onto Natural Loess. Environmental
Science and Pollution Research, 50-62.
Li, H., Yu, Q., & Yang, B. (2014). Electro-catalytic oxidation of artificial human urine by
using BDD and IrO2 electrodes. Journal of Electroanalytical Chemistry, 738, 14-19.
Maurer, M., Larsen, T. A., & Pronk, W. (2006). Treatment Processes for Source-Separated
Urine. Water Research, 3151-3166.
Rmer, W. (2006). Plant Availability of P from Recycling Products and Phosphate
Fertilisers in a Growth Chamber Trial with Rye Seedlings. Journal of Plant Natural
Soil Science, 826-832.
Sakthivel, S. R., Tilley, E., & Udert, K. M. (2012). Woods Ash as a Magnesium Source for
Phosphorus Recovery from Source Separated Urine. Sci. Total Environment, 68-75.
Udert, K. M., Buckley, C. A., Wachter, M., McArdell, C. S., Kohn, T., Strande, L., . . . Etter,
B. (2015). Technologies for the Treatment of Source Separated Urine in the
eThekwini Municipality. Dubendorf: Swiss Federal Institute of Aquatic Science and
Technology.
Udert, K., Larson, T. A., Biebow, M., & Gujer, W. (2003). Urea hydrolysis and precipitation
dynamics in a urine-collecting system. Water Research, 25712582.
UNHCR. (2015, January 1). Zambia. Retrieved from The UN Refugee Agency:
http://www.unhcr.org/pages/49e485ba6.html
Voigt, E., Jaeger, H., & Knorr, D. (2012). Securing Safe Water Supplies: Comparison of
Applicable Technologies. Oxford: Academic Press.
18
Wilsenach, J., Schuurbiers, C., & Van Loosdrecht, M. (2007). Phosphate and Potassium
Recovery from Source Separated Urine Through Struvite Precipitation. Water
Research, 458-466.
Woisetschlager, D., Humpl, B., Koncar, M., & Siebenhofer, M. (2013). Electrochemical
oxidation of wastewater - opportunities and drawbacks. Water Science Technology,
1169-1173.
Zollig, H., Fritzsche, C., Morgenroth, E., & Udert, K. M. (2015). Direct electrochemical
oxidation of ammonia on graphite as a treatment option for stored source-separated
urine. Water Research, 69, 284-295.
19
Appendix A: Calculations
A.1 Volume of Waste Treated Daily
Range of daily urine output = 0.8 2 L
Average = (0.8+2)/2= 1.4 L
Output daily by ten people = 1.4 x 10 = 14 L
A.2 Solid Fertiliser Production Rate
A.2.1 Struvite Precipitation Method
1.72g/L of ammonia and 0.076g/L of phosphate are present in hydrolysed urine (Udert et
al 2003). Etter et al. (2011) reported that 95% of the phosphate is removed, and around
3% of the ammonia is removed as part of MgNH4. Water is assumed to be retained.
0.076 0.95=0.0722 g
1.72 0.03=0.0516 g
17.031 g /mole
0.0516
17.031
(3.029 103)24.305=0.0736 g
0.0736+0.0722+0.0516=0.197 g
0.197 14=2.764 g
Kabdasli et al. reported that around 50% of ammonia is precipitated. Calculating with the
same process gives 30.18 g struvite produced per day.
A.2.1 Adsorption Method
The adsorption capacity of natural loess is 23.34 mg/g for ammonia and 4.01mg/g for
phosphate. Capacity for ammonia + phosphate = 27.35 mg/g
Ammonia and phosphate present in 14L of urine = 1.72 x 14 (ammonia) and 0.076 x 14
(phosphate) = 24.08 g (ammonia) and 1.064 g (phosphate)
20
Loess required to individually adsorb ammonia and phosphate in 14L =
24080 1064
+
=919.34 g
27.35 27.35
A.3 Product Water Flow-rate
Refer to mass balance.
A.4 Removal Rate of Nutrients and Contaminants
Values are obtained from Udert et al, 2003. Total ammonia and phosphate removal by
adsorption is assumed. Filters are assumed to be 100% effective, hence this is more like
an estimation. kg/d removal calculated by the g/L concentration of contaminants x14,
divided by 1000.
A.5 System Wastes
Waste is found by the mass removed daily of all contaminants minus ammonia,
phosphate, and chlorine. Data from Udert et al, 2003
A.6 Energy Requirements
Based on the chemical equation of electro-oxidation (Li et al, 2014), and assuming 7L per
day is diverted to disinfectant production, power for electro-oxidation could be found.
1.49+1.36
C l 2 +2 e
2C l
++OC l
HOCl H
= 1.36V
= 1.49V
2.85V
Grams of Chlorine in 1 Litre of urine = 1.4g
mass of chlorine 7 L=7 1.4
9.8
moles of chlorine=
9.8
35.45
0.276 mol
For every two moles of hypochlorite, one mole of hypochlorite ion formed.
0.276
moles of hypochlorite=
2
0.138 mol
21
moles of hypochlorite=0.138
Hypochlorite to electron ratio = 1:2
moles of electrons=0.138 2
0.276
Charge (e) of 1 mole of electrons= 96,485C/mol
Assuming electro-oxidation persists for 24 hours:
en
I=
t
Where: I =current,
96 485 0.276
I=
86400
e =electron charge,
t =time (s)
0.308 A
Power=VI
2.85 0.308
0.87 W /d
Nave, R. (n.d.). Standard Electrode Potentials. Retrieved March 21, 2016, from
Hyperphysics: http://hyperphysics.phy-astr.gsu.edu/hbase/chemical/electrode.html
A.7 Cost
Cheapest found online 0.45 m membrane filter is $26, while portable reverse osmosis
filter is $40. Cheapest 1W solar panel comes at $3.89. Assumption is made that the
maximum cost for containers and pipes will be $50. Natural loess is assumed to be able to
be naturally acquired. 14L are processed daily.
Ebay Australia. (2016, March 21). Home. Retrieved from Ebay: http://www.ebay.com.au/
Capital cost =
26 +40+3.89+50
14
= $8.56
22
Ebay Australia. (2016, March 21). Home. Retrieved from Ebay: http://www.ebay.com.au/
Appendix B: Tables
Table 2. Water Quality Standards for Irrigation
Component
Acceptable Standards
Pathogenic Bacteria
10 cfu/100mL
Organic Micro-pollutants
Full Removal
pH
6.5 8.4
2000 mg/L
<9