8

Daily Tutorial Sheet

Choose the correct alternative. Only One choice is Correct.

1.

Consider the following reversible reaction : NO(g) NO3 (g) 2NO 2 (g)
If 1.0 mol of NO is mixed with 3.0 mol of NO 3, x mol of NO2 is produced at equilibrium. If 2.0 mol of NO is added
further, x mol of NO2 is further produced. What is the value of equilibrium constant?

2.

Carbonic acid, H2CO3, is a diprotic acid for which K1 = 107 and K2 = 1011. Which solution will produce a pH closest
to 9?
(A)
0.1 M H2CO3
(B)
0.1 M Na2CO3
(C)
0.1 M NaHCO3
(D)
0.1 M NaHCO3 and 0.1 M Na2CO3

3.

When 0.22 mole of CH3NH2 (ionization constant, Kb = 10 ) is mixed with 0.02 mole HCl and the volume is made up

to 1 litre, find the [H ] of resulting solution at 25C.

(A)

10 M

(B)

2 10 M

(C)

2 10 M

(D)

10 M

4.

The ionization constant of an acid-base indicator (a weak acid) is 1.0106. The ionized form of the indicator is red
whereas the unionized form is blue. The pH change required to alter the colour of the indicator from 80% blue to 80%
red is
(A)
2.00
(B)
1.40
(C)
1.20
(D)
0.80

5.

Find f H for HCl(g) from the following data:

(A)
6.

NH3(g) + HCl(g) NH4Cl(s);

rH = 176 kJ/mole

N2(g) + 3H2(g) 2NH3(g);

rH = 92 kJ/mole

N2(g) + 4H2(g) + Cl2(g) 2NH4Cl(g);

rH = 629 kJ/mole

536.5 kJ/mol

(B)

361 kJ/mol

(C)

92.5 kJ/mol

(D)

None

Which of the following statement(s) is(are) correct :

Statement (A) : The entropy of isolated system is always maximized at equilibrium
Statement (B) : It is possible for the entropy of close system to decrease in an irreversible process.
Statement (C) : Entropy can be created but can not be destroyed.
Statement (D) : Ssystem is always zero for reversible process in an isolated system.
(A)

Statement a, b, c (B)

Statement b, d

(C)

Statement a, b, d (D)

All

Paragraph for Questions 7 - 9

Observe the following graphic representation of four basic thermodynamic processes.

Isobaric
Pressure

Isothermal
Adiabatic

Isochoric
Volume

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Daily Tutorial Sheet

Read the paragraph carefully and answer the following questions:

7.

8.

Which of the following is true for isochoric process?

(A)
V = 0
(B)
U = q + PV (C)
Which of the following is not true for isothermal process?
V
w exp 2.303nRT log 2
(A)
(B)
V1
T = 0
(D)
Cp
1.30 then the atomicity of gas will be:
If the ratio
Cv
(A)
1
(B)
2
(C)
(C)

9.

10.

dP
dt

dn

dt

The overall rate

(A)

12.

(D)

w exp 2.303nRT log

All of these

P1
P2

T1V11 T2 V2 1

(D)

dP
dC
dn
For a gaseous reaction, the rate of reaction is expressed in terms of
instead of
or
, where C is concentration
dt
dt
dt
and n is the number of moles. Hence, the relation between expression is :
dC dn
V dP
dC 1 dn
1 dP
(A)
(B)

d t d t RT d t
d t V d t RT d t

(C)

11.

U = qv

dC

d P
dt
2

(D)

dt

K kf [A] [C]

None of these

K (capital)
kf

, for the reaction 2A

P is given by :
B; B C

(B)

K [A] [B]

(C)

kf [B]

(D)

K kf [A] [B] [C]

The following plot represents the variation of the concentration of a species A and B against time
Reaction : A
B.

The point of intersection of the two curves represents :

(A)
(B)
(C)
t1/ 2
t3 / 4

t2 / 3

(D)

13.

An azeotropic solution of two liquids has boiling point lower than either of them when it:
(A)
Shows negative deviation from the Raoults law
(B)
Shows no deviation from the Raoults law
(C)
Shows positive deviation from the Raoults law
(D)
Is saturated

14.

Which of the following graphs represent the behaviour of ideal binary liquid mixture?

t1/ 3

(A)

Plot of 1 / PTotal aginst y A is linear

(B)

Plot of 1 / PTotal aginst y B is non-linear

(C)

Plot of PTotal aginst y A is linear

(D)

Plot of PTotal aginst y B is linear

(Here, y A and y B are the mole fraction of components A and B in vapour).

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15.

Daily Tutorial Sheet

The EMF of the following cell is 0.265 V at 25C and 0.2595 V at 35C.

Pt H2 HCl aq AgCl Ag.

The heat of reaction taking place at 25C is
(A)
90.8 kJ
(B)
80.8 kJ
16.

17.

82.76 kJ

(D)

41.38 kJ

Which of the following types of structure is not possible for organic compound having molecular formula C4H6?
(A)

Structure having only sp2 hybridized carbon atoms

(B)
(C)
(D)

Structure having only sp3 hybridized carbon atoms

Structure having only one type of CC bond length
Structure capable to show geometrical isomerism

Evaluate each of the following processes applied to cyclononatetraene, and identify in which process(es) the species
formed is aromatic?

(A)

Addition of one more electron, to give C9 H10

(B)

2
Addition of two more electron, to give C9 H10

(C)
(D)
18.

(C)

Loss of H+ from the sp3-hybridized carbon

Loss of H+ from one of the sp2-hybridized carbons

In FCC crystal, which of the following shaded planes contains the following type of arrangement of atoms :

(A)

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(B)

(C)

(D)

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Daily Tutorial Sheet

11

Choose the correct alternative. Only One choice is Correct. However, questions marked with '*' may have More than One
Correct option.
1.

Consider a uniform rectangular plate of mass M and dimensions (a b). Its moment of inertia about one of the diagonal
is:
(A)

2.

Ma 2 b 2
6(a 2 b 2 )

(B)

Ma 2 b 2
3(a 2 b 2 )

(C)

Ma 2 b 2
12(a 2 b 2 )

(D)

None of these

A uniform rod rotating in gravity free region with certain constant angular velocity. The variation of tensile stress with
distance x form axis of rotations is best represented by which of the following graphs.

(A)

(B)

(C)

(D)

3.

A vessel contains 1 mole of O2 at a temperature T. The pressure of gas is P. An identical vessel containing 1 mole of the
gas at a temperature 2T has
(A)
P
(B)
2P
(C)
3P
(D)
4P

4.

A vessel of uniform cross section (open at the top with an orifice at the bottom contains oil
(relative density 0.8) on top of water. Water flows out of the vessel. The initial speed of water
for the values given in the figure is nearly.
(A)
10.0 m/s
(B)
8.0 m/s
(C)
16.7 m/s
(D)
5.0 m/s

5.

Oil
Water

5m
10m

A particle executes simple harmonic motion between x = A and x = +A, the time taken for it to move from x = 0 to

A
A
A
is T1 and to move from
to
is T2, then
2
2
2
(A)
T1 < T2
(B)
T1 = T2
(C)
x

T1 = 2T2

(D)

T2 = 2T1

6.

In a sonometer wire the fundamental frequency of the wire is 260Hz. In a sonometer the tension is maintained by
suspending a 50.7 kg mass. When the suspended mass is completely submerged in water fundamental frequency
becomes 240 Hz. The suspended mass has a volume
(A)
0.002 m3
(B)
0.0075 m3
(C)
0.004 m3
(D)
0.006 m3

*7.

For the situation shown in the figure, mark out the correct statement(s)

(A)

q
Potential of the conductor is
4 0 (d R )

(B)

Potential of the conductor is

(C)

Potential of the conductor cant be determined as nature of distribution of induced charges is not known

(D)

Potential at point B due to induced charges is

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Hollow neutral conductor

q
4 0d
qR
4 0 (d R )d

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12

*8.

Daily Tutorial Sheet

Two sources of current of equal e.m.f. are connected in series and have different internal resistances r1 and r2. An
external resistance R is connected in series with these sources of e.m.f.
(A)
R = (r1 r2), for terminal potential difference to be zero across source 1
(B)

R = r1r2 , for terminal potential difference to be zero across both sources

(C)

R = (r2 r1), for terminal potential difference to be zero across source 2

(D)

data insufficient to arrive at a conclusion

*9.

When a current carrying coil is placed in a uniform magnetic field with its magnetic moment anti-parallel to the field
(A)
torque on it is maximum
(B)
torque on it is zero
(C)
potential energy is maximum
(D)
dipole is in unstable equilibrium

*10.

A ball of mass m is projected from the ground with an initial velocity u making an angle with the horizontal. Then
choose the correct statement(s).
(A)
the change in velocity between the point of projection and the highest point is u sin j (downward)

11.

(B)

the average velocity averaged over the time of flight is u cosi (horizontal)

(C)

the change in velocity in the complete projectile motion is 2usinj

(D)

the rate at which momentum of the ball is changing is constant

A heavy spherical ball is constrained in a frame as shown in figure. The inclined

surface is smooth. The maximum acceleration with which the frame can move

30

n
without causing the ball to leave the frame is
. Find value of n.
3
12.

Board A is placed on board B as shown. Both boards slide, without moving with respect to each other, along a
frictionless horizontal surface at a speed 6 m/s. Board B hits a resulting board C "head-on". After the collision, boards B
and C stick together and board A slides on top of board C and stops its motion relative to C in the
position shown on the diagram. What is the length (in m) of each board? All three boards have the same mass,
size and shape. The coefficient of kinetic friction between boards A and C and between boards A & B is 0.3.
(Take g = 10 m/s2)

13.

One side of a spring of initial, unstretched length l0 = 1 m, lying on a

frictionless table, is fixed, the other one is fastened to a small puck of mass m =
0.1 kg. The puck is given velocity in a direction perpendicular to the spring, at
an initial speed v0 = 11 m/s. In the course of the motion, the maximum
elongation of the spring is l = l0/10. If k is the force constant of the spring (in SI
units), find k/30?

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14.

13

In column 1, a uniform bar of uniform cross - sectional area under the application of forces is shown in the figure and in
Column 2, some effects/phenomena are given. Match the entries of Column 1 with the entries of Column 2.
Column-1

15.

Column-2

(A)

(p)

Uniform stress developed in the rod

(B)

(q)

Non-uniform stresses developed in the rod

(C)

(r)

Compressive stress developed

(D)

(s)

Tensile stresses developed

The diagrams below depict different processes for a given amount of an ideal gas. Match Column-I and II:
P

(i)

(ii)
Ft
(V)

Ft

(iii)
i

Ft

tF

(iv)

(1/V)

Column 1

Column 2

(A)

In fig.(i) as the system proceeds from the initial state to the

final state

(p)

Temperature will remain constant

(B)

In Fig. (ii), as the system proceeds from the initial state to

the final state

(q)

Pressure will decrease

(C)

In fig. (iii), as the system proceeds from the initial state to

the final state

(r)

Volume must increase

(D)

In fig. (iv), as the system proceeds from the initial state to

the final state

(s)

Temperature may increase, may decrease

or may first increase and then decrease

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14

Daily Tutorial Sheet

Choose the correct alternative. Only One choice is Correct.

1.

a, b, c, d are distinct integers such that

equal to :
(A)
r

2.

(B)

x a x b x c x d 4

2r

(C)

has an integral root r. Then a b c d is

3r

(D)

4r

If u a 2 cos 2 b 2 sin 2 a 2 sin 2 b 2 cos 2 , then the difference between maximum and minimum values of

u 2 is given by :
(A)
3.

a b 2

(B)

(C)

xl

(C)

xm

xn

l m n
l m 2 m n 2 n l 2
2
The points L, M, N are collinear
ar LMN

Lim

f x

(B)

abc

(B)

(D)

None of these

(D)

f x

(C)

f 1 x

(D)

f 1 x

a b c
3

(C)

abc

(D)

(abc)1/3

All its solutions real but not all positive.

(B)
Two of its solutions positive, two negative. (D)
x tan 1 / n log 1 / n

(C)

10.

(C)

3 ( x a ) ( x b) ( x c) x =

If f x lim e
(A)

9.

LMN is a right angled triangle

The equation ( x 2 3x 4) 2 3( x 2 3x 4) 4 x has :

(A)
(C)

8.

(B)

The reflection about the line x y 0 of the inverse function f 1 x of a function f (x) is :

(A)
7.

None of these

If A (0,) and B (0,) , , > 0 are two vertices of a variable triangle ABC where the vertex C (x, 0) is variable.

(A)
6.

(D)

2 2

The value of x for which ACB is maximum is :

(A)
(B)
2
5.

a 2 b2

If L 1 , l ; M 1 , m ; N 1 , n where xk 0 , denotes the kth terms of a H.P. for k N , then :

(A)

4.

a b 2

, and

Only two of its solutions real.

None of its solution real.

f x

3 sin11 x cos x dx g x C (C being the constant of integration). Then :

3
g
4 2
15

g
4
8

(B)

g x is continuous for all

(D)

g
4
2

It 5 letters are put in the 5 envelopes. Find the no. of ways so that atleast 2 letters are in wrong envelope :
(A)
120
(B)
119
(C)
118
(D)
117

min ( x1 x2 ) 2 12 1 x12 4 x2

(A)

4 5 +1

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(B)

x , x R is :
2

4 5 1

(C)

5 +1

(D)

5 -1

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