Daily Tutorial Sheet

Choose the correct alternative. Only One choice is Correct. However, questions marked with '*' may have More than One
Correct option.
1.

2.

In the reaction : CrO5 + H 2SO 4

Cr2 (SO 4 )3 + H 2 O + O 2
How many moles of O2 are liberated by 1 mol of CrO5 in above reaction?
(A)
5/2
(B)
5/4
(C)
9/2

7/4

3/ 2

1
r r / a0
2 e
a0
4 2 a 0
Where a0 is Bohrs radius. If the radial node in 2s be at r 0, then r0 would be equal to :
The Schrodinger wave equation for hydrogen atom is : 2s

(A)
*3.

(D)

a0
2

(B)

2a0

(C)

2a 0

(D)

a0
2

Select the correct statement(s):

(A)
At the limit of vanishing pressure, where all gases behave ideally, the volume tends to infinity and
intermolecular distances becomes enormously large
(B)
Gases with weak intermolecular forces obey the ideal gas law at relatively high pressures
(C)
Gases with strong intermolecular forces obey the ideal gas law at relatively low pressures
(D)
All the statements are incorrect

Paragraph for Questions 4 - 5

For an ideal gas P, V curve is hyperbola but for any real gas the
curves show variation. Andrew has observed the curve for CO2
and concluded that other real gases also show similar curve.
At high temperature real gas behaves similar to an ideal gas.
Answer following questions on the given information.
4.

5.

6.
*7.

The gas cant be liquefied when :

I.
Pressure is greater than 73 at 30.98C
II.
Pressure is smaller than 73 at 30.98C
III.
Both P and T are greater than 73 and 30.98 respectively.
IV.
At T2 temperature pressure applied is 73
(A)
TTTT
(B)
FTTF
(C)
TFTF
For the curve ABCD. The vapour pressure is given by :
(A)
Pressure corresponding to any point for AB (B)
(C)
Pressure corresponding to any point for BC (D)

(D)

FFTT

Pressure corresponding to any point for CD

Pressure corresponding to any point from A to D

The highest temperature at which the gas can be obtained in liquid state is :
(A)
31.1
(B)
30.98
(C)
13.1

(D)

21.5

Which of the following statement is correct about mean free path :

(A)
remains unchanged on heating the gas in a closed container
(B)
remains constant on heating the gas in a closed rigid container
(C)
On increasing the T, increases (P and n constant)
(D)

is inversely proportional to T

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Daily Tutorial Sheet

*8.

An open flask contains air at 27C. Calculate the temperature at which it should be heated so that 2/3 rd of air measure
at final temperature escapes out.
(A)
400 K
(B)
450 K
(C)
500 K
(D)
227C

*9.

In which pair first compound has more dipole moment than second compound?
(A)
P(CH3)2(CF3)3, P(CH3)3(CF3)2
(B)
CH3Cl, CH3F
(C)
NH3, NF3
(D)
Benzene, Borazine

*10.

In the molecular axis is z-axis, then which of the following sets of orbitals are not affected by s p mixing for N2
molecule?
2p x , 2p y
* 2p x , * 2p y
(A)
(B)
(C)
(D)
2s, 2p z
2s, * 2s

11.

Which of the following has planar geometry in both monomeric and dimeric forms?
(A)
ICl3
(B)
AlCl3
(C)
NO2
(D)

12.

BH3

2HI(g) .
The equation for the reaction in the figure below is : H 2 (g) I 2 (g) Heat

At the instant 3 min, what change was imposed into the equilibrium?
(A)
Pressure was increased
(B)
Temperature was increased
(C)
Iodine was added to the system
(D)
Hydrogen was added to the system

PARAGRAPH FOR QUESTIONS 13 - 15

Paragraph : Two containers A and B of capacity 1 litre and 2 litre respectively is connected by tube of negligible volume.
The tube is initially closed by stopcock and A contains small amount of H2O(l) and B contain initially pure COCl2(g) at
pressure of 100 torr. The gas COCl2 partially dissociates at experimental condition into CO(g) and Cl2(g).
Now the stopcock connecting two container is opened and sufficient time is given to attain final equilibrium. The final pressure
at equilibrium is found to be 100 torr in both containers.
Using given data and taking following assumption calculate the mole fraction of CO(g) in final state.
Given : Vapour pressure of H2O at experimental temperature 'T' is equal to 20 torr.
Assumption 1 :

Volume of H2O(l) is small and can be neglected but sufficient to create vapour pressure in both container.

Assumption 2 :

COCl2, CO and Cl2 gas do not dissolve in H2O(l).

Assumption 3 :

Whole experiment is carried out under isothermal condition.

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13.

Pressure of COCl2(g) in the gaseous mixture in final state :

(A)

80

(B)

80/3

(C)

160/3

(D)

40/3

14.

The ratio of number of moles of CO(g) to total number of moles of gases in the final state.
(A)
4/15
(B)
8/15
(C)
6/15
(D)
2/15

15.

Ratio of the partial pressure of CO(g) and COCl2(g) in final state :

(A)

*16.

18.

(B)

4:1

(C)

1:4

(D)

1:5

The structural formula of organic compound having molecular formula C3H4 may contains
(A)
(C)

*17.

5:1

both sp and sp3 hybridized carbon atoms

both sp2 and sp3 hybridized carbon atoms

(B)
(D)

both sp and sp2 hybridized carbon atoms

None of these

In which of the following sets of open chain and close chain intermediates, both types can be easily formed during
reaction?
(A)

(B)

(C)

(D)

If a stands for the edge length of the cubic systems : simple cubic, body centered cubic and face centred cubic,
then the ratio of radii of the spheres in these systems will be respectively :
(A)

a a 3 a 2
:
:
2 2
2

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(B)

a : 3a : 2a

(C)

a a 3 a
:
:
2 4 2 2

(D)

a
a
: 3a :
2
2

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Daily Tutorial Sheet

Choose the correct alternative. Only One choice is Correct. However, questions marked with '*' may have More than One
Correct option.
1.

The position of particle moving along x-axis is given by x = 3t2 t3 where x is in m and t is in s. Consider the following
statements :
(i)
Displacement of the particle after 4s is 16m
(ii)
Distance traveled by the particle upto 4s is 24m
(iii)
Displacement of the particle after 4s is 16m
(iv)
Distance covered by the particle upto 4s is 22m
Select the correct alternative :
(A)
Statements (i) and (ii) only are correct
(B)
Statements (ii) and (iii) only are correct
(C)
Statements (i) and (iii) only are correct
(D)
None of these

2.

A man thinks about 4 arrangements as shown to raise two small bricks each having mass m. Which of the arrangement
would take minimum time?

(A)
3.

(D)

F m M g

M m
M m g
t
M m

(B)

F Mg
t
M m

M
A

B
F

t
m
M m
F
A thin wire is bent in form of a helix of radius R and height H. The pitch of helix is H/2 and mass per unit length of
wire is Moment of inertia of wire about the axis of helix is:

(C)

5.

(C)

The elevator has a mass M and the counter weight at A has a mass m. A constant
force F on the cable at B is applied. Neglecting the mass of the pulley and cable,
the speed of the elevator at time t after starting from rest is :
(A)

4.

(B)

(D)

(A)

HR 2

(B)

2R 2 H 2 4R 2

(C)

R 2 H 2 4 2 R 2

(D)

None of these

Overall changes in volume and radii of a uniform cylindrical steel wire are 0.2% and 0.002% respectively when

subjected to some suitable force. Longitudinal tensile stress acting on the wire is Y 2.0 1011 Nm 2
(A)

3.2 109 Nm 2

(B)

3.2 107 Nm 2

(C)

3.6 109 Nm 2

(D)

4.08 108 Nm 2

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6.

For a given thermodynamic process, the P V diagram is as shown below:

Which of the following is the V T diagram for the process?

(A)
*7.

A B : isothermal
B C : adiabatic
C A : isothermal

B
T

(B)

(C)

(D)

Figure shows a container filled with a liquid of density . Four points A, B, C and D
on the vertices of a vertical square. Points A and C lie on a vertical line and points B
and D lies on a horizontal line. Choose the correct statement(s) about the pressure at
the four points.
(A)

PD = PB

(C)

PD PB

PC PA
2

(B)

PA PB PD PC

(D)

PD PB

PC PA
2

*8.

Which of the following quantities are always negative in a simple harmonic motion?



(A)
(B)
(C)
(D)
F .a
v .r
a .r

F.r

*9.

First over tone is produced in an open pipe, if the length of the pipe is
(A)
(B)
(C)
/2
/3
/2

(D)

*10.

A particle of mass m and charge q is thrown in a region where uniform gravitational field and electric field are present.
The path of particle (Neglect relativistic effects)
(A)
may be a straight line
(B)
may be a circle
(C)
may be a parabola
(D)
may be a hyperbola

11.

When a cell is connected in a circuit, a current I flows in the circuit. When one more identical cell is series with the first
one a current I2 is found to flow in the circuit. When same cell is connected in parallel with the first one, the current is
found to be I3. If I1 = 18/7A and I2 = 3A, Find I3(in Amps).

12.

A uniformly charged ring of radius 10 cm rotates at a frequency of 104 rps about its axis. The ratio of energy density of
electric field to the energy density of the magnetic field at a point on the axis at distance 20 cm from the centre is
9.110a. Find a.

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6
13.

Daily Tutorial Sheet

In the figure shown, the two projectiles are fired simultaneously.
What should be the value of n if initial speed of the left side projectile is

14.

15.

2
m/s for the two projectile to hit in mid-air?
3

A man of mass M is standing on a platform of mass m1 and holding a string passing over a system of
ideal pulleys. Another mass m2 is hanging as shown. (m2 = 20kg, m1 = 10 kg, g = 10 m/s2)
Column 1
Column 2
Weight of man for equilibrium
(A)
(p) 100 N
Force exerted by man on string to accelerate upwards.
(B)
(q) 150 N
Force exerted by man on string to accelerate downward. (r)
500 N
(C)
Normal
reaction
of
platform
on
man
in
equilibrium
600 N
(D)
(s)
A particle is moving on a straight line. It is initially at rest.
v = instantaneous velocity ; P = instantaneous power ; S = displacement ; F = force ; t = time
Match the possible expression of the quantities in column-1 with the situation in column-2.
Column 1
Column 2
3
(A)
v S
(p)
P = constant
(q)

Pv

(C)

v2 t
v2 S

(r)

F = constant

(D)

v t

(s)

(t)

P t

(B)

1
v

Choose the correct alternative. Only One choice is Correct.

1.

The number of real solutions to the equation

(A)

2.

(B)

2
4

If x sin y sin
z sin
, then
3
3

(A)

3.

1/2

(B)

1 2

(C)

x2 6 x 280 is(are) :

(D)

(D)

None of these

xy
(C)

If the points where the lines 3 x 2 y 12 0 and x ky 3 0 intersect both the coordinate axes are concyclic,
then the number of possible real values of k is:
(A)
1
(B)
2

4.

3x 2 18 x 52 2 x 2 12 x 162 =

(C)

(D)

Three concentric circles of which the biggest is y 2 a a 2 x , have their radii in A.P. If the line y x 1 cuts all
the circles in real and distinct points. The interval in which the common difference of the A.P. will lie is:
2 2

1
0,
0, 1
0,
(A)
(B)
(C)
(D)
None of these

4
2 2
4

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5.

Let f (x) be any function. The graphs of y f x 1 and y f x 1 are symmetric about the line :
(A)

6.

y=0

(B)

x=0

(C)

x=1

(D)

x = 1

2 x e x x x ln 2 1

,x 0 .The value of k so that

Let f be a function defined on / 2, / 2 as follows : f x
xtan x

,x 0
k
f is continuous at x = 0 is :
(A)
(C)

7.

1
2

ln 2 2

1
2

ln 2 1

ln 2 2 ln 2

(B)

(D)

Point 'A' lies on the curve y e

x2

ln 2 2 ln 2 1
2

1
2

ln 2 2 ln 2

and has the coordinate (x, e

x2

1
2

) where x > 0. Point B has the coordinates (x, 0).

If 'O' is the origin then the maximum area of the triangle AOB is :

1
2e

(A)

8.

The integral

1
4e

(B)

(C)

1
e

(D)

1
8e

sec3/2 sec1/2
tan d is :
2 tan 2

(A)

sec 1
2 tan 1
C
2sec

(B)

(C)

1
sec 1
tan 1
C
2
2sec

(D)

1
2

log e

2 log e

sec 2sec 1
sec 2sec 1
sec 2sec 1
sec 2sec 1

C
C

9.

You are given an unlimited supply of each of the digits 1, 2, 3 or 4. Using only these four digits, you construct n digit
numbers. Such n digit numbers will be called LEGITIMATE if it contains the digit 1 either an even number times or not
at all. Number of n digit legitimate numbers are :
(A)
2n + 1
(B)
2n+1 + 2
(C)
2n+2 + 4
(D)
2n 1(2n + 1)

10.

The locus of a point on the variable parabola y 2 4ax, whose distance from focus is constant k, is equal to:
(a is parameter)
(A)

4 x 2 y 2 4kx 0

(B)

x 2 y 2 4kx 0

(C)

x 2 2 y 2 4kx 0

(D)

4 x 2 y 2 4kx 0

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