XX
Cation Atom Anion
Radius of Its cation < Radius of atom < Radius of Its Anion
Amongst different ions the order of radius is as follows (as number of protons are increasing):
Radius of C+> N*> 0?> F> Ne> Na’> Mg*> AP> Si*> P*
Ionization Potential or Ionization Energy (LP. or I.E.) : The energy required for removing an electron
from the outermost orbit of an isolated, gaseous atom or ion. It is expressed as ki/mole, kCal/mole or eV.
The energy required for successive removal of electron is called successive ionization potential.
X—» X* + e (First ionization Potential, I,)
X" 9 X* + € (Second ionization Potential, 1,)
XX + &- (Third ionization Potential, I.)
x" > Xe*+ & (ath ionization Potential, 1.)
1,<1, p> d> f.
€. Electronic Configuration: An atom or ion with completely filled or completely half filled orbitals
possess stable configurations and high I.P.
Electron Affinity (E.A.) : The energy released, when an electron is added in the outermost orbit of an
isolated, gaseous atom or ion. It is also expressed as kl/mole, kCal/mole or eV.
‘The energy released during successive addition of electron is called successive electron affinities,
Xt+e 9X (First Electron Affinity, E,)
Xote XE (Second Electron Affinity, E,)
x +e > XP (Third Electron Affinity, E,)AL 12 Objective Chemisty
xm +e —>X™ (nth Electron Affinity, E,)
E>E>E, E,
Factors Influencing Electron Affinity :
a. Atomic or Ionic Radius : E.A. increases with increase in size of atom or ion. Hence, down the group
EA. decreases and actoss the period E.A. increases.
b. Nuclear Charge : As the nuclear charge increases E.A. also increases.
¢. Electronic Configuration : An atom or ion with completely filled or completely half filled orbitals
possess stable configurations and low E.A.
Exceptions in Electron Affinity :
i, Electron affinity of Be, Mg, N, P and inert gases etc. are zero or extremely low.
E.A. of the elements of IInd period (except Li and Be) are less than the elements of their own group in
Ilrd period. This is because of their small size due to which the elecirons already present repulse the
incoming electron.
Electronegativity : The tendency of a covalently bonded atom in the molecule to attract the shared pair of
electron is called clectronegativity.
Down the Group : Decreases
er the nuclear charge of the atom morc is the electronegativity.
Across the Period (Left to Right) : Increases
Fluorine is the most electronegative element of the periodic table.
Measurement of Electronegativity:
1.
a. Pauling Scale: E,,_)= Experimental E,, ,—[VE,_.)* Eg
X,—Xq = KE,» [k (a constant) = 0.208]
Here, E,_y,~ Bond energy of A—B obtained experimentally
Eun
Bond energy of A—A molecule
Eq_»,= Bond energy of B—B molecule
X, & X, = Electronegativities of A and B respectively
b. Millikan Seale: X,
ist lonization Potential + IInd lonization Potential)/2
Xun — Xa) = 2.78 (X,4 Kyo)
Xu, & Xq = Millikan’s electronegativities for A & B
X,q & Xpq = Pauiling’s electronegativities for A & B
Memory Based Questions
DALTON'S THEORY
According fo Dalton’s atomic theory, an atom
can?
(a) Posttively charged particles
(b) Negatively charged particles
(c) Neutral particles
(a) Becreated {b) Be destroyed (d) None of these
(c) Neither be created nor destroyed Cathode rays have 7 [CPMT 1962]
(d) None {a) Mass only
2. According to Dalton's atomic theory, an atom? (0) Charge only
(a) Gan be further subdivided (©) Nomass and charge
(b) Cannot be subdivided (d)_ Mass and charge both
(c) Contains neutrons, protons and electrons: Cathode rays are ? [Z..PM.E.R 1987]
(d) None ® sloctromagnatc waves
TRON stream of a-particles
THE ELEC! (©) stream of electrons
3. Cathode rays are made up of ?/Aligarh 1963] (@) stream of positrons‘Structure of Atom and Chemical Periodicity
6.
10.
1.
12.
13,
14.
15.
16.
17.
Cathode rays are deflected by 2{CPMT 1982]
(a) Anelectric field only
(b) A magnetic field only
(c)_ Neither electric nor magnetic field
()_Both electric and magnetic field
In the discharge tube, emissionof cathode rays
requires ?
(a) Low potential and low pressure
(b) Low potential and high pressure
(©) High potential and high pressure
(d) High potential and low pressure
The ratio of e/m for a cathode ray?
(a) Has the smallest value when the dis-
charge tube is filled with H,
(b) Is constant
(C)_ Varies witn the atomic number of gas in
the discharge tube
(d)_ Varies with the atomic number of an ele-
ment forming the cathode in the discharge
tube.
‘The mass of one mole of electron i
(a) 91x10%g ——(b} 0.55 mg
(c) 91x10%g ——_(d) 1.008mg
Mass of an electron is?
(a) 91%10%g — (b) 91x 108g
(©) 91x10%q — (d) 9.x 10g
‘The charge on an electron is?
(@) 48x10%esu (bo) 48x10es.u
(c) 48x 10%e5u — (d) None
An electron is identical wit
[Delhi PMT 1982, MADT Bihar 1980)
(a) An a-tay particle
(b) A Bray particles
(c)_ A hydrogen ion
(d)_ None of these
Density of the olectron is calculatod as 7
(a) 2.17% 10" giec (b) 4.38 x 10” glee
(c) 2.17% 10% glee _(d) None
‘The charge to mass ratio (e/m) of an electron
was determined by ?
(a) Goldstein (b) Rutherford
(c)_ Thomson (d) Chadwick
‘Which of the following is false in case of an
electron?
(a) Itis a particle
(b) thas wave property
(©) It gives out energy while moving in orbits
(d)_Its motionis effected by a magnetic field
Compared to mass of lightest nucieus the
mass of an electron is only? [CBSE1991]
(a) 1/80 (b) 1/360
(©) 1/1800 (6) 1/1000
The number of electrons in an atom of an
element is equal to its? [BHU 1979}
18.
19.
20,
2.
22,
24,
AL 13
(a) Atomic weight — (b) Atomic number
() Equivalent wieght (d) Electron affinity
THE PROTON
‘The nature of anode rays depend upon:
[CPMT 1987]
(@) Nature of residual gas
(0) Nature of electrode
(©) Nature of discharge tube
(@ all
What is wrong about anode rays ?
(@) Their e/m ratio is constant
(0) Fhey are deflected by electrical and
magnetic field
(¢) They are produced by ionisation of
molecules of the residual gas
(a) Their e/m ratio depends on nature of
residual gas,
‘Anode rays were discovered by ?
[Delhi PMT 1985}
(b) J. Stoney
{d) J.J. Thomson
{a) Goldstein
(c) Rutherford
The mass of proton is 7
(a) 1.672 x 10% gm
(©) 1.672 x 10 gm
(e) 1.672 x 10% gm
(d) 1.672 x 10* gm
Which is correct statement about proton ?
[GPMT 1979, MPPMT 1985, NCERT 1985)
fa) Proton is nucleus of deuterium
{b) Proton is ionized hydrogen molecule
(¢) Proton is ionized hydrogen atom
(@) Proton is a-particle
Proton is ? INCERT 1976, CPMT 1971]
(@) Anionized hydrogen molecule
(0) Ana-ray partcle
(©) A fundamental particle
(@) Nucleus of heavy hydrogen
Penetration power of praton is :
ICPMT 1982, BHU 1985]
(a) Greater than electron
(b) Less than electron
(©) Greater than neutron
(d) None
THE NEUTRON
The discovery of neutron became very late
because? ICPMT 1987]
(@) Neutrons are present in nucious
(b) Neutrons are fundamental particles
(c) Neutrons are chargeless
@ atl
The mass of a neutron is of the order of 7
IMLNR 1988)Ad
2.
30.
at
92.
14
(a) 10° Kg (b) 10Kg
(©) 10**kg (@) 107"Kg
‘The credit of discovering neutron goes to?
[MPPMT 1992]
(a) Rutherford (0) Langmuir
(©) Chadwick (@) Austen
Mass of the neutron is 7
(a) Same as proton .
(©) Very much less than that of proton
(c)_ Slightly less than that of a proton
(@)_ Slightly more than that of proton
Mass of neutron is times the mass of
electron:
(a) 1840 (b) 1480
(c) 2000 (@) None
Neutron possesses?
(a) Positive charge _(b) No charge
(c) Negative charge (4) All are correct
When beryllium is bombarded with alpha
particles (Chadwick's experiment) extremely
penetrating radiations, which cannnot be
deflected by electrical or magnetic field are
Given out. These are : [CPMT 1983]
(a) Abeam of protons
(b) Alpha rays.
(©) Abeam of neutrons
{d) Abeam of neutrons and protons
THE NUCLEUS
Rutherford's alpha particle scattering
experiment eventually led to the conclusion
that: IIT 1986)
(a) Mass and energy are related
() Electrons occupy space around the
nucleus
(c) Neutrons are buried deep in the nucleus
(d) The point of impact with matter can be
precisely determined.
In Rutherfords experiment most of the a-
particles were
(a) Passed undetlected
(b) Defected
(c) Thrown back — (d) Absorbed
‘When atoms of the gold sheetare bombarded
bya beamof a-particles, only a few a-particies
get defected where as most ofthem go straight
undeflected. This is because
IMNR 1978, NCERT 1980]
(a) the force of attraction on a-particles by
the oppositely charged electron is not
sufficient.
{b) the nucleus occupies much smatier
volume as compared to the volume of
atom.
Objective Chemistry
(©) the force of repulsion on fast moving a-
Particles is very small
(@) the neutrons in the nucleus do not have
any effect on a-particlos.
35. Discovery of the nucleus of an atom was due
to the experiment carried out by :
[CPMT 1963]
{a) Bohr (b) Mosley
() Rutherford (d) Thomson
36. Rutherford’s model of the atom could not hold
good because ?
(a) It did not account for the stability of the
atom
(©) The atom did not have a nucleus and
electrons
(6) It did not account for the attraction
between the proton and the electron
(d) Thoro is actually no space between the
nucleus and the electron
87. The volume of nuclaus is about ?
(a) 10° times that of an atom
(b) 10°” times that of an atom
(©) 10° times that of an atom
{d) 10° times that of an atom
38, The size of nucleus is measured in?
[EAMCET 1988}
(@) amu. (©) Angstrom
(©) Fermi (d) Cm
38. Experimental evidence for the existence of the
atomic nucleus comes from: [CBSE 1989]
(a) Milikan's oil drop experiment
(b) Atomic emission sy
(c) The magnetic bending of cathode rays
(d) Alpha scattoring by a thin metal foil
40. One Fermi unit is equal to?
(a) 10cm (b) 10% em
{e) 10+cm (2) 104 cm
ATOMIC NUMBER AND ATOMIC WEIGHT
41. X-rays are produced when a stream of
electrons in an X-ray tube?
(a) Hits the glass wall of the tube
(b) Strikes metal target
(c) Pass through a strong magnetic field
(¢) None
‘42, Which of the following is a whole number ?
IMPPMT 1986]
(a) Atomic weight
(>) Atomic radii
{c) Equivalent weight
{d) Atomic number
43. The number of neutrons in tritium nucleus is:
{[Dethi PMT 1982}Structure of Atom and Chemical Periodicity
47.
51.
(a) 1 (o) 2
(©) 3 (4
Many elements have non-integral atomic
masses because : HT 1984)
(a) They have isotopes
(b) Their isotopes have non-integral masses
(c) Their isotopes have diferent masses
(d) The constituents, neutrons, protons and
electrons, combine to give fractional
masses:
‘Atom ofan slement shall contain equal number
of
(a) Protons and neutions
(b) Protons and electrons
(c) Neutrons and electrons
(2) Alithe above
‘Though the three fundamental particles are
present in almost all elements, one element
does not possess
(a) Proton (b) Electron
() Neutron (d) Nucleons
The atoms ,C” and ,C* will differ in their
(a) Position in the periodic table
(b) Chemical properties
(c) Number of orbital electrons
()_ Number of neutrons in the nucteus
Davisson and Germers experiment showed
that :
(a) P-particles are electrons
(b) Electrons come from the nucleus
(e) Electrons show wave nature
(d)_ None of the above
How many molecules are present in one gm
of hydrogen?
(a) 6.023 10% (b} 3.0125 x 102
(©) 623x102 (d) 3.015 x 10%
Neutrons are not present in the nuclei of :
(a) Chlorine (b) Deuterium
(©) Hydrogen (d) Oxygen
ca-particle is identical with :
(a) Protium nucteus
(b) Deuterium nuctous
(c). Positron
(@) Helium nucleus
Wfthe mass number of an element is W and its
atomic number is N, then: [CPMT 1989}
(a) Number of ¢*=W-N
(b) Number of H'=
(c) Number of .n''= W—N
(d)_ Number of .n' = N
‘Smallest part of an lament which exists as
‘olomont is ? [EAMECT 1963}
55,
(@)
©
56.
57.
58.
61.
Al 15
(@) May be different (b) Are different
(6) All are alike
(@)_ Have different properties.
‘According to Thomson's experiment the radius
of circular path r, is related to the charge e,
mass m velocity v of the electron in the
magnetic field H and is given by
m my
@rg oe
a mH
©" {d), Fea
according to Thomson's method is given
by
v ) v
() PH
v a 2-2
mn PRE 8) in” FH
ISOTOPES, ISOBARS AND ISOTONES
Which of the following property is different for
neutral atoms of the two isotopes of the same
element?
(@) Atomic weight
(0) Atomic number
(c)_ No. of protons.
(@)_No. of neutrons
‘sotopes differ in :
(a) The number of protons
(0) The valency number
(©) The chemical activity
(@)_ The number of neutrons
teotopes of sume olemorts have sams number
[BHU 1984]
5 Protons (b) Neutrons
(c) Deutrons. (a) None
The following statement (s) is (are) incorrect
for the hydrogen atom :
(a) It exists only in two isotopic forms
(0) Its electronic configuration is 1s°
(¢)_Ithas no neutron in its nucteus
(d) tis the smallest atom
‘The postulate that all the atoms of an element
are exactly alike was proved incorrect by the
discovery of :
(a) Isobars
(0) X-ray and radioactivity
(©) Isotopes
(2) Allotropy
Moder basis (standard) of atomic weight is :
IMP PET 1989}Al
62.
63.
64.
65.
67.
68.
16
{a) Isotopes H' = 1.000
(0) Ordinary oxygen = 16.000
(c) Isotope O'*= 16.000
(a) Isotope GC? = 12.000
The present atomic weight scale is ?
[EAMCET 1988}
fa) ce (b) OF
() Ht (8) o»
The atomic nucleus is composed of :
[MADT 1980; Delhi PMT 1982, 85; CPMT
1973, 74, 78, 83, 84)
(a) Neutrons
(b) Electrons + Protons
(c) Protons + neutrons
(8) Electrons + Protons + Neutrons
The introduction of a neutron into the nucteus
of an atom would lead to a change in
{a) the number of electrons
(b) the chemical nature of the atom
(c)_ Its atomic number
(@) its atomic weight
ELECTROMAGNETIC RADIATIONS AND
PLANCK'S THEORY
Light, a well known form of energy, is treated
8 a frm of mater, by saying that & consists
w
(a) Protons or bundles of energy
(b) Electrons or a wave like matter
(c) Neutrons, since electrically neutral
(@)_ None
Which of the following statemenis concerning
light is false?
(a) itis a form of energy
(0) it cannot be deftected by a magnet
(c)_ it consists of photons of same energy
(d)_ it is part of electromagnetic spectrum
‘The relation between energy of aradiation and
its frequency was given by ?
(a) de - Broglie (b) Einstein
(c) Planck (@) Bohr
Which one of the following statements is
correct 7
(a) All electromagnetic radiations do not
possess the same velocity
(b) Matter waves are associated with
electrical and magnetic fields
(c) Matter waves and electromagnetic
radiations are alike
(a) The velocity of matter wave is generally
less than that of light
Aquantum of energy is
(@) afixed quantity
(0) directly proportional to the radiation
70.
m1.
72,
73,
74,
75.
76.
19.
at.
Objective Chemistry
(c)_ inversely proportional to the wavelength
of the radiation
(0) directly proportional to the velocity of the
radiation.
Allltypes of electromagnetic radiation possess
some
(a) Eneroy (b) Velocity
(c)_ Frequency (@) Wavelength
Which of the following is not electromagnetic
in nature?
(a) Infrared rays (b) X-rays
(c) Cathode rays (¢) rays
Wavelength of radiowaves is
(a) Anda mungkin juga menyukai