I I,::::
a1 Sie,u
Copyright Reserved
ACKNOWLEDGEMENT
Questions from past examinations are reproduced by permission
of the University of Cambridge Local Examination Syndicate &
SNP Publishing Pte. Ltd.
PUBLISHED BY
Z VS7.2717S (/996) 47
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Saq2t4a
r6r-674-47o
paz; gog-674-0497
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The
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PREFACE
Assessment and Revision Course in Chemistry for CXC consists of a
compilation of questions specifically designed for use by students attempting the
CXC 0 Level examination in Chemistry.
The objective of the book is to provide practice in answering questions and to
extend knowledge gained during the Course. The wide range of questions that
span the entire syllabus will help students to build the confidence and ability
necessary to master examination techniques.
Accordingly, the book is set to provide practice in Paper 01
Multiple Choice,
Paper 02 Structured Questions, and Paper 03 Essay Type Questions in
the same format and level as CXC.
Particular attention has been given to Question I of the structured paper in which
actual experiments performed by students are used as examples to cover the
data response questions. Questions on Section C, Paper 03, of the Syllabus are
included so that students have adequate practice.
The student is therefore challenged to attempt 600 Multiple Choice items, 50
Structured Questions and 60 Essay Type Questions. It is envisaged that with
such practice in an array of Questions, success in CXC Chemistry is guaranteed.
cONTENTS
of:
There are ten (10) sets of examinations. Each examination consists
Paper 01
Paper 02
Paper 03
SUGGESTiONS
Suggested Time and use
attempt of 1
The test is intended for use over a ten week period with an
examination (Paper 01, Paper 02 and Paper 03) per week.
ts working at
Teachers can use the book for class revision as well as studen
d to use their
home in preparation for the examination. Teachers are advise
allocation for
individual marking scheme for questions but to remain within the
each paper.
ACKNOWLEDGEMENT
of the University
Questions from past examinations are reproduced by permission
of Cambridge Local Examinations syndicate.
Published by:
e66ea oo Deze6aeow (1996) &d.
Sodzz ad
c
#10 9
Sa4q1c44
7d,: g6g-674-?72o
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paz: 4
Paper
Type of Paper
Duration
Marks
01
Multiple Choice
1 hour 15 minutes
60
02
1 hour 30 minutes
90
03
1 hour 30 minutes
60
04
80
Paper 01
1 hour 15 minutes 60 marks
Sixty (60) compulsory Multiple Choice items.
Paper 02
1 hour 30 minutes 90 marks
A series of five structured questions with Question 1 (Data response) related to
Practicals completed during the two academic years.
Paper 03
1 hour 30 minutes 60 marks
The paper is divided into Three (3) sections with 2 questions in each section.
Candidates must answer one (1) question from each section.
Paper 04
School Based Assessment (S.B.A.)
over their last two years.
TIME:
1 hour 15 minutes.
INSTRUCTIONS TO CANDIDATES
There are sixty (60) questions in this paper. Answer all questions. For each question,
there are four possible answers A, B, C and D. Choose the one you consider correct and
record your choice in soft pencil on the separate answer sheet.
Read the Instructions on the answer sheet very carefully.
3 of water.
3 sample of alcohol is mixed with 50cm
A 50cm
3
50 cm
of alcohol
50cm
3
of water
.
3
The volume of the mixed alcohol and water is found to be 97cm
Which of the following is the best explanation?
The diagram shows a chromatogram which was prepared using spots of five different
inks.
starting lIne
H
solvent
flow
How many different dyes were used to make the five inks?
A
12
boiling point[C
carbon monoxide
191
nicotine
247
tar
350 to 400
water
100
A gas X is soluble in water and less dense than air. An impure supply of X contains water
vapour and a water-soluble impurity.
1j
12
LiY
water
--
W18L
drying-
agent
In which order should the pieces of apparatus be joined together to collect a pure, dry
sample of X?
1,32,4
D
1,32,5
C
B
1,23,5
1,2,3,4
A
5
3
0
2
U
3
U0
6
U0
ion
protons
Li
3
Al
13
14
10
10
17
20
16
Cr
0
6
U
_-_%
/
4
7
(\
__nucleus
conLning
\____--
7 protons and
,l
8 neutrons
3
N
2
Q
Ne
iA
key
carbon atom
a silicon atom
physical state
soft solid
soft solid
hard solid
hard solid
10 A compound P is the only substance formed when two volumes of ammonia gas react
with one volume of carbon dioxide (both volumes being measured at r.t.p.).
What is the most likely formula of P?
A
Ii
3
C
2
)
4
(NH
0
4
C
NH
N
2
O
H
(NH
C
)
2
0
00
4
NH
N
2
H
cat
etectrode
concentrated
-
aqueous
nickel(It)
cNoride
bromide i s only
electrons only
protons only
AgAg+e
Ag+eAg
2AgBr
2
2Ag+Br
AgBrAg+Br
by exposing a
15 Which of the following industrial manufacturing processes does not use a catalyst?
A ethanol from ethene and steam
B
16
In the graph, curve X represents the result of the reaction between 1 Og of granulated zinc
and an excess of acid at 30C.
total
volume ot gas
produced
(measured
at r.t.p.)
17
time
In two separate experiments, a substance was decQmposed and the gas evolved was
collected.
The graph shows the total volume of gas collected against time for each experiment.
experIment 2
volume
of gas
coflected
Which graph shows how the speed of reaction varied with time in each experiment?
B
C
Spo&d
of
18
time
time
time
Xonly
XandY
C
6
Yonly
YandZ
19
Two solutions were mixed in a beaker and the mass of the beaker and contents was then
recorded at various times. The graph shows the results.
time
20
21
The table gives information about the sofubilities of the hydroxides, carbonates, and
sulphates of calcium, sodium and zinc.
hydroxide
carbonate
sulphate
calcium
slightly soluble
insoluble
slightly soluble
sodium
soluble
soluble
soluble
zinc
insoluble
insoluble
soluble
Shake solid zinc hydroxide with aqueous sodium hydroxide and pass in carbon dioxide.
Shake solid zinc sulphate and solid calcium carbonate with water.
Shake solid zinc sulphate .ith water and add aqueous sodium carbonate.
Shake aqueous zinc sulphate with solid calcium hydroxide and pass in carbon dioxide.
22
23
3
A1
2
Ca
2
Cu
2
Zn
sodium
24
25
iron
lead
26
calcium
It is decolourised by chlorine.
Element X occurs naturally as the uncombined metal; element Y is obtained by heating its
oxide with carbon; element Z is obtained by electrolysing its molten chloride.
What is the order of reactivity of X, Y and Z?
most reactive
least reactive
BY
27
steel wool
air
water
level
at
bennir
o experiment
25
aluminium
calcium
copper
iron
DCI
30
4
CD
OD
5
D
2
C
CaOD
31
32
33
food containers
oil pipelines
roofing sheets
magnesium
tin
zinc
tin
zinc
magnesium
tin
magnesium
zinc
zinc
magnesium
tin
Which reaction will not occur using cold, dilute sulphuric acid?
A
nylon
poly (ethene)
P.V.C.
Terylene
______
34
35
Si
C
4
I
4
S10
6
H
2
Si
C
D
37
4
SiN
Which statement indicates that diamond and graphite are allotropic forms of carbon?
A
Both have giant molecular structures.
B
36
density.
mass.
empirical formula.
stage 0
ethanoic
ethene
b.
39
b.p.
b.p.
b.p.
-x_-x--x _x_
What is X?
A
carbon
hydrogen
C
10
nitrogen
oxygen
B
4
41
Which one of the following is the best pair of reagents for preparing copper (II)
sulphate crystals?
A
42 Which of the following is most likely to be the melting point of an ionic solid?
A
12C
78C
35C
534C
11
43
potassium hydroxide
sodium chloride
sulphuric acid
calcium hydroxide
44 What are the products of electrolysis of concentrated aqueous sodium chloride using
inert electrodes?
45
cathode (-ye)
anode (+ve)
hydrogen
chlorine
sodium
chlorine
sodium
oxygen
hydrogen
oxygen
Lead iodide can be prepared by the reaction of lead nitrate and potassium iodide
according to the following equation:
Pb(N0
(
2
)
3
aq)
2K1(aq)
2KNO
a
3
q
Pbl
(
2
S)
Which of the following methods can be used to separate the lead iodide from the
mixture?
46
distillation
evaporation
filtration
crystallization
covalent bonds
12
i & ii only
i, ii & iii
?
49 Which liquid is the best conductor of electricity
ethanoic acid
B
ethanol
A
C
sugar solution
51
4
H
2
C
8
H
3
C
0
C
1
H
4
1
H
6
C
0.5
1.0
1.5
+ve
-ye
13
54 Why are a few drops of dilute sulphuric acid added at the beginning of the experim
ent?
A
To neutralize the water
B
+7
14
metal?
59 In which of the following reactions is there a decrease in the oxidation state of the
)
9
(
2
2 + H
Zn
2 2H
Zn
A
B
3
Fe
3e
Fe(s)
2
Fe
20H
)
s)
2
Fe(OH
(
2C1+2e
2
Cl
15
1 hour 30 minutes.
INSTRUCTIONS TO CANDIDATES
1. You must use this booklet when responding to the questions. For each question,
write your answer in the space provided.
2. All working must be shown.
3. There are five questions in this booklet. Answer all five questions.
IM
1th1A-
3
3 of an aqueous solution of sodium hydroxide containing 8.05g dm
(a) 20 cm
X
2
3 of an aqueous solution of an acid H
are neutralized exactly b 25.0 am
containing 0.080 mol dm
(i)
3 of aqueous solution?
X are present in 25.0 cm
2
How many moles of the acid H
-
or
(ii)
o w
i tlvv
3 of the
How many moles of sodium hydroxide, NaOH, are present in 20 cm
solution?
,--
0)
(a) How many moles of sodium hydroxide, NaOH, react with one mole of the
X?
2
acid H
+--
*)
, calculate its
3
H, contains 10.05 gdm
X
(c) If the aqueous solution of the acid, 2
molecular
mass.
relative
(d) Name a suitable indicator, and state the change that occurs with your choice
of indicator. The indicator was added to the acid.
(iv) Use your resufts from (iiic) to show whether or not the acid, H
X, is sulphunc
2
acid, 4
S0
2
H
.
(v)
(b) The following tests were carried out on substance Y which is composed of two
oxides of the same metal. The observations were recorded in the table. Based
on these observations, deduce what you can about these two oxides and the
identity of any gas or gases evolved and name the metal ion present.
TEST
OBSERVATIONS
CONCLUSTIONS
iiia
iiib
A white
formed.
precipitate
was
iiic
A white
formed.
precipitate
was
1 (c) The following experiments were carried out to find out the conditions which
caused the rusting of iron.
pieces ot
anhydrous
calcium chloride
oiI
cotton wool
...
5 boiled
water
to remove
dissolved air
iron nali
Tube I
Experiment I
water
Tube II
Tube Ill
Experiment 2
Experiment 3
(ii)
zrL
.JJ
(iii) What was the purpose of the layer of oil in Tube II?
.
--
O4
-
--
0
L
1
-I
L.
Lk
(L
(
S
(v) What could be done to the nail in Tube Ill to slow down the rate of rusting?
SS
55
%JJ
L.
(a)
;.
eL!
(ii)
(b) The following equations represent changes that occur during electrolysis. Use only these
equations to answer the questions.
2Cl
Cu
+
2
2e
Cu
2H+2e40H
(i)
C1
+
2
2eCu
2e
2
Cu
2
H
04e2H
2
0
(ii)
Write the equation that shows the process which must occur when an object is
electroplated with copper.
(iii)
Write two equation which show the processes that occur when dilute sulphuric acid
is electrolysed.
1
2
(a)
[4]
Uranium-235 and uranium-238 are two isotopes of uranium The table below shows the
numbers of the particles in one atom of uranium-235.
(i)
particle
number
electron
92
neutron
143
proton
92
n:..
____
________
______
____
_______
(ii)
In the table below, give the numbers of particles found in an atom of uranium-238.
number
particle
electron
neutron
_L
proton
(iii)
(b)
3 portions of an acid
A student added lqm
3 potassium
3 of 0.10 mol/dm
HA to 25cm
hydroxide. After each addition of thern
acid, the student measured the pH of the
mixture, using a pH meter. From his
results, the student drew the graph shown
below.
(a) What is the pH of a neutral solution?
WJIH
86 i.ni
IIIIII;4
pH
1t11
11;Ir
rjrr111r IH
1:1.111
I I 1111111 iiI
H I I
.:
(b)
(I)
(ii)
j....j
III
I H
I I, III I I
I III 11111
I
HP
IM
(c)
(a)
Suggest a way, other than using a pH meter, by which the student could follow the
pH changes during this reaction
[6)
Fats contain the ester linkage. The structure of a tat can be represented by the diagram
(a) Fat is one of the three main energy sources present
NaO
tw
(b)
An ester such as ethyl ethanoate reacts with aqueous sodium hydroxide as shown
by the diagram below.
HO
H
+
NaOH
HO
Na
HOCCH
1I4
Draw the structures of two products of the reaction of a fat with aqueous sodium
hydroxide.
(c)
Terylene is a polyester.
Draw the structure of Terylene.
j9
[6]
(b)
In an experiment, copper (II) oxide was reduced by heating it with powdered chromium.
Chromium (Ill) oxide and copper were formed.
The table below gives some information about the substances involved.
substance
action of water
chromium, Cr
insoluble
insoluble
copper, Cu
insoluble
insoluble
(a)
(ii) At the end of the heating experiment, all four substances were present in the reaction
mixture.
Suggest how a pure dry sample of copper can be obtained from this mixture.
(iii)
(iv)
Similar experiments between other metals and metal oxides were carried out. The
findings from these experiments are shown in the table below.
metal used
chromium
yes
copper
no
lead
no
sodium
yes
(.1)
Place the metals chromium, copper, lead and sodium in order of decreasing
reactivity.
Most reactive
Least reactive
(ii)
(a)
The following questions refer to compounds with the structures drawn below.
H--coH
H
1-4
D
H
I-
C CC H
H
HCCH
(ii)
L..
.
1
?
[4]
(b
Complete the following table which refers to the uses of some gaseous elements.
use
element
chlorine
hydrogen
nitrogen
[4]
oxygen
(i)
(ii)
.
2
fluorine, F
fluorine
(ii)
Explain why sodium fluoride has a higher melting point than fluorine.
.1XL?
ot
srr3
%4
(r
M
0
L
[5]
Time:
1 hour 10 minutes.
INSTRUCTIONS TO CANDIDATES
Candidates MUST answer THREE questions on this paper. They must choose ONE from
Section 1, ONE from Section 2, and ONE from Section 3.
All working MUST be shown for calculations.
(b) (i)
(C)
(a) (i)
H, to give a
C
O
9
H
(b) Concentrated sulphuric acid reacts with butanol, 4
compound X.
Compound X decolourises aqueous bromine.
(i) What is the molecular formula of X?
(ii) Suggest two possible structures for X.
[3]
[3]
Section II
Answer one (1) question from this section.
3
Silicon carbide, SiC, has a diamond-like structure and a very high melting point. It is
made by heating pure sand, SiC
, with carbon at a very high temperature. Carbon
2
monoxide is the other product.
-
The exhaust gases of a motor car contain several pollutants, among them carbon
monoxide and oxides of nitrogen. The flowchart below shows the arrangement of a
two-stage catalytic converter in a motor car engine and exhaust system.
air
petrol
engine
first catalytic
converter
I,
second catalytic
converter
1
exhaust
gases
SECTION III
Answer ONE question from this section
5.
6.
[2]
(a) Give a definition of weighting of fibres.
[2]
(b) What benefits does weighting impart on fabrics?
necessary. [6]
(C) Describe how a given fabric is weighted, giving equations where
(d) Other than weighting, describe one process whereby the properties of natural
fibres may be adjusted by chemically modifying groups in the molecules of the
[6]
fibres.
[4]
(e) Why cant the properties of fibres be chemically modified?
7N
Plant Protein
7
N0
Nitrogen
Ammonia
Animal Protein
Humus
ant role in
The above figure represents part of the nitrogen cycle. Bacteria play an import
this cycle.
the name
(a) Name the two bacteria A and B which takes part in the cycle and state
of the process which converts elemental nitrogen into Y.
nitrogen (11) oxide
2
(b) The formation of Y involves a series of reactions N
nitrogen IV oxide nitric acid Y.
(i) Write formulae for nitrogen 11 oxide and nitrogen IV oxide.
2 nitrogen IV oxide.
(ii) Hence write chemical equations to represent N
(c) Calculate the oxidation number of nitrogen in
3
(ii) NH
2
(i) N0
(d) How do modern farming methods upset the natural nitrogen cycle?
and state
(e) Many gardeners follow a simple rotation of crops. Give an example
what are the disadvantages of crop rotation.
Name
(f) The mealy-bug pest can be controlled by the use of the lady bird beetle.
two advantages and one disadvantage for the use of this type of control.
4
1 hour 15 minutes.
INSTRUCTIONS TO CANDIDATES
There are sixty (60) questions in this paper. Answer all questions. For each question,
there are four possible answers A, B, C and D. Choose the one you consider correct and
record your choice in soft pencil on the separate answer sheet.
Read the Instructions on the answer sheet very carefully.
3 of water.
A 50cm
3 sample of alcohol is mixed with 30cm
50 cm
3
of alcohol
50cm
3
of water
.
3
The volume of the mixed alcohol and water is found to be 97cm
Which of the following is the best explanation?
Some alcohol molecules evaporate.
ne diagram shows a chromatogram which was prepared using spots of five different
inks.
I
I
I
starting line
solvent
flow
How many different dyes were used to make the five inks?
12
boiling point/C
carbon monoxide
191
nicotine
247
tar
350 to 400
water
100
?X
CuS
.
4
0
5H
,
O changes
The reaction scheme shows how hydrated copper(lI) sulphate, 2
when heated.
250C
90C
p- CuSO
4
.H
4
CuSO
0
2
.5H
4
CuSO
0
2
-
A little water was accidentay spilled into a basin containing hydrated copper (II) sulphate.
0?
2
. 5H
4
What could be done to remove the water, leaving pure, dry CuSO
In which of the following pairs do the elements form a compound by sharing electrons?.
A
by sharing one pair of electrons, both electrons provided by the magnesium atom
by sharing two pair of electrons, both pairs provided by the oxygen atom
by sharing two pair of electrons, each atom donating one pair of electrons
What volume of sulphur dioxide (at r.t.p.) is giver off on heating 9.7 g of zinc sulphide,
ZnS?
2ZnS + 302
2ZnO + 2S0
2
3
1.2dm
3
24dm
3
3.6dm
3
3
4.8dm
10
11
1+
2+
3+
4+
A sample of copper contained as impurity a metal below it in the reactivity series. The
diagram shows the apparatus used for refining the sample.
+
impure
copper
anode
pure
copper
cathode
aqueous
copper(H)
sulphate
The loss in mass of the anode (positive electrode) was 50g and the gain in mass of the
cathode (negative electrode) was 45g.
What was the percentage purity of this sample of copper?
A
12
10.0%
11.1%
90.0%
95.0%
volume of
/dm
2
0
3
24
12
12
12
12
24
13
14
15
What are the products when concentrated aqueous lithium chloride is electrolysed?
at the anode
(positive)
at the cathode
(negative)
chlorine
hydrogen
chlorine
lithium
oxygen
hydrogen
oxygen
lithium
The products of the reaction have less energy than the reactants.
A chemical reaction between a solid and an acid is too fast for safe use by a class of
students.
Which set of changes is most likely to make the reaction safe for the students to use?
16
pieces ot solid
acid
temperature
larger
less concentrated
lower
larger
more concentrated
higher
smaller
less concentrated
lower
smaller
more concentrated
higher
0(l)
2
2H
(g)
2
0
17
The graph shows how the total volume of hydrogen produced by reaction between
hydrochloric acid and an excess of magnesium varied with time.
total volume
of hydrogen
produced
time
18
Hydrogen peroxide, H
, reacts with an oxide, M
0
2
0.
2
0(s)
2
M
l)
H
(
0
2
2M(s)
0(l)
2
H
(g)
2
0
19
a dehydrating agent
a reducing agent
an acid
an oxidising agent
Two bottles in a laboratory are unlabelled. One bottle is known to contain aqueous sodium
iodide and the other aqueous sodium chloride.
Whch :est would identify the scutions?
20
21
22
23
aluminium hydroxide
calcium hydroxide
Which substance is not used to prepare zinc chloride by reaction with hydrochloric acid?
A
zinc carbonate
zinc hydroxide
zinc nitrate
zinc oxide
ammonia
carbon dioxide
chlorine
hydrogen chloride
electron structure
2,4
2, 8, 2
2,8,5
2,8,6
2,8,8,1/
C,3,J
P and S
Q and T
A and S
R and T
Element M has a high density and a high melting point. It forms two chlorides MCI and
.
2
MCI
What does this suggest about element M?
A
It is a Group If metal.
B
C
It is a Group IV metal.
It is an alkali metal.
It is a transition metal.
25
26
It forms a molecule At
.
2
Which of the following oxides is most readily reduced to the metal by heating in a stream
of hydrogen?
A
27
calcium oxide
copper(ll) oxide
sodium oxide
zinc oxide
ZGG
28
29
30
Fe
(
2
aq)
Cu(s)
2H(aq)
Cu(s)
Mg
(
2
aq)
Zn(s)
Fe(s)
Cu
(
2
aq)
H(g)
Cu
(
2
aq)
Mg(s)
Zn
(
2
aq)
Diammonium hydrogenphosphate, ,
HP0 is a widely used tertiliser.
2
)
4
(NH
Which of the following could be added to this compound to produce a mixture providing
the three principal elements needed for plant growth?
A
ammonium sulphate
magnesium nitrate
potassium chionde
argon
carbon dioxide
oxygen
water vapour
8
31
indicator
methyl orange
red
bromothymol blue
yellow
yellow
phenolphthalein
pH at which colour
change takes place
colourless
4.0
blue
6.5
pink
9.0
If equal volumes of these three indicators were mixed, which colour would be observed at
pH 5?
A
blue
green
orange
32
2
2S0
+ 2
3
2S0
What conditions of pressure and temperature are used for this reaction?
pressure/atm
33
34
35
temperaturelC
200
20
200
500
20
500
making nylon
making pvc
a reducing agent
an acidic oxide
an oxidising agent
What are the molecular formula and empirical formula of ethanoic acid?
molecular
empirical
formula
formula
A
0
4
H
2
C
0
4
H
2
C
B
0
4
H
2
C
O
2
CH
0
4
H
2
C
0
4
H
2
C
0
6
H
2
C
0
6
H
2
C
9
yellow
36
Which set contains the correct process for converting substance S to the product(s)?
37
38
product (s)
substance S
process
A
addition polymerisation
an ester
Terylene
condensation polymerisation
starch
glucose (a sugar)
hydrolysis
protein
amino acids
reduction
ethanol
ethanoic acid
?
4
Which set contains all the possible combustion products of methane, CH
A
7
H
How can X be classified?
A
39
ccCCCC
CL
Cl
Cl
Cl
ci
HCH
CI
CC
CI
H=CH
11
10
Cl
Cl
HCCH
40
/H
soH
H\/0\/ H
\/
HCC
SOH
H
11
27
56
cs
Fr
59
La
Ba
1,,
Cs
C..w.r
Ac
Re
99
227
226
87
Ln
139
Yttsfl
Sr
37
733
99
96
Key
Zr
91
72
48,.n
Hf
75
Zvwnr
40
22
Ti
49
bwponnx17be
xato1T9cs1nbo
97
55
31
Rb
59
Rd&,,
79
Sc
Ca
Pan
Sk
45
20
72
Mg
Na
39
24
33
II
40
ii
ii
90
18
73
41
Ta
787
Ncon
Nb
93
Mo
98
Tc
Nd
744
9wa.r
93
93
U....4n
226
745d5n
75
Re
786
IflMfum
43
25
U9
Mn
56
Ru
107
Pm
0,n.n,
Os
II)
Np
93
7*8t
91
P75
76
44
Pw.,.sn
28
fron
Fe
58
--
Sm
790
.o.r
Ir
92
.un
Rh
703
94
Pts.,n
Pu
Snnn,
82
77
45
21
Cob.4
Co
56
759
Am
(s.s.,
Eu
152
Psr
Pt
59
kn..,,
83
78
44
109
Pd
PMbr
28
NI
Ni
56
Gd
757
044
Au
797
S*
Ag
708
Cosn.
98
Cats.,
Cm
Gr
64
79
47
29
84
Cu
59
49
207
Bk
1..
Th
756
Ms..y
Hg
97
96bs.
85
Cd
172
Z.n
Ca*vsir
30
59
Zn
II
49
31
73
74
Dy
762
Ths.,
TI
204
war
In
115
Gn
Ga
70
Cf
119
Es
s.6s...
Ho
1*
L.
Pb
201
Is.
Sn
(ss.l,.r
99
87
82
50
32
G.nn.n
Ge
73
21
Si
27
Al
C..SIons.,,,
59
72
II
iii
DDa,.s.,
66
97
Pa
Ps.,n
Th
fln
Yws.,n
232
Cw,s,n
741
Pr
1,.n
784
740
49
74
43
M&VtftJrn
24
CNnn
Cr
52
Ce
T,86,n
23
57
Group
DATA SHEET
The Periodic Table of the Elements
Fm
E9.n
Er
787
I.n.4w
Bi
200
AflaW
Sb
122
AC
103
Fw,.,
96
93
51
33
As
75
Md
t7.O4n
Tm
796
Po
I.s.nn
To
121
S.n
Ms.bssr
90)
96
94
52
34
Se
79
S9h.
79
Phi
32
31
76
vi
P
15
74
Yb
773
A.8,.
At
1.
727
Br
59
Cl
355
No
P86Hss.
101
70
Lwa
Lu
773
Rn
8ns
Xe
731
K99c.
Kr
94
A,n
j.r.ssr
703
77
98
54
39
18
Ar
40
7W
70
F4.o...
20
lIe
Na
Vlblsr
96
53
35
17
II
\ii
41
Which of the following can be represented by the ionic equation below in which X is the
symbol for a metallic element?
X(s)
42
45
iron
sodium water
copper
steam
calcium
iron
potassium
Which of the following is most likely to form ions with charges of +2 and +3?
A
44
iron
2H(aq)
A
43
copper
aluminum
iron
calcium
addition polymerization
condensation polymerization
deamination
hydrolysis
It is usually brittle
46
Aqueous sodium hydroxide is added to a solution containing zinc ions until no further
change takes place.
47
48
13
49
50
the sulphate
the chloride
the carbonate
sour taste
Isomerism
Polymerization C
Hydrogenation
Esterification
Each option may be used once, more than once or not at all.
51
H
HH
I
II
CtCCC-H
Ill
HHH
H
52
53
This type of reaction can occur across the double bond of compounds.
54
55
propane
propene
ethane
ethene
14
56
Barium is in the same group of the Periodic Table as calcium. Which of the foflowing
statement is likely to be true of barium? it is..
A
easily reduced
a non metal
Items 57
From the following list, select one method by which each of the following may be
separated from the mixtures. Each method may be used once, more than once, or not
at all:
A
filtration
fractional distillation
chromatography
sublimation
57
58
59
60
Which of the following solutions will turn green when either sulphur dioxide or hydrogen
sulphide is bubbled through?
A
Potassium chloride
Potassium dichromate
Potassium nitrate
15
1 hour 30 minutes.
INSTRUCTIONS TO CANDIDATES
1. You must use this booklet when responding to the questions. For each question, write
your answer in the space provided.
2. All working must be shown.
3. There are five questions in this booklet. Answer all five questions.
Temperature of mixturelC
33.5
35.0
36.5
38.0
39.0
38.0
36.5
35.0
(i)
Write an equation for the reaction between sodium hydroxide and hydro
chloric acid.
44O
(ii)
-C
L)
(iii) Extend your graph so that it crosses the temperature axis. What is the
temperature of the sodium hydroxide solution at the beginning of the
experiment?
5
(iv) Use the graph in (ii) above to determine the volume of acid needed to
neutralize 25cm
3 of sodium hydroxide used.
-w
C,
3,,
V
C
..
.L.44
-I ,
-:
ft -f-i.
.-4 .4
4..
4-
41..
4 .4...
-+
.4---
.4.
.4.
.4
...
.4.
4.
4
4.
-.- 1
fi
-a--
.4
4..
..
..E
.
4
I-
q_
...-
4...
L 4
4
t
.4
._.._
4.
--
.4.
..
..
....,...... .,..
.5
i-!-.w
.4
4-
.4
4-
4-
. 3..
4...L
4-H
,
.
4..
.4.
-.f ..4
4--
.4
...3
4r-
.
.
4.-
4-,.
.,.
.4.
:-
..-q.
4.-,..
-.-.-.
.4-
,....,
,..,. ...
.
..,..,.,...
.
----i-
.---_
.3
4.
..
.,.,
..4..4.4.
.4---
..
I
-4,
.L..
.......,
..t
,
. ..
..,....,,.
-4-h-
.4.
-..
.....L
..
..-.
-i
4q.4_4..._..4.4.444
4.
--
j Jt
.4.
._.,
3..
4._.4_.
_.
--
._
.4
-.
.
.
44.
4.
.14.1
..3
.-
.4.
.-:
- .
.4
4..
.-----
4....
4......,
:,..
4...
.4
4.
-.
4-
3.4...
4-1
.4.
j..
4.
..
4..
..,
,.
L.
.,
.4-3
.,
.4..L
1 -
...
.4...
-:
..r..
- 444-.4
4_4_44-
-i
r-
L-q-
.., ..
-,
.
4...L .4
..4..4
. .3
.4
ZE2E
4--
- 4-.4444
-.-
--.
..
.,-..,..
4.4.
. . . .
-.-...
--;
-1-i+4
..,
. . .-...,
.
..
3.
...
.4. .4.
3... , .3.4
......
.4.4....
.
-4--f
_4+
.-.4-..
.....,
4.
-.4
4.4.
...
1
Z.-
...
...,.._.1..
;
LZZ
.3.
.,
.4.4.
3..
:-E
---
.4
4
r-
....j
:-
r4
,-.
...
4
---.I
.
3--.-.444j---4-.I
-3--
C
b
.j
1
i
iEEEEEEE
r-
..
-.4,
...!
Te
(v) Calculate the number of moles of acid in the volume of acid obtained in (iii)
above.
moles of acid in
cm
Y
3
.
(vi) From your answer in (v) above, calculate the concentration in mol/dm
3 of
hydrochloric acid in solution Y.
The following tests were carried out on a sample salt N. Complete the following table.
TEST
OBSERVATIONS
ii
iii
Lime water
cloudy
iv
vi
Deep blue
formed
CONCLUSIONS
turned
complex
r L4
k
1,
2,
4,
5,
6,
9,
20,
80.
2(a) Choose one of the numbers above to complete each of the sentences (a) to (g).
Each number may be used once, more than once, or not at all.
(a) The percentage by volume of oxygen in the atmosphere is
(b) The total number of atoms in one molecule of methanol is
(C)
[7]
By naming the reagent and giving the observation, describe a simple test to
confirm that olive oil contains an acid.
Reagent:
Observation:
(ii)
(iii) By naming the reagent and giving the observation describe a simple test tc
confirm that oleic acid is unsaturated.
Reagent:
Observation:
[5]
.
31
H
H
2
17 CO
(b) The molecular formula of oleic acid is C
How many double bonds between carbon atoms are present in one molecule of
oleic acid?
Explain your answer.
Number.
Explanation.
[2]
(a)
Potassium nitrate is a salt which can be prepared by reacting an acid with an alkali,
using the titration method.
(i)
(ii)
Explain why the titration method is suitable for the preparation of potassium
nitrate.
[4]
(b)
Lead (II) iodide is a salt which can be prepared by the precipitation method.
Name suitable reagents for the preparation of lead (II) iodide.
(i)
Reagents:
(ii)
Explain why the precipitation method is suitable for the preparation of lead (II)
iodide.
[4]
4
(A)
The diagrams below represent the flames on a burner using methane as the fuel.
;
V
FLL
E
I
..
(A) The equation for the complete combustion of methane in zone A is:
4 + 202
CH
2 + 2H
CO
0
2
(a) What colour would you expect the flame to be in
zone B
zone C
(b) (i)
(ii)
[2]
(C)
CI
C=C
H
Suggest a name for, and sketch the structure of, the macromolecule formed
when fluorochloroethene polymerises.
(ii) When 20 tonnes of fluorochioroethene polymerised, 18 tonnes of the polymer
were obtained. Calculate the percentage yield.
(iii) Name and give a use for a commercially available polymer containing a
[5]
halogen.
(i)
(b) Pure oxygen is obtained from air and is used as an aid to breathing in hospital
oxygen masks.
(i) Describe in outline how pure oxygen is obtained from air.
[3]
(ii) Give a commercial use for oxygen other than as an aid to breathing.
(C)
One problem with oxygen is that it is the essential element in causing corrosion
of metals.
One method of limiting corrosion is known as sacrificial protection.
[2]
Explain what is meant by sacrificial protection.
The incomplete diagram below represents the arrangement of the ions in crystals of
either sodium chloride or magnesium oxide.
N
2
a positive ion, Na or Mg
\
\
a negative ion, CI
or 02
l
(a) (I)
(ii)
(iii) What feature of the ions in the two compounds explains why the melting
point of magnesium oxide, 2800C, is much higher than that of sodium
chloride, 801C?
[6]
(b) Give a commercial use of magnesium oxide which depends on the high value for
its melting point.
[1]
5
(b) At 150C and a pressure 1 one atmosphere, the reversible reaction between gas
A and gas B reaches a dynamic equilibrium.
A(g) + 2B(g)
AB
(
2
g): 1H = 220 kJ/mol
(a) Is the formation of AB
2 exothermic or endothermic? Explain your answer.
[2]
(b) (i)
(ii)
[4]
(C)
[2]
1 hour 10 minutes.
INSTRUCTIONS TO CANDIDATES
Read the Instructions on the answer sheet very carefully.
Candidates MUST answer THREE questions on this paper. They must choose ONE from
Section 1, ONE from Section 2, and ONE from Section 3.
JI working MUST be shown for calculations.
Section I
Answer one (1) question from this section.
I
(a)
confirm that
(1)
(2)
(a)
The diagram represents an apparatus used to investigate the reaction between metals
and metallic oxides.
magnesium fuse
crucible
mixture of metal
and metallic oxide
sand
metallic oxide
(I)
(II)
metal
aluminium
oxide
calcium
oxide
iron (Ill)
oxide
tin (IV)
oxide
aluminium
no
yes
yes
calcium
yes
yes
yes
iron
no
no
yes
tin
no
no
no
(III) Construct the equation for the reaction between calcium and tin(IV) oxide. [3]
(b)
Describe how the action of heat on the carbonate of a metal depends on the position
[2]
of the metal in the reactivity series.
(C)
(d)
(I)
(II)
By naming the reactants, the products and the catalyst, give an example of a
[3]
reaction which uses a catalyst.
Describe the bonding in metals. How does this bonding explain the ability of metals
[21
to conduct an electric current?
Section II
Answer one (1) question from this section.
How many electrons, protons and neutrons are present in one atom of the chlorine
.
(a)
isotope Cl?
(b)
Give the equations for the eJectrode reactions by which hydrogen and chlorine
are formed.
(II)
Explain why much less chlorine is collected when iron electrodes are used.
(Iii) Name the product, other than hydrogen and chlorine, which is manufactured by
the electrolysis of concentrated aqueous sodium chloride. Give a major use of
[5]
this product.
(C)
Why is the electrolysis of concentrated hydrochloric acid not used for the manufacture
[2]
of chlorine?
Solid sodium chloride does not conduct electricity but an aqueous solution of
sodium chloride does.
(b) A dilute solution of copper (II) sulphate is electrolysed using platinum electrodes.
A current of 0.025 A is maintained until 96.5 coulombs of electricity has passed
through the cell.
(I)
Explain in terms of ions and electrons the changes taking place at the anode
and the cathode in the solution.
(ii) What changes would you expect to observe at the anode, at the cathode
and in the solution?
(iii) For how many seconds must a current of 0.025 A be maintained to pass
96.5 coulombs of electricity?
Section III
Answer ONE question from this section.
5. (a) Describe the differences between fibres, fabrics and textiles.
(b) List four desirable properties of textiles.
(C)
[31
[4]
Describe what is done when a fibre does not, possess all the desired properties of
a good textile.
[3]
[6]
(e) Give a definition of a mordant and show, using equations how two different
mordant can be formed.
[4]
[2]
[4]
(c) Potassium, Phosphorous and Magnesium are three important elements needed
for plant growth. Plan and Design an investigation to show the effects of the
deficiency of there elements.
[8]
(d) At the end of the experiment in (c), list two measurements that can be taken. [4]
(e) What would be the effect of growth on this experiment?
[2]
1 hour 15 minutes.
INSTRUCTIONS TO CANDIDATES
There are sixty (60) questions in this paper. Answer all questions. For each questio
n,
there are four possible answers A, B, C and D. Choose the one you consider correct
and
record your choice in soft pencil on the separate answer sheet.
Read the Instructions on the answer sheet very carefully.
__
___
ammonia
hydrogen
0
I,J
by chromatography
by crystallisation
by distillation
by filtration
The table shows the melting and boiling points of four pure substances.
evaporate if left expbsed
Which substance is a liquid at room temperature and would rapidly
to the air?
substance
melting points 1C
boiling points IC
-100
-35
-7
58
-6
225
44
280
PtoQandRtoS
PtoQ
OtoR
RtoS
temperature
0
2
lime
Protons
17
17
20
20
neutrons
20
18
20
21
electrons
17
18
18
20
X and Z
0
7
melting point
type of bonding
in its oxide
good
high
ionic
good
low
covalent
poor
high
ionic
poor
low
convalent
The gaseous element X is a diatomic. One volume of the element combines with one
volume of hydrogen to form two volumes of gaseous hydride.
Which is the formula for the hydride of X?
A
HX
2
HX
X
2
H
X
2
H
10
11
12
13
lto8
lto2
ltd
2tol
2
Ni(OH)
Ni
O
2
H
What are the products when concentrated aqueous sodium chloride is electrolysed using
inert electrodes?
anode (+)
cathode ()
chlorine
hydrogen
chlorine
sodium
oxygen
sodium
oxygen
hydrogen
The diagram shows the results of an electrolysis experiment using inert electrodes.
Which of the following could liquid X be?
._
ethanol
liquid X
-II,
14
62 into
The scheme shows four stages Ito IV in the conversion of solid candlewax CH
carbon dioxide and water.
II
I
CH(s)
-,
CH(l)
Ill
CH(g)
-,
3000
(
2
g)
3GCO(g)
31H
0
2
(g)
31H
0
2
(l)
landli
IlandlIl
lIlandlV
andlV
15
When an excess of calcium carbonate is added to dilute hydrochloric acid, the reaction
gradually becomes slower and finally stops.
Which statement best explains why this happens?
A
An insoluble layer of calcium chloride is formed on the calcium carbonate:
16
17
carbon dioxide
glucose
nitrogen
water
concentrations of 01-Lions
high
none
high
low
low
D
18
high
low
19
20
calcium
copper
phosphorus
sulphur
Which of The following pairs consist of substances that produce a precipitate when their
aqueous solutions are mixed?
A
Tests on a sample of polluted water from a factory gave the following results.
reagent added
result
white precipitate
aqueous ammonia
white precp;ate
insoluble in excess
aluminium chloride
aluminium sulphate
zinc chloride
zinc sulphate
21
22
hydrogen
nitrogen
The table gives the formulae of the catalysts used in some industrial processes.
catalyst
process
Haber process
Contact process
Fe
Mo
5
0
2
V
cracking of alkanes
Polymerisation of ethene
3
0
2
A1
manufacture of silicones
CuC!
2
Si0
C
2
A1(
3
)
5
H
4
TiCI
or as compounds) in the
How many different transition metals are included (as elements
list of catalysts?
06
5
C
84
3
A
23
D
24
most reactive
25
least rective
After copper (II) oxide h2s been reduced to copper as shown, the burner is turned off but
the hydrogen is kept Jwing until the tube is cold.
excess hydrogen
dry
I
hydrogen
burner
26
?
3
0
2
What is the mass of alUminium in 204 g of aluminium oxide, A1
A
27
26 g
27g
54 g
108 g
sodium
water
metal X
calcium
copper
7
potassium
28
29
Air contains about 21% oxygen by volume. When a sample of river water was boiled the air
expelled was found to contain 30% oxygen.
What is the best explanation of this difference in oxygen content?
A
Carbon dioxide is more soluble in water than in oxygen.
30
An NPK tertiliser is made by mixing together one mole of each of three compounds.
Which mixture will contain equal numbers of atoms of nitrogen, phosphorus and potassium?
components
31
S0
2
K
4
(P0
3
Ca
2
)
4
3
KNO
NO
4
NH
3
4
Na2HPO
3
KNO
C0
2
)
4
(NH
3
HPO
2
K
4
3
NaNO
S0
2
)
(NH
4
(PO
3
Ca
)
4
S0
2
K
4
3 sulphuric acid?
What is the concentration of hydrogen ions in 0.05 mol/dm
A
32
mixture
3
0.025g/dm
3
0.05 g/dm
3
0 lOg/dm
3
0.2g/dm
2NaOHNaCli-H
C1
2
0
-i- 2NaOH
2
C1
NaCI
2Ct+NaOH
2
NACIHCI+0
2Ct+ 2NaOH
2NaCI
NaC1O
2HCI
0
2
H
2HCI
+ 02
33
9i-0-Si--0
SiO--Si 0--
siDsifl
cc
0
fJ
11
EEi
0SiOSi0
DOSiD0Si
ES
34
35
C and C
6
H
3
4 and C
H
2
C
IIo
HC
0H
36
it decolourises bromine.
B
C
water out
water in
condenser
heat
9
ethanol
reforming agent
37
The macromolecules of proteins, fats and carbohydrates can all be broken down into their
simple units by a similar process.
What is the process called?
A
38
39
hydrolysis
oxidation
reduction
poly(ethene)
poly(chloroethene), pvc
Terylene
D
40
esterification
A 10 cm
3 sample of a gaseous hydrocarbon was completely burnt in oxygen. The total
volume of the products was 70 cm
.
3
Which equation represents the combustion of the hydrocarbon?
A
(g) + 20
4
CH
(g) C0
2
(g) + 2H
2
0(g)
2
B
C
(
4
H
2
g)
30
(
2
g)
2C0
(
2
g)
2H
0
2
(g)
C
(
8
H
3
g)
50
(
2
g)
3C0
(
2
g)
4H
0
2
(g)
2C
(
6
H
2
g)
70
(
2
g)
4C0
(
2
g)
6H
0
2
(g)
10
V
24
Cr
Fr
99
776
89
57
Ac
tnsn
Key
x aonic so
bpm(on(alm*)ntxnbe
1= r.Iiv. at1
mill
72
9.
c..,..,,,
54
179
Hf
136
La
137
Ba
133
Cs
90
89
73
41
III
29
Mn
Fe
27
Co
26
Ni
29
30
222
93
Pj,,
91
93
Np
te4,
U
*J4.
Pa
Pu
94
P*.n
150
Sm
99
Am
16
97
Bk
b1b4.
Cm
Cm
99
Cf
90
Es
10?
Fm
No
l4
10?
Md
Mb.im
101
LWa
*0?
Lr
U,n
11
91I.
70
1)4.n
E,*.n
Dr.o..W
46
ti,.
175
Lu
173
Yb
189
Tm
167
Er
165
Ho
152
89
Dy
99
94
159
99
52
Rn
P.
At
99
54
A.b*.
i.
131
Xe
Kr
127
36
II
c.
Th
97
62
53
39
17
40
Ar
Cl
35.5
lbo
157
91
Po
Te
12*
Se
32
10
Gd
65
93
152
66
79
52
34
16
20
Ne
F
0
II
VII
16
VI
Eu
(,n,..n,
93
70
Th
236
Pln*t..,.
61
N,,...,
03
Cu.,,
Pm
144
Nd
141
77
InIl
Bi
L
G4d
P*,
Uy
Ti
9,n
200
207
Pb
204
201
Hg
197
51
Au
199
80
Sb
122
As
Pt
..
33
Jr
49
118
Sn
In
32
115
Ge
192
49
Ga
G..,n
190
47
31
15
A._.._
14
13
31
29
Si
27
Al
Os
46
5E.
P.n
45
Cd
Ag
Pd
Rh
Ru
Pr
76
44
112
109
Z.
106
Zn
Cu
Co
103
N.I
101
140
75
9?...m
wn
50
74
199
Re
194
TWW
43
Tc
26
Ce
Ta
42
rb
Zr
40
Sr
SI
Rb
6.*
31
Mo
Nb
36
96
93
23
V.,,,
91
87
22
11
99
55
37
21
Sc,,
99
96
20
KC
I2
IQr
24
Mg
23
Na
Po,
Sc
Ie1
t__,
5
Be
14
12
Ii
.L_______
Group
DATA SHEET
The Perfoc Table of the Elements
41
42
43
44
45
calcium hydroxide
copper hydroxide
ammonium hydroxide
Which of the following methods is NOT suitable for softening water that is permanently
hard?
A
distillation
iron-exchange
boiling
In the reaction: X + 2H
X+ H,
copper and sulphuric acid
A
Metals high in the electrochemical series are usually extracted from their ores by:
A
Reduction of the oxide with carbon
B
12
46
47
immiscible liquids
miscible liquids
48
3C0
502
3
2cm
0
2
4H
3
4cm
3
8cm
The number of coulombs equivalent to 2.5 amp flowing for 8 mins is:
C
A
60
600
B
1200
D
10 cm
3
1800
Polymerization
Addition
51
Hydrolysis
Dehydration
49
50
51
52
53
If the following ions are in solution in equivalent amounts, then the one most likely to be
discharged at the anode on the passage of an electric current would be:
A
2
4
S0
OW
13
CF
54
Caesium is an element similar to that of potassium. The equation for the decomposition
by heat, of caesium nitrate is most likely to be:
2 +02
2CsNO
3
2CsNO
2 Q2
B
2Cs0 + 4N0
A
3
4CN0
C
55
B
C
D
2
2N0
+02
2
)
3
2Cs(N0
CsO
2
4N0
polyester
COOH
polystyrene
peptide linkage
glycosidic linkage
58
Which of the following would NOT speed up the reaction between magnesium and
hydrochloric acid?
Adding concentrated acid
B
Heating the reaction flask
A
Using finely divided magnesium
D
Adding water
C
59
60
+02
the same number of electrons and protons but differing number of neutrons
the same number of electrons, protoiis and neutrons
57
2Cs
56
3
2CsNO
Solar energy
The action of dilute nitric acid on copper can be represented by the equation:
0 + 2N0
2
x Cu(N0
2 + 4H
)
3
3
X Cu + y HNO
The values of x and y are:
B
x=3,y4
A
x2,y6
14
x3,y8
x=1,y3
1 hour 30 minutes.
INSTRUCTIONS TO CANDIDATES
1. You must use this booklet when responding to the questions. For each question, write
your answer in the space provided.
2. All working must be shown.
3. There are five questions in this booklet. Answer all five questions.
vtl
(a)
2 is dHute
106. BA
30
28
29
29.
31
Titration 3
Titration 2
Titration i
30
Figure 1
(I)
Use the informtion if Figure 1 above to complete the following table of results.
TITRATION
Burette Reading
Final Reading
Initial Readtng
cm
1
-
2
Volume of solution BA
usedIcm
(..,
(ii)
(iii)
3
1 in molt dm
Calculate the concentration of BA
(I)
How many moles are there in the average volume of HCI calculated in (i)?
.ib$
(ii)
J(O
.c-
(iv) What is the most likely value of X?
11
/,v
[R.A.M.
12, 0
16]
water out
(b)
tOC
water n
ethyl butanoeie
heat
The above figure shows the first stage in the production of ethanol by the
reaction of heat on a mixture of ethyl butanoate and sodium hydroxide.
(i)
(ii)
(iii) Explain how the arrangement of the condenser might help to promote the
completeness of the reaction.
(iv)
(v)
(iii)
an acid that forms a white precipitate when mixed with aqueous barium nitrate;
HCI
sodium chlorate(l)
NaOC1
household bleach
sodium chtorate(V)
3
NaCIOO
weedkiller
sodium chloride
NaCI
food preservation
(i)
(iii) Household bleaches containing sodium chlorate(1) can be made by reacting chlorine
with sodium hydroxide.
0
2
NaCI+ NaOCI + H
2
2NaOH + Cl
Explain why this is a redox reaction.
(iv) Give another use of chlorine, Cl, not mentioned in the table.
[4]
3A
, burns in oxygen to give a very hot Ilame. The temperature is so high that the
H
2
Ethyne, C
flame can be used to cut metal.
c)
5
(a)
(I)
(II)
(2)
..
(b)
Construct an equation, inchjding state symbols, for the reaction between calcium
carbide and water. The molecular formula for ethyne is
(ii)
The mixture obtained after reaction was tested using Universal Indicator.
What was the final colour of the Universal Indicator? Explain your answer.
6]
3B The table below shows some data about the homologous series of alkanes.
alkane
number of carbon
atoms per molecule of
alkane
n
melting
pointiC
boiling
pointiC
energy released by
complete combustion
of one gram! kJ
E
number
of
isomers
methane
183_
162
55.6
ethane
propane
183
188
89
52
42
1
1
butane
pentane
2
3
4
5
138
130
0
36
49.7
49.2
2
2
hexane
heptane
6
7
95
91
69
96
48.8
48.5
5
9
(i)
(ii)
(iv) Give the molecular formula of an alkane that is a liquid at roori temperature and
pressure.
(e)
(f)
4A
b)
(1)
(ii)
3 of ozone, O3 is decomposed,
What volume of oxygen, O2 is formed when 40cm
both volumes being measured at the same temperature and pressure?
molecules.
4B The table below shows some data about some of the components of air.
component
melting pointiC
boiling point IC
argon
carbon dioxide
krypton
neon
nitrogen
oxygen
water vapour
-189
78
157
249
210
219
0
186
78
153
246
196
183
100
(a)
(b)
(C)
Air is a source of nitrogen, oxygen and the noble gases. These are obtained by the
fractional distfllaiton of liquid air. Before air is liquefied, carbon dioxide and water are
removed.
(I) Suggest why air is dried before it is liquefied.
.Qi)
5A
carbon
chromium
helium
magnesium
phosphorus
sodium
sulphur
In your answers, you may use an element once, more than once, or not at all.
Choose one element which
(i)
(ii)
exists as allotropes.
[5]
5B
The elements shown below are all in Group I of the Periodic Table.
element
symbol
lithium
sodium
potassium
rubidium
caesium
Li
Na
K
Rb
Cs
electronic structure
2,
2,
2,
2,
2,
1
8, 1
8, 8, 1
8, 18, 8, 1
8,18, 18, 8, 1
(a)
(b)
(C)
(d)
TIME:
1 hour 10 minutes.
INSTRUCTIONS TO CANDIDATES
Candidates MUST answer THREE questions on this paper. They must choose ONE from
Section 1, ONE from Section 2, and ONE from Section 3.
All working MUST be shown for calculations.
Section I
Answer one (1) question from this section.
I
(b)
If an aqueous solutin of glucose is heated with alkaline copper (II) sulphate, a brickred
precipitate is formed. The precipitate is an oxide of copper.
[1]
(i)
(ii)
(iii)
[4]
(c)
Describe the conditions needed for the fermentation of glucose to give ethanol.
(d)
(I)
Name an organic product formed when ethanol reacts with acidified potassium
dichromate (VI).
(ii)
Draw the structural formula of the organic product you have named.
[3]
[2]
Another gas must be earned by a space shuttle in order to burn the hydrogen.
What is the name of this gas?
(ii)
Suggest a reason why a space shuttle carries liquid hydrogen rather than
[2]
hydrogen gas.
.
(b) (i)
(ii)
(iii)
(c) (I)
In terms of the bonds broken and the bonds formed, explain why the burning of
[6]
hydrogen is exothermic.
It has been suggested that hydrogen could be developed as an alternative fuel for
the future.
Suggest one advantage hydrogen has over fossil fuels.
(ii)
[2]
Section II
Answer one (1) question from this section.
The table below showsthe results of an experiment using 0 lOg of magnesium ribbon
and
3 of 2.0 mol/dm
25cm
3 sulphuric acid. In the experiment, magnesium ribbon was mixed
with dilute sulphuric acid and the total volume of hydrogen produced was measured every
live seconds. After fifty seconds, the rection had stopped
time from start of
experiment/s
3
produc
edm
31
10
54
15
71
20
85
25
94
30
99
35
100
40
100
45
100
50
100
(a)
(b)
The equation for the reaction of magnesium and dilute sulphuric acid
is given below
Mg +H
4
S
2
0
(c)
13)
2
H
MgSO
(i)
(ii)
[2)
The experiment was repeated using the same mass of magnesium but
25 3
cm of 3 0
3 sulphuric acid.
mol/dm
State and explain how
(I)
(d)
(ii)
Give
(.
\
c
[5]
Draw a diagram of an atom of silicon, showing how the electrons are arranged and
[3]
the numbers of protons and neutrons in the nucleus.
(b)
Carbon and silicon each form dioxides in which the bonding between the atoms is
covalent. Carbon dioxide has a simple molecular structure whereas silicon (IV) oxide
(silicon dioxide) has a macromolecular structure.
(I)
(j)
0
Sirb
/ \
0\
Si
0
Silicon (IV) oxide has a high melting point whereas carbon dioxide is a gas.
Explain this in terms of the structures of the two oxides.
(iii) Does silicom (IV) oxide conduct electricity? Explain your answer with
[5]
reference to its structure.
(c)
(ii)
[2]
Section III
Answer ONE question from this section.
5
(a) Using illustrations, show the differences in the methods by which acid dyes and
basic dyes work on fabric.
[4]
(b) Give an example of one acid dye and one basic dye.
[2]
[6]
(d) Describe the differences between mordant dyeing and direct dyeing.
[3]
(e) Describe how one dye, e.g., alizarin, can be used to produce two different
colours in mordant dyeing.
[5]
6.
I
N
/
H
C\
0H
C=12
0=16
N=14
H=1
S=32)
[4]
(d) Discuss the use of organic manure versus commercial fertiliz
ers in terms of cost
and effect on the soil.
[4]
(e) Ammonium sulphate is a soluble salt. Ammonia is a soluble
base Suggest and
describe a method you would use to make a sample of ammo
nium sulphate. [4]
1 hour 15 minutes.
INSTRUCTIONS TO CAND
IDATES
There are sixty (60) quest
ions in this paper. Answ
er aH questions. For ea
there are four possible an
swers A, B, C and D. Ch
ch question,
oo
record your choice in soft
se the one you consider
correct and
pencil on the separate an
swer sheet.
Read the Instructions on
the answer sheet very ca
refully.
INFORMATION FOR CA
NDIDATES
Each correct answer wil
l score one mark.
answer.
th a mixture of
nsde a balloon tilled wi
s
cle
rti
pa
of
nt
me
ge
arran
Which diagram shows the
n?
helium and argo
D
key
C
B
A
...heiium atom
70
00 0
oQo
/0
00
00000
t soluble in water.
ils at 12OC and is no
bo
C,
9O
at
lts
me
X
Compound
of X with water?
pure X from a mixture
n
tai
ob
to
ed
us
be
n
D
Which apparatus ca
B
the apparatus
onal distillation using
cti
fra
by
ter
wa
d
an
parate ethanol
A student tries to se
shown.
water out
condenser
water in
receiver
heat
4
D
3
titration value 1cm
20.4
20.4
20.5
20.6
22.0
r 5?
t
Which statement could explain the result obtained by studen numbe
The burette was washed out with hydrochloric acid.
A
The pipette was washed out with the tablet solution.
B
4
O
e=electron
p proton
allotropes
ions
isomers
R
6
a covalent compound of formula P
an ionic compound of formula PR
2
an ionic compound of for mula PR
isotopes
water
water
water
ammonia
methane
sodium chloride
water
methane
ammonia
sodium chloride
10
27
30
87
90
Which quantity is the same for one mole of ethanol and one mole of ethane
?
A
mass
C
P
number of atoms
number of molecules
volume at r.tp.
11
Which of the following, when added to water, makes a solution that is a good conductor of
electricity?
12
calcium carbonate
copper
ethanol
sodium hydroxide
Aqueous copper (II) sulphate is electrolysed using copper electrodes. The current is constant
and the cathode (negative electrode) is weight at regular intervals.
Which graph is obtained when the mass of the cathode is plotted against time?
0
13
time
time
time
....wire
metalX
metalY
dilute
sulphuric
iron
zinc
zinc
calcium
zinc
magnesium
zinc
iron
time
14
The table shows the energy released by the complete combustion of some compounds
used as fuels.
compound
formula
Mr
H, in kJ/mol
methane
4
CH
16
880
ethanol
H
C
O
5
H
2
46
1380
propane
8
H
3
C
44
2200
heptane
6
C
1
H
7
100
4800
Which fuel produces the most energy when ig of the compound is completely burned?
A
15
16
17
18
heptane
ethanol
methane
propane
hydrogen
hydrochloric acid
zinc oxide
water
copper
magnesium chloride
zinc
magnesium oxide
carbon monoxide
watei
carbon dioxide
A man suffering from an excess of acid in his stomach has no indigestion tablets.
7
Which substance could he now take to lower this acidity
A
aspirin (pH6)
19
20
pH of
sample
white precipitate
no reaction
no reaction
11
white precipitate
Which ion, in aqueous solution, forms a white precipitate when dilute sulphuric acid is
added?
A
21
sample
Ag(aq)
aq)
Cu
(
2
aq)
Ba
(
2
Fe(aq)
Salt P0 is to be prepared by reacting the carbonate of P with the acid HO. The titration
method is to be used to carry out the preparation.
What are the solubilities of the carbonate, the acid and the salt?
22
the carbonate of P
the acid HO
the salt P0
insoluble
soluble
insoluble
insoluble
soluble
soluble
soluble
insoluble
insoluble
soluble
soluble
soluble
Key
x= Yelectron
H electron
Ill
IV
VI
23
19
Fluorine,
element
number of
valency
electrons
melting
point/C
boiling
pointfC
colour of
vapour
chlorine
71
101
-35
yellow-green
bromine
160
+59
red-brown
iodine
254
+114
+184
violet
24
25
2,8
2,8,8
2,1
2,8,1
2,88,1
2,7
2,8,7
2,8,19,7
2,8,3
2,8,4
2,8,5
HO
-_-
2HCI
+
2R0
H
2
RCI
no reaction
2
H
26
aluminium
calcium
copper
iron
What describes the solution formed and the gas evolved when potassium reacts with cold
water?
solution
gas
alkaline
al k all r. e
alkaline
neutral
neutral
akaIine
neutral
n E J I 1?
27
The diagram shows the cell used in the electrolytic extraction of aluminium
cathode
Which reaction takes place at the electrode where the aluminium is formed?
A
Atoms gain electrons and form ions.
28
29
The apparatus shown is used to determine the percentage by volume of oxygen in the air.
substance X
ng?t1syring
tube
Which of the following could substance X?
30
calcium oxide
carbon
copper
Which compound does not provide one of the essential elements needed for plant growth?
A
ammonium sulphate
B
calcium hydroxide
calcium phosphate
potassium chloride
9
31
C-CO-bO--C----CO--EZ_O_
CCNL]N(__N_E]_N_
o LI o
LI
LI
LI
34
35
LI
I
LI
LI
H(aq)
A
33
o LI
OSiOSi----OSiO
32
0H(aq)
SO(aq)
SO(aq)
What are the formulae for lime, limestone and slaked lime?
lime
limestone
slaked lime
CaO
3
CaCO
2
Ca(OH)
CaO
2
Ca(OH)
3
CaCO
2
Ca(OH)
3
CaCO
GaO
3
CaCO
2
Ca(OH)
GaO
sterilising water
manufacturing plastics
/GC\
H
A
H\
H\
HC-- C\
Cl
/CGCH
H
H
10
HCC-ccH
H
36
37
, reacts with
CO
2
CHJCH
What is the formula of the ester formed when propanoic acid, H
ethanol?
A
O
H
3
CH
C
2
O
H
3
CH
C
2
O
H
3
CH
C
2
O
H
3
CH
C
2
Which of the following has a type of linkage similar to that of a poly (carbonate)?
starch
poly(propene) D
C
B
a polyester
A
a polyamide
38
39
In the tractional distillation of crude oil, which product has the highest boiling point?
A
bitumen
lubricating oil
paraffin (kerosene)
petrol (gasoline)
c=c
H
H
Which polymer can be made from this monomer?
Cl
Cl
I I
CCCc
I I I I
F
Cl
40
Cl
Cl
Cl
Cl
I I
CCCc
H
Cl
C---C-C-C
B
C
It is an unsaturated compound.
It is formed by the oxidation of ethanoic acid
Cl
Cl
CL
I I I
CCCC
I I I I
H
H
41
1 2 dm
3
2.4 dm
3
4.8 dm
5
7.2 dm
2
42
Which one of the following suggests that matter is made up of particles in continuous
motion?
A
43
44
46
neLitralization
diffusion
melting
The charging of atoms by friction as metallic and non-metallic atoms collide with
one another
45
oxidation
ethane
ethene
methane
carbon dioxide
Diamond has a giant molecular structure but graphite has an ionic structure
To which group in the homologous series does the compound below belong:
H
HC
//
//
C
3
OH
A
a;Kanes
akenes
12
akar:oc acids
esters
47
48
48
is a conductor of electricity
80% by mass of
A compound containing only the elements carbon and hydrogen has
carbon. The empirical formula of this compound is:
A
2
CH
3
Cl-i
4
CH
,
C
H
2
50
ed that caesium.
Caesium (Cs) is a metallic element similar to sodium. It can be predict
A
2)
forms a hydroxide of formula Cs(OH
C=C/H
H-CC
H-CCC-H
Ii
13
51
52
54
alkenes
alcohols
acids
53
alkanes
substitution
hydration
reduction
addition
Compound A and B both have isomers. The number of isomers in A and B are:
Isomers in A
Isomers in B
Isomers in A
Isomers in B
HI
bCC
H
CH
J
3
n
55
56
methane
ethane
ethene
propene
A solution containing lead (II) ions was added to a solution containing iodide ions and a
yellow precipitate was formed. Which of the following represents the equation of the
reaction that occurred?
A
Pb
Pb
21
Pbl
2
Pb1
t
2
Pb
F *
2
Pb
21
PbI
2
PbI
C, H,
C H
+
2
,
2
C, H
13
C H
1
,
2
_
57
58
59
60
Heating water
en?
Which of the following methods cannot be used for the production of hydrog
Add magnesium to dilute sulphuric acid
A
B
When ions are discharged at the cathode, the process is one of:
oxidation
C
neutralization
B
reduction
A
hydration
when treated
A solid X is insoluble in water. It gives off a gas when heated and also
with dilute sulphuric acid. X could be:
copper (II) carbonate
B
calcium hydroxide
A
C
sodium carbonate
zinc oxide
1 hour 30 minutes.
INSTRUCTIONS TO CANDIDATES
1. You must use this booklet when responding to the questions. For each
question, write
your answer in the space provided.
2. All working must be shown.
3. There are five questions in this booklet. Answer all five questions.
______
10
12
12
10
10
15
20
10
(i) Draw a graph of height of precipitate against volume of I .Om silver nitrate.
3
(ii) From your graph, find the height of the precipitate formed by mixing 3.0cm
solution.
chloride
of metal [X]
nn
Is. 1
(i) Find the two volumes of silver nitrate solution that would give a precipitate
whose height is 12.5mm.
1.
2.
Li. 3
-
U-
mm.
3 of i.oM
cm
,N
(v) Write the equation for the reaction of metal X chloride and silver nitrate
solution:
(b) Complete the table of results for tests carried out on a substance D which was
dissolved into water and divided into three portions.
(i)
(II)
(iii)
(iv)
TEST
To the first portion aqueous sodium
hydroxide was added
The contents of the tube form (1)
were allowed to stand for a few
minutes
OBSERVATIONS
a green precipitate
was formed
ft
ow
pr
1S
precipitate
white
formed insoluble in
excess
CONCLUSIONS
w
(2
zrt.I.A
-4.
nflj
Th
Th
_yc.-S
,
-.
re.t
$4
--P-
z.Ji
..-
-t i_.t..
.-... L J_....
.4..
.L-.-
2-p..
It
4--j
.-.
Ii-
..
Thtit__
L
--4
..L...
--.-L--.
1-,--
.
4-4-;
t_
-4-.
-rc-----:---;
i;L:
4
+
4-
,,i-__i.4-
-4_4_ I
+t r:L:
:4.
-if-
-.
;..:U;LZL
rTrt
-4
:-------
C
4
LZ :
:L1
---
::::
.r1$Tr1
t-.
.-
r-
.--
--.4-.--.
rr
rr-r
.4-
,;,
...
-,
-4.
4
-.-j-
-r-r
1.-lw-
-4-
.L..
4
t
I
I;;tt
ih
.._i._._._4.L
I
:.
_i z..z
Litr
111
ffr
s_-fl-i
Titlt
tt
--
-.
cC
14tII.
.______L_:,
..---
__
:.Jll4L
4
.
ZY
!7,jZu.rCf
.Z!-Lt iLt
htTt .UZ nil all
I
II-
ZtLI ifl
-fl-i
--
-,
.-
LL
-r
I -
-it--r
J_...___ 1 -r
._....__L. ..L.L.....
O7fl.CtkI
-1--
.yJ/
tsw
ian
CV\
(c) The red colouhng matter in a preserved fruit was extracted by a solvent. Two
drops of the red solution were placed at the centre of a circle of filter paper and
allowed to dry. Drops of solvent were slowly added to the centre of the filter
paper. After a time, four coloured circles were seen as shown in the diagram
below.
N filter paper
/
red circle
red circle
paper
orange cirde
(i)
(ii)
Name a piece of apparatus that can be used to drop the solvent on the filter
paper.
(Ni) How many different dyes are present in the preserved fruit?
An alternative set of apparatus was set up as shown below for this
experiment.
r
beaker
strip of filter paper
position of red spot
solvent
___________
lid
(iv) Label on this diagram the results you would expect if this was set up and left
until the solvent reached the top.
2A
The following statements are taken from a students notebook. Each statement is incorrect
but can be corrected by changing one word. Underline one word that should be changed
and give a correct word in the space provided.
(a)
(b)
(c)
(d)
In an atom, the particles with a negative charge are protons and the particles with no
charge are neutrons.
Correctword
(e)
(f)
(&
(a)
[7]
tt
4
4t
4
wjo
ir(..
pv+icIt-sa-.oC
0
c
t
c
d
fl.flt
pv.aavt
Ohv3
attt
t4F
-4
(i)
(ii)
(iii)
..
(iv)
(c)
the same
Samples of the gases carbon dioxide, M,= 44, and hydrogen, M= 2, are at
temperature.
Compare the speeds of the molecules in these two gases
[11
Equal masses of steam and of water contain the same number ci molecules.
Explain why the volume of the steam is much greater than that of the water
[1]
fertiliser
Phosphorus is one of the elements essential for plant growth. The effect of using a
table.
containing phosphorus on the yield of potatoes from a field is given in the
phosphorus added! kg
potato yield! kg
1300
2600
3100
3400 a4
3500
3500
0
10
20
30
35
55
sos)
(a)
Give the names of the two other elements essential for plant growth, which are
commonly present in fertilisers.
[1]
and
(b)
After studying the table, a farmer decided to use 15kg of phosphorus on his field.
Estimate the yield of potatoes the farmer expected.
(I)
(II)
(c)
Use the data in the table to suggest why the farmer decided to use only 15kg.
[3]
:
\.
The phosphorus was added to the field as superphosphate fertiliser. This contains
P0j
Ca(H
.
phosphorus as calcium dihydrogenphosphate (V), 2
Calculate the relative molecular mass, M,, of calcium dihydrogenphosphate (V).
(I)
(ii)
[3]
6
4A
name
formula
code
sodium chloride
NaCl
1117
2r
FeB
26, 35(2)
aluminium oxide
3
0
2
A1
13(2). 8(3)
name
.
formula
.
code
KBr
29, 6, 8(3)
sulphur dioxide
16]
4B
(a)
key p
proton
(i)
(ii)
,x =
electron
[2]
(b)
IQ\
Y*4f
Qt
(3
7
(1
(c)
4 In the
H
2
Ammonia and carbon dioxide react to form water and a solid, urea, CON
3 of carbqtl dioxide at r.t.p. are converted to urea
reaction, 72dm
(I)
Write the equation, including the state symbols, for the tormation of urea
{ii)
[5]
5
(a)
alkane
alkene
amide
hydrocarbon
polymer
From this list, choose two terms which can be applied to each of the compounds
given below.
(I)
.L:r.i.
methane
and
(ii)
hexene
v.
and
(hi) poly(ethene)
and
.*:
p.dsptmt..r
(lv)nylon
18]
and
(b)
One of the general characteristics of homologous series is that all the members can
be represented by a general ormula.
(I)
9
What is the general formula of the alkene series
(ii)
(:...
.....:
...
[2]
1 hour
INSTRUCTIONS TO CANDIDATES
Candidates MUST answer THREE questions on this paper. They must choose ONE from
Section 1, ONE from Section 2, and ONE from Section 3.
All working MUST be shown for calculations.
Section I
Answer one (1) question from this section.
Instructions for preparing hydrated crystals of magnesium sulphate are given, below.
Add one spatula full ot magnesium carbonate to 50cm
3 of dilute sulphuric acid. When it
has reacted, add further amounts until no more will dissolve. Then
ermixture.
Evaporate the filtrate to about half its volume. Allow the filtrate to cool. Filter off the crystals.
Dry them on filter paper Do not heat the crystals.
(a)
(b)
Because it has a larger surface area, powdered magnesium carbonate reacts more
rapidly than lumps of magnesium carbonate.
[5]
Explain why the larger surface area leads to a greater rate of reaction.
[1]
(c)
(2]
(d)
Name three substances, other than magnesium carbonate, which react with dilute
sulphuric acid to form magnesium sulphate.
(21
(a)
The diagram represents the electrolysis of aqueous copper (II) sulphate using copper
electrodes.
copper
copper
copper(ll) sulphate
(i)
(ii)
(iii)
Explain why solid copper (II) suiphate does not conauci an electric current
is
(b) Electrolysis is used for the manufacture of aluminium, chlorine and sodium hydroxide.
For one of these manufacturing processes, give
(i) the electrolyte used.
(ii) the materials used for the electrodes.
151
Section II
Answer one (1) question from this section.
3(a) For each of the following reactions.
(I) state the observations you would expect to make,
(ii) name the product(s) of the reaction(s).
(iii) explain the changes which take place.
1. Aqueous sodium hydroxide is added to aqueous iron (II) sulphate and the mixture
is allowed to stand.
2. Chlorine is bubbled into aqueous potassium iodide. The solid product is collected
[6]
and then heated.
(b) Hydrogen can be manufactured using the reversible reaction between methane and
steam. The formation of hydrogen is endothermic.
(i) Write the equation for this reaction.
(ii) Explain why this reaction is best carried out at a high temperature but at a low
pressure.
[4]
(c) Study the following reaction scheme.
Colourless Gas
+
Calcium
Hydroxide
Solution
White precipitate
C
Yellow solid B
[3J
(b) Give the names or the symbols of two memrs of each of the follow
ing.
(i) the halogens;
(ii)
Section III
Answer ONE question from this section.
5. (a) Describe the composition alone type of cement.
131
quarried limestona
(b) Outline the process of the manufacture of cement from
glass.
(c) Show the structural differences between cement and
[6]
nt.
(d) Describe what occurs when water is added to ceme
[41
[4]
[4]
ystem.
6. (a) Briefly describe how energy flows in a soil ecos
Outline the nitrogen cycle
(b) One of the nutrient cycles in soil is the nitrogen cycle.
[6]
e.
giving illustrations and chemical formulae where applicabl
131
(c) Describe the importance of the use of fertilizers in soil.
nic manure as a fertilizer
(d) Describe how nutrients are released using orga
14]
compared to commercial inorganic fertilizers.
ed after repeated use of
(e) Show, using equations why soil should be treat
[3]
ammonium fertilizers.
1 hour 15 minutes.
INSTRUCTIONS TO CANDIDATES
There are sixty (60) questions in this paper Answer all questions. For each question,
there are four possible answers A, B, C and D. Choose the one you consider correct and
record your choice in soft pencil on the separate answer sheet.
Read the Instructions on the answer sheet very carefully.
INFORMATION FOR CANDIDATES
Each correct answer will score one mark.
answer.
What can be deduced about two gases which have the same molecular mass?
They have equal solubility in water at room temperature.
A
C
They have the same rate of diffusion at room temperature and pressure.
black
blue
brown
green
rect
yellow
Slack ink can be made by mixing green, red and yellow inks.
Brown ink can be made by mixing blue and red inks.
Yellow ink can be used to make brown ink.
Yellow ink may be present in green ink.
in a
In an experiment to find the formula of magnesium oxide, magnesium metal is heated
covered crucible:
magnesium
heat
A
B
C
U
LhemiotueIer-.
mixture
of liquic
heat
C
D
6
protons
neutrons electrons
16
18
18
17
18
18
conductivity
of solid
A
good
good
S
o
poor
poor
conductivity
of mo/ten compound
conductivity
c aqueous so/ut/on
ad
good
toor
coca
) or
The bonding in sulphuric acid can be represented by the structural formula below.
0
HV 0
What is the total number of electrons in the covalent bonds surrounding the sulphur atom?
A
4
*6
CS
0
12
It is now known that carbon has an allotropic torm containing molecules of formula C.
What is the mass of one mole of these molecules?
A
10
11
12
12g
60g
360g
720g
suiphide
formula
MS
90
2
FeS
120
MoS
160
PbS
239
-k
V
N..
04
r
lb.
4
D
Iead{tI) bromide
13
purified ore by
The diagram represents a method for extracting aluminium from its
electrolysis.
waste gases
molten aluminium
14
aluminium
aluminium chloride
aluminium
aluminium oxide
carbon
aluminium chloride
carbon
aluminium oxide
tetrachioromethane
water
15
B
C
The total enerGy of the products is greater than that of the reactants.
liquid Z
iv
A
C
17
i, ii and iv only
The rate of the reaction between a given mass of calcium carbonate and 1 mol/dm
3
hydrochloric acid was studied by collecting the released carbon dioxide in a graduated
syringe. The calcium carbonate completely reacted.
The results are shown in the graph.
lotal volumo
of carton
time/mn
How would the results change if the experiment was repeated using the same mass of
calcium carbonate and the same volume of hydrochloric acid but of twice the concentration?
maximum volume of carbon
dioxide collected
3
90cm
less than 4 mm
3
180cm
less than 4 mm
3
180cm
exactly 4 mm
90cm
more than 4 mm
18
19
Which element burns in air to form an oxide which, when shaken with water, gives a
solution with a p1-I greater than 7?
A
20
carbon
hydrogen
calcium
sulphur
An acid, X, was added to a solution of the nitrate of a metal, Y. A dense white precipitate
was formed.
What are X and Y2
21
acidX
metalY
hydrochloric
calcium
nitric
zinc
sulphuric
aluminium
sulphuric
barium
When aqueous sodium hydroxide is added to a solution, a white precipitate forms which
dissolves when more sodium hydroxide is added
Which ion could be present in the solution?
A
22
23
AP(aq)
Ca
(
2
aq)
Cu
2
(aq)
Na(aq)
A solution was tested with Universal Indicator and with aqueous potassium iodide.
Which results show that the solution contains both lead (II) nitrate and nitric acid?
Universal Indicator
pH 3
yellow precipitate
pH 5
no reaction
pH 7
yellow precipa1e
pH 9
no reaction
Atoms of elements in the same group nave the same total numoer of electrons.
In Group reacnvity decreases wrr increasing proton (atomic) lumber.
In Group VH me melting point of the eJe:ents increases with cro; (atomic) number
24
25
i
3
C
2
ln
3
InC!
The table gives the symbols or formulae of the catalysts used in some industrial processes.
catalyst
substance manufactured
hydrogen (from methane)
Ni
synthetic rubber
3
0
2
A1
3
0
2
Cr
polyesters
3
0
2
Sb
PVC
I
KCI
2
CuC
+
Pt
Cr
Rh
How many different transition metals are included (as elements or in compounds) in the
above catalysts?
6
D
5
C
84
3
A
26
The diagram shows a blast furnace used to extract iron from iron ore.
hot gases
hot at
molten slag
molten iron
Which substance is added with the iron ore and coke at the top of the furnace?
oxygen
0
hn,estone
C
carbon
B
bauxite
A
27
chloride and
When zinc foil is placed in an aqueous solution containing both magnesium
7
cooper (II) sulphate, which element is displaced
magnesium
0
h;drogen
C
copper
B
chlorine
A
Discs of the same size and shape of three different metals were dropped into dilute
hydrochloric acid.
The diagram shows the results.
tube 1
tube 3
lube 2
SRII
iron
copper
magnesium
iron
magnesium
copper
magnesium
copper
iron
magnesium
iron
copper
water
1 only
1 and2only
land3only
1.2and3
air
graduated tube
waler
I:H
123456
123456
Uniolday,
123c56
Iimeddays
brnoJdays
12345t
mo/dsys
31
32
33
35
36
37
P0
3
)
4
(NH
sulphur
(l)
H
0
the water molecule, 2
34
carbon
chlorine
oxygen
calcium carbonate
calcium hydroxide
calcium oxide
calcium sulphate
f:action
use
bitumen
fuel in cars
oetrol (gasoline)
aircraft fuel
paraffin (kerosene)
lubricating fraction
9
V.iu:h compound has an aju;on reaction with chcr2c
HOH
7
C
C
C,H
S
A
to
CH,CQH
38
39
ethanoic acid
O
2
C
3
CH
H
methane
4
CH
propene
5
H
3
C
te combustion ot
The table shows how many moles of products are formed by the comple
four hydrocarbons.
stion?
Which hydrocarbon requires 11 mol of oxygen gas, 2 for this combu
hydrocarbon
carbon dioxide/mo!
water/mol
e
C
H
3
H,
5
C
2
,
2
H
6
C
6
C
1
H
7
40
er?
Which of the following pairs shows the correct monomer for making the polym
polymer
monomer
H
H
H
H
H
H
HCCH
I-I
I-I
I-f
1-f
I-f
3 H
CH
CC
CC----O---C---C-O
C==C
i-f
Cl
I-I
CCCC
HCC-OH
CCCC
Cl
C?
3
3 CH
3 CH
3 OH
CH
CCCC
{
CH
F
3
11
I-f
41
Which pair of the following compounds has the same molecular formula 0
12
H
C
?
6
A
Ethanol and Sucrose
B
Fructose and Glucose
C
Sucrose and Glucose
D
Ethanol and Fructose
42
43
CH.
44
Which is the best sequence for preparing crystals of a soluble salt starting with an acid
and a metal?
A
Excess acid
Excess metal
acid
Excess metal
acid
Excess acid
metal
metal
_.
recrystallize
45.
When the gas carbon dioxide is passed through an aqueous solution of W, a white
precipitate X is formed. This precipitate dissolves when more carbon dioxide is bubbled
through forming a colourless solution of Y. The formulae of these compounds could be
3
CaCO
x
i002
2
Ca(OH)
V
3
Ca00
GaO
2
Ca(OH)
2
)
3
Ca(HCO
3
CaCO
2
Ca(OH)
3
cabo
2
Ga(HGO)
2
)
3
Ca(HCO
12
46
47
49
2
Y
3
X
2
H
2e
2e
2
H
2
H
3
Y
2
X
3
XY
molten aluminium
copper metal
4
XY
An oxide of sulphur contains 50% by mass of sulphur. What is the empirical formula of
this oxide?
SO
A
B
503
C
D
504
602
=
32, 0
16]
Which of the following elements requires the smallest number of Faradays for 1 mole of
atoms to be liberated during electolysis?
calcium
magnesium
sodium
aluminium
An isotope of element Y has 17 protons and 18 neutrons in its nucleus. Which is the
correct symbol for the ion of Y?
Y
18
17
0
17
17
1/
Which is the correct order in decreasing activity of the metals in the reactivity series
9
A
calcium, copper, zinc
B copper, zinc, calcium
C
53
graphite
52
2e
A
51
fr
Which one of the following conducts electricity entirely by the movement of ions?
[R.A.M. S
50
2H
2
H
_..
The atomic number of an element X is 6, the atomic number of an element Y is 17. The
probable formula of a compound formed between X and 1 is:
A
48
2K-
13
54
Rubidium is in group I of the periodic table. The formula for rubidium sulphate is:
(S0
2
Rb
3
)
4
0
SO
2
Rb
4
C
2
)
4
Rb(S0
B
4
RbSO
A
55
H
I
HCCCH
HCCH
H
0
H
HCC=
HCH
56
57
aid photosynthesis
Which of the following occurs in the production of sulphuric acid by the contact process?
A
58
produce sugars
Which one of the following structures represents the linkage between units in both
proteins and nylon?
H
H
B
H
0
A
I
I
i
II
CC
C--C
I
I
I
H
H
H
C
0
Ii
C
H
I
N
Dro
II
LC
14
_
59
2
H
X2HCI
no reaction
b
XC
2
H
I
calcium
copper
:H
15
TIME:
1 hour 30 minutes.
INSTRUCTIONS TO CANDIDATES
s carefully.
Read the following direction
1.
h question.
ding to the questions. For eac
pon
res
en
wh
t
kle
boo
s
thi
use
You must
vided.
write your answer in the space pro
2.
3.
ns.
booklet. Answer all five questio
s
thi
in
ns
stio
que
five
are
ere
Th
1.
(ii)
The contents were warmed in a water bath until the solid dissolved.
(i)
The thermometer was placed in the boiling tube and after a few minute
s. the
boiling tube was removed from the bath and allowed to cool.
The
temperature at which crystals first appeared was recorded.
(iv)
(v)
portions of water to
Volume of
Number
3
Waterl
crn
10
Teniperaturef
79
-_
_
16
Calculation of
Solubility
Solubility per
GmsIlOO
3 water
100cm
3 H
cm
0
2
15x100
10
56
-
18
51
20
48
22
45
00cm of water
nitrate in grams per 1 3
Plot a graph of solubHity of potassium
against temperature in C.
bility of potassium nitrate in grams per
(ii) Use your graph to determine the solu
100cm at 65C.
3
(a) (i)
Solublilty:
eriment.
(Hi) List two sources of error in this exp
1.
2.
the following reaction takes place:
(b) When potassium nitrate is heated,
KNO +02
KNO * 2
3
(i)
(ii)
CONCLUSIONS
OBSERVATIONS
The gas
ammonia
To an aqueous solution of
Z sodium hydroxide was
mixture
and
added,
warmed
To a second portion of an
aqueous solution of Z,
dilute nitric acid was added
(allowed by sliver nitrate
A white
formed
precipitate
was
evolved
was
4
S
2
H
a
O.i
q)
Na QH
+
3
NaN
O
2Na OH() +
1
0
2
H
A H = -57KJ
7
N
S
2
+
1
O
2H
O
a A H =-114KJ
(i)
(ii)
4(aq)
3(aq)
-1 -ti 44-t
rrt
..:
r -r
.4.
.4
-I-
.4-.
.4
II,
4.
.1
.-i I.
.4.-
I
I
1
.1.
4-4..
4.
4-
4-
.4,
4
.4
.444
I,
*
j_.
1
1-
4.
,-:i-.:I.
44-
f.r 1,j
4-
.4
..
.4.
.4
4!
[4
h -ri: 4;.;;
t
-tr
I,J_L
4 i
ff
t
m
4.-.-t
.4.
4.?
.4
-a
4.
..
-i
.:
Hit
-:
d.t..-4--
TI
44 +4_
JI
4.
-14--- -t
-1 4- 1.. .4 .4 .4+4..
1
-.4.4..
+
1-
.4.
I.
44
it,
4 4
444
...
--
11
tl I
4,*
.4
.4..
H-ht
;+.i_4
-.
-,
.4- 4-
.4.4
.4,.
-fH
:tL:Lt:
4. .4-.
4..
Li:
4,,
.4--h tit
.t
4
k-
4.4.
4.
44
:t:tZtt
.4
II
.4.4_a.
.pr
IL
_.4.4.
_
qfr cLr
i4
ui4tLL____
J.Lt tLi
tt
tr n
.4-,
441*,
2A
carbon monoxide
copper(il) oxide
magnesium oxide
nitrogen dioxide
zinc oxide
Each oxide can be used once, more than once, or not at all.
Name an oxide from the list above which
is acidic,
(I)
(1]
is amphoteric,
(ii)
[11
contains an element in the +3 oxidation state,
(iH)
ill
(iv)
(e)
[1]
Ill
28 The diagram represents the structure of a metal.
(a)
0000
0i00
4 4N-ct) r 0
[1]
QUfr at)
Give two other physical properties of metals.
1
(b)
2
(c)
[2]
JA
(a)
Complete the loliowing table which gves information about tvio Cins.
of
protons
numLer
ion
F
number of
neutrons
!;.;.;oer of
electrons
nucleon
number
10
24
10
2
Mg
(b)
F
.
2
(Mg
in magnesium fluoride )
Draw adot and cross diagram to show the bonding
Include all the electrons in your diagram.
[2]
38 The following question is concerned with ionic equations.
nic equation. The first one has been
(a) Rewrite each of the following equations as anio
done as an example.
2
MgSO + H
HS0 - 4
Mg + 4
equation
2
2 +H
Mg
ionic equation Mg + 21t
.
(I)
equation
Ca
2HCI
2I
CaC
equation
2
H
ionic equation
(II)
2NaBr
2NaCI
Cl
2
Br
[2]
ionic equation
(b)
4A
2Fe
2Ct
ced.
Explain, in terms of electrons, why chlorine has been redu
Name the salt formed in the reaction.
Za:.
[2]
ared by precipitation.
Barium sulphate is a white insoluble salt. It can be prep
precipitate of barium sulphate.
(a) Name two solutions which on mixing will produce a
[2]
(b)
(b)
[31
Q are called
and 8
7
4C
potassium bromide
silica
(b)
(c)
Which substance conducts electricity when molten but not when solid?
[3]
5A
percentage produced
(supply)
percentage required
(demand)
3
14
9
15
10
49
4
25
3
7
22
39
(a)
S/
Define hydrocarbon
a
.:_..:
(b)
[1]
(I)
For which fraction does the demand exceed the supply by the greatest amount?
(ii)
For which fraction does the supply exceed the demand by the greatest amount?
[2]
(c)
Cracking involves the breakdown of large hydrocarbon molecules into smaller ones.
(i) Give the conditions needed for cracking hydrocarbons.
(ii)
Explain how cracking can match the demand for a fraction with its supply.
(iii) A hydrocarbon, F
12 is cracked to give only two products One of the products
C
is butane
What is the molecular formula of the other product?
[4]
8
5B
(c)
The temperature of the mixture initially begins to rise as the potassium hydroxide is
added to the sulphuric acid. It then reaches a maximum and eventually falls as more
potassium hydroxide is added.
The graph shows how the temperature of the mixture varies with the volume of
aqueous potassium hydroxide added.
(I)
.11
24
(ii)
72
20
--
tTTtzJ
r7#.v
iz
(ill) Explain why the temperature taIls ii more than this volume ot aqueous potassiul
hydroxide is added.
[4]
1 hour
INSTRUCTIONS TO CANDIDATES
Section I
section.
Answer one (1) question from this
on dioxide.
ted they decompose to produce carb
hea
are
als
met
e
som
of
tes
ona
When carb
on into the rate of
show (he results of an investigati
Study the graphs below which
te was heated to
h experiment 0.010 mol of carbona
eac
In
a
ate
bon
of
car
n
itio
pos
om
dec
ry minute.
dioxide produced was measured eve
on
carb
of
e
um
vol
The
e.
atur
per
tem
the same
i_ti Iii
iUlilURlflhitlflInui
100
I,
801
ELI
C,
t
CuCO,
40
C,
20-
,r
0
0
itilili
11111 j_i_l
I
ri i rr,r,rr,rH4f1-44f4
lime! minutes
.
experiment the rate was very slow
Suggest why, at the start of each
the fastest rate?
(ii) Which carbonate decomposed at
onates
phs that the decomposition of the carb
(iii) How could you tell from the gra
was not complete?
used rather
of moles of carbonate had to be
(iv) Explain why the same number
[5]
a fair comparison
than the same mass of carbonate to get
121
calcium carbonate.
of
s
use
ial
ustr
ind
two
te
Sta
(b)
n products of
n they are heated. The decompositio
(c) Nitrates also decompose whe
gas nitrogen
wn
MgO, a bro
Mg(N0 are magnesium oxide.
.
2
)
magnesium nitrate, 3
a glowing splint.
, and a colourless gas which relit
2
dioxide, NO
Name the colourless gas.
(i)
[3]
n
ng slate symbols for the decompositio
(Ii) Construct the equation includi
(a)
(I)
chloride
by the electrolysis ot aQueous sodium
Sodium hydroxide is manufactured
duced
Hydroger and chlorine are also pro
e sodium hydro*:dc
in one of the processes j: mak
The diagram shows the cell useo
c1onne
hydtoii
-j
aqueous
hydra ide
positive
electrode
(anode)
pofous
inontnzto
negative
electrode
(cathode)
[ij
ne
[11
(c) State a use for sodium hydroxide.
[1]
(d) 1 mole of sodium hydroxide, NaCH, and
0.5 mole of chlorine, CL
. are produced
2
from 1 mole of sodium chloride, NaCI.
(i) Calculate the mass of sodium hydr
oxide that can be produced from 117g of
sodium chloride.
(H) Calculate the volume of chlorine,
at room temperature and pressure, that
can be produced at the same time.
[4J
(e) Aqueous sodium hydroxide can also
be electrolysed in the laboratory using inert
electrodes.
(I) State the formulae of the ions presen
t in aqueous sodium hydroxide.
(H) Predict the product fan-ned at the ano
de.
(Hi) Predict the product formed at the cath
ode.
[31
Section II
Answer one (1) question from this sec
tion.
Natural gas is mainly methane, CH
. It is often contaminated with smal
4
l amounts of
hydrogen sulphide, H
5. Normally, the hydrogen suiphide
2
is removed before the
methane is used as a fuel.
(a) (i) Construct the equation to show the
combustion of hydrogen sulphide to form
sulphur dioxide and water.
(ii) A sample of methane was found to be
contaminated with I .70g of hydrogen
suiphide.
Calculate the mass of sulphur dioxide
produced when the contaminated
methane was burnt.
(iH) Suggest why it is important that hyd
rogen sulphide is removed from the
methane before it is used as a fuel.
[5}
3
t.
in the presence of ultra-violet ligh
(b) Chlorine reacts with methane
reaction.
of the substances formed in this
two
of
ula
form
or
e
nam
the
te
Sta
(i)
place?
(ii) What type of reaction has taken
t.
t with methane in uftra-violet ligh
(iii) Gaseous bromine will also reac
chlorine?
Is this reaction faster or slower with
[4]
Explain your answer.
ultra-violet
h chlorine in the presence of
wit
t
reac
to
e
pan
pro
ect
exp
you
(c) Would
light?
[1)
Explain your answer.
tion between
er process by the reversible reac
(a) Ammonia is made in the Hab
nitrogen and hydrogen.
liquid air for use in this process?
(i) How is nitrogen obtained from
er process.
and the conditions used in the Hab
lyst
cata
the
of
e
nam
the
te
Sta
(H)
[4]
3 of water, the temperature
ate dissolves in 50 cm
(b) When 4 gm of ammonium nitr
falls by 6C.
endothermic?
(I) Is the reaction exothermic or
for the water?
(ii) How much energy is absorbed
3 of water = 1 gm
Assume that 1 cm
Specific Heat capacity 4.2 J/gC.
for the reaction:
(iH) Draw an energy level diagram
)
H
O
aq
N
4
(
H + Water = 3
NO
4
)
5
(
3
(RMM of
moles of ammonium nitrate used
(iv) Calculate the number of
ammonium nitrate 80.
[4]
per mole of ammonium nitrate?
(v) What is the heat of solution
cture of an acid.
(c) One use of ethanol is the manufa
al formula.
Name the acid and draw its structur
[2J
Section III
Answer ONE question from this sec
tion.
& (a) What are fibres?
[2]
(b) List the three sources from whi
ch fibres can be obtained and give two
examples
of each type of fibre.
161
(e) Draw partial structures of the
three types of fibres in part (b)
showing the
chemical bonds responsible for ma
intaining the structure of each type
of fibre. [6]
(d) Briefly describe how synthetic fibr
es are produced from a polymer
solution or a
polymer melt.
[3]
(e) Using an example, describe
the benefits of the fibric produc
ed when a natural
fibre is blended with a synthetic
fibre.
[3]
TIME:
1 hour 15 minutes
INSTRUCTIONS TO CANDIDATES
There are sixty (60) questions in this paper. Answer all questions. For each question,
there are four possible answers A, B, C and D. Choose the one you consider correct and
record your choice in soft pencil on the separate answer sheet.
Read the instructions on the answer sheet very carefully.
B
C
The diagram shows the colours of two indicators, methyl orange and metyl red, at different
pH values.
pH
colour of
methyl orange
red
5
yellow
colour of
methyl red
yellow
red
pH
WandX
XandY
YandZ
Zonly
The reaction between aqueous lead (II) nitrate and aqueous potassium iodide can be
represented by the following equation.
aq)
Pb(N0
(
2
)
3
colourless
2Kl(aq)
s)
Pb1
(
2
yellow
colourless
chromatography
cryslaflisation
distil;ation
filtraUon
2KNO,(aq)
colourless
The diagram shows apparatus used to separate hexane (boiling point, lot) and heptane
(boiling point, 98t).
therrnomeler
/ water out
I
water in
distillate
heat
Which graph would be obtained if the temperature at point T was plotted against the total
volume of distillate collected?
ioo
tolal volume
of distillate
lo(aI volume
of distillate
of distillate
total volume
of distillate
total volume
16
17
18
19
Element V has the electronic structure 2, 8, 2. Element 2 has the electronic structure
2,8,6.
The compound formed between Yand 2 will probably
A
B
C
02
ice
72Mg
0
2
2H
10
graphite
36.Og
density
A solid deposit of element R is formed at the cathode when an aqueous solution containing
ions of R is electrolysed.
Which statement about element R must be correct?
A
A forms negative ions.
B
11
o
12
Which statement is correct for the electrolysis of concentrated aqueous sodium chloride
using inert electrodes?
A
B
Sodium
is
13
14
The thermometers show the temperature at which the reaction started in each beaker.
In which beaker will the reaction be fastest?
{2000L
Ig marble powder
In 200cm
3 moVdm F-IC!
15
ig marble chips
in 200cm
3
2 mol/dm Ho!
ig marble chips
in 200cm
3
3 HO!
2 mol/dm
16
lg marble powder
in 200cm
1 mot/dm HC1
g2H
012
2Fe
Cct 42H
H
2
-C0
0
2r
Br
2Fe+2Ct
2Br+
12
17
18
19
What is the ionic equation for the neutralisation of aqueous sodium hydroxide with dilute
nitric acid?
A
H+OH
Nw
3 3
NwHNO
NaNO
i
-H
NaQH+H
NO;
-,
NaNO
0
2
Nw+H
Which element forms an oxide that reacts with water to give an acidic splution?
A
aluminium
sodium
sulphur
zinc
(ii)
21
2
Ca
IC
2
Zn
Which element shows variable valency, can act as a catalyst and forms coloured
compounds?
A
22
A&
carbon
chlorine
iron
sulphur
Which statement correctly describes the changes in the elements from lett to right across
a period of the Periodic Table?
A
23
Lithium is the first element and rubidium is the fourth element in Group I of the Periodic
Table.
Which statement is correct?
B
24
25
calcium
copper
silver
copper
zinc
sodium
sodium
copper
calcium
zinc
copper
calcium
is insoluble in water;
26
calcium hydroxide
sodium carbonate
zinc oxide
27
28
29
Which pair of gases explodes when ignited to form a product which, when mixed with
water, produces a solution of pH 7?
A
Which substance present in car exhaust fumes, does not pollute the atmosphere?
A
carbon monoxide
lead compounds
nitrogen
nitrogen oxides
solid
hydroxide
moist universal
indicator paper
heat
When the test-tube was heated, the indicator paper turned blue.
What could be solid Z?
30
aluminium oxide
ammonium sulphate
calcium hydroxide
It decreases the pH to 1.
It decreases the pH to 3.
It increases the pH to 7.
It increases the pH to 9.
31
7%
other uses
10%
making other
organic
alkanes
11%
making
compounds
20%
12%
1210
making hydrogen
chloride and
domestic bleaches
34%
54%
61%
/
33
The flow diagram shows how precipitate Y can be obtained from solid X.
colourles
so Id
h0at
solution
73%
34
3
CaCO
3
CaCO
3
CaCO
2
Ca(OH)
2
Ca(OH)
2
Ca(OH)
2
Ca(OH)
3
CaCO
35
2
CH
2
C
1
CH
H
O
O,
21
CH
CH,OH
R
H
i-f
HC COC H
I
I
I
I
HCC-CO-H
H
I
I
36
37
PandOonly
Pandflonly
OandRonly
P,QandR
nylon
protein
nylon
Terylene
sugars
protein
Terylene poly(ethene)
10
I
I
HCC CH
OH
Linkage?
38
stage 1
stage 2
cracking
oxidation
fermentation
distillation
hydrolysis
fermentation
C)
polymerization
hydrolysis
The diagram shows how useful products can be obtained by cracking long chain
hydrocarbons.
substance X
used as a
rocket fuel
long chain
hydrocarbons
_catalyst__J
other products
39
40
ethanol
propene
hydrogen
ethene
methane
ethane
steam
ethene
substance V
used to make
plastics
a polymer
a protein
an unsaturated hydrocarbon
H
HC H
substitution
H_C
H
HC
I-I
I-I
H:CcCc
11
41
Freezing
with ice
Pure water
aluminium
silicon
chlorine
Select from the list above, an element which fits the following descriptions:
42
43
44
45
0
2
0H
O
4
CH
12
0
3
H
2
C
0
4
H
2
C
46
The reaction between magnesium and hydrochloric acid can best be represented by:
Mg (aq)
Mg(s) + HCI(ao)
A
..
47
2H(aq)
Mg(S)
) 2H(aq)
5
Mg(
)
5
Mg(
cr (aq)
Mg
(Sq)
t
Mg
HCI(aq)
CF(aq)
Hz(g)
Mg Cl2(aqj
)
H
(
2
g)
(H
2
48
51
strongly acidic
slightly alkaline
strongly alkaline
with
When a nail is placed in the solution of a metal sulphate, the nail becomes coated
be:
could
ted
deposi
metal
the metal and iron ions are produced in solution The
sodium
ID
magnesium
C
B
copper
calcium
A
Which one of the following involves oxidation?
* Mg(s)
B
2 + 2e
Mg
A
C
52
50
list is
All three metals in one of these lists displace hydrogen from dilute acids. Which
correct?
silver, magnesium, aluminium
B
copper, aluminium, iron
A
C
49
Br,+2e
s-2Br
211
)
9
(
2
H
2&
2Br-2e
Br,
Which one of the following is MOST likely to form ions with charges of +2 and +3?
Chlorine
ID
Iron
C
Carbon
B
Copper
A
13
53
ii
iii
iv
A
54
The following table gives the number of protons, neutrons and electrons in particles W,X,Y,
w
protons
17
17
20
20
neutrons
20
18
20
21
electrons
17
18
18
20
Which one of the following pairs of particles combine with each other to give and ionic
solid?
A
55
56
WX
XV
WZ
XZ
+5
-i-S
14
57
CH
II
Hm
rH
I-I
IC
I
LH
L[Jn
C
58
Ljn
U
V-c
3
Cl-i
C5H5n
If ethanol is dehydrated, what type of reaction will occur when the product formed reacts
with hydrogen in the presence of a nickel catalyst?
A
59
CH
Addition
oxidation
substitution
neutralization
60
Below is a list of polymers. Which pair consists of similar type linkages within their
structures?
A
iS
TIME:
1 hour 30 minutes.
INSTRUCTIONS TO CANDIDATES
1.
2.
3.
There are five questions in this booklet. Answer all five questions.
(a)
The table below shows a table of results for the formation of hydrogen in the reaction
of calcium with excess water at 20C.
Time (s)
Volumeof
3
hydrogen cm
0
0
10
6
20
14
I. I. t
30
26
40
41
5060
58
73
70
89
t t t I.
for
4 11790
110
137
120
140
t t I. t
of
calcium
and
130
141
water
Write
(H)
(Hi)
Sketch on it the lines you would expect if the water was kept at (a) 3000 (b)
10C.
(iv)
Why is the experiment slower at (a) the beginning, and (b) the end of the
experiment?
equation
reaction
100
131
(i)
an
the
80
102
H
- w
S
dsv.)v%
ts
Draw the apparatus you would use to carry out the experiment.
4
(v)
:y;;:,
._
h-----
I)
2\* ci
I
.r;
t
_.zt
.
(b)
The diagram shows an apparatus used to prepare dry ammonia in the laboratory
19JWL
Fig 1
2
Examine Figure 1 and then answer the following questions below in the spaces
provided.
(I)
Why does the gas jar have its open end downwards?
and
,Oo
2A
For each of the following reactions, describe what you would see and name the reaction
product which is responsible tar the observation.
(a)
(b)
nanieof product
(c)
ak
,.-
nameof product
I
(d)
3A
(a)
The following terms are used for elements in the PeriodicTable. Name two examples
of each type of element.
alkali metals
(b)
[8]
and
..:
halogens
and
noblegases
and
transition elements
and
4.z
[4]
The element hydrogen has three isotopes. hydrogen, H. deuteriurn 0 and tritium, T.
The nucleon (mass) numbers of the isotopes are one, two and three respectively.
(I)
(II)
Complete the table to show the numbers of particles in the three nuclei.
neutrons
protons
nucleon (mass) number
name
hydrogen
deuterium
tritium
0 is 100.0C. Suggest a
2
0 is 1O1.6t but that of H
2
The bailing point of D
reason for this difference.
[1
(c)
4A (a)
D
0
Calcium reacts with cold water. Construct an equation for the reaction between 2
and calcium.
[2]
equation
Heptane is an alkane with seven carbon atoms per molecule.
It is a colourless liquid with a boiling point of loot.
(I)
(ii)
Suggest two tests you would use to decide whether a colourless liquid was
heptane or water.
Predict the results of the tests for both heptane and water.
test 1
result with heptane
result with water
test2
result with heptane
15]
H0
H-CCCCccH
I
$
H
H
H
0 H
H
5
-n
(i)
(ii)
..
Suggest why the term carbohydrate is used for this type of compound.
4...
p
---
name
4B
13]
and
name
relative molecular
mass, M
b.p.
PC
heat evolved on
burning one mole
Ad
methanol
32
65
715
78
1371
ethanol
propanol
60
2010
74
117
2673
[3]
(b)
(c)
[2]
SA
(ii)
[51
test
equation
, was weighed. The results were as follows.
2
The Iead(ll) iodide, Pb1
mass of ore sample = 6.60g
mass of lead (II) iodide = 1.47g
(c)
(I)
.
2
Calculate the relative molecular mass, Mr of lead (II) iodide, Pbl
(ii)
1]
TIME:
1 hour
INSTRUCTIONS TO CANDIDATES
Candidates MUST answer THREE questions on this paper. They must choose ONE from
Section 1, ONE from Section 2, and ONE from Section 3.
All working MUST be shown for calculations.
Section I
Answer one (1) question from this section.
(a)
(b)
(ii)
Explain why the compound named in (I) will not be the only fertilizer used by a
farmer.
12)
(c)
(i)
Write the equation for the reaction between the surface layer of rust and dilute
sulphuric acid.
(ii)
Explain why the steel sheets must only be left in contact with the sulphuric acid
for a short period.
[2J
One stage in the manufacture of sulphuric acid is the oxidation of sulphur dioxide to
sulphur trioxide.
For this stage
(d)
(a)
(I)
(ii)
(iii)
[3]
(ii)
[3)
(b)
(I)
Give me names and formulae of all the ions present in this solution. Explain
what happens to each of these ions as it arrives at an electrode. Give ionic
equations for the reactions at the electrodes where appropriate.
(II)
9
Why would steel not be a suitable material for the anode
[61
Hydrogen chloride is a gas. The molecule contains a single covalent bond. When
hydrogen chloride is mixed with ammonia, a white solid is formed.
(I)
(II)
Construct a dot and cross diagram to show the outer shell electrons in a
molecule of hydrogen chloride.
Give the equation, including the state symbols, for the reaction between hydrogen
[4]
chloride and ammonia.
Section II
Answer one (1) question from this section,
The table gives some information about three metals.
(Ill)
(a)
(I)
metal
order of
reactivity
zinc
colourless
4
ZnSO
nickel
green
4
NiSO
copper
blue
4
0uSD
Given samples of the three metals and of their aqueous sulphates, describe the
experiments by which you could confirm the order of reactivity of these metals.
In your account, clearly state the observations you would look for and explain
how the observations lead to the reactivity order.
(ii)
Give an equation to show the effect of heat on nickel carbonate. Suggest why
nickel carbonate decomposes at a lower temperature than zinc carbonate [8]
(b)
Name an alloy made from copper and zinc. Explain why a bar of the alloy is harder
[2]
and stronger than a bar of copper.
(a)
(ii)
Give the equation for this reaction between methane and steam
(iii) Calculate the maximum volume of hydrogen! measured at r.t.p, which can be
obtained from 16g of methane.
[3]
(b)
(ii)
Dii
ae
[2]
(c)
I
..._.___C
I
H
I
C
I
CL
CL
I
C
I
(I)
Name this plastic and draw the structure & the monomer from which it is
made.
(ii)
(d) If this plastic is burned, a thick, black smoke and a very acidic gas are produced.
(i)
(ii)
[2]
Section Ill
Answer ONE question from this section.
5.
(a) List the three components of paints and give the uses of each component.
[6]
(b) Give the formula of two pigments used in paints and state the colour imparted by
each pigment.
[41
(c) Describe the difference between the components of an oil-based paint and a
water-based paint.
[2]
(d) Describe the two different processes which occur when oil-based and waterbased paints are applied to a surface.
[6]
6.
(e) What are the differences in the uses of oil-based and water-based paints?
[2]
(a) Describe, giving examples, how pests are controlled by biological means.
[41
(b) Describe, giving examples, how pests are controlled by chemical means.
[4]
(c) Discuss the advantages and disadvantages of controlling pests by biological vs.
chemical means.
[6]
(d) Descnbe the difference between a herbicide and a pesticide.
[2]
(e) Show how the use of one herbicide can be advantageous to a farmer while the
use of another herbicide may be disadvantageous to the farmer.
[4]
TIME:
1 hour 15 minutes.
INSTRUCTIONS TO CANDIDATES
There are sixty (60) questions in this paper Answer all questions. For each question,
there are four possible answers A, B, C and D. Choose the one you consider correct and
record your choice in soft pencil on the separate answer sheet.
Which diagram shows the arrangement of atoms inside a balloon containing helium?
D
C
B
A
ILI
time
time
time
N
bme
How can the rate of evaporation of water from an open beaker be decreased?
A by blowing air over the beaker
B
10C?
The number of outer shell electrons for the atoms of the first 12 elements in the
Periodic Table was plotted against the proton (atomic) number of the element.
Which graph was obtained?
0
B
A
-r
I,
4
I
4,
*4 II 4 U
I:
II I I
::K::
I :
1141111
2i4111
DflI4X4
*W141)
,KKtQ
methane
ii
74447 I
4141111
p4o1 r.tTt.i
water
neutrons
electrons
10
10
10
10
10
10
18
The table gives information about the ability of four substances to conduct electricity.
substance
HCL
NaCL.
Pb
HCL
NaCL
Pb
HCL
Pb
NaCI
NaCL
HCI.
Pb
10
(g)
2
N
(g)
2
3H
12
3
25cm
3
75cm
3
100cm
3
150cm
ethanol, 2
CH
3
CH
O
glucose, 2
H,
C
6
0
methanal, ECHO
methyl methanoate, 3
CH
2
1-ICO
(g)
2
0
0(g)
2
2H
13
Two different hydrocarbons each contain the same percentage by mass of hydrogen.
Ii follows that they have the same
14
empirical formula
number of isomers.
structural formula.
electrodes
copper
carbon
carbon
platinum
15
Which element requires the smallest number of electrons for one mole of atoms to be
liberated during electrolysis?
A
16
17
18
aluminium
calcium
copper
sodium
What are the products when concentrated aqueous lithium chloride is etectrolysed?
at the anode
(positive)
at the cathode
(negative)
chlorine
hydrogen
chlorine
lithium
oxygen
hydrogen
oxygen
lithium
tin.
tim.
D
temperature
temperature
t.nporatur.
IanleFatLSe
19
time
In which reaction is the pressure least likely to affect the rate of reaction?
A
C(s)
(g)
2
(g) 0
2
2S0
(g)
2
(g) 3H
2
N
NaOH
(g)
2
C0
2C0(g)
(g)
3
2S0
2NH;(g)
HCI(aq)
NaCI(aq)
+ H
0(I)
2
time
20
Dilute hydrochloric acid was reacted with magnesium ribbon and the volume of hydrogen
gas evolved was measured for the first 80s.
hr
total
volume of
N11 L
0
10
20
33
50
40
60
70
80
0,4 cmIs
s
2.5cm
/
3
s
4cm
I
3
s
40cm
/
3
colour at pHI
pH at which
colour changes
colour at pH 12
thymol blue
red
yellow
congo red
blue
red
colourless
10
red
indicator
phenolphthalein
Which colours would be obtained when each indicator was added separately to pure water?
22
23
thymol blue
congo red
phenolphthalein
red
blue
red
yellow
blue
colourless
yellow
blue
ted
yellow
red
colourless
Which of the following reacts with dilute sulphuric acid to give a gas and water as two of
the products?
A
zinc
zinc carbonate
zinc hydroxide
zinc oxide
Which oxide reacts tith an acid to form a saH but does not react with an alkali?
A
aluminium oxide
carbon dioxide
magnesium oxide
zinc oxide
6
24
4
BaSO
25
Which arrangement of electrons is that of a gas normally used to fill light bulbs?
2,8,8
D
2,8,2
2,6
C
2
A
B
26
Using the apparatus shown, chlorine was passed through the tube. After a short time,
coloured substances were seen at P, 0 and R.
potassium bromide
potassium iodide
OR
chlonne
____________
lit
gentle heat
27
azP
atO
at R
green gas
violet vapour
black solid
green gas
red-brown vapour
violet vapour
red-brown vapour
violet vapour
black solid
violet vapour
red-brown vapour
red-brown vapour
28
calcium oxide
sodium oxide
magnesium oxide C
zinc oxide
rod of
metal Z
----5
observation:
metal W
aisplaced
aqueous
saltof
metalW
jJir
metal W
I
metal X
Js1aced
fl
rod of
metalX
aqueous
salt of
metal X
metal V
metal Y
aispiaced
29
30
least reactive
An 80cm
3 sample of air is trapped in a syringe. The air is slowly passed over heated iron in
a tube until there is no further decrease in volume.
iron
Ill 111.11 blPIIIjIIIJ
,/lrr_7
3 of air
80cm
heat
When cooled to the original temperature, which volume of gas remains?
3
16cm
0
3
20cm
3
64cm
B
C
3
80cm
A
31
32
water
Which of the following would be true of a solution of chlorine in 9
It is a good oxidizing agent
It has no effect on potassium iodide solution
ii.
It does not form a precipitate with silver nitrate
0 H and iH only
C i and H only
Hi only
B
A. I only
The following scheme shows four stages in the conversion of sulphur to sulphuric acid.
In which stage is a catalyst used?
stage B
stage A
[suipnurj
air
air
concentratec
stage C
stage D
concentrated
suiphunc acj
B
water
sulphuric
acid
LLizJ
33
34
What are different forms of the same element in the same physical state called?
*
35
36
allotropes
isomers
polymers
isotopes
The equation shows a molecule of hexane being spilt into two smaller molecules by heating
to a high temperature.
HHHHH
I
I
I
I
HCC--C----CC---CH
I I I
I I
H H HH
I
I
I
HCCCCH
I
I
I
I
substanceX
B
H
HCCH
H
37
H
C
/\
C
H
H
C=C
H
H-C
H
C=C
I
H
H
H
OH to
5
H
2
When C
OH is oxidised it forms substance Z. This substance reacts with C
5
H
2
produce an ester.
What is substance Z?
A
H
2
HCO
CO
3
CH
H
2
3
CH
C
H
2
H
O
3
CH
C
H
2
H
O
38
u.
RQCG0H
CH
N
2
NCHC
and
H-
H
Which diagram show the structure of the polymer?
It
II
II
11
II
II
II
Ii
l
CCjCH
-C-N
CHcN
2
C--O
II
II
II
IL
OH
HO
II
II
II
II
cO--cC---OCC-C
2
NH
39
2
NH
A
/HH\
7HH\
/HH
c-c
\\)fl
40
\HCH,Jn
\HC,I-s/fl
7HH
bc-c
\HG.%fl
addition
condensation
10
fermentation
hydrolysis
The following are the electronic structures of four elements in the Periodic Table. Which one
represents a non-metal?
41
2.1
2,8,2
2,8,7
2,8,3
42 Which one of the following represents the ions in aqueous copper (II) sulphate?
A
Cue; S0
; H; OR
2
4
Cu; S0
; H; OF-f
2
4
2
4
CLC;S0
Q2-
Cut; S0
; H;
2
4
H;
Q2
43 Which one of the following displaces ion from its aqueous slution?
A
lead
copper
silver
zinc
2W+2e
+2e
2
1
b
0
2
H
S
2
2e
2r
Mg+2e
Mg
45 Which type of particle is responsible for the movement of electricity through metals?
A cations
C protons
B anions
0 electrons
46 Which of the following are true of ionic compounds?
i
ii
iv
i and ii only
iii
47
ii and iv only
48
Groupl
Groupll
GrouplIl
GrouplV
In which one of the following formulae does sulphur show an oxidation state of +4?
I.
F-fSO
ii.
3
NaSO
iii.
2
SO
iv.
i and ii only
i and iv only
calcium hydroxide
litmus solution
aqueous bromine
11
4
S
2
Na
O
ii and iv only
50
51
A concentrated solution of sodium chloride is electrolyzed using inert electrodes. The gas collected at
the anode:
A
13
Which one of the following is formed when ethanol is oxidized using acidified potassium dichromate?
A
52
54
55
COOH
5
H
2
C
COOH
3
CH
COOK
3
CH
Propene reacts with hydrogen in the presence of phosporic acid as a catalyst to form:
A
53
ONa
5
H
2
C
8
H
3
C
COOH
3
CH
OH
7
H
3
C
8
CH
Which of the following substances reduce iron (Ill) oxide to iron in the blast furnace?
A
carbon dioxide
carbon monoxide
coke
limestone
A sample of ammonium sulphate was warmed gently with aqueous sodium hydroxide. The gas
produced:
A
56
57
12
neutralization
58
A certain quantity of electricity liberated 4,Og of calcium from a fused calcium salt. What mass of
sodium would be liberated from a sodium salt by the same quantity of electricity?
[R.A.M. Ca
A
59
60
2.3g
40, Na
23]
1.159
11.59
23g
Which of the following pairs does NOT consist of two compounds of the same homologous series?
A
Metal A reacts more readily with water than metal B. It would be expected that:
A
13
TIME:
1 hour 30 minutes
INSTRUCTIONS TO CANDIDATES
1.
You must use this booklet when responding to the questions. For each question write
your answer in the space provided.
2.
3.
There are five questions in this booklet. Answer all five questions.
1.
A spirit lamp was weighted empty and then reweighed with some ethanol.
(H)
200cm of water was placed in a soft drink can and the initial steady
3
temperature recorded.
(Ni) The spirit lamp was used to increase the temperature of the water and this
final temperature was recorded.
(iv) The spirit lamp was removed then reweighed after putting out the flame.
Record of Results:
Mass of empty spirit lamp
Mass of spirit lamp + ethanol
Mass of lamp + ethanol after burning
Mass of ethanol burnt
Initial temperature of water
Final temperature of water
Temperature rise (At)
(i)
=
=
=
=
=
=
22.5g
63.OOg
62.20g
31C
51C
CC
Based on the results above, calculate the heat change AH for the
combustion of ethanol. Assume that the heat capacities and densities of the
solutions are about the same as those of water).
1 C
Cspecific heat capacity of water = 4.2Jg
Density of water: lg = 1cm
3
[Enthalpy change AN = mass of solution x 4.2 x At
(N)
[R.AM.: C
12,0
16, H
1]
(IN) Hence, calculate the heat given out when 1 mole of ethanol burns in air
(b)
The insoluble salt lead (II) chloride was prepared by the reaction between lead (II)
ions and chloride ions.
%AA
j&
tia- ctfEy
c4pk4oQai.. coey.
h;:Lkctt
1-
(v)
How could lead chloride have been separated from the mixture?:
(vi)
How could a pure sample of lead (H) chloride have been obtained from the
sample in (V)?:
.
0
Ja
(c)
(I)
(ii)
Write a balanced equation for the reaction between marble chips and
hydrochloric acid:
(Hi)
(iv)
Ca
40. C
12,0
16, H
1, Cl -35.5
2A
This question is concerned with chlorides. Use the following chlorides as the answers.
aluminium chloride
ammonium chloride
copper(ll) chloride
hydrogen chloride
silver chloride
sodium chloride
Each chloride can be used once, more than once, or not at all.
Name a chloride which
(a)
(b)
is prepared by precipitation,
[1]
(c)
Iii
(d)
will react with hot aqueous sodium hydroxide to produce an alkaline gas.
[1]
(e)
2B
Complete the table which shows the names of reagents needed to produce some gases.
reaction
number
reagent 1
reagent 2
gas produced
ethanol
ethene
hydrogen
carbon dioxide
[2}
3A
One of the isotopes of an element M has a proton (atomic) number of 20 and a nucleon
(mass) number of 39.
(a)
[1
(b)
2o
number of protons
number of neutrons
number of electrons
electronic structure
131
(c)
(d)
38
The displayed formulae of three organic compounds are shown below. Name the
homologous series to which each belongs.
H
(a)
H.j
H\
/
0=0
homologous series
1
N-
(b)
HCC----COH
homologous series
(c)
H
homologous series
C
H
3
4A
C C
H
0H
Hydrogen reacts with chlorine to produce hydrogen chloride This reaction is exothermic
During the reaction covalent bonds are broken and new covalent bonds are formed
H
(
2
g)+ C4(g)
(a)
(I)
2HCI(g)
AH
lS4kJ / mel
(ii)
--
formed?
(Ill) Which is the larger of the energy changes taking place in the reaction above,
bond breaking or bond forming?
Explain your answer
[3]
(b)
When 1 mole of chlorine gas reacts the energy change, tH, isi 84kJ.
Calculate the energy change when 1 42g of chlorine reacts completely with hydrogen.
Energy change
(c)
(I)
[3]
(II)
Draw a dot and cross diagram to show the bonding in a molecule of hydrogen
chloride. You need only draw the electrons in the outer shells.
[21
48 Experiments were carried out to compare the effects of four different catalysts on the
decomposition of hydrogen peroxide.
0
g)
0(l)+
2
2H
aq) (
2H
(
0
2
3 of O.5omolldmD aqueous hydrogen
Each time 0.01 mol of catalyst was added to 10cm
peroxide. The volume of oxygen produced was measured at regular time intervals.
The results were used to draw the graphs below
140
:i,...,.
I20
100
WIIIIfl1IID11$ThWMI l t
I IIIMIIH*llllffiIllJ*JL
a
l5
33
(a)
Draw a labelled diagram of the apparatus that could be used tar these experimentsj2]
(b)
(c)
The experiment using iron (Ill) oxide was left until the reaction had stopped.
Predict the final volume of oxygen produced.
cm
(d)
[1]
SA
[2]
In an experiment to determine the mass of iron in steel, a sample of the steel was
reacted
with excess dilute sulphuric acid. The iron in the steel was converted to iron (II)
sulphate.
(a) Write the equation, including state symbols, for the reaction of iron with dilute
sulphuric
acid.
[2]
(b)
The aqueous iron(II) sulphate produced was titrated with aqueous potass
ium
manganate (VII), KMnO
. The ionic equation for the reaction is written below.
4
MnO, (aq)
8H(aq)
5Fe
(
2
aq)
5F&(aq) Mn
(aq) + 4H
2
O(O
2
In the experiment, 0.020 mol of potassium manganate (VII) ions
was used.
(I)
Calculate the number of moles of iron(lt) ions that reacted.
(ii)
(Iii) What is the name given tc the type of chemical change that
converts Fe
(aq)
2
into Fe
(aq)?
3
(Iv) The colour of the aqueous potassium manganate (VII)
change during the
reacnon. Describe the colour change.
from
to
(c)
[4]
P.
5 The atmosphere is a mixture of gases including nitrogen, oxygen, carbon dioxide, water
vapour and the noble gases.
n in clean air?
(a) What are the percentages by volume of oxygen and nitroge
[1]
nitrogen
oxygen
(b)
st how respiration,
The composition of the air does not vary very much. Sugge
of the air fairly constant.
combustion and photosynthesis help to keep the composition
[4j
(c)
source of pollutant
carbon
monoxide
incomplete combustion of
fossil fuels such as petrol
burning fossil fuels such
as coal at a power station
corrosion of buildings
lead compounds
[1
TIME:
1 hour
INSTRUCTIONS TO CANDIDATES
Candidates MUST answer THREE questions on this paper. They must choose ONE from
Section 1, ONE from Section 2, and ONE from Section 3.
All working MUST be shown for calculations.
Section I
Answer one (1) question from this section.
Many millions of drink cans made from aluminium are produced each day. Much research
into the design of these cans has been carried out to minimise the amount of aluminium
used per can, while still maintaining its strength. A typical drink can uses 1 3.5g of aluminium.
(a)
A(
3
0
Aluminium is manufactured from aluminium oxide. 2
Outline the manufactured of aluminium from pure aluminium oxide.
(I)
What is the mass of aluminium oxide required to make a typical aluminium soft
drinks can?
(iii) Suggest why the manufacturers of aluminium cans should minimise the amount
(6]
of aluminium used per can.
(II)
(b)
(c)
Give one use of aluminium, other than making containers for food or drinks, and
[2]
state one physical property of aluminium that makes it suitable for this use.
2
One of the components in crude oil is undecane, C,,H
(a)
One of the reactions of undecane is shown by the equation below. This reaction
takes place during one of the processes used in an oil refinery.
+
(I)
8
H
4
C
(b)
(i)
(ii)
(c)
Butene, C
. can exist as isomers. Draw the displayed formulae of two of
6
H
4
these isomers.
[3]
Suggest a use of butene, other than as a fuel.
Water is a very important resource. Water needs to be purified for domestic and industrial
use.
(a) State two processes used to purify river water so it can he used as drinking water
Give ensons for the processes you mention.
(b)
The water quality of drinking water can vary. The table gives information about Inc
concentration of ions in drinking water from lour ditferen ocations.
2
location
A
B
C
D
cubicl
pH
2
Ca
Na
C1
SO
N0
4.2
2.7
0.35
0.25
2.4
06
0.3
cL4
20
4A
0.4
0
25
2.0
71
0.1
0.2
0.4
76
8.2
67
0.2
(I)
(II)
In which location would the drinking water not give a white precipitate with
acidified barium nitrate?
(lii) Write the formulae of two compounds that give rise to the ions found in the
drinking water at location 0.
(lv)
In which location is the water most likely to be. polluted by fertiliser Explain
your answer
[5]
(c)
(a)
(2]
density in kg/rn
3
174
31
glass
257
3 7
kevlar
145
3.6
polyester
138
Keviar and carbon fibre composites are used in the building of spacecraft
Suggest reasons why.
(I)
polyester composites,
(Ii)
(Ill)
Terylene is a polyester
Draw a section of the structure of this polyester showing clearly the nkages
between the small unils that make up the polymer
(iv) Give the name of a raw material used in making glass
(b)
(c)
[5]
The ethanol
is
made by the
Name
two
Section III
Answer ONE question from this section.
5.
[2]
[2]
[5]
(ci) List the properties of two alloys. Relate these properties to the use of each alloy.
[6]
(e) Describe the advantages that a given alloy has over the components from which
[5]
it is made.
6.
(a) What are fertilizers and what are their major components?
141
[2]
1 hour 15 minutes.
INSTRUCTIONS TO CANDIDATES
There are sixty (60) questions in this paper. Answer all questions.
For each question,
there are four possible answers A, B, C and D. Choose the one you
consider correct and
record your choice in soft pencil on the separate answer sheet.
Read the Instructions on the answer sheet very carefully.
INFORMATION FOR CANDIDATES
Each correct answer will score one mark.
answer.
.7
I.
50
25
25
50
75
100
125
150
temperature/C
A beaker of nitrogen was inverted over a porous pot containing carbon monoxide as shown.
The water level did not change.
beaker
nitrogen
carbon monoxide
porous pot
water
What is the reason for this?
B
C
The graph gives the melting points of mixtures of lead and tin.
400
400
m.p
04
P4Jt 4&d
300
300
200
200
100
100
melting
point/C
50
0
0%
100
The graph shows that any mixture of lead and tin must have a melting point
A
above that of tin.
B
0
4
Which property of an ester could be used to check its purity before use as a food flavouring?
A
boiling point
B
colour
smell
solubility in water
The table shows the number of protons, neutrons and electrons in four ions.
For which ion is the data correct?
number of
ion
protons
neutrons
electrons
2
Ca
20
20
20
10
10
12
Na
11
12
10
nucleon number.
number of electrons.
number of neutrons.
number of protons.
Which statement explains why magnesium oxide has a very high melting point?
A
Magnesium atoms and oxygen atoms are joined by strong double bonds.
B
C
graphite
ice
Y.
2
The elements Xand Yform the compound X
What is the correct electron arrangement of the atoms X and Y?
electron arrangement:
atom of X
atom dY
2,7
2,2
2,7
2,2
2,6
2,1
2,6
10
What Is the maximum mass of chromium, Cr, that can be extracted from 76g of chromium
?
3
0
2
(Ill) oxide, Cr
152g
0
104g
C
52g
S
A
48g
11
12
13
14
same
1249 of phosphorus vapour has the same volume as 71g of chlorine gas at the
temperature and pressure.
What is the formula of a molecule of phosphorus?
P
0
2
P
C
B
4
P
5
P
A
sodium
und
Which technique could be used to obtain the elements X and V from the ionic compo
XY7
filtration
D
electrolysis
C
distillation
B
A crystallisation
4
15
When the experiment shown was set up, the bulb lit, but there were no decomposition
products at the electrodes.
b lb
What is
X?
rH ij
sodium chloride
bromine
0 mercury
L.__..ve
electrodes
16
The formation of hydrogen iodide from hydrogen and iodine is an endothermic reaction.
HHll-H--lH--l
What may be deduced from this information?
A
The number of bonds broken is greater than the number of bonds formed.
B
The formation of H I bonds absorbs energy.
C
The products possess less energy than the reactants.
D
17
15
The total energy change in bond formation is less than that in bond breaking.
cracking of hydrocarbons
synthesis of ammonia
Copper (II) oxide catalyses the decomposition of aqueous hydrogen peroxide to give oxygen
and water.
In a laboratory experiment, aqueous hydrogen peroxide was shaken with copper (II)
oxide in a test-tube.
What did the test-lube contain when the reactIon was complete?
A
a black solid and a colourless liquid
B
19
20
C
D
Which of the following does not react with dilute sulphuric acid?
A
magnesium hydroxide
C
magnesium metal
magnesium nitrate
magnesium oxide
22
21
A
B
23
24
FCSeO,
25
In the Periodic Table, how many periods include the elements of atomic numbers
8
D
6
C
2
3
S
A
26
27
28
29
sodium
air
carbon dioxide
carbon monoxide
limestone
B
C
The apparatus is used to show the reaction between zinc and steam.
mineral wool
saturated with water
zinc
0
2
Zn-i-H
Zn
0
2
2H
2
+H
2
Zn(OH)
0
2
Zn+-4H
)
Q
j-3F-1
Zn(OH
+
2
2Zn 3H
0
2
ZnO 7
+2H
2
Zn(QH)
-18?
30
aluminium sulphate
calcium carbonate
zinc carbonate
excess
(aq)
3
HNO
colourless
solution
fNaON(a)
r
31
white precipitate
which dissolves in
excess NaOH(aq)
The steel bodies of cars can be protected from rusting by spraying them with zinc.
Why is zinc used?
32
33
sulphur compound
use
sulphur dioxide
a fuel
sulphur dioxide
sulphuric acid
making detergents
sulphuric acid
making fertilisers
34
haematite
limestone
mica
quartz
(s)
3
CaCO
CaD(s)
CO(q
Which volume of carbon dioxide at rip, would be produced, if 50g of calcium carbonate,
M= 100, is heated?
A
3
12dm
3
22dm
C
8
24 dm
3
44 drn
2
35
HCCH
and
HCH
H
H
HCCCl
H
36
HR
HCCCl
and
C=C
Cl
I-I
Cl
Cl
HCC--H
and
HCCCl
Cl
and
Cl
Cl
C=C
H
H
H
0H
0CH
What are the similarities and differences between the two compounds?
37
similarities
differences
molecular formula
reactions
molecular formula
structure
molecular formulae
structure
ethanoic acid
ethanol
ethyl etharioate
methanoic acid
38
39
What is the catalyst used in the preparation of ethyl ethanoate from ethanol and ethanoic
acid?
A
nickel
yeast
II
II
II
N 0N
C 0C
N flN
H
II
0NCC
NON---C0C
II
II
H
0
C--0N---C-0N
II
II
CN---0NC---
40
hydrogenation.
hydrolysis.
polymerisation.
12
H
nC
6
O
simple sugar
starch
A
10
The element Y has an electronic structure, 2,82. The element is therefore in:
Period 1 group I
A
B
Period 3 group II
41
Period 3 group II
Period 1 group II
H
I
HHH
ill
H-C-OH
H
A
42
H-C-C-C-H
Iii
HHH
H
B
H-C--C
H
0H
D
A reversible reaction takes place between B and D. The forward reaction is:
esterification
A
B
polymerization C
hydrolysis
synthesis
D
44
esterification
polymerization
synthesis
hydrolysis
45 Which of the compounds is least likely to produce carbon dioxide and water when burnt?
46 The following substances are all members of the same homologous series EXCEPT:
10
H
4
C
A
B
16
H
8
C
C
H:
6
C
5
0
C
.
1
H
6
47 Which of the following list describes the solution formed and the gas evolved when calcium
reacts with cold water?
Solution
Gas
Alkaline
Neutral
Acidic
Neutral
Neutral
Alkaline
Alkaline
Acidic
11
12 neutron?
48 Which of the following contains 10 electrons 11 protons and
I) Ne
C Ne
B Na
Mg
A 24
10
10
11
12
I)
Potassium nitrate
Copper nitrate
tate on mixing?
Which of the following aqueous solutions would form a precipi
Potassium chloride and barium chloride
i
ii
iii
iv
A
andHi
i and iv
12
56
A i only
57
58
D ii and iv only
An electrolyte is:
A
C
59
60
4
H
2
C
H
3
C
8
H
4
C
0
C
1
H
4
hydrogen is called:
The type of reaction that occurs between propene and
dehydration
D
addition
C
hydration
B
substitution
A
13
1 hour 30 minutes,
INSTRUCTIONS TO CANDIDATES
1.
2.
3.
There are five questions in this booklet. Answer all five questions.
________
I.
What is a catalyst?
(ii)
80
140
185
220
230
240
240
240
(iii) Draw a graph of volume of oxygen (vertical axis) against time horizontal axis
on the graph sheet provided.
(iv) What is the maximum volume of oxygen given off?_____________________
(v) How long did it take for the hydrogen peroxide to decompose?
(vi) Explain why the graph for the first four minutes is a curve and not a straight
line.
(b) (i)
A few cm
3 of potassium dichromate (VI) solution were added to a gas jar
containing sulphur dioxide and the mixture was shaken.
What would have been observed?____________________________________
C.,
..
,-
..
t;-
4.,
4-
4.
r:::
-t
.
.4..
.-
.t
1
1
-4q
I-
.1,1
4-
:.
..
4.4
4-
.._._
..
.
4
.::::::
.4
...
-.
4-
..4
-t
4
.11
.
1
*I
....4
i....-.
4.
-.
-i-
..
,-,
i_I_I
::::n
4--s
11.14
-1
.:
Lt ..
I-.---*
ILj.
41
-I.
4441.
njt
i
t
4
.. ._t.
4.11
.
a..i
i__f.4.i
I
4-.--
r--
..4...-l.T...
.4.JI
-T
-rihH*r:4-i.2t.
4.
.::;
1t
t
,i
tL
-
_I
4...
.
.1
.:zt: .-_.JL..J.
.4.
.*4__l...
.4.--
4..
.:;:tf4
.:.
.-
..,:..
.r-.--
..
.4
-.
...
4.i
F.-FI
,-fri-
..
--
m:
I.
L_.i
-.
}.j.j_..L._.J
...*_i
i...
..
41
4.
tz -Lfi
.4:4)4.2
.:.
-4-.__
.4...
:tL Ir
._
T
LiZ.
1
E_
4..
.:
.-
--r---i
: .4:+ i-: 4
Ht
-.
I-!-j.
.-...i
4.
.:
4
r- 4-
+
.. 44
I
I,,
-*444_TI
J,,
.4-..
..
...
-----
.i..p
4...,...
4
t
*4
,...
I..
__
__________
______
(iii)
A solid was heated with sodium hydroxide. The gas evolved turned moist red
litmus paper from red to blue. Name the gas produced.
The gas was also allowed to mix with hydrogen chloride.
What would have been observed.
(c)
The diagram below show parts of the stem of the thermometer as each
temperature reading was taken.
After Scm
After 10cm
After 15cm
After 20cm
TI
(I)
Read and record the temperatures in the table below and suggest values which
would have been obtained when the total volume of distillate collected was
3 and 30 cm
25cm
.
3
flilume of distillate/cm
flmeraturerc
(ii)
I 10
15
20
25
30
(a)
Which student at experiment 1 and 4 is not using the correct technique for
reading the thermometer.
(b)
Section I
Answer one (1) question from this section.
2A Consider the following list of common substances.
air
brass
glass
salt
sugar
water
limestone
(b)
is a mixture of compounds.
(c)
is a mixture of elements.
(d)
(e)
symbol
proton
number
relative
atomic mass
b.p.
1K
density at rip.
3
in gldm
helium
He
0.167
neon
Ne
20
27
0.833
argon
Ar
18
40
87
Kr
36
84
xenon
Xe
54
131
radon_[
Rn
86
222
(a)
(b)
121
3.50
165
5.46
9.25
(f)
Suggest why argon costs less to produce than any of the other noble gases.
[81
3(a) (I)
I
I
I
I
HCC-C C-H
(ii)
Br
Sr
this alkene.
bromine
the reaction product
(iv) Explain why this reaction is an example of an addition reaction.
f7J
(ii) The molecular formulae of the first three members of a homologous series
of
hydrocarbons are:
H
6
C
9
H
7
C
H,
0
C
(i) Give the molecular formula of the next member of this series.
(ii)
3(b) (I)
,
O was heated in the
5H
2
CuS
.
4
A sample of hydrated copper (II) sulphate, 0
apparatus shown below.
crystals
heat
cold
water
indicator
paper
On gentle heating, the blue crystals changed to a white solid P and
liquid Q was collected in the tube cooled by cold water.
Name the white solid and the neutral liquid.
neutral
white solid P
[2J
neutral llquid Q
(ii) On stronger heating, the white solid P changed to a black solid R and a gas was
evolved which dissolved in liquid Q to form solution S. The indicator papei
turned red as solution S was formed.
Addition of aqueous barium chloride to solution S gave a white precipitate.
(i)
()
4A
(a)
Which molecules, hydrogen or oxygen, are moving faster? Give a reason for
your answer.
fastermolecules
reason
(II)
If the gas jar is warmed to 50C, what happens to the speeds of the molecules?
[3]
(b)
The hydrogen and oxygen in the gas jar in (a) are allowed to react together.
(I) Write the equation for the reaction which takes place.
(II)
Name the substances which wilt be present in the gas jar after the reaction.
and
(c)
[3]
Nitrogen dioxide, NO
, is an atmospheric pollutant.
2
One source of nitrogen dioxide in the air is from the gases from car engines.
Explain how nitrogen dioxide is formed in a car engine and indicate how its emission
can be limited.
formation
5A
The diagram represents a simple cell for the production of electrical energy.
One
electrode is copper and the other is one of aluminium, copper, iron, magnesium,
or
zinc.
copper elrode
metal electrod
electrolyte
(a)
(b)
Give an equation for the reaction taking place in this cell when zinc is used as the
other electrode.
(c)
Explain how the reading on the meter is linked to the position of the metal in the
reactivity series.
(d)
Complete the table by inserting the names of the metals, aluminium, copper, iron,
magnesium, and zinc.
meter reading
N
metal
2.72
2.00
1.10
0.78
0.00
[8]
TIME:
1 hour
INSTRUCTIONS TO CANDIDATES
Section I
Answer one (1) question from this section.
(a)
An electric current was passed through dilute sulphuric acid. The reactions at the
electrodes are shown below.
at the anode
40H
at the cathode
2H(aq) 2e H
(g)
2
0(l)
2
2H
(g)
2
0
4e
(I)
Explain why the volume of hydrogen formed in this electrolysis is twice the
volume of oxygen formed.
(II)
Give the formula of the other ion present in dilute sulphuric acid.
(b)
Predict the products which will be obtained at the anode (ve), and at the cathode
[2]
(ye), when an electric current is passed through aqueous sodium sulphate.
(c)
(d)
(I)
(II)
[4]
j3]
(a)
I-ICI(aq)
NaCI(aq)
0(I)
2
H
(I)
Name the two pieces of apparatus used to measure accurately the volumes of
the solutions in this titration.
(II)
(Ill) Explain the meaning of the symbols (aq) and (I) in this equation.
(b)
(c)
[5]
(II)
[3]
.
2
An element, symbol E, forms an ionic oxide, P0
Predict, giving your reasons,
(I)
(II)
[2]
Section II
3
(a)
(b)
Give one use for each of the named allotropes and explain
how this use is
linked to the structure of the allotrope.
[51
4 (a)
(I)
(c)
Section III
Answer ONE question from this section.
5.
[2]
[4]
[4J
(d) Illustrate the differences in the structures of natural animal fibres and natural
[4]
vegetable fibres.
(e) Describe why natural animal fibres can be dyed directly by natural vegetable
[61
fibres cannot be dyed directly.
6.
(a) Lime is frequently used by farmers. Why is lime added to the sail?
(b) Lime is mainly impure calcium carbonate.
reaction of calcium carbonate with acid.
(c) What do you expect to happen to the pH of the soil when lime is added to the
soil?
(d) List three effects on plants when soils are too acidic.
(e) The garden shop attendant advises a farmer not to add lime and the ammonium
fertilizer he purchased at the same time. Why should this precaution be taken?
(f)
Write a chemical equation for the reaction taking place in (e) above.
TIME:
1 hour 15 minutes.
INSTRUCTIONS TO CANDIDATES
There are sixty (60) questions in this paper. Answer all questions. For each question,
there are four possible answers A, B, C and D. Choose the one you consider correct and
record your choice in soft pencil on the separate answer sheet.
2
N
250C
2
.
4
CuSO
0
5H
4
CuSO
A little water was accidentally spilled into a dish containing hydrated copper (II) sulphate.
What could be done to remove the water, leaving pure, dry 0
2
.
4
CuSO
5H
?
Heat the dish over a boiling water-bath.
A
jr
4
number of
neutrons
electronic
structure
10
Z8
20
2,8,8
x
Y
17
In which set do the three particles each have the same total number of electrons?
A
Ct
Br
F-
Ne
Na
2
Ca
Br
Li
Nr
substance
melting
point/C
boiling
point/C
when liquid
114
85
none
114
78
none
none
180
218
none
insoluble
808
1465
good
good
oxygen
good
steam
0
9
In which oxide does X have the same oxidatioon sta:e as in the chloride, XC;:
2
X0
0
0
2
X
x
a
2
C
A
0
3
X
B
10
429
11
12
cathode product
solution produced
hydrogen
acidic
hydrogen
alkaline
rubidium
acidic
rubidium
alkaline
13
14
at anode ( ye)
at cathode
anode dissolves
anode dissolves
no change
no change
the electrolyte
What is the equation for the change that takes place at the cathode (negative electrode)
during the electrolysis of molten magnesium chloride?
A
2
Mg-2e
-Mg
2
M
2w-M
g
g
Mg-t-e--Mg
Mg
2
2e- Mg
o
15
( ye)
o
C
16
The rate of the reaction between a given mass of calcium carbonate and an excess of
hydrochloric acid was studied by collecting the released carbon dioxide in a graduated
syringe.
The results are shown in the graph.
P IfEHIHU !I
L.
tim&min
How much time was required for halt the calcium carbonate to react?
A
17
1.5 mm
2.0 mm
3.0 mm
10N
3
N
2
18
0.95 mm
toNQ
3
NH
toNO
NH
3
I0NH
2
N
3
When gas X is passed over heated copper (II) oxide the products are copper and steam
only.
What is gas X?
A
19
ammonia
carbon monoxide C
hydrogen
methane
Acidified potassium dichromate (VI) can be used to detect the presence of ethanol vapour
in the breath of a person who has consumed alcohol.
7 -f.-...
20
a catalyst.
an alkalL
an oxidising agent.
a reducing agent.
A white compound produces a mixture of gases when heated This mixture turns moist
Universal Indicator paper red and relights a glowing splint.
What does this mixture contain?
21
When two liquids are mixed, a solution with a pH value 017 is formed.
Which of the following are the pH values of the two liquids?
22
23
first liquid
pH
second liquid
pH
12
14
Which of the following describes a step in the preparation of insoluble barium sulphate
from aqueous barium chloride and dilute sulphuric acid?
A
B
C
24
Which properly decides the order of the elements in the Periodic Table?
A
B
C
D
25
26
0
2
1n
3
0
2
1n
28
2
mO
From knowledge of the manufacture of aluminium and of iron, what is the order of chemical
reactivity of aluminium, carbon and iron towards oxygen?
least reactive
most reactive
27
mO
aluminium
carbon
iron
aluminium
iron
carbon
carbon
aluminium
iron
carbon
iron
aluminium
Copper (II) carbonate, calcium carbonate and zinc carbonate decompose when heated.
The temperature at which decomposition takes place depends upon the position of the
metal in the reactivity series.
What is the correct order for their decomposition?
highest temperature
lowest temperature
zinc carbonate
calcum carbonate
calcium carbonate
zinc carbonate
zinc carbonate
copper(fl) carbonate
caIcir carbonate
zinc carbznate
calcium carbonate
ccpe: ) carbonate
29
30
13
DCI
iron
nail
water
iron
nail
water
copper
water
Iron
nail
zinc
magnesium
Xonly
Yonly
3
NH
XandZonly
13
YandZonly
3+H
2O2-* HNO
3 + NH
HNO
3
3
N0
4
N
+
What is the madmum mass of fertiliser that can be made if only 17 tonnes of ammonia is
available?
A
32
33
34 tonnes
40 tonnes
80 tonnes
13 97 tonnes
S
2
H
(
4
aq)
0
(g)
3
2NH
S
2
H
(
4
aq)
0
(aq)
2
BaCI
S
2
H
(
4
aq)
0
CuC(s)
13
(aq)
4
HSO
C
2
Na
(
3
aq)
O
S
2
)
4
(NH
(
aq)
0
(s)
4
BaSO
(aq)
4
CuSO
2HC1(aq)
0(I)
2
H
S
2
Na
(
4
aq)
O
(g)
2
C0
0(!)
2
H
The formula of china day (aluminium silicate) was shown in an old book as
A1 25i0
.
3
0
2
. 2H
2
0.
2
This formula is shown in a modem book as Ab(OH)Si
O.
2
34
35
Which of the following pairs of substances are both manufactured using calcium carbonate?
A
To reduced atmospheric pollution, the waste gases from a coal-burning power station are
passed through powdered calcium carbonate.
Which waste gas will not be removed by the powdered calcium carbonate?
36
37
carbon monoxide, CO
nitrogen dioxide, NO
2
sulphur dioxide, SO
2
aircraft fuel
diesel oil
furniture polish
margarine
Which of the following describes the ways in which isomers are identical and different?
identical
different
chemical properties
molecular formulae
molecular formulae
structures
physical properties
chemical properties
structure
molecular o:mulae
38
Which structure shows a compound that reacts with ethanol to give a sweet-smelling liquid?
A
H
C
H
1111/
C=C
Hcc-cc
/
\
\
II
H
H
I/I
II
HCc
0H
0
H
III
40
HocCCC--H
?1
39
PVC
soap
starch
Terylene
Starch can be broken down into smaller molecules by heating with a dilute acid.
What is this type of reaction called?
A
cracking
fermentation
10
hydrolysis
D reduction
.4
45
22
44
27
50
20
Cs
Fr
C....r
64
34
Ri
224
IS...,
51
257
La
Ky
.ICwrr rr
1.100 rYS
72
HI
90
73
U
0wrr
PI51flCr
29
30
77
Np
564,
Pm
93
4*Otfl%t
SI
94
L.IWS
Pu
S.,a,o.r,,
07
Sm
50
Pd
Pt
Oe...n
T.,.
Gd
C...
54
Eu
64
Dy
ISa
SI
T%S-.r
Th
(rgo.r
47
64
Cr..,
44
Cl
C..gs
Bk
aM
Cm
Am
I4tSjt
CI
64
III4I
Hg
201
Ti
064
44
64
Fm
I3
No
.a4
110
Md
CI
M.a b
10
Is
ta.t.
71
7,.
70
C...
Na.w.
OP
75
Lu
73
Yb
105
Tm
07
Er
Sr,..,
05
.54
Rn
.
At
4fl
Po
c._,-
Di
Es
frIe..
Ho
43
ew
a#.14r
54
III
k454
Xe
24
bsrn
127
24
1.
179
kIrtr
52
34
54
Kr
64
Br
79
S.
IS
Ar
C san.,
00
47
52
L4
Pb
*,ur,
I.
cn.,.
07
74
Au
07
S4.4
Sb
51*
Sn
115
In
Il?
a,..
I?
33
Cd
53
4er_
Ag
fl
te,.I,,.
31
G.f I
Cso
In
P..,
75
24
75
As
73
Ge
Ga
64
Zn
54
Cu
55
Ni
70
ct_I
IS
IS
I3
255
31
24
Si
17
Al
01
735
Pa
222
Tb
r,,It
Nd
Pr
rs,,.r.
Ce
I.
70
Ir
nn
Os
0.I.
ft.
Re
Cr..r
92
75
,SAr.,,.
44
l4.r
344
74
W
.wl
141
540
Ta
.,,nr
44.,
42
r,s....r
t.r,.r..
.....
r5_,
I1..o.rs
4.t.a.,.
__.z
103
Rh
101
Ru
Tc
44
Mo
43
Nb
Zr
54
C.4.4
64
54s
Co
Sr
75
4n.
54
Fe
55
Mn
64
a,.
23
r.....
On,,e,
14
52
Cr
5?
Ti
Rb
S.ssw,
15
Sc
57
55
C.al
20
4....
II
40
Ca
Mg
50
an
4
4_.
!__.
24
II
Na
--_-__
50
Ne
F
0
Be
54
II
54
ImINIv[hI0
II
ii
Group
DATA SHEET
The Perio6c TabI. of the Elecn.nts
41
Which one of the following provides the best evidence for the particle theory of matter?
A
42
Crystallization
Diffusion
Chromatography
Dehydration
do not move
melt
43
Which of the following metals reacts with water to give a solution which forms a white precipitate with
carbon dioxide.
copper
U
magnesium
C
B
sodium
calcium
A
44
3 is:
The oxidation state of nitrogen in N0
A
45
Copper (H) sulphate crystals can be separated from sand using the four processes listed below. The
order in which these processes should be used is:
4th
3rd
2nd
1st
A
filtration
solution
crystallization
evaporation
solution
evaporation
filtration
crystallization
filtration
solution
evaporation
crystallization
solution
filtration
evaporation
crystallization
46 Which one of the following elements burns in air to give a compound which in water gives a solution of
pHi
hydrogen
D
sulphur
sodium
C
B
aluminium
A
47
48
49
Fe
Mg
Cu
Na
50
51
52
53
chromatography
subhmation
Fractional distillation
3
HNO
ii and iii
Hydrochloric acid
Methanoic acid
Hi
Sulphuric acid
iv
Carbonic acid
iand ii
Hiandiv
i and iv
lB
ionly
i,HandiH
iHonly
iandiionly
What are the products given off during the electrolysis of molten magnesium bromide between carbon
electrodes?
Anode
Cathode
magnesium
bromine
oxygen
magnesium
bromine
magnesium
oxygen
hydrogen
54
55
oxidation
56
57
Which one of the following best describes the reaction of butene with bromine:
A
unsaturated
B
addition
C saturated
0
substitution
13
58
59
60
?
Which one of the following produce an amphoteric oxide on heating
D
zinc nitrate
sodium nitrate C
calcium nitrate B
A
14
copper nitrate
TIME:
1 hour 30 minutes.
INSTRUCTIONS TO CANDIDATES
1.
2.
3.
There are five questions in this booklet. Answer all five questions.
1.
Experiment
No.
Volume of
3
Aci&cm
Volume of
3
thiosuiphate cm
Volume of
water/crn
concenfration
lime t
Sec.
50
0.15
44
40
10
0.12
55
30
20
0.09
74
20
30
0.06
115
0.03
245
40
10
(i)
(ii)
lit.
secs
(iii) Assuming lit is a measure of rate of reaction, how does rate depend on
concentration of thiosulphate?______
__________
(b)
_____
Complete the table below for tests carried out on V which were dissolved in water
and divided into five portions.
TEST
To the first portion diluted hydrochloric
acid was added followed by barium
(i)
OBSERVATIONS
white precipitate formed
CONCLUSIONK1
-
chloride
(iii)
(iv)
(c)
no precipitate formed
-
4)
11
(d)
L
,
r
tpp 4111
4t#-f -4-L4t
it?.
--t-t
I-
i-i
Hi
4-H-i-
r:
1
t
!
.,
.:
4..
..
tr:,
-.:;
.4
;..
;.u;
i.
4
4
__
..
4.
..
;4
.:
...
..
_.
rirtt
-.,
:tr
-;
-.
--
..
t-----r-t
i-
,.
.
rrr
--._
ii_.iL.Li_Lr
!J
,:L,z--
.
-
-.
----t-
------.
-I,
*
..
---
-*----s.4---4+--
--
--
_L-
-:-
-cI-
2A
bromine
calcium
chlorine
hydrogen
iodine
iron
magnesium
nitrogen
oxygen
Each element can be used once, more than once, or not at all.
Name an element which;
(a) forms two different positive ions,
[11
(b)
11]
(c)
(d)
(a)
11)
28 The diagram shows how silicon is manufactured from sand.
caon monoxide
(a)
(b)
silicon
Use the information in the diagram to explain why the manufacture of
involves a redox reaction.
[2]
(c)
(II)
3A
A chemical reaction takes place when the glue sets solid. An experiment is carried out to
(the
find out how changing the temperature changes the time for the glue to set solid
setting time).
The graph below shows the results of the experiment.
1I[F
T1
IW}ilfi1llhifJ}MII1IIE 1iiiIi!1
Trru1nannnutn qw.!
setting
time?
minutes
..
30
rtt1JiI1i!JIfI1
lfllflEfl4jIjflfljfl[I. H
J ttHHNflflHftN-l
flhltllhtlltflhltll
U Ililhlifli H
III ttl I t
o ml lit
10
5
o
2
15
20
iomperatur&C
25
30
35
(a)
(b)
[1]
(I)
(II)
Explain your
[3]
(c)
3B
atomic
symbol
electronic
structure
melting
point/C
boiling
point/C
density
in g/cm
3
atomic
radius4m
lithium
Li
2, 1
180
1330
0.53
152
sodium
Na
2, 8. 1
98
892
0.97
186
potassium
2, 8, 8,1
64
760
0.86
231
rubidium
Rb
2, 8, 18, 8, 1
(a)
[4]
(b)
(c)
2H
0
2
(l)
2LiOH(aq)
H
(
2
g)
(ii)
[61
4A
(a)
.
2
The alkanes are a series of hydrocarbons. They have the general formula CH
(I) Give the name of the alkane having n = 3.
(II)
5.
[31
(b)
(ii)
,
(iii) Describe a test you can use to d:sflnguish between an aikane and an alkene
and give the results you would expect.
reagent
observahon with an alkane
observation with an alkene
[5]
BA
CFCs are compounds that contain only carbon, chlorine and fluorine They are
atmospheric
pollutants and destroy ozone in the upper atmosphere.
(a)
12]
(b)
2HF
CC
+
2
F
2HCI
1
[31
58
(a)
Name two aqueous solutions which will react to form a precipitate of silver
chloride,
AgCI.
and
(b)
11]
(c)
Describe how you would obtain a pure, dry sample of the silver
chloride precipitate
from the mixture in (a).
[31
TIME:
1 hour
INSTRUCTIONS TO CANDIDATES
Section I
Answer one (1) question from this section.
Hydrogen is used as a fuel in some space rock
ets.
(a) Describe how hydrogen is manufactured from
(b)
[3]
(c)
[1]
[Total 10]
2
[3]
Ammonium nitrate, 3
NO
4
,
H amrnonium sulphate, 4
(NO
S
2
,
Hj and urea, 2
(N
C
)
0,
H
are all fertilisers that can be made from amm
onia. The three fertilisers all provide
plants with nitrogen.
(I)
[5]
(2]
[Total :10)
7
Section II
Answer one (1) question from this section.
of food They can all be
Carbohydrates, fats and proteins are the three main constituents
s
alkali.
aqueou
hydrolysed, either by aqueous acid or by
(a)
What is formed by
(I) the acid hydrolysis of carbohydrates,
(Ii)
(b)
(c)
(d)
[2]
(I)
(Ii)
electrodes or copper
Aqueous copper (II) sulphate can be electrolysed using either carbon
electrodes.
[1]
(a) Give the formulae of the ions present in copper (II) sulphate.
(b)
(c)
electrodes, a
When aqueous copper (II) sulphate is electrolysed using carbon
colourless gas is formed at the anode (positive electrode).
What is the name of this gas?
(I)
[21
(II) Describe a test for this gas.
des.
Aqueous copper (II) sulphate is electrolysed using copper electro
Explain why the anode decreases in mass.
(I)
(II) Explain why the cathode increases in mass.
(III) Write an equation for the reaction at the cathode.
[3]
(d)
(a)
11]
[Total :101
3
Section III
Answer ONE question from this section.
5.
[21
(b) Describe how clay particles are able to hold water molecules to their surface
s.
What is the purpose of these water molecules?
[5]
(c) List three properties of clay.
[3]
(d) Describe the basic process of producing pottery from clay, showing how
the
properties listed in part (c) are utilized in the process.
[6]
(e) List three products of clay and state one similarity between clay produc
ts and
glass products.
[4]
6.
[3]
(e) Describe how a deficiency of three named elements affects green plants.
[5]
TIME:
1 hour 15 minutes.
INSTRUCTIONS TO CANDIDATES
There are sixty (60) questions in this paper. Answer all questions. For each question,
there are four possible answers A, B, C and D. Choose one you consider correct and
record your choice in soft pencil on the separate answer sheet.
Read the Instructions on the answer sheet very carefully.
The cover-plates were removed from the gas jars shown in the diagram. After several
days, the colour of the gas was the same in both jars.
-
oxygen
cover-plate
bromine
, is 160.
4
The relative molecular mass, M of copper (II) sulphate, CuSO
The relative molecular mass, Mr of water is 18.
?
5H
2
.
4
CuSO
What is the percentage by mass of water in copper (II) sulphate crystals 0
A
18x100
160
5xlBxlOO
160
18x100
160+18
Sxl8xlOO
160+(5x18)
student
utration value/cr&
20.4
1-
2
20.5
204
20.6
-f
The titration flask was wsned out with the iaoc: Diuiion
sI
22.0
From which mixture can the underlined substance be obtained by adding water, stirring
and filtering
An atom of helium has two protons and tour neutrons in its nucleus.
Which of the following ions has the same number ol electrons as a krypton atom, atomic
number 36?
A
7
He?
chlorine
rubidium
xenon
conduction of electricity
substance
melting point
when liquid
PC
sodium
in aqueous
solution
114
none
none
114
none
good
180
none
insoluble
808
good
good
The diagram shows the arrangement of electrons in the outer shells ol the atoms in the
.
2
compound YZ
Which pair of elements could be V and 7
calcium
fluorine
carbon
sulphur
oxygen
hydrogen
sulphur
chlorine
I
electrons of Y
x
electrons f 7
10
Fe(NQ,)
Fe.](N0J)]
3
FeN0
,
(N0
3
Fe
)
70g
7
What is the mass of oxygen contained in 72 g of pure water
[Relative atomic masses: H
A
11
lSg
1:0
16]
C
32g
64g
0
2
2H
2NaOH
2
H
13
The heat-reflecting shields of some space rockets are gold-plated, using electrolysis.
Which electrodes and electrolyte would be used to gold-plate the heat shield?
14
negative electrode
positive electrode
electrolyte
carbon
heat shield
gold compound
gold
heat shield
copper compound
heat shield
carbon
copper compound
heal shield
gold
gold compound
shown
A current was passed through concentrated aqueous lithium chloride, LiC1, as
concentrated aqueous
lithium chiorci
15
16
Lh only
Ct and 0H
LV only
C! on!y
LV and H
C/ only
Lfr and H
Ct and 0H
the formation of a carbohydrate and oxygen from carbon dioxide and water
Dilute sulphuric acid reacts with copper (Ii) oxide to form copper (Il) sulphate and water
What would not alter the rate of this reaction?
17
40 g of HC! in
1000 cm
3 of water
20 g of HC! in
3 of water
1000cm
lOg of HOt in
100 cm
3 of water
g of HC1 in
3 of water
50cm
D
18
pcnducedper
minuio
20
O
emperaIiuerC
40
&
50
19
20
21
22
Which compound, when added to aqueous iron(ll) sulphate, takes part in a redox reaction?
A
ammonia
barium chloride
sodium hydroxide
Samples of polluted air are passed through two reagents, acidified potassium dichromate(Vi)
and aqueous potassium iodide.
Which colour changes will be seen if the polluted air contains sulphur dioxide?
acidified potassium
dichromate (VI)
aqueous potassium
iodide
green to orange
brown to colourless
green tc crange
no change
orange to green
colourless to brown
orange to green
no change
aqueous ammonia
calcium carbonate
water
The diagram shows some ot the stages in the manufacture of ammonium sulphate
2
From wnc connecting pipe would a major leak most increase the pH value of rain
nitroce-
ann
Ernon I________________
hydrooc
ammonia
PIPE S
PIPE A
.-
N
ammonurn
sulphate
__
Th
ion
rca
so,
fl_
reaction -il
3
2
S
2
H
)
yessel
6
PIPE C
23
Which compound in solution produces a precipitate with aqueous ammonia that does not
dissolve when an excess of ammonia is added
2
A
potassium hydroxide
zinc chloride
Element X forms a diatomic molecule. An atom of X requires one electron to form a stable
X- ion.
24
25
It is a halogen.
It is a noble gas.
It is a reducing agent.
The bar chart shows the period of elements from lithium to neon
prope
Li
BeB
element
1 hour
INSTRUCTIONS TO CANDIDA
TES
lly.
Fr
Ra
226
I,
Ac
227
Key
I X
[_J
5ITWC
a 9ifl sin)
XaMonlC.vnlbCi
2S42a.#!
Hf
72
La
L.n.-
Ba
9..
Cs
C,n.,.,
40
dl
94
58
71
IS,,
41
PttIsII
Pa
P,,00,I,
34
,n
Nd
ISA
6..
Re
946
92
82
t5
Ii
ISA4rI,
75
To
M.4n,.
75
Pm
Os
94
Tha,
Ru
CI
98
33
Sm
350
,n,,
Ir
97
d.
Rh
53
Sr,-fl
C
fl
45
77
Ca.,
1!!
NpPu
6SAII-
PIw 6,.
76
44
24
Am
Eu
52
P98,,r
Pt
IZ
63
74
44
00
Pd
.,tO.,
26
NtkI
Group
04
73
43
29
C .0,
Cm
Gd
57
C06
Au
97
Ag
00
Clo..
Bk
1n
Th
150
Ma
f
3
l
Hg
201
Sa,tr
82
44
Cd
117
2c
CO
20
Cl
Dy
IC
TI
C$,.,,I
94
60
01
204
.e.,
In
115
CJA..,
Es
Ho
IC
Lno
Pb
207
6,
I ,ws.
49
6)
62
Sn
119
C.,4,.,.n
32
4a%.,,,
:4
71
Si
27
Cst
Al
49
2:
B
901a
ii
ns
..n.
112
Fm
tm,,4
Er
67
Sn.,
Bi
200
Ate.,
Sb
f.,,..,
903
53
51
7)
A,t
Md
Tm
leO
Dt,.,
Po
Te
179
3.
9r
32
2fl
101
9Seab.1
94
64
52
34
94
C154,
Cl
355
F%A
Yb
172
Ann
At
.,,..
12
Ba
No
152
f.w,
70
94
5,3
35
20
Is
Lu
75
Rn
Xc
wb
A9al
&
40
Na
903
t,s.,.I6,,
21
90
54
30
10
IiiiIivlvIviIvii;
Th
232
0...-
149
Pr
Ia
54
ItO
74
47
Ce
1.a*
Ta
191
*2t44p
Mo
Nb
24
V
Zr
2)
94
27
70
39
22
58
36
11
37
fl
Sr
t*.
Rb
94
p-so.
*9)
Mg
I4._es,
Na
24
SAO.n
23
o
9
Be
I%
Li
Lc_
II
DATA SHEET
Th. Periodic T&,Ia of the EImn.nts
41
-1 is:
10
1
4
The number of isomers of butane C
C
B
2
Al
n
42 Which of the following nitrates does NOT decompose with the evolution of nitroge
dioxide gas when heated:
(NO
2
)
Pb(NO) 13 Cu 3
2
C
3
KNO
B
A MgNO
3
43
neutral
45
amphoteric
When ions are discharged at the anode the process is one of:
hydration
oxidation D
neutralization C
B
reduction
A
ally changed:
46 Which one of the following will conduct electricity without being chemic
solid sulphur
B
solid magnesium chloride
A
C
solid copper
crystalline solids
soluble in water
13
non electrolytes
12
50
SI
Fluorine is in a group(VlI) of the Periodic Table. Its chemistry will most closely resemble
that of:
A
52
56
iodine
sodium
11
20
oxygen
carbon dioxide C
argon
chlorine
55
boron
Which gas is used to fill electric light bulbs and prevent burning away of the filament
7
A
54
The element with atomic number 4 is likely to have similar chemical properties to the
element with atomic number:
A
53
neon
slightly acidic
strongly acidic
slightly alkaline D
strongly alkaline
sodium chloride
ammonium chloride
calcium carbonate
lead nitrate
In which pair do the elements combine to form a compound with an ionic attica
A
57
The atomic numbers of three elements, P0 and Rare 17, 18 and 19 respectively.
Which of the following is a correct statement regarding P, 0 and R?
A
2
P and R Combine to give an ionic compound PR
D
58
59
60
O
2
CH
O
4
CH
0
4
H
2
C
0
6
H
2
C
Caesium is an element in the same group of the Periodic Table as sodium. It can be
predicted that caesium:
A
2)
forms a hydroxide of formula Cs(OH
Polythene
Ethene
14
Nylon
P.V.C.
TtME:
1 hour 30 nilnutes.
INSTRUCTIONS TO CANDIDATES
1.
2.
3.
There are bye questions in this booklet. Answer all five questions.
1.
3 of solution.
X is a solution potassium manganate (VII) containing 3.2 gmsldm
.
3
V is a solution hydrated iron (II) sulphate containing 22.5 gmsldm
The student is required to titrate X against V.
In this reaction a redox reaction takes place according to the following equations.
Mn
4 5Fe
Mn0
2 +
or
5Fe
2+
5 MoIs Fe
3+
(aq)
(i)
(ii)
Figure 1 shows the reading in the burette before and after each titration against
3 of solution V.
25cm
23
25
24
2t
Titration 1
Titration 3
Titration 2
11TRATION
2
Final Reading
Initial Reading
Volume of solution x used/cm
3
(v) Calculate the number of moles in the average volume calculated in (ii).
(viii) Calculate the reactive molecular mass of the hydrated iron II sulphate.
RAM.
K=39
Mn=55
0=16
Fe=56
S=32
H=l
Solution of glucose
and subitancc
w
(I)
(c)
Ov
Name gas Y.
(v)
(vi)
(vii
(viii)
n
When the mixture was allowed to stand for a week, thepHof the solutio
result.
this
dropped to about 5 How would you expiain
(i)
(ii)
(i)
(tv)
Oily water
conducts e!ecthcity
when solid
melting point/V
dissolves in water
sodium chloride
no
808
yes
sulphur
no
113
no
tungslen
yes
3377
no
wax
no
35-50
aiunithiuni
no
yes
660
no
(a) (I)
[1)
(ii) How can you tell from the table that the subs
tances you have chosen in (I)
are metals?
ru
(b) How can you tell from the table that wax is a mixture?
Lii
(c)
(I)
(ii)
111
[II
(d)
(e)
ZA
(a)
fraction
basting range/C
2570
70115
115200
200380
11
(b)
?
Which trachon corflains the ongesl chao molecules
(c)
r1
ars of nydrocarbon X
Draw aDrans to show the structures at two isom
sed
(Ill) Explain why hydrocarbon X can be nolymeri
141
6
38
The reaction ri
(a) is
12]
(c)
The value of the enihalpy change icr this reaction is given as:H
Is this reaction exothermic or endothermic
7 Explain your answer
285 kJ/nio[
[1]
(d)
Suggest one reason why burning hydrogen may cause tess envitOnmenaI damage
than burning hydrocarbons.
Ill
(e)
A pressurised gas cylinder contains 50 got hydrcgen. Catcuate the volume that the
hydrogen would occupy at room temperature and pressure.
[3]
4
AgNO
(
3
aq)
A
Ca(N0
(
2
)
3
aq)
B
M(tO)
(
2
aq)
C
CuQQ
(
2
)
3
aq)
D
(a)
(I)
(ii)
(b)
The experiment was repealed Zinc strips were used instead of the metal strips in all
four beakers
From looking at the reactivity is!. in which beakers would you expect to see a reaction?
[11
(C)
The experiment was repeated a third time, using strips of aluminium in all four beakers.
No reachons happened
Explain why ajuminium does not react.
[21
SA
Hydrogen. H, deuterium. D, and tritium, T, are isotopes of one anoiher. Their atomic
siructures are shown below.
deulerium
hydrogen
(a)
tritium
particle
proton
charge
mass
1
.
)C
(b)
[21
(c)
of
titium. T,
[1
(d)
on.
(i)
(i
si
thearrangernentof pariIes
31
All ammonium salts on heating with sodium hydroxide produce ammonia gas.
From which ammonium salt can the greatest mass of ammonia be obtained?
32
P0
3
)
(NH
0.5 mol 4
),S0
(NH
0.5 mol 4
CI
4
1.0 mol NH
1.0 mol 3
NO
4
NH
Compound X reacts with some metals to liberate hydrogen and is used to make fertilisers.
It gives a white precipitate when added to aqueous barium nitrate
What is X?
33
34
35
animonium sulphate
hydrochloric acid
potassium nitrate
sulphuric acid
calcium carbonate
calcium silicate
sodium silicate
It is a carbon compound.
It is a macromolecule.
It is used as a lubricant.
ammonium sulphate
lime
oxygen
sulphur dioxide
36
37
H
1
C
6
C,I-l
H
8
C
2
H
&
I
/
HCCCC
I
H
I
I
I
HC-CC--CH
I
I
i
H
HCCH
HC--CCH
HCC-H
I-I
1
/\
38
1and2ony
1,2and4orily
12sand4
3and4only
An organic compound X reacts with sodium hydroxide to give a compound with formua
C
0
5
H
3
,Na
Wia; is compound X?
A
39
ethano
prcpano:c acid D
propane
propanol
A
B
2
0H
-CH-
CHCH
01
Cl
0
U
40
I-I
What is prcstjed when ethanol is boieo with an excess of acjd,ied potassium dichromate
(VI)
eihane
ethanc c ace
10
ether.e
ehyt ethanoat
Section I
Answer One (1) question from this section.
Sodium phosphate, 4
PO is a soluble salt, used as a water softener in washing
3
Na
,
powders. 1 is made by reacting dilute phosphoric ad. HP0. with an aikalL
(a) Give the formulae of the ions present in sodium phosphate.
[1]
(b) (i) Name the alkali which reacts with phosphoric acid to make sodium
phosphate.
Write
(ii)
an equation for this reaction.
[21
(cj
Given solutions of phosphoric acid and alkali, a suitable indicator and standard
laboratory apparatus, explain how you would obtain crystals of sodium
phosphate.
[31
(d) Sodium carbonate also reacts with phosphoric acid to make sodium phosphate.
(i) Name the gas formed during this reaction.
(ii) Describe the test for this gas.
[2]
Ce) Calcium phosphate is used to make fertilizers.
(i) Deduce the formula of calcium phDsphate.
(ii) What essential plant element does calcium phosphate provrde
121
[Total: 10]
[1]
10]
Section II
Answer one (1) question from this section.
3
--
j
400
300
tnta
volume of
200
TI
rH
Frn-T-1]J.1
-t
-44
L4L44
.1
F i-i-I-,
nitH
0
m
Irn
4
1
4
L
time/seconds
(a) (i) State two observations which would be made after adding lithium to the
water.
(ii) Name a 5ubstance which could be added to the water to show that a
[3]
solution containing hydroxide ions had been produced.
(b) (I) State how the rate of reaction changes during the experiment,
(ii) Explain why the reaction stops,
(C)
[2]
1]
Experiment 2 was the same as experiment 1. except 0.1 9 lithium were used.
Experiment 3 was the same as experiment 1, except the water temperature was
raised by 1OOC.
(i) Use the graph to find the total volume of hydrogen produced in experiment
1
(H) Deduce the tota] volumes of hydrogen produced for each of experiments 2
and 3.
(iii) Deduce how the rates of reaction for each of experiments 2 and 3 wou:d be
[4]
different from experiment 1.
Fotal 101
sium
chlorine
[2)
[1)
sodium
chlorine
[31
(e)
[1
[Total :1OJ
Section LU
Answer ONE question from this section.
[2]
13]