Thomas F. McGowan
TMTS Associates, Inc.
FIGURE 1. This wood-fired boiler furnace with a pneumatic spreader stoker shows lots of wood particles
and burning embers above the grates
cle density and the nature of the upstream process and feedstock. The
smaller the particle, the more easily it is carried by the fluegas, even
at relatively low gas velocity. As the
gas velocity increases, larger particles can be carried by the fluegas
stream, and the number of particles
of all sizes that can be carried increases (Figure 1).
U.S. federal and state regulations related to particulate matter vary with the process and
the scale of the equipment. In
the U.S., historic state and federal particulate limits (for example,
FIGURE 2. The image at left shows two baghouses installed in parallel. On the right, the cage is inserted
into filter bags, and pulse-jet pipes provide blowback to clean the dust off the filter
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Bionomic Industries
Verantis Ceilcote
Charging section
Packing
Venturi throat
Inlet
Acid gas absorber
FIGURE 4. In this two-stage ionizing wet scrubber, particles are charged, then removed on grounded
plates and on packing; a periodic wash flushes and cleans the plates and packing
CHEMICAL ENGINEERING
lations. Disposal options for the removed particulate matter (that is,
the resulting dry dust, wet sludge, or
stabilized mixture that is formed during treatment) is another major factor in decision making. Cement kilns
are an example, where baghouses
are used to capture cement kiln dust
(CKD), which is a salable product,
while a wet capture system would
form unsaleable (and system-fouling)
cement solids.
For dry ESPs, the resistivity of
the collected flyash is an issue, and
changing the coal feed source can
Verantis Ceilcote
100.00%
99.00%
IWS
Removal/efficiency
98.00%
97.00%
Baghouse
96.00%
95.00%
ESP
94.00%
0.0
1.0
Particle size, microns
2.0
FIGURE 5. In this graph of particle size versus removal efficiency, three of the most commonly used APC
devices experience a decline in collection efficiency as the particle size of the pollutants falls. This phenomenon is least pronounced for the ionizing wet scrubber (IWS)
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63
Tom McGowan
and dry ESP. Note that the collection efficiency for all of these devices
begins to fall off for smaller particles,
with the IWS having the least-rapid
decay of its efficiency curve. IWS are
frequently used in series with two or
three in a row, in part, to maintain
removal efficiency during their required periodic wash cycle; in this
scenario, a downstream unit operates while the upstream unit is being
washed down.
Perfection is
Acid-gas removal
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64
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AUGUST 2016
FuelTech
Reagent
injectors for
SNCR NOx
control
NOx control
EPA requires control of NOx, as
NOx reacts with organic vapors in
the presence of sunlight to produce
ground-level ozone. The low-cost
way to limit NOx is to do so upCHEMICAL ENGINEERING
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www.tri-mer.com
Since 1960 Factory & Headquarters: Owosso, MI
Copyright 2016 Tri-Mer Corporation
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65
much higher capital costs. Computational fluid dynamics (CFD) modeling (Figure 7) is frequently done for
SNCR systems, to help users to optimize injection points, enhance mixing and estimate NOx-removal efficiency. In general, CFD is not used
as frequently for modeling SCRs, because such systems use a chamber
to house the catalyst and the catalyst pressure drop helps to even out
fluegas flow.
VOC control
The primary non-transportation
sources of VOC emissions are chemical process operations (such as reactions); storage and transfer (such
as pumping and working losses and
tank-breathing losses); manufacturing (solvents); and surface coating
(spray painting and dipping).
Three primary control technologies
are used for VOC: thermal oxidation;
adsorption via activated carbon or
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New Orleans Morial Convention Center
September 24 28, 2016
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66
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Emission
Organic vapors
Organic vapors
Particulate matter
Acid gases
Submicron liquid aerosols
Particulate matter
Particulate matter
Particulate matter
Pressure drop
1 in. water column (w.c.)
15 in. w.c.
1080 in. w.c.
26 in. w.c.
10 in. w.c.
48 in. w.c.
1 in. w.c. per stage
1 in. w.c. per stage
Pressure
Drop, in. w.c.
10 in.
60 in.
7 in.
Particulate
loading, gr/dscf
<0.08
<0.02
<0.02
Motor
horsepower
75
400
50
emissions do not exceed limits. Capture tests can be eliminated if a permanent total enclosure (PTE) is used
to prevent VOC losses in a manufacturing environment. For tank farms,
conservation vents reduce losses to
the ductwork system [7].
Condensing systems return the
vapor back into a usable liquid; however, they only work on vent streams
with relatively high concentrations
(for instance, 50 vol.% VOC). Carbon and zeolite adsorbers capture
the VOCs temporarily, then release
them when the adsorbent is heated
with steam or hot air. Some of these
systems can concentrate the material sufficiently for recovery while others send the concentrated vapors to
thermal oxidizers.
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67
John Zink
Durr Environmental
Independent burners
Clean
process air
Purge air
Heat
exchange
media
Auxiliary systems
Fans and blowers. These components are of prime importance because they move both the air into a
combustor and the fluegas or process vent streams out of it. Combustion air is supplied by either a
forced-draft fan, an induced-draft
fan or both.
Fans may be driven by electric
motors or in large sizes, steam turbines. The speed of the fan may be
variable or fixed. Fixed-speed fans
Tri-Mer
Particulate
captured
on filter
surface
Nano-catalysts embedded
in the walls of the filter
PM does not
penetrate walls
of the filter
Airflow
Airflow
Multi-pollutant control
While individual APC components
can be placed in series to get the job
done, single units with multiple capabilities also exist. An example are fil68
FIGURE 10. This example of an all-in-one, multi-pollutant-removal system uses reagent injection and
catalytic bag filters
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PROTECT PUMPS
DRYRUNNINGCAVITATIONBEARINGFAILUREOVERLOAD
MONITOR PUMP POWER
BestSensitivity
DigitalDisplay
PUMP POWER
AMPS
POWER
VALVE CLOSING
PUMPING
FULL LOAD
VALVE OPENING
No Sensitivity
For Low Loads
NO LOAD
NO FLUID
FULL LOAD
CHEMICAL ENGINEERING
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69
70
Closing thoughts
When selecting new APC or upgrading old, look first at your regulatory
limits, then factor in the characteristics of the fume, and all the pollutants that must be controlled. Then
select candidate systems, and estimate capital and operating costs
before making your final, welln
informed choice.
Edited by Suzanne Shelley
References
1. McGowan, Thomas F., D. Coughlin, B. Axon, T.
Wechsler and J. Santoleri, VOC Emission Controls
for the CPI, Chem. Eng., February 2007.
2. McGowan, T., Chief Editor, Biomass and Alternate Fuels Systems: An Engineering and Economic
Guide, AIChE/John Wiley & Sons, 2009, ISBN: 9780-470-41028-8. Associate Editors Brown, M., Bulpitt, W., and Walsh Jr.
CHEMICAL ENGINEERING
3. McGowan, Thomas F., Charting a Path for Costeffective NOx Control, Chem. Eng., October, 2004.
4. U.S. EPA AP-42, Emission Factors; by chapter and
fuel type (www.epa.gov/ttn/chief/ap42/ch01/) and
by industry (www.epa.gov/ttn/chief/ap42/).
5. McGowan, Thomas F., VOC and Air Toxics Control by
Oxidation and Other Methods, Air Pollution Control,
September 2014.
6. McGowan, Thomas F., Oxidizers for Control of VOCs
and Other Air Toxics: Application and Design, Process Heating, October 2013.
7. Industrial Ventilation: A Manual of Recommended
Practice for Design, 28th Ed., www.acgih.org/
Author
Thomas F. McGowan is president
and founder of TMTS Associates
Inc. (399 Pavillion St., Atlanta, GA
30315; Phone: 404-627-4722;
Email:
tmtsassociates1000@
mindspring.com; www.tmtsassociates.com), a firm that specializes in thermal systems and airpollution control. He was
previously employed by RMT/Four
Nines, the Georgia Tech Research Institute, and Particulate Solid Research, Inc. McGowan has 40 years of experience in air-pollution control, filtration, combustion,
and bulk-solids handling. He holds an M.S.Ch.E. from
Manhattan College in New York City, and an M.S. in
industrial management from Georgia Tech.
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