mining and exploration companies, operates Environmental, Oil, Food and Pharmaceutical laboratory
divisions. The ALS group of companies is owned by Campbell Brothers Limited, a publicly listed Australian
company (ASX code CPB on the Australian Stock Exchange).
ALS Chemex was formed in 1999 through the acquisition of Chemex Labs and the subsequent merger of
Chemex laboratories with the existing ALS Mineral laboratories. Since that time the operations have been
fully integrated to the point where we can now present a single Schedule of Services to the mining and
exploration industry. These services are now provided from our locations in North and South America,
Australia, Asia and Africa. This worldwide coverage puts us in a unique position to be able to provide you
with the same consistency of service no matter where your projects may be situated.
The combined expertise of ALS Chemex has enabled us to put together a very comprehensive list of
services. Innovative new packages allow you to tailor our services to your exploration and mining needs.
The services for exploration geochemistry have been expanded to include the most comprehensive range of
total, partial and selective leach multi-element packages commercially available. With state-of-the-art
equipment we have pushed sensitivities to the lowest practical levels, while resisting the temptation to list
artificially low sensitivities that only reflect instrument capabilities for ultra-pure solutions, rather than the
complex matrices that are obtained from the digestion of geological materials.
In order to provide you with the lowest possible price in each geographic region where we operate, we have
produced a number of different Fee Schedules. These Fee Schedules can be obtained by contacting the
nearest ALS Chemex office, and will also be available on-line at our global website www.alschemex.com.
Corporate Office
212 Brooksbank Avenue
North Vancouver, BC, Canada V7J 2C1
Table of Contents
SAMPLE TRACKING SYSTEM ...........................................................................4
QUALITY ASSURANCE.......................................................................................4
SAMPLE PREPARATION ....................................................................................5
SAMPLE PREPARATION PACKAGES ........................................................................ 5
SAMPLE PREPARATION PROCEDURES.................................................................... 5
Drying ........................................................................................................................ 5
Crushing .................................................................................................................... 6
Splitting...................................................................................................................... 6
Pulverization .............................................................................................................. 6
Screening .................................................................................................................. 7
Miscellaneous Procedures......................................................................................... 7
SAMPLE STORAGE...................................................................................................... 7
PRECIOUS METALS............................................................................................9
Canada
USA
Mexico
Additional ISO 9002
certification in
Peru
Australia
NATA Registration in
Australia
GOLD ............................................................................................................................ 9
Fire Assay ................................................................................................................. 9
Aqua Regia Digestion .............................................................................................. 10
Cyanide Leach......................................................................................................... 10
SILVER........................................................................................................................ 11
Trace level............................................................................................................... 11
Ore grade ................................................................................................................ 11
Concentrates ........................................................................................................... 11
Bullion...................................................................................................................... 11
PLATINUM, PALLADIUM AND OTHER PRECIOUS METALS ................................... 11
Trace level............................................................................................................... 11
Ore grade ................................................................................................................ 11
COPPER.............................................................................................................12
COPPER IN GEOLOGICAL MATERIALS ................................................................... 12
COPPER CATHODES ................................................................................................. 12
Description
Application
All samples.
Quality Assurance
ALS Chemex laboratories operate according to the guidelines set out in ISO/IEC Guide 25 - "General
requirements for the competence of calibration and testing laboratories". The ALS Chemex quality system is
implemented across all laboratory sites. QA staff control monthly inter-laboratory test programs covering both
gold and base metal determinations and monitor the quality control data generated by the laboratories.
Regular internal method audits are also undertaken to ensure compliance with documented procedures.
Each laboratory employs a comprehensive quality control program covering both sample preparation and
analysis. Sample preparation procedures include the use of a barren wash of sample preparation equipment
between sample batches and, where necessary, between highly mineralized samples. Quality assurance of
the analytical process requires the use of appropriate reference materials to monitor accuracy and replicate
analyses to monitor precision. ALS Chemex maintains an extensive library of international and in-house
standards. For large projects ALS Chemex will prepare a standard from the client's own material to ensure a
matrix match.
Sample Preparation
The purpose of sample preparation is to produce a
homogeneous sub-sample that is fully representative of
the original field material, and at the same time, suitable
for laboratory analysis. Our staff ensure that this purpose
is achieved by 1) strict adherence to standard operating
procedures, 2) by using state-of-the-art sample
preparation equipment and dust collection systems, and
3) by maintaining strict sample tracking and quality
control systems. To assist clients in selecting the best
procedures, we recommend they discuss their sample
preparation requirements with our staff. Below are the
most commonly used procedures.
Sample Preparation Packages
The packages described below are used to produce a sub-sample ready for analysis.
Code
Description
Application
PREP-21
PREP-22
PREP-31
PREP-41
Drying
Drying charges are applied only to samples that are excessively wet.
Code
Description
Application
DRY-21
DRY-22
DRY-23
Air-drying of samples.
Crushing
Samples that are too coarse to be put directly into a large pulverizing mill, or where the particle size needs to
be reduced before we are able to take a representative split for further pulverization, are crushed using jaw
and/or rolls crushers.
Code
Description
Application
CRU-21
CRU-31
CRU-32
Splitting
Some samples require the division of one or more size fractions into representative splits.
Code
Description
Application
SPL-21
SPL-22
Pulverization
All pulverization procedures make use of flying disk or ring and puck style grinding mills. Unless otherwise
indicated, all pulverization procedures guarantee that for most sample types at least 85% of the material will
be pulverized to better than 75 micron (200 Mesh).
Code
Description
Application
PUL-31
PUL-32
Pulverization of 1 kg split.
PUL-21
Screening
For some sample types, one or more particular size fractions need to be separated from the bulk sample.
Other mesh sizes, as well as multiple screening procedures are also available.
Code
Description
Application
SCR-41
SCR-42
SCR-43
SCR-45
SCR-31
Miscellaneous Procedures
Code
Description
Application
CMP-21
CMP-22
Volumetric procedure
Gravimetric procedure
WSH-21
WSH-22
TRA-21
Sample Storage
Materials that have been submitted for analysis are retained at our laboratories for a limited time only. The
prepared master pulps are stored free of charge for 90 days from the time that we issue the final certificate of
analysis. Coarse and fine reject fractions are stored free of charge for the first 90 days, except for large reject
fractions (>3 Kg) which are stored for a nominal charge. Monthly charges will be levied for storage of all
sample types beyond the first 90 days.
Code
Description
Application
STO-21
STO-22
STO-23
STO-24
RET-21
Archived samples.
DIS-21
RTN-21
Returned samples.
Description
Application
PKP-21
Sample Dispatch
Samples can be dispatched to any of the addresses listed in the back cover. Free pre-addressed adhesive
labels and sample submission booklets are available on request. We also offer advice on shipping samples
to any of our labs by surface carrier, air cargo courier and air cargo.
To expedite sample processing and therefore delivery of results, please clearly mark sample bags using
waterproof ink. In addition to marking the outside of the bag, the use of assay tags inside sample bags is
strongly encouraged. Fill out and enclose the sample submittal form with each sample shipment. Include
your return address, billing instructions and the type of analyses required for the enclosed samples. Retain a
copy of the sample submittal form as a field record. Clearly mark all international sample shipments to our
offices in the Americas as "GEOLOGICAL MATERIALS - NO COMMERCIAL VALUE".
For sample
shipments to our offices in Australia, mark as GEOLOGICAL MATERIALS, but indicate a nominal dollar
value, such as US$25.00
On-site Sample Preparation
For remote project locations, ALS Chemex can also assist by installing a fully supervised on-site sample
preparation facility. This will ensure that the samples you submit for assay are representative of the actual
material recovered from your drill holes and delivered to the preparation facility. We will prepare your
samples according to mutually agreed upon procedures, pack the pulps to ensure that they are tamper proof
and air freight them to the ALS Chemex laboratory of your choice. Residual material will be correctly labelled
for future reference and records will be provided to ensure that an accurate audit trail exists.
The size of the sample preparation facility and the equipment to be installed will depend on the metal(s)
being sought, the type and size of the samples being submitted and the expected sample throughput.
Location may also have a bearing on the type of facility and on the equipment to be installed. These details
can be decided upon consultation with appropriate ALS Chemex management.
Description
Au-MS21
Au-MS22
Trace level
Au by fire assay and ICP-MS.
30 g nominal sample weight.
50 g nominal sample weight.
Au by fire assay, solvent extraction and AAS.
30 g nominal sample weight.
50 g nominal sample weight.
0.001 - 1
Au-AA21
Au-AA22
0.005 - 10
Au-AA23
Au-AA24
Range (ppm)
0.001 - 2
0.01 - 100
Au-AA25
Au-AA26
Au-GRA21*
Au-GRA22*
0.05 - 1,000
Au-SCR21*
Au-SCR22*
Au-GRA23*
Concentrates
Au by fire assay and gravimetric finish. 30 g nominal sample weight.
1 - 15,000
Au-GRA24*
Bullion (fineness)
Au in bullion samples by fire assay and gravimetric finish.
Fineness 1-1,000
Description
Range (ppm)
0.0001 - 0.1
Au-ZF41
Au-ZF42
Au-GF41
Au-GF42
Trace level
Au by aqua-regia digestion, extraction and graphite furnace AAS.
25 g nominal sample weight.
50 g nominal sample weight.
Au-AA41
Au-AA42
Ore grade
Au by aqua-regia digestion, solvent extraction and AAS.
25 g nominal sample weight.
50 g nominal sample weight.
0.001 - 1
0.01 - 100
Samples containing sulfidic, carbonaceous or organic material require the roasting procedure RST-21 as an
additional preparation step prior to the aqua-regia digestion.
Cyanide Leach
Cyanide leach procedures are used in grass roots exploration where cyanide extractable gold from a very
large sample can sometimes detect small gold anomalies that otherwise would go unnoticed, and in mine
development and exploration to establish potential gold cyanide extraction efficiency.
Method code
Description
Range (ppm)
Au-AA11*
Trace level
Au by cyanide leach, extraction and AAS.
500 g nominal sample weight.
0.001 - 10
Au-AA12*
0.0001 10
Au-ZF13*
0.00005 1
Au-AA13*
Ore grade
Au by cyanide leach and AAS. 30 g nominal sample weight.
0.03 50
Au-AA14
0.01 200
Au-AA15
0.01 300
Metallurgical Samples
Method code
Description
Range (ppm)
Au-AA16
Cyanide liquors
Au in liquor by extraction and AAS.
0.01 - 50
Au-AA27
0.01 - 50
Au-AA44
Carbons
Au by ashing, aqua-regia digestion and AAS. Duplicate analysis.
1 - 1,000
10
Silver
Method code
Description
Range (ppm)
Ag-AA45
Trace level
Ag by aqua-regia digestion and AAS.
0.2 - 100
Ag-AA61
0.5 - 100
Ag-AA46
Ore grade
Ag by aqua-regia digestion and AAS.
1 - 1,500
Ag-AA62
1 - 1,000
5 3,500
Ag-GRA21*
Ag-GRA22*
Ag-GRA23*
Ag-GRA24*
1 - 15,000
Fineness 1-1,000
Description
Range (ppm)
Trace level
Pt, Pd and Au by fire assay and ICP-MS.
Pt
Pd
Au
(0.0005 - 1)
(0.001 - 1)
(0.001 - 1)
PGM-MS23
PGM-MS24
Rh-MS25
0.001 - 1
PGM-MS26
Pt
Pd
Ir
Os
(0.002 - 1)
(0.002 - 1)
(0.002 - 1)
(0.002 - 1)
Pt
Pd
Au
(0.05 - 100)
(0.05 - 100)
(0.05 - 100)
PGM-MS27
Ore grade
Pt, Pd and Au by fire assay and ICP-MS. 30 g
nominal sample weight.
Rh
Ru
Au
(0.002 - 1)
(0.002 - 1)
(0.005 - 1)
At your option, precious metals reporting units can be specified as ppb, ppm, g/t or oz/t (except for bullion assays).
Using proprietary custom designed fire assay systems, ALS Chemex has sufficient capacity to
provide superb turnaround times for any size project, anywhere in the world. However, if your project
requires on-site fire assay services we can work with you to design a highly efficient semi-automatic
system that will minimize in-the field labour expenses, while maximizing efficiency and throughput.
From design, construction, on-site training or on-site management, ALS Chemex has the experience
and the resources to assist you with your on-site analytical requirements.
11
Description
Range (ppm)
Cu-AA45
Trace level
Cu by aqua-regia digestion and AAS.
1 - 10,000
Cu-AA61
1 - 10,000
See pages 13-15 for multi-element methods that include Cu at trace and ultra-trace levels
Cu-AA46
Ore grade
Cu by aqua regia digestion and AAS.
Cu-AA62
Cu-ICP81
50 ppm - 30%
Cu-AA04
Cu-AA05
10 ppm - 10%
Cu-AA17
Cu-PKG06
Cu-VOL61
Cu-ELE61
Concentrates
Cu by HNO3-HCl-HClO4-H2SO4 acid digestion, formation of iron
complex and volumetric finish.
Copper Cathodes
Method code
Description
ME-PKG07
Cu plus 21 elements in
copper cathodes, according
to BSI 7317.
Cu
Ag
As
Bi
C
Cd
(0.01%)
(0.3)
(0.2)
(0.1)
(2)
(0.2)
Cl
Co
Cr
Fe
Mn
Ni
(5)
(0.8)
(1.0)
(0.5)
(0.4)
(0.8)
O2
Pb
P
S
Sb
Se
(2)
(0.3)
(1)
(1)
(0.2)
(0.1)
Si
Sn
Te
Zn
(2)
(0.2)
(0.1)
(1)
In addition to copper cathode analysis, physical inspection of copper cathodes is also available.
Please contact the nearest ALS Chemex office for details.
12
Exploration Geochemistry
13
(1 - 1,000)
(0.1 - 1,000)
(1 - 10,000)
(0.1 - 1,000)
(0.5 - 10,000)
(0.1 - 1,000)
(2 - 10,000)
(1 - 10,000)
(0.5 - 10,000)
(5 - 10,000)
Pb
Pr
Rb
Sm
Sn
Sr
Ta
Tb
Th
(5 - 10,000)
(0.1 - 1,000)
(0.2 - 10,000)
(0.1 - 1,000)
(1 - 10,000)
(0.1 - 10,000)
(0.5 - 10,000)
(0.1 - 1,000)
(1 - 1,000)
Tl
Tm
U
V
W
Y
Yb
Zn
Zr
(0.5 - 1,000)
(0.1 - 1,000)
(0.5 - 1,000)
(5 - 10,000)
(1 - 10,000)
(0.5 - 10,000)
(0.1 - 1,000)
(5 - 10,000)
(0.5 - 10,000)
14
15
(0.1 - 200)
(1 - 10,000)
(1 - 10,000)
(0.01% - 15%)
Mg
Mn
Mo
Ni
(0.01% - 15%)
(5 - 10,000)
(1 - 10,000)
(1 - 10,000)
Pb
Sb
Zn
(1 - 10,000)
(5 - 10,000)
(1 - 10,000)
(1 - 10,000)
(1 - 10,000)
(0.01% - 15%)
(0.01% - 15%)
Mn
Mo
Ni
P
(5 - 10,000)
(1 - 10,000)
(1 - 10,000)
(10 - 10,000)
Pb
S
Sb
Zn
(1 - 10,000)
(0.01% - 10%)
(2 - 10,000)
(1 - 10,000)
Inductively Coupled Plasma with Mass Spectrometry and/or Atomic Emission Spectroscopy are the
analytical techniques of choice for multi-element analysis at ultra-trace and trace levels.
16
Ag
As
Bi
Ca*
Cd
Co
Cu
Fe
Mg*
Mn
Mo
Ni
P
Pb
S*
Sb*
Zn
Description
Silver
Arsenic
Bismuth
Calcium
Cadmium
Cobalt
Copper
Iron
Magnesium
Manganese
Molybdenum
Nickel
Phosphorus
Lead
Sulfur
Antimony
Zinc
Grassroots exploration
Method code
Range (ppm)
Ag-AA45
0.2 - 100
As-AA45
1 - 10,000
Cd-AA45
Co-AA45
Cu-AA45
Fe-AA45
0.1 - 200
1 - 10,000
1 - 10,000
0.01% - 15%
Mn-AA45
Mo-AA45
Ni-AA45
5 - 10,000
1 - 10,000
1 - 10,000
Pb-AA45
1 - 10,000
Sb-AA45
Zn-AA45
5 - 10,000
1 - 10,000
Geochemical characterization
Method code
Range (ppm)
Ag-AA47
1 - 100
As-AA47
2 - 10,000
Bi-AA47
5 - 10,000
Ca-AA47
0.01% - 15%
Cd-AA47
1 - 10,000
Co-AA47
5 - 10,000
Cu-AA47
2 - 10,000
Fe-AA47
0.01% - 15%
Mg-AA47
0.01% - 15%
Mn-AA47
5 - 10,000
Mo-AA47
5 - 10,000
Ni-AA47
5 - 10,000
P-AA47
10 - 10,000
Pb-AA47
10 - 10,000
S-AA47
10 - 10,000
Sb-AA47
5 - 10,000
Zn-AA47
5 - 10,000
*Depending on matrix, elements marked with * are more likely to represent only the acid leachabe fraction
Ag
Al
As
Ba
Bi
Ca
Cd
Co
Cr
Cu
Fe
K
Mg
Mn
Mo
Na
Ni
P
Pb
S
Sb
Sr
Ti
V
W
Zn
Zr
Element
Silver
Aluminum
Arsenic
Barium
Bismuth
Calcium
Cadmium
Cobalt
Chromium
Copper
Iron
Potassium
Magnesium
Manganese
Molybdenum
Sodium
Nickel
Phosphorus
Lead
Sulfur
Antimony
Strontium
Titanium
Vanadium
Tungsten
Zinc
Zirconium
Grassroots exploration
Method code
Range (ppm)
Ag-AA61
0.5 - 100
Ba-AA61
10 - 10,000
Ca-AA61
0.01% - 15%
Co-AA61
Cr-AA61
Cu-AA61
Fe-AA61
2 - 10,000
2 - 10,000
1 - 10,000
0.01% - 15%
Mg-AA61
0.01% - 15%
Mo-AA61
2 - 10,000
Ni-AA61
2 - 10,000
Pb-AA61
2 - 10,000
Sr-AA61
1 - 10,000
V-AA61
5 - 10,000
Zn-AA61
5 - 10,000
17
Geochemical characterization
Method code
Range (ppm)
Ag-AA63
1 - 100
Al-AA63
0.01% - 25%
As-AA63
5 - 10,000
Ba-AA63
10 - 10,000
Bi-AA63
5 - 10,000
Ca-AA63
0.01% - 25%
Cd-AA63
5 - 500
Co-AA63
5 - 10,000
Cr-AA63
5 - 10,000
Cu-AA63
5 - 10,000
Fe-AA63
0.01% - 25%
K-AA63
0.01% - 10%
Mg-AA63
0.01% - 15%
Mn-AA63
5 - 10,000
Mo-AA63
5 - 10,000
Na-AA63
0.01% - 10%
Ni-AA63
5 - 10,000
P-AA63
10 - 10,000
Pb-AA63
5 - 10,000
S-AA63
0.01% - 5%
Sb-AA63
5 - 1,000
Sr-AA63
10 - 10,000
Ti-AA63
0.01% - 10%
V-AA63
10 - 10,000
W-AA63
10 - 10,000
Zn-AA63
5 - 10,000
Zr-AA63
20 - 10,000
Element
Arsenic
Bismuth
Gallium
Germanium
Antimony
Selenium
Tin
Tantalum
Tellurium
Thallium
Tungsten
Method code
As-MS62
Bi-MS62
Ga-MS62
Ge-MS62
Sb-MS62
Se-MS62
Sn-MS62
Ta-MS62
Te-MS62
Tl-MS62
W-MS62
Range (ppm)
0.5 - 10,000
0.02 - 2,500
0.1 - 2,500
0.1 - 2,500
0.1 - 2,500
1 - 2,500
0.5 - 2,500
0.2 - 500
0.05 - 2,500
0.05 - 2,500
0.1 - 2,500
Description
Arsenic
Barium
Cerium
Lanthanum
Niobium
Rubidium
Thorium
Uranium
Tungsten
Yttrium
Zirconium
Method code
As-XRF05
Ba-XRF05
Ce-XRF05
La-XRF05
Nb-XRF05
Rb-XRF05
Th-XRF05
U-XRF05
W-XRF05
Y-XRF05
Zr-XRF05
Range (ppm)
5 - 5,000
10 - 10,000
10 - 10,000
10 - 10,000
10 - 10,000
2 - 10,000
4 - 10,000
4 - 10,000
10 - 10,000
2 - 10,000
10 - 10,000
Hg
pH
eH
U
LOI
F
Br
Cl
I
Description
Mercury / cold vapor
Soil pH (1:1 ratio)
Soil Conductivity
Uranium / DNC-NAA
LOI at 1000 oC
Fluorine / electrochem.
Bromine / NAA
Chlorine / NAA
Iodine / NAA
Method
code
Hg-CV41
OA-ELE05
OA-ELE06
U-DNC05
OA-GRA05
F-ELE81
Br-NAA05
Cl-NAA06
I-NAA07
Range (ppm)
0.01 - 100
0.2 - 1,000
0.01% - 100%
20 - 10,000
0.5 - 10,000
100 - 10,000
20 - 10,000
18
ME-ICP06
Si
Al
Fe
Ca
Mg
Na
K
SiO2
Al2O3
Fe2O3
CaO
MgO
Na2O
K2O
(0.01 - 100)
(0.01 - 100)
(0.01 - 100)
(0.01 - 100)
(0.01 - 100)
(0.01 - 100)
(0.01 - 100)
Cr
Cr2O3
(0.01 - 100)
Ti
TiO2
(0.01 - 100)
Mn MnO
(0.01 - 100)
P
P2O5
(0.01 - 100)
Sr
SrO
(0.01 - 100)
Ba
BaO
(0.01 - 100)
Loss on Ignition (0.01 - 100)
Method code
Element or
Parameter
Description
Range (%)
C-IR07
0.01 - 50
C-GAS05
0.2 - 50
Fe-VOL05
FeO
0.01 - 100
OA-IR05
H2O
0.01 - 100
OA-IR06
H2O
0.01 - 100
0.01 - 50
S-IR08
(0.1 - 1,000)
(0.5 - 10,000)
(0.1 - 1,000)
(0.5 - 10,000)
Pr
Sm
Tb
Th
19
(0.1 - 1,000)
(0.1 - 1,000)
(0.1 - 1,000)
(1 - 1,000)
Tm
U
Y
Yb
(0.1 - 1,000)
(0.5 - 1,000)
(0.5 - 1,000)
(0.1 - 1,000)
Geochronology
We are pleased to offer a new and exciting service to our clients in 2001. Geochronology is becoming ever
more useful in the overall picture for mineral exploration as well as in its traditional use in research and
academia. We can now offer U-Pb dating and Pb isotopic analyses at very competitive rates and attractive
turnaround times through a mutually exclusive contract with the Geochronology Laboratory at the University
of British Columbia, a facility with more than 20 years of experience and expertise providing radiogenic age
and isotopic data to the mining, exploration and geological communities.
The selection of specific isotopic systems is crucial for
your overall dating strategy and we recommend that
clients contact us for a consultation prior to submitting
samples. We also have information on our website that
will assist you in choosing the right method for your
particular application. Sampling strategy design and
data interpretation of regional isotopic data sets are
also available on a consulting basis.
Method code
Description
GMS01
U - Pb age determination.
GMS02
GMS03
U Pb dating.
U-Pb geochronology of zircons and other accessory minerals is generally accepted as the best method for
determining precise, absolute crystallization ages for a wide variety of volcanic and plutonic rocks. The U-Pb
method is extremely robust, and it is usually possible to obtain the original crystallization age of rock units
despite strong weathering, hydrothermal alteration, or metamorphism. The range of application of this
technique includes dating most intermediate to felsic intrusive and extrusive rocks, some mafic intrusive
rocks and regional metamorphic events. In some cases it is also possible to obtain U-Pb ages for perovskite
from kimberlite samples, or hydrothermal minerals such as rutile or cassiterite. For specialized U-Pb dating
investigations such as these we highly recommend discussions of sampling strategy prior to submitting
samples. As some samples have complex isotopic systematics, we will choose the number of individual
zircon fractions required to produce an acceptable date for each sample submitted. Accessory phases such
as titanite and monazite may also be analyzed. This service includes all mineral separation. For samples
which do not yield datable minerals, cost will be for mineral separation only. A table of analytical data, a U-Pb
concordia plot or U-Pb isochron diagram of the data and a brief age interpretation are distributed to the
client.
Pb isotopic analyses.
Common lead studies have applications in both igneous petrology and mineral deposit studies. Lead isotopic
studies well constrained by geology can provide important information regarding the relative age and
source(s) of metals in a deposit, can relate different mineral occurrences within a district or link various styles
of mineralization to genetically related magmatic suites. Lead isotopic signatures may also be used on a
reconnaissance scale to isotopically fingerprint specific styles of mineralization. We offer two types of
common lead analysis:
Galena Pb analyses (model ages meaningful for some styles of syngenetic mineralization may be
calculated)
trace Pb isotopic analyses on materials including (but not limited to) whole rocks, feldspar separates,
soils, nongalena sulphide or sulphosalt samples, and other minerals containing lead (some minerals
pose problems during dissolution refer to our website for details).
A table of data is distributed to the client and consulting services such as geological interpretation of the data
are also available.
20
ICP-MS provides the ultra-trace detection limits that are necessary for selective leach geochemistry.
21
Non-Proprietary Methods
Cold hydroxylamine hydrochloride
The cold hydroxylamine leach has been used extensively by explorationists because it is selective for
manganese oxides, long known to be powerful scavengers of heavy metals of geochemical significance.
Manganese forms several oxidation states and exists in a variety of amorphous and crystalline forms. As a
result manganese oxide has an extraordinarily high cation exchange capacity, accommodating many
different trace elements on its surfaces. This leach does not dissolve crystalline iron oxides but does dissolve
very small amounts of amorphous hydrous iron oxide.
Hot hydroxylamine hydrochloride
The hot hydroxylamine leach, which combines a higher concentration of hydroxylamine with elevated
temperature (60C) and a reducing acid environment, is capable of effectively dissolving amorphous
hydrous iron oxide while leaving crystalline iron oxide substantially intact (typically <1% dissolution). As
amorphous hydrous iron oxide is a much more effective scavenger than crystalline forms of iron oxide, this
leach can be quite informative about metal ion mobility.
Sodium Pyrophosphate
Organic matter in soils and sediments is capable of forming chelation complexes with metals. A solution of
neutral (pH 7) sodium pyrophosphate liberates these organically-bound heavy metals. Variations in the
concentrations of organically-bound metals such as copper, zinc, cobalt, nickel, iron and aluminum have
been used as indications of buried mineral deposits. Extraction with pyrophosphate does not attack sulfides
nor does it dissolve significant amounts of amorphous iron oxides.
Method code
Description
ME-MS05
ME-MS06
ME-MS07
Ag
Al
As
Au
B
Ba
Be
Bi
Br
Ca
Cd
Ce
Co
Cr
Cs
Cu
(0.002)
(1)
(0.1)
(0.05)
(2)
(0.05)
(0.05)
(0.005)
(2)
(10)
(0.01)
(0.005)
(0.05)
(0.05)
(0.005)
(0.05)
22
Dy
Er
Eu
Fe
Ga
Gd
Ge
Hf
Hg
Ho
I
In
K
La
Li
Lu
(0.005)
(0.005)
(0.005)
(5)
(0.05)
(0.005)
(0.1)
(0.01)
(0.1)
(0.005)
(0.1)
(0.005)
(5)
(0.005)
(0.05)
(0.005)
Mg
Mn
Mo
Na
Nb
Nd
Ni
P
Pb
Pr
Rb
Re
Sb
Se
Sm
Sn
(1)
(0.1)
(0.01)
(10)
(0.01)
(0.005)
(0.05)
(5)
(0.1)
(0.005)
(0.01)
(0.001)
(0.005)
(0.5)
(0.005)
(0.05)
Sr (0.05)
Ta (0.01)
Tb (0.005)
Te (0.05)
Th (0.01)
Ti (1)
Tl (0.005)
Tm (0.005)
U
(0.005)
V
(0.05)
W (0.01)
Y
(0.005)
Yb (0.005)
Zn (0.2)
Zr (0.05)
Final pH
Proprietary Methods
Regoleach
Description
ME-MS08
Regoleach
and ICP-MS.
Ag
As
Au
Ba
Bi
Ca
Cd
(0.005)
(0.005)
(0.001)
(1)
(0.005)
(1)
(0.005)
Ce
Co
Cr
Cu
Fe
Hg
K
(0.1)
(0.01)
(0.01)
(0.01)
(5)
(0.005)
(1)
La
Mg
Mn
Mo
Na
Nb
Ni
(0.1)
(1)
(1)
(0.01)
(1)
(0.01)
(0.01)
Pb
Pt
S
Sb
Se
Sn
Sr
(0.01)
(0.001)
(1)
(0.005)
(0.005)
(0.005)
(1)
Te
Tl
U
W
Zn
(0.005)
(0.005)
(0.01)
(0.005)
(0.05)
Description
ME-MS09
Cu
Pb
(0.01)
(0.01)
Zn
Cd
(0.02)
(0.001)
ME-MS10
Au
Ag
Pd
(0.0001)
(0.0001)
(0.0001)
Ni
Co
(0.003)
(0.00025)
ME-MS11
Cu
Pb
(0.01)
(0.01)
Zn
Cd
(0.02)
(0.001)
ME-MS12
Ni
Co
Pd
Nb
(0.003)
(0.00025)
(0.0001)
(0.0001)
Cr
Mg
Y
Rb
(0.001)
(0.01)
(0.0001)
(0.0001)
ME-MS13
As
Sb
Hg
(0.001)
(0.001)
(0.003)
Mo (0.005)
Se (0.002)
Fe (0.1)
ME-MS15
U
Th
Pb
(0.001)
(0.001)
(0.01)
Ta
Sn
W
23
(0.0002)
(0.0002)
(0.0002)
Hydrogeochemistry
The methods below are used for the geochemical analysis of ground water samples during mineral
exploration. These methods are not suitable for water samples with high metal content or for environmental
samples. In order to check for possible sample contamination, we suggest the use of a trip blank, i.e., a
distilled water sample that travels to the sampling site and is sent together with the actual water samples to
the lab.
Method code
ME-PKG05
Method code
ME-MS14
(10)
(1)
(10)
(10)
Mo
Ni
Pb
Se
(50)
(10)
(50)
(1)
Sr
Ti
V
Zn
(1)
(10)
(10)
(1)
Pb
Pr
Rb
Sb
Sc
Se
Sm
Sn
Sr
Ta
Tb
(0.01)
(0.01)
(0.1)
(0.1)
(0.1)
(0.1)
(0.01)
(0.01)
(0.01)
(0.01)
(0.01)
Te
Th
Tl
Tm
U
V
W
Y
Yb
Zn
Zr
(0.1)
(0.01)
(0.01)
(0.01)
(0.01)
(0.1)
(0.01)
(0.01)
(0.01)
(0.1)
(0.1)
(0.01)
(10)
(0.05)
(0.5)
(0.1)
(1)
(50)
(0.01)
(0.01)
(0.1)
(100)
24
Method code
ME-MS63
Method code
ME-MS81d
(0.01% - 25%)
(0.1 - 500)
(0.01% - 10%)
(0.5 - 500)
(0.01% - 15%)
(5 - 10,000)
Na
Nb
Ni
P
Rb
Sr
(0.01% - 10%)
(0.1 - 500)
(0.2 - 10,000)
(10 -10,000)
(0.1 - 500)
(0.2 - 10,000)
Ti
V
W
Y
Zn
Zr
(0.01% - 10%)
(1 - 10,000)
(0.1 - 10,000)
(0.1 - 500)
(2 - 10,000)
(0.5 - 500)
(0.01 - 100%)
(1 - 1,000)
(0.1 - 1,000)
(1 - 10,000)
(0.1 - 1,000)
(0.01% - 100%)
(0.5 - 10,000)
(0.1 - 1,000)
(0.01% - 100%)
(0.01% - 100%)
Nb
Nd
Ni
P
Pr
Rb
Sm
Sn
Sr
Ta
(1 - 10,000)
(0.5 - 10,000)
(5 - 10,000)
(10 - 10,000)
(0.1 - 1,000)
(0.2 - 10,000)
(0.1 - 1,000)
(1 - 10,000)
(0.1 - 10,000)
(0.5 - 10,000)
Tb
Th
Tm
U
V
W
Y
Yb
Zn
Zr
(0.1 - 1,000)
(1 - 1,000)
(0.1 - 1,000)
(0.5 - 1,000)
(5 - 10,000)
(1 - 10,000)
(0.5 - 10,000)
(0.1 - 1,000)
(5 - 10,000)
(0.5 - 10,000)
Method code
Description
ME-MS12
Ni
Co
Pd
Nb
25
(0.003)
(0.00025)
(0.0001)
(0.0001)
Cr
Mg
Y
Rb
(0.001)
(0.01)
(0.0001)
(0.0001)
Code
Element or parameter
and description
Range (%)
Element or parameter
and description
Code
Range (%)
Ag-AA46
Ag Aqua regia - AA
1 - 1,500**
Mg-AA62
Mg* HF-HNO3-HClO4 - AA
0.01 - 50
Ag-AA62
Ag HF-HNO3-HClO4 - AA
1 - 1,000**
Mg-ICP81
0.01 - 30
Ag-GRA21
0.01 - 50
Al-AA62
Al* HF-HNO3-HClO4 - AA
0.01 - 50
5- - 3,500**- Mn-AA46
Mn-AA62
Mn* HF-HNO3-HClO4 - AA
0.01 - 50
Al-ICP81
0.01 - 30
Mn-ICP81
0.01 - 30
As-AA46
As Aqua regia - AA
0.01 - 30
Mo-AA46
Mo Aqua regia - AA
0.001 - 10
0.01 - 20g/cm
Mo-AA62
Mo HF-HNO3-HClO4 - AA
0.001 - 10
Ba-XRF07
0.01 - 50
Na-AA62
Na* HF-HNO3-HClO4 - AA
0.001 - 30
Bi-AA46
Bi
Aqua regia - AA
0.001 - 30
Ni-AA62
Ni
HF-HNO3-HClO4 - AA
C-IR07
Total Carbon
0.01 - 50
Ni-ICP81
Ni
Fusion - ICPAES
C-CAL05
0.05 - 50
P-ICP62
P*
HF-HNO3-HClO4 - ICP
C-GAS05
Ca-AA62
Ca* HF-HNO3-HClO4 - AA
Ca-ICP81
Cd-AA46
0.01 - 30
0.005 - 30
0.01 - 50
0.2 - 50
Pb-AA46
Pb Aqua regia - AA
0.01 - 30
0.01 - 50
Pb-AA62
Pb HF-HNO3-HClO4 - AA
0.01 - 30
0.01 - 30
Pb-ICP81
Pb Fusion - ICPAES
0.01 - 30
Cd Aqua regia - AA
1 ppm - 10%
Pb-AA06
Pb Nonsulfide - AA
0.01 - 10
Cd-AA62
Cd HF-HNO3-HClO4 - AA
1 ppm - 10%
S-IR08
Co-AA62
Co HF-HNO3-HClO4 - AA
0.001 - 30
OA-CAL06
Co-ICP81
Co Fusion - ICPAES
0.002 - 30
0.01 - 50
Cr-AA81
Cr* Fusion AA
0.01 - 50
S-GRA07
0.01 - 100
Cu-AA46
Cu Aqua regia - AA
0.01 - 30
0.01 - 20g/cm
Cu-AA62
Cu HF-HNO3-HClO4 - AA
0.01 - 30
Sb-AA08
Sb KClO3-HCl - AA
0.01 - 20
Cu-ICP81
Cu Fusion - ICPAES
0.01 - 30
Si-AA81
Si* Fusion - AA
0.01 - 100
Cu-AA05
Cu Nonsulfide - AA
0.001 - 10
Sn-XRF08
0.01 - 50
Fe-AA46
Fe Aqua regia - AA
0.01 - 30
Sr-AA62
Sr
0.01 - 20
Fe-AA62
Fe HF-HNO3-HClO4 - AA
0.01 - 30
Ti-AA81
Ti* Fusion - AA
0.01 - 50
0.01 - 30
Fe-ICP81
Fe-VOL05
Fe Fusion - ICPAES
0.01 - 50
0.01 - 50
HF-HNO3-HClO4 - AA
0.05 - 30
V-AA62
W-XRF09
0.01 - 50
0.01 - 100
Zn-AA46
Zn
Aqua regia - AA
0.01 - 30
0.01 - 100
Zn-AA62
Zn
HF-HNO3-HClO4 - AA
0.01 - 30
0.01 - 30
Zn-ICP81
Zn
Fusion - ICPAES
0.01 - 30
Zn-AA07
Zn
Nonsulfide - AA
0.01 - 10
OA-IR06
0.01 - 100
OA-IR05
K-AA62
HF-HNO3-HClO4 - AA
o
0.1 - 100
HF-HNO3-HClO4 - AA
26
27
ABAPKG01
ABAPKG02
Method code
ABAPKG03
ABAPKG04
ABAPKG05
28
Elements
Method description
Au-GRA25
Au
Ag-GRA25
Ag
Au-GRA26
Au
Ag-GRA26
Ag
Au-GRA27
Au
Ag-GRA27
Ag
Cu-VOL64
Cu
Pb-VOL65
Pb
Zn-VOL81
Zn
Sample type
Elements/parameters
Method description
ME-ICP82
Analysis of
Production Rutile,
Synthetic Rutile and
Leucoxene.
Fusion, ICP-AES
ME-ICP83
Analysis of
production Zircon.
Fusion, ICP-AES
ME-ICP84
Analysis of
production Ilmenite.
Fusion, ICP-AES
ME-ICP94
Analysis of
Intermediate plant
products.
Fusion, ICP-AES
Sn-MS85
Various
SnO2
Fusion, ICPMS
Th-MS86
Various
ThO2
Fusion, ICPMS
U-MS87
Various
U3O8
Fusion, ICPMS
As-MS88
Various
As2O3
Fusion, ICPMS
OA-MIN05
Various
Free quartz.
OA-VOL06
Various
FeO
S-IR09
Various
OA-RAD05
Various
Radioactivity
Radiometry
OA-GRA10
Various
Moisture
Gravimetric
OA-GRA
Various
LOI (1050 C)
29
Gravimetric
Industrial Minerals
Method
code
Sample type
Elements/parameters
Method
description
ME-ICP85
Silicates
Fusion, ICP-AES
ME-ICP86
Limestone, Dolomite,
Magnesite, Magnesia
Fusion, ICP-AES
OA-VOL07
Limestone, Dolomite,
Magnesite, Magnesia
Neutralising value
Acid digestion,
titrimetric
ME-PKG82
Limestone, Dolomite,
Magnesite, Magnesia
Acid digestion,
ICP-AES
ME-ICP87
Iron ore
Fusion, ICP-AES
ME-ICP88
Bauxite
Fusion, ICP-AES
ME-ICP89
Phosphate rock
Fusion, ICP-AES
ME-ICP90
Manganese Ore
Fusion, ICP-AES
ME-PKG84
Barytes
Fusion, ICP-AES,
Pycnometer
ME-ICP91
Cementitious
Material
Fusion, ICP-AES
Cl-VOL66
Cementitious
Material
Acid digestion,
titrimetric
ME-PKG85
Fusion, ICPAES/ICP-MS
ME-PKG86
Fusion, ICPAES/ICP-MS
ME-ICP05
Gypsum
Acid digestion,
ICP-AES
ME-ICP92
Gypsum
Fusion, ICP-AES
ME-MS42
Acid digestion,
ICP-MS
ME-MS83
Ashing, Acid
Digestion, ICP-MS
ME-MS84
Ashing, Fusion,
ICP-MS
ME-PKG08
Sulfuric acid
Titrimetric, ICP-MS
ME-ICP93
Nickel laterites.
Fusion, ICP-AES
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rendered by ALS shall be within thirty (30) days from the date of invoice. ALS Chemex reserves the right to
discontinue work on behalf of any client failing to observe these terms. If accounts are not paid within the said 30
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the date of payment at the rate of twenty percent (20%) per annum.
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dependent on the analytical techniques required.
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The service provided is subject to detection limits and confidence intervals inherent in our current methodology.
Because each client is reliant upon assay results for a particular purpose and often in a unique geological or
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31