Contents:
1.
2.
3.
4.
a.
b.
Steam is the gas formed when water passes from the liquid to the gaseous state. At
the molecular level, this is when H2O molecules manage to break free from the
bonds (i.e. hydrogen bonds) keeping them together.
In steam-using industries, two commonly referred to types of steam are dry steam
(also called saturated steam) and wet steam.
Dry steam applies to steam when all its water molecules remain in the
gaseous state. It's a transparent gas.
Wet steam applies to steam when a portion of its water molecules have
given up their energy (latent heat) and condense to form tiny water droplets.
Take the example of a kettle boiling water. Water is first heated using an element.
As water absorbs more and more heat from the element, its molecules become
more agitated and it starts to boil. Once enough energy is absorbed, part of the
water vaporizes, which can represent an increase as much as 1600X in molecular
volume.
Sometimes a mist can be seen coming out of the spout. This mist is an example of
how dry steam, when released into the colder atmosphere, loses some of its energy
by transferring it to the ambient air. If enough energy is lost that intermolecular
bonds start forming again, tiny airborne droplets can be seen. This mixture of water
in the liquid state (tiny droplets) and gaseous state (steam) is called wet steam.
For more information about the nature and various types of steam, read the
following article on thetypes of steam.
Steam is now mostly known for its heating applications, as both a source of direct
and indirect heat.
The principle behind steaming food is that by allowing steam to come in direct
contact with the product being heated, the latent heat of steam can be directly
transferred to the food, and the water droplets formed through condensation can
supply moisture.
In industry, the direct steam heating method is often used for cooking, sterilization,
steam smothering, vulcanization and other processes.
The indirect steam heating method refers to processes where steam is not in direct
contact with the product being heated. It is widely used in industry because it
provides rapid, even heating. This method often uses a heat exchanger to heat the
product.
The advantage of this method over direct steam heating is that the water droplets
formed during heating will not affect the product. Steam can therefore be used in a
variety of applications such as for melting, drying, boiling and the like.
Indirect steam heating is used in a wide range of processes such as those for the
production of foods and beverages, tires, paper, cardboard, fuels such as gasoline
and medicine to name a few.
For greater details on the usage of steam in industry, read the following article on
the principal applications for steam.
a.
b.
Vacuum Steam
2.
3.
4.
5.
6.
7.
Steam is used in a wide range of industries. Common applications for steam are, for
example, steam heated processes in plants and factories and steam driven turbines
in electric power plants, but the uses of steam in industry extend far beyond this.
Here are some typical applications for steam in industry:
Heating/Sterilization
Propulsion/Drive
Motive
Atomization
Cleaning
Moisturization
Humidification
In the sections that follow, we will discuss various types of applications for steam,
and provide some examples of steam-using equipment to illustrate them.
In a heat exchanger, steam raises the temperature of the product by heat transfer,
after which it turns into condensate and is discharged through a steam trap.
Steam Oven
Vacuum Steam
The use of steam for heating at temperatures below 100C (212F), traditionally the
temperature range in which hot water is used, has grown rapidly in recent years.
When vacuum saturated steam is used in the same manner as positive pressure
saturated steam, the temperature of the steam can be quickly changed by adjusting
the pressure, making it possible to achieve precise temperature control unlike
applications using hot water. However, a vacuum pump must be used in conjunction
with the equipment, because merely reducing the pressure will not drop it to below
atmospheric pressure.
Heating with Latent (Steam) Heat
Compared with a hot water heating system, this system offers fast, even heating.
The set temperature is rapidly reached without causing unevenness in temperature.
The driving force from the steam causes the fins to turn, which then causes the
rotor on the attached power generator to rotate, and this rotation generates
electricity.
High pressure motive steam enters the jet ejector through the inlet nozzle and is
then diffused. This creates a low pressure zone which entrains air from the surface
condenser.
In a similar type of application, steam is also the primary motive fluid for secondary
pressure drainers, which are used for pumping condensate from vented receiver
tanks, flash vessels, or steam equipment that experiences stall conditions.
In flares, steam is often mixed in with the waste gas before combustion.
The moisturizing of the feed softens the feed and partially gelatinizes the starch
content of the ingredients, resulting in firmer pellets.
Steam is used to humidify air within an air duct before the air is distributed to other
regions of a building.
Types of Steam
Contents:
1.
2.
a.
3.
4.
Superheated Steam
a.
b.
5.
Supercritical Water
6.
If water is heated beyond the boiling point, it vaporizes into steam, or water in the
gaseous state. However, not all steam is the same. The properties of steam vary
greatly depending on the pressure and temperature to which it is subject.
In the article Principal Applications for Steam, we discussed several applications in
which steam is used. In the sections that follow, we will discuss the types of steam
used in these applications.
Saturated (dry) steam results when water is heated to the boiling point (sensible
heating) and then vaporized with additional heat (latent heating). If this steam is
then further heated above the saturation point, it becomes superheated steam
(sensible heating).
Property
Rapid, even heating through
latent heat transfer
Pressure can control
temperature
Advantage
Improved product quality and productivity
Temperature can be quickly and precisely
established
Tips
Having said this, it is necessary to be mindful of the following when heating with
saturated steam:
Heating efficiency may be diminished if steam other than dry steam is used
for process heating. Contrary to common perception, virtually all of the steam
generated from a boiler is not dry saturated steam, but wet steam, which contains
some non-vaporized water molecules.
Radiant heat loss causes some of the steam to condense. The generated wet
steam thus becomes even more wet, and condensate also forms, which must be
removed by installing steam traps at appropriate locations.
Heavy condensate that falls out of the steam flow can be removed through
drip leg steam traps. However, the entrained wet steam will reduce heating
efficiency, and should be removed through point-of-use or distribution separation
stations
Steam that incurs pressure losses due to piping friction, etc., may result a
corresponding loss in steam temperature as well
Superheated Steam
Superheated steam is created by further heating wet or saturated steam beyond
the saturated steam point. This yields steam that has a higher temperature and
lower density than saturated steam at the same pressure. Superheated steam is
mainly used in propulsion/drive applications such as turbines, and is not typically
used for heat transfer applications.
the degree of superheating as well as the pressure raises the enthalpy at the
turbine inlet side, and is thereby effective at improving thermal efficiency.
Property
Disadvantage
Reduced productivity
coefficient
Variable steam
constant pressure
the system
Temperature may be
extremely high
temperature even at
transfer heat
product quality
For these reasons and others, saturated steam is preferred over superheated steam
as the heating medium in exchangers and other heat transfer equipment. On the
other hand, when viewed as a heat source for direct heating as a high temperature
gas, it has an advantage over hot air in that it can be used as a heat source for
heating under oxygen-free conditions. Research is also being carried out on the use
of superheated steam in food processing applications such as cooking and drying.
Supercritical Water
Supercritical water is water in a state that exceeds its critical point: 22.1MPa, 374 C
(3208 psia, 705F). At the critical point, the latent heat of steam is zero, and its
specific volume is exactly the same whether considered liquid or gaseous. In other
words, water that is at a higher pressure and temperature than the critical point is
in an indistinguishable state that is neither liquid nor gas.
Supercritical water is used to drive turbines in power plants which demand higher
efficiency. Research on supercritical water is being performed with an emphasis on
its use as a fluid that has the properties of both a liquid and a gas, and in particular
on its suitability as a solvent for chemical reactions.
Unsaturated Water
This is water in its most recognizable state. Approximately 70% of the weight of the
human body is from water. In water's liquid form, hydrogen bonding pulls water
molecules together. As a result, unsaturated water has a relatively compact, dense,
and stable structure.
Saturated Steam
Saturated steam molecules are invisible. When saturated steam is released to the
atmosphere by being vented from piping, part of it condenses by transferring its
heat to the surrounding air, and clouds of white vapor (tiny droplets of water) are
formed. When steam includes these tiny droplets, it is called wet steam.
In a steam system, steam released from steam traps is often misinterpreted to be
saturated (live) steam, while it is in fact flash steam. The difference between the
two is that saturated steam is invisible immediately at the outlet of the pipe
whereas flash steam contains visible water droplets the instant it is formed.
Superheated Steam
As long as it retains its superheated state, superheated steam will not condense
even if it comes into contact with the atmosphere and its temperature drops. As a
result, no clouds of vapor are formed. Superheated steam stores more heat than
does saturated steam at the same pressure, and the movement of its molecules is
more rapid so it is has lower density (i.e., its specific volume is greater).
Supercritical Water
Though it is not possible to tell by visual observation, this is water in a form that is
neither liquid nor gaseous. The general idea is of a molecular movement that is
close to that of gas, and a density that is closer to that of a liquid.
Flash Steam
Contents:
1.
a.
2.
3.
a.
b.
4.
Flash steam is a name given to the steam formed from hot condensate when the pressure is
reduced.
Flash steam is no different from normal steam, it is just a convenient name used to explain how
the steam is formed. Normal or live steam is produced at a boiler, steam generator, or waste
heat recovery generator whereas flash steam occurs when high pressure / high temperature
condensate is exposed to a large pressure drop such as when exiting a steam trap.
High temperature condensate contains an excess of energy which prevents it from remaining in
liquid form at a lower pressure. The result is that the excess energy causes a percentage of the
condensate to flash.
Condensate discharged out of the orifice of a trap partially evaporates (flash evaporation) due to
the pressure difference (illustration).
where:
hf1 = Specific Enthalpy of Saturated Water at Inlet *
hf2 = Specific Enthalpy of Saturated Water at Outlet
hfg2 = Latent Heat of Saturated Steam at Outlet
As seen in the below examples, a higher % of flash steam is generated when condensate is
discharged to atmosphere (example 1) compared to when it is discharged into a closed return
system (example 2):
SI Units
Imperial Units
Tip
Use TLV's online Engineering Calculator for quick and accurate
calculation of:
Flash Steam Generated by Hot Condensate.
Access Now
Steam is much less dense than water, which means that a small increase in the percentage of
flash steam generated can appear as a large increase in volume of steam generated. The
animation below shows the difference in ratio of steam to condensate for examples 1 and 2 (see
above) when applied to condensate return piping.
The greater the pressure difference, the larger the amount of flash steam generated at discharge.
To understand with great detail, the specific volume of condensate at 100 C (212 F) is 0.00104
m3/kg (0.0167 ft3/lb), and the specific volume of atmospheric steam is 1.67 m3/kg (26.8 ft3/lb).
When high temperature condensate at 1.0 MPaG (145 psig) is discharged to lower pressure such
as atmosphere, 16.1% by mass of that condensate flashes into steam. The resulting volumetric
ratio can be contrasted as follows:
Calculating Flash to Condensate Ratio (Metric)
Flash steam from a high pressure system is recovered into a flash tank and reused as steam in a
low pressure system.
2.
3.
4.
Just as a map (or GPS navigation system) is necessary when driving in a new area or
a flight timetable is indispensable when taking the plane, steam tables are essential
to steam users in industry. This article will introduce steam tables, pointing out the
different types and offering an overview of the different elements found within
them.
Legend:
hf = Specific enthalpy of saturated water (energy required to heat water from 0C (32F)
to the boiling point)
hfg = Latent heat of evaporation (energy required to transform saturated water into dry
saturated steam)
hg = Specific enthalpy of saturated steam (total energy required to generate steam from
water at 0C (32F)).
Heating processes using steam generally use the latent heat of evaporation (H fg) to
heat the product. As seen in the table, this latent heat of evaporation is greatest at
lower pressures. As saturated steam pressure rises, the latent heat of evaporation
gradually decreases until it reaches 0 at supercritical pressure, i.e. 22.06 mPa (3200
psi).
Tip
Looking for TLV's online steam tables?
Access them here:
T E M P.
SP E C IF IC VO LUM E
SPECIFIC ENTHALPY
k Pa G
m3/kg
kJ/kg
Vf
Vg
Hf
Hfg
Hg
99.97
0.0010434
1.673
419.0
2257
2676
20
105.10
0.0010475
1.414
440.6
2243
2684
50
111.61
0.0010529
1.150
468.2
2225
2694
100
120.42
0.0010607
0.8803
505.6
2201
2707
P R E SS .
(GAUGE)
SP E C IF IC VO LUM E
SPECIFIC ENTHALPY
k Pa G
m3/kg
kJ/kg
Vf
Vg
Hf
Hfg
Hg
100
0.093
0.0010435
1.672
419.1
2256
2676
110
42.051
0.0010516
1.209
461.4
2230
2691
120
97.340
0.0010603
0.8913
503.8
2202
2706
130
168.93
0.0010697
0.6681
546.4
2174
2720
140
260.18
0.0010798
0.5085
589.2
2144
2733
150
374.78
0.0010905
0.39250
632.3
2114
2746
T E M P.
SP E C IF IC VO LUM E
SPECIFIC ENTHALPY
k Pa
m3/kg
kJ/kg
Vf
Vg
Hf
Hfg
Hg
--
--
--
--
--
--
20
60.06
0.0010103
7.648
251.4
2358
2609
50
81.32
0.0010299
3.240
340.5
2305
2645
100
99.61
0.0010432
1.694
417.4
2258
2675
T E M P.
SP E C IF IC VO LUM E
SPECIFIC ENTHALPY
k Pa G
m3/kg
kJ/kg
Vf
Vg
Hf
Hfg
Hg
99.97
0.0010434
1.673
419.0
2257
2676
20
105.10
0.0010475
1.414
440.6
2243
2684
50
111.61
0.0010529
1.150
468.2
2225
2694
100
120.42
0.0010607
0.8803
505.6
2201
2707
Important note: Problems can easily occur when absolute pressure is mistaken for
gauge pressure (or vice versa), so it is always extremely important to pay close
attention to the pressure units used in the table.
Summary Table
Gauge pressure:
The above superheated steam table contains data about Specific Volume (Vg), Specific Enthalpy
(Hg) and Specific Heat (Sg) at typical values of pressure and temperature.