Aiits 1416 PT IV Jeem Jeea Main Solutions Solutions

1
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AIITS-PT-IV-PCM(SOL)-JEE(Main)/16
JEE(Main)-2016
ANSWERS, HINTS & SOLUTIONS
PART TEST IV
(MAIN)
Q. No.
PHYSICS
CHEMISTRY
MATHEMATICS
1.
2.
3.
4.
5.
D
B
B
D
C
B
6.
7.
8.
B
B
C
B
C
B
9.
10.
11.
A
C
C
A
A
B
12.
13.
14.
15.
D
C
A
A
A
D
16.
17.
18.
19.
20.
21.
22.
23.
24.
25.
26.
27.
28.
29.
30.
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website: www.fiitjee.com
2
AIITS-PT-IV PCM(SOL)-JEE(Main)/16
HINTS AND SOLUTION
Physics
1.
PART I
3
1 3 / 2 1

2v
30
v = + 90 cm
4
3
(4 / 3) (3 / 2)
3f 2 90
60
f 69 cm.
2.
Refractive index of bubble with respect to water is less than 1. So shifting of the fringe pattern would
be towards B.
3.
R=
4.
use ev =
6.
7.
=
2
d / 4
A
4
R=
d2
R
d

100
2
100 = 4.05 %
R
hc
W
1 1 1

V U f
1
1
1
y= , x= ,c=
V
U
f
yx=c
y=x+c
Intercept
c = 0.2 /cm from graph
1
f = 5cm
c
Time at which no. of un-decayed nuclei become 0.37 N0 is equal to the mean life of the sample.
tav 1
1
7.5 =
1
=
/ min.
7.5
-t
8.
N = N0 e = N0 e
N
N = 40
e
sini
1
sin90
3.25
30
7.5
= N0 e
-4
3
sin i =
1
3.25
0.8A
(A x) (0.8A)
1
3.25
0.8A
0.64A 2
1
2
2
(A x) (0.8A)
3.25
2
2
x + 2Ax 0.44 A = 0
x = 0.2 A
i
x
9.
10.
1
1
1
v 15 10
v = 30 cm.
h
v
m = 2 2
u
1
Shift of image = II = (2 + 1) = 3 cm.
I
h2
O
1 cm
I
1 sin 30 = 2 sin r
1
1 = 1 and tan r =
2
1
sin r =
5
2
R
R/2
300
B
1/ 2
5
2 =
2
1/ 5
11.
1 1 2

u v R
1
1
1

15 v
10
v = 30 cm.
dh2
v dh1
v
30
vI =

.v 0 =
2 4mm / s .
dt
u dt
u
15
12.
Resultant intensity is
IR = 4I cos2 /2
Imax = I0 = 4I
3I
IR = I0 cos2 (/6) = 0
4
13.
Number of lines obtained =

=
14.
(7 2)(5 1)
15
2
(n2 n1 )(n2 n1 1)
2
n2 = 7
n1 = 2
Number of nuclei of z will increase till the rates will become equal
4
i.e. k = Nmax or k N =
Nmax =
dN
,
dt
15.
Maximum K.E. of the photoelectron is

hc
KEmax =
1242eV nm
=
2.5eV = 1.9 eV
280nm
since 0 k.E. 1.9 eV
K.E. 2.4 eV.
16.
X A z 2 XA 8 n 2He 4 m10
4n = 8
2n m = 2
n = 2, m = 2
17.
Angular fringe width
= =
d
If 2 & d d/2
then new fringe width =
18.
20.
21.
4
4
d
hc
1
1
z 2Rhc
2
2
(n
1)
n
n3
A b
b
0.1 0.01
2
2
A =
(10.0 1.00)cm = 0.2 cm

10.0 1.00
+ = 900
0
2 = 90
0
= 45
M2
300
60
M3
300
60
30
M1
25.
Energy received at photo sensitive surface per unit time =
ks
4a2
5
ks
2
4
Number of photons = a
hc
hc
Maximum energy =
26.
ks
4 hca2
dU he2
2
dr
2r
2
mv
he 2
F=
2
r
2r
h
Also mvr =
2
F =
solving equation we get r =
. . . (i)
. . . (ii)
. . . (iii)
h
.
2 me 2
2
6
Chemistry
1.
PART II
Total pressure of a mixture of 2 volatile liquids is given by
1
3
80 = (25 + 60) = 85 mm Hg
4
4
Mole fraction of A in the vapour phase (X A ) is given by
PTotal = PA XA + PB XB = 100
100
P
4 25
XA = A
=
= 0.294
85
PT
85
XB = 0.706
These mole fractions will go into the distillate. The total vapour pressure of the distillate would be
= PA X A
PTotal
PB X B = (100 0.294) + (80 0.706)
= (29.4 + 56.48) = 85.88 mm Hg.

2.
At the same temperature, isotonic solutions will have same concentrations.

Na2SO 4
1
C Na
SO 4
2Na + SO 24
2
= C glu cos e
0.04(1 + 2) = 0.1
= 0.75
3.
2KI + HgI2 K2[HgI4]

2K+ + [HgI4]2
Thus, there is net decrease in number of ions present in solution and freezing point is raised
4.
Tf = i Kf m
0.0054 = i 1.80 0.001
i=3
i = 1 + (n 1)
n =3
The correct formula of the compound is [Pt(NH3)4Cl2]Cl2
5.
As2 S3 (NH4 )2 S 2 (NH4 )3 AsO3

soluble
9.
The number of units of AB in a unit cell (fcc) = 4

r
Now, for octahedral co-ordination = 0.414
r
r 100 10 10 1010 cm
r
10 10
r
So, r 241.5 pm
Hence, (A).
7
0.0591
(Cr 3 )
log
n
(Cr2O72 )1/ 2 (H )7
10.
E Eo
11.
Pt H2 H H H2 Pt
104 1 atm
1 atm x
0.0591
(10 4 )2
log
2
x2
6
x = 10 M
Ecell
13.
Ag e Ag ; Eo 0.799 V; Go 7.71 10 4 J
Ag(NH3 )2 Ag 2NH3 ; K 6 10 8 ; Go ( 2.303 RT)logK 4.12 10 4 J
o
Gnet
( 7.71 104 J) (4.12 10 4 J) 3.59 10 4 J
Eo
14.
Go
0.372 V
nF
2+
3+
The total charge of Fe and Fe should be 2.

Let, the percentage of Fe3+ = x
Hence, 3 x + 2(0.93 x) = 2
x 0.14
% of Fe3+
0.14
100 15%
0.93
17.
It does not dimerise due to delocalization of odd electrons.
19.
2HBr + SO3 H2O + Br2 + SO2;
20.
Ti + 2I2
21.
Carnallite is an important ore of magnesium. Its formula is KCl.MgCl2.6H2O.
23.
PbS + 2PbO 2Pb + SO2, SnO2 + C Sn + CO, SnO2 + 2CO Sn + 2CO2.
25.
VOSO4 VO2+ + SO42

So oxidation state of V is +4.
26.
CO2 H2 O
H2CO3
500K
TiI4
Volatile stable
compound
1700K
Ti
+ 2I2
Pure metal
CrO24 2H
Cr2 O7 H2O
orange red
27.
2+
Mn : 3d 4s
In presence of weak field ligand, three will be no pairing of electrons, so it will form a high spin
complex i.e. the number of unpaired electrons = 5.
8
Mathematics
PART III
SECTION A
1.
Let c (c1, c 2 , c 3 ), then
| c | | a | | b | 2 c12 c 22 c 23
It is given that the angles between the vectors are identical and equal to (say), then

a.b
0 1 0 1
cos
2
| a || b |
2 2

c1 c 2 1
c c3 1
a.c
b.c
and 2

| a || c |
2
2
2
2
| b || c |
Hence c1 c 2 1,c 2 c 3 1and c12 c 22 c 23 2
1
4
1
On solving the equation, we get c1 1, ;c 2 0, ;c 3 1,
3
3
3
1 4 1
Hence co-ordinates of c are (1, 0, 1) or , , .
3 3 3
Trick : Obviously, length of the vector (1, 0, 1) i.e., i k is equal to length of a and b . Also it makes
equal angle with a and b and equal to that of between a and b i.e. , .
3
2.
3.
Since the vectors a cxi 6j 3k and b xi 2j 2cxk make an obtuse angle, therefore

a.b 0 cx 2 12 6cx 0 for all x
c 0 and Discriminant 0
c 0 and 36c 2 48c 0
c 0 and 3c 4 0 c 0 and 3c 4 0
4
c 0.
3

[p qr ] p.(q r )

bc ca
ab
.
a.b c a.b c a.b c

(b c). (c a) (a b)

[a .(b c)]3

(b c). {(c a).b}a {(c a).a}b

[a.(b c)]3

(b c) {(c a).b}a

,
(c a).a 0
3
a.(b c)
(b c) {(a.(b c)}a [a.(b

c)] [(b c).a]

[a.(b c)]3
[a.(b c)]3
9
1
.
a.b c
4.
Let P be any point in the plane of the triangle ABC. Then

A
PA PB PC PA (PB PC) PA 2PD
(1 2)PG 3PG
Since G divides AD in the ratio 2 : 1.

SA SB SC 3SG 2SG SG

GO SG SO , ( OG 2SG) .
5.
6.
7.
[ abc ] 0

2
Also |[ ab c ]| = [ b c c a a b] = [ ab c ]
or t2 = |t| t2 = t, t = 0, 1, -1
but [ ab c ] 0, [ab c] = 1
and [ abc ] = -1

a b a b a a b b a b a.b a | a |2 b | b |2 a a.b b
a.b a b b a
( | a || b | 1 )

a.b 1 a b

Hence a b a b is parallel to a b
x 1 y 3 z 5
.....(i)
3
5
7
Then x 3 1, y 5 3,z 7 5
General point on this line is (3 1,5 3,7 5)
Let
x2 y4 z6
.....(ii)
1
3
5
Then x 2,y 3 4,z 5 6
A general point on this line is ( 2,3 4,5 6)
For intersection, they have a common point, for some values of and , we must have
bcx cay abz 0 ,
Again let
(5 3) (3 4), (7 5) (5 6)
From first two we have, 3 3
(iii)
and 3 5 7
..(iv)
From (iii), put the values of in (iv), we have 3(3 3) 5 7
10
9 9 5 7 or 4 2 or
1
2
1
3
1
in (iii), we get
(Putting )
2
2
2
The required point of intersection is
3 5
7
1 1 3
2 1 , 2 3 , 2 5 2 , 2 , 2 .
Put
8.
6 2 12
1 4
sin1
sin
.
406
14 . 29
9.
The equation of plane, in which the line
x5 y7 z3
lies, is
4
4
5
(i)
(ii)
A(x 5) B(y 7) C(z 3) 0

Where 4A 4B 5C 0
x8 y4 z5
Also, since line
lies in this plane

7
1
3
7A B 3C 0
(iii)
A
B
C
By (ii) and (iii), we get
17 47 24
The required plane is
17(x 5) 47(y 7) ( 24)(z 3) 0
17x 47y 24z 172 0.
10.
Equation of a plane passing through origin is ax by cz 0, but it also passes through (1, 2, 1)
and (3,2,3), therefore a 2b c 0 and 3a 2b 3c 0 .
3c
a 2c and b
2
3c
Plane is 2cx
y cz 0 4x 3y 2z 0.
2
4
3
2
Hence direction cosines of plane are
,
,
29 29 29
11.
Let A (1, 1, 0), B (1, 0, 1)

direction ratios of segment AB are (2, 1, 1). If '' be the acute angle between segment AB and
normal to plane,
| 2.2 1.1 1.6 |
3
cos =
4 1 36. 4 1 1
246
Length of projection = (AB) sin =
12.
6.
9
=
246
237
units.
61
Given line passes through (1, 2, 4) and this point also lies on the given plane.
x 1 y 2 z 4
Thus, required line will be in the form of
.
l
m
n
Any point on the given line is (r1 + 1, 3r1 + 2, r1 + 4).
If r1 = 1, this point becomes P = (0, 5, 5)
Let Q = (a, b, (C) be the reflection of P in the given plane, then
11
a
b5
5c
.1
.1
.1 7
2
2
2
a b5 c5
i.e., a + b + c = 4, and
= (say)
1
1
1
a = , b = 5 + , c = 5 +
10 + 3 = 4 = 2
Thus, Q (2, 3, 3)
Hence, direction ratios of reflected line are (3, 1, 1)
x 1 y 2 z 4
Thus, it's equation is
3
1
1
13.
14.
In first trial he gets a head =

probability that say in first trial he gets a trial then in dice throwing we should get (1 to 4) and then
1 4 1 1
head comes. Probability of that
2 6 2 6
1 1 1
1/ 2
3
So total probability will become
...
2 6 18
1 1/ 3 4
No one dies probability = (1 p)n
n
atleast one dies 1 = 1 (1 p)
now A1, A2, An can make n! cases between them if the fix A1 to die first then rest A2 An will make
n 1! 1
(n 1)! cases between them so probability of A1 dies first
n!
n
1
n
So, total probability of A1 dies and dies first
1 1 p .
n
15.
We have
or
100
C50 p50 (1 p)50
100
C51(1 p)49
1 p
100!
50! . 50! 50
p
51! . 49!
100!
51
or 51 51p 50p
p
16.
51
.
101
The man will be one step away from the starting point if (i) either he is one step ahead or (ii) one step
behind the starting point.
The required probability P(i) P(ii)
The man will be one step ahead at the end of eleven steps if he moves six steps forward and five steps
backward. The probability of this event 11C6 (0.4)6 (0.6)5 .
The man will be one step behind at the end of eleven steps if he moves six steps backward and five
steps forward.
The probability of this event 11C6 (0.6)6 (0.4)5 .
Hence the required probability
11C6 (0.4)6 (0.6)5 11C6 (0.6)6 (0.4)5
11C6 (0.4)5 (0.6)5 (0.4 0.6) 11C6 (0.24)5 .
17.
P(x 1.5) 1 P(x 0) P(x 1)
: expected minimum positive integer
12
P(x k) e
k
k!
e : Euler number.
P(x 1.5) 1
18.
1
2
3
2 1 2 .
2
e
e
e
1( 3n 1) n ( 2n 2n ) 2n (n 4n )
[( 3 )n 1] 0 2n [ n ( 3 )n .n ]
1 1 0 2n [n n ] 0 .
19.
As we have A 2 2A I A 2 .A (2A I) A
A 3 2A 2 IA 2(2A I) A A 3 3A 2I
4
IA A and A
2A I
Similarly, A 4A 3I,A 5A 4I..

Hence yb em ,x c y d en .
20.
We have a1,a2 ,a3 ..... an in G.P.

then r
a2
a
a
i.e., r n 1 n 2 ..... ..
a1
an
a n 1
Hence logr log(an1 ) log(an ) log(an 2 ) log(an1 ) ...

logan
Now logan 3
logan 6
logan 1
logan 2
logan 4
logan 5
logan 7
logan 8
Operate C2 C2 C1 and C3 C3 C2
logan
21.
(logan 1 logan )
(logan 2 logan 1 )
= logan 3
logan 6
(logan 4 logan 3 ) (logan 5 logan 4 )
logan
= logan 3
logan 6
logr logr
(logan 7 logan 6 ) (logan 8 logan 7 )

logr logr
0.
logr logr
c n 1 3 1 2 (11)2 121 .
But we have to find the value of the square of the determinant, so required value is (121)2 14641 .
22.
23.
Since (AB)1 B1A 1 .

3
1 x
x3
For the given matrix to be singular, we must have,
2
x2 0
2
3 1 x 2
x 0 , [R 2 R2 R1,R3 R3 R1 ]
13
x 4 1 x 2
x 0 , [C1 C1 C2 C3 ]
0
2
(x 4)(0 x ) 0 x 4,0
Note that only 4 [4, 1] .
24.
sin1 x
2
2
sin1 y
2
2
sin1 x sin1 y
so for sin1 x sin1 y
& sin1 y
2
2
x = 1 and y = 1
sin1 x
area required 1
(x 1)
dx 1
25.
1 2
sq. units.
3 3
The curves given by y = x + sin x and y = f1(x) are images of each other in the line y = x.
Hence required area =
x sin x x dx cos x 0 2
0
26.
Circle has (2, 1) as its centre and radius of this circle is 2.

Thus if P(x, y) be any point on it, then x [0, 4].
x3
x
Let g(x)
100 50
3x 2
1
g'(x)
0 x (0,4]
100 50
The g(x) is increasing in [0, 4]
18
g(0) 0, g(4)
25
18
g(x) 0, x [0,4] [g(x)] = 0 x [0, 4]
25
x3
x
y
, represents the x-axis.

100 50
CA = CB = 2, CD = 1
CD 1
cos

CA 2
3
2
1
2
ACB
, ACB 22 sin
3
3
2
3
1
2
4
Area of sector ACB 22
=
sq. units
2
3
3
27.
Since
f(x)dx
0
a2 a
sina cosa
2 2
2
Differentiating both sides w.r.t. a, we get

14
a
1
f(a) a cosa sina sina

2
2
2
1
1

f 0 .1 .1
2
2
2
2 2
28.
For x 1, 4 / 3 , y sin1 0 sin1

4/3
So required area
sin1 dx
1
sin1 Sq. units.
3
x2
1
A x 2 dx 3 / 2
6
60
29.
f x
30.
y (c1 c 2 )cos(x c 3 ) c 4 e x c 5
y1 (c1 c 2 )sin(x c 3 ) c 4e x c5
y 2 (c1 c 2 )cos(x c 3 ) c 4 e x C5 y 2c 4 e x c5
y 3 y1 2c 4 e x c 5 y1 y 2 y
Hence the differential equation is y 3 y 2 y1 y 0 , which is of order 3.

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1

HINTS AND SOLUTION

Number of lines obtained =

Maximum K.E. of the photoelectron is

Angular fringe width

then new fringe width =

(10.0 1.00)cm = 0.2 cm

Energy received at photo sensitive surface per unit time =

solving equation we get r =

Total pressure of a mixture of 2 volatile liquids is given by

PB X B = (100 0.294) + (80 0.706)

= (29.4 + 56.48) = 85.88 mm Hg.

At the same temperature, isotonic solutions will have same concentrations.

2KI + HgI2 K2[HgI4]

As2 S3 (NH4 )2 S 2 (NH4 )3 AsO3

The number of units of AB in a unit cell (fcc) = 4

The total charge of Fe and Fe should be 2.

It does not dimerise due to delocalization of odd electrons.

2HBr + SO3 H2O + Br2 + SO2;

Carnallite is an important ore of magnesium. Its formula is KCl.MgCl2.6H2O.

PbS + 2PbO 2Pb + SO2, SnO2 + C Sn + CO, SnO2 + 2CO Sn + 2CO2.

VOSO4 VO2+ + SO42

Let c (c1, c 2 , c 3 ), then

(b c) {(a.(b c)}a [a.(b

Let P be any point in the plane of the triangle ABC. Then

PA PB PC PA (PB PC) PA 2PD

The equation of plane, in which the line

A(x 5) B(y 7) C(z 3) 0

lies in this plane

Let A (1, 1, 0), B (1, 0, 1)

In first trial he gets a head =

C50 p50 (1 p)50

P(x 1.5) 1 P(x 0) P(x 1)

: expected minimum positive integer

Similarly, A 4A 3I,A 5A 4I..

We have a1,a2 ,a3 ..... an in G.P.

Hence logr log(an1 ) log(an ) log(an 2 ) log(an1 ) ...

(logan 4 logan 3 ) (logan 5 logan 4 )

(logan 7 logan 6 ) (logan 8 logan 7 )

Since (AB)1 B1A 1 .

For the given matrix to be singular, we must have,

so for sin1 x sin1 y

Hence required area =

Circle has (2, 1) as its centre and radius of this circle is 2.

, represents the x-axis.

Differentiating both sides w.r.t. a, we get

f(a) a cosa sina sina

For x 1, 4 / 3 , y sin1 0 sin1

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