Heat Engine
The science of thermodynamics deals with the relationship between heat and
work.
It is governed by two laws, neither of which have ever been proved.
On the other hand no violations of either law have ever been observed.
First Law of Thermodynamics
The energy that can be extracted from a process can never be more than the
energy put into the process
In other words
Energy out = Energy in
This is essentially the law of conservation of energy, i.e.
Energy can be neither created nor destroyed, it can only be converted
from one form to another
The second law of thermodynamics
The first law is concerned with the totality of energy in a process
The second law tells us how much work we can extract from a given amount
of heat.
Carnots statement was to the effect that we cannot convert all the the
available heat into work.
The second law is also concerned with whether a process can occur at all. For
example,
Heat will always flow from a high to a low temperature
A gas under pressure will expand; compression does not occur
naturally
Heat Engines
A heat engine is a device for extracting work from a hot fluid. For example
A car engine extracts power from the combustion of fuel with air
A steam steam turbine extracts power from steam
Both of these function by allowing a hot fluid to expand so as to cause motion
in a critical component of the engine.
In the process, high grade energy is said to be degraded to lower grade
energy.
TH TL
T
1 L
TH
TH
The temperature is in the Kelvin or absolute scale
This efficiency is called the Carnot efficiency
These result in lower efficiencies than the Carnot cycle but permit useful work
to be done.
Other cycles
Otto, Diesel and Gas turbines all involve an initial compression stage, but are
otherwise open cycle processes.
Combined cycle gas turbine:
This combines a gas turbine with a Rankine steam cycle to maximise
the work extracted from the fuel.
Efficiencies are much closer to Carnot efficiencies than in other
practical cycle used to date.
Example
Steam from a geothermal well is expanded in a Carnot engine from a
temperature of 150C to 50C. How much work is extracted from 1kg of
steam?
If the steam is heated to 250C before expansion, how much work is now
extracted in relation to the extra heat added
Heat capacity of steam = 1.9 kJ kg-1 K-1
0C = 273 K
Solution
Energy extracted = 1 1.9 100 = 190 kJ
1
Efficiency
50 273
24%
150 273