Wear
journal homepage: www.elsevier.com/locate/wear
Gazi University, Industrial Arts Education Faculty, Technology Education Department, Glbas, Ankara, Turkey
Gazi University, Tech. Education Faculty, Metal Education Department, Besevler, Ankara, Turkey
c
Karabuk University, Tech. Education Faculty Manufacturing Education Department, Karabuk, Turkey
b
a r t i c l e
i n f o
Article history:
Received 24 January 2008
Received in revised form
23 December 2008
Accepted 4 March 2009
Available online 18 March 2009
Keywords:
Boronizing
Abrasive wear
AISI 8620 steel
a b s t r a c t
In this study, AISI 8620 steel was boronized using the solid state boronizing technique. Processes were
carried out at the temperatures of 850, 900 and 950 C for 2, 4 and 6 h of treatment. Abrasive wear behavior of the samples boronized at different temperatures and treatment durations have been examined.
Using boronized and unboronized samples, abrasive tests were conducted using pin on disc test apparatus. 80 and 120 mesh aluminum oxide (Al2 O3 ) abrasive papers were used in the abrasion experiments
and the samples were subjected to abrasion under 10, 20 and 30 N loads. Boronized steels exhibited an
improvement in abrasive wear resistance reaching up to 500%. Microstructures and wear surfaces of the
samples were inspected using SEM microscopy. SEM examinations revealed that the thickness of the
boride layer on the steel surfaces changes with changing process durations and temperatures. The presence of boride formed in the borided layer at the surface of the steels were determined by XRD analysis
and microhardness values of the iron borides (FeB, Fe2 B) formed on the steel surface were found to be
over 1600 HV.
2009 Elsevier B.V. All rights reserved.
1. Introduction
Boronizing is one of the methods used on steels and iron
to improve their surface properties [1]. Boronized steel parts
exhibit excellent performance in various tribological applications
in mechanical engineering and in the automotive sector [2]. In the
past 40 years, boronizing has become an increasingly better surface
protection method [3]. Boronizing of steels is used against adhesive,
sliding and abrasive wear and is recognized as an effective method
to combat these effects [113]. The most widely known boronizing
procedure is forming iron borides on the steel surface [5]. Boronizing is one of the most widely used methods in many tribological
applications where wear and friction control are paramount [14].
The boronizing process is a chemical heat treatment that aims to
form borides with the substrate metal by diffusing the boron atoms
into the sample surface [14]. Boron is a metal that can form many
minerals and compounds [6]. Because it is a relatively small element, the process may be applied to many types of materials such as
ferrous and non-ferrous metals [15], nickel and cobalt alloys, metal
bound carbides, refractory alloys [13] and some super alloys [15].
Boronizing of ferrous products is usually conducted between 840
and 1050 C [7,14]. There are several techniques available for surface boron enrichment process [8]. The process can be carried out
employing any of the solid, liquid, gaseous state [7,14], plasma and
Corresponding author.
E-mail address: mizciler@gazi.edu.tr (M. Izciler).
0043-1648/$ see front matter 2009 Elsevier B.V. All rights reserved.
doi:10.1016/j.wear.2009.03.006
1107
G
mm3 /Nm
dMS
Si
Mn
Cr
Mo
Ni
0.20
0.24
0.85
0.019
0.009
0.55
0.21
0.5
1108
Fig. 2. Cross section SEM image of the borides formed on the surface of AISI 8620 steel with 400 magnication. (a) 850 C, 6 h; (b) 950 C, 6 h; (c) 900 C, 2 h; (d) 900 C, 6 h.
geneous throughout the matrix (Fig. 2(b)). SEM images taken from
the center of the sample boronized for 6 h at 950 C revealed that
the sample has grain growth. This is because the sample was cooled
in air after 6 h of boronizing at 950 C.
Scanning electro microscopy (SEM) examinations of the
boronized steels revealed that the borides on the surfaces of these
samples have smooth branched morphology. It was observed that
the thickness of the boride layer increased with boronizing time and
temperature [9,17]. Boronized surfaces had three distinguishable
zones. These are (i) layer with FeB and Fe2 B borides, (ii) diffusion
zone beneath the boride layer where boron makes a solid state solution with the steel and which has lower hardness than the borides
but higher hardness than the steel, and (iii) steel matrix free of
boron [14] (Fig. 2(a)(d)).
Fig. 2(a)(d) shows that increasing the boronizing temperature
and treatment duration increases the boride layer thickness. Boride
layer thickness is observed to increase more than twice depending
on boronizing time (Fig. 2(c) and (d)). Also, with increasing temperature and treatment duration, grain growth was observed; ferrite
and pearlite structures exhibited growth. Similarly, the inspection of (a) and (d) within Fig. 2 shows that the Fe2 B core formed
according to the composition of the main material and procedural
conditions is layer out along the boron gradient. Therefore, the high
stress areas and cage distortions that appears near the point of the
Fe2 B core allow the layer to grow colonically. The growth mechanism of the FeB phase show similarity to that of the Fe2 B phase.
The colonical formations between the FeB/Fe2 B layers are less than
those seen between the Fe2 B/matrix layers. The reason for this is
that the Fe2 B phase is based on a more ductile material in comparison to the FeB phase, resulting in the achievement in a harder
FeB phase [28]. Dybkov et al. indicated that the boron layer formation is not simultaneous, and that the Fe2 B phase is formed rst
[18]. Fig. 3 displays the XRD analysis used to determine the phases
formed on the samples boronized for 6 h at 950 C. Uslu et al. have
also reported in their study on P 20 steel that the Fe2 B phase is
formed before the FeB phase [29].
Fig. 3. X-ray analysis of AISI 8620 steel sample boronized for 6 h at 950 C.
1109
Fig. 4. (a) Microhardness values of the samples boronized at 850 C for 2, 4 and 6 h; (b) microhardness values of the samples boronized at 950 C for 2, 4 and 6 h.
There are three zones present on the hardness distribution diagram; (i) borides, (ii) boron rich transition zone, and (iii) matrix [14].
Since boronizing treatment is a thermo-chemical diffusion process,
boride layer thickness increases depending both on the treatment
temperature and time. Bejar and Moreno and Uslu et al. have also
reported that the boride layer thickness increases under higher
temperatures and longer durations [13,29]. Furthermore, zdemir
et al. and Sahin have also reported that the boride layer thickness
increases together with the boronizing duration [30,31]. With the
increasing temperature, the boride layer thickness was observed
to increase. The boride layer thickness of the sample boronized at
950 C for 6 h was measured to be 250 m, the boride layer thickness of the sample, boronized at 950 C for 2 h was measured to
be 110 m, the boride layer thickness of the sample, boronized at
850 C for 6 h was measured to be 150 m while that of the sample
boronized at 850 C for 2 h was 80 m.
Fig. 5. (a) Wear rate of the unprocessed AISI 8620 steels with 80 and 120 mesh Al2 O3 sandpaper. Wear rate of the AISI 8620 steels boronized at 850 C for different treatment
times using (b) 80 mesh Al2 O3 sandpaper, (c) 120 mesh Al2 O3 sandpaper. Wear rate of the AISI 8620 steels boronized at 950 C for different treatment times using (d) 80 mesh
Al2 O3 sandpaper, (e) 120 mesh Al2 O3 sandpaper.
1110
Fig. 6. SEM images of the worn surfaces of AISI 8620 steel at 200 magnication worn using 80 mesh sandpaper (a) side image of the sample boronized at 850 C for 2 h
under a load of 30 N; (b) side image of the sample boronized at 850 C for 6 h under a load of 30 N; (c) side image of the sample boronized at 950 C for 6 h under a load of
30 N; (d) side image of the sample boronized at 950 C at 6 h under a load of 10 N.
it is advantageous to boronize for longer durations at lower temperatures. Great care was taken to decrease the sliding distance
to determine the effects of these layers on wear resistance. Martini et al. in their study, Adhesive and Abrasive Wear Behavior of
Fig. 7. SEM images of the worn surfaces of AISI 8620 steel at 200 magnication worn using 120 mesh sandpaper (a) side image of the sample boronized at 850 C for 2 h
under a load of 30 N; (b) side image of the sample boronized at 850 C for 6 h under a load of 30 N; (c) side image of the sample boronized at 950 C for 6 h under a load of
30 N; (d) side image of the sample boronized at 950 C at 6 h under a load of 10 N.
1111
Fig. 8. SEM images of the worn surfaces of unboronized AISI 8620 steel at 200 magnication. (a) Image of the surface worn under a load of 30 N and using 80 mesh Al2 O3
sandpaper; (b) image of the surface worn under a load of 30 N and using 120 mesh Al2 O3 sandpaper; (c) image of the surface worn under a load of 10 N and using 80 mesh
Al2 O3 sandpaper.
Boride Coatings, have concluded that the wear rate is very high
both under abrasive and adhesive conditions because of the brittle
outer layer with irregular crystal structure over the boride coating. Celebi et al. have observed as a result of their studies on AISI
8620 steel that the fracture toughness of the borides formed on the
steel boronized at higher temperatures is higher than those formed
at relatively lower temperatures. As for the effects of the abrasive paper mesh size on wear behavior, as can be seen in Fig. 4(a),
large grained (80 mesh) abrasive paper causes more wear than ne
grained (120 mesh) ones. All these ndings agree with the literature on this subject [13,5,13,23]. Goddard and Wilman found that
the wear behavior changes with the average grain size of the abrasive material and that the wear rate is increased with the increasing
grain size. As it can be seen in Fig. 4(a)(e), with the increasing load
applied on unit surface area, wear increases. Modi et al. reported in
their (2003) cooperative work that the wear rate exhibits changes
depending on the load and wear rate increases with increasing load
[32]. When the comparing with previous study [27], in this study,
boronizing process gives higher wear resistance than carburising
under 80 mesh abrasive paper.
When the SEM images of the worn surfaces of unboronized samples are examined, it can be seen that the wear marks in Fig. 5(a) are
larger and deeper. Least wear with the thinnest marks are observed
in (c).
Examining Fig. 6(a)(d), it is clear that the wear scars are deeper
and wider with increasing load and wear scars are getting wider and
deeper in the samples boronized at the same temperature while the
boronizing time decreases.
Examining Fig. 7(a)(d), it is clear that the wear scars are deeper
and wider with increasing load and decreasing boronizing time.
When Figs. 6 and 7 are compared, it can be seen that with the average grain size of the abrasive the wear changes; wear marks become
deeper and wider.
When the SEM images taken from wear surfaces are examined, it
can be observed from Figs. 68 that the samples unboronized have
deeper and wider wear scars than those of the boronized samples.
It is also clear that wear rate increases, with increasing load. Images
taken from the side of the sample boronized at 950 C for 6 h show
fractures because of the FeB layer. Again, from the gures, it is clear
that the wear scars are deeper and wider with increasing load.
4. Conclusions
In this study, abrasive wear behaviors and mechanical properties of AISI 8620 steels, both unboronized and boronized at different
temperatures for different treatment times were studied. Experimental results show that borides formed on the substrate exhibit a
smooth branched morphology. Microhardness values of the borides
formed on the AISI 8620 steel are much higher than that of the original substrate. Hardness of the sample boronized at 850 C for 2 h
1112
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