EXPERIMENT TITLE
ISOTHERMAL CSTR
NAME OF CANDIDATE
WITH REG NO.
SESSION DATE
DATE OF SUBMISSION
REG No.
NAME
1103143014
1103142004
1103142021
1103143020
Santya Gopalan
Mohaan Sockalingam
Assvinraj K munusamy
Brighton Marandu
SIGNATURES
MARKING
DETAILS
TOTAL
MARKS
AWARDED
Participation
and Attitude
Lab Report
Total
INTRODUCTION
dvantag &disadvantags
PROCEDURE
(Summary)
Using your OWN word, explain
10
10
15
20
25
CONCLUSION&RECOMMENDATION
Summary of the results to relate the
findings or results with the theory
applicable to the experimental.
Suggest improvements in apparatus or
measurement procedure, or experimental
procedures for future.
REFERENCES(ATLEAST3)
APPENDICES
Attach ALL calculation made in this
experiment
Raw data
FORMATS
TOTAL(70%)
Chop received:
TABLE OF CONTENTS
Page
2
S. No.
DESCRIPTION
PAGE No.
Abstract
Introduction
4-5
Procedure
5-8
8-12
12
References
13
Appendix
13-14
1. ABSTRACT
Page
3
temperature at 50oC, air pressure at 0.8 kg/cm2 and flow rate of NaOH and ethyl acetate was
adjusted at equimolar flow rate for a certain time. After approximately 10 minutes, the sample were
collected exactly 10 ml from the outlet feed tank using measuring cylinder that already contains 20
ml of HCL solution. Then, the sample solution was titrated using phenolphthalein as an indicator to test
the presences of NaOH ions. The reading of the burette were noted down. At every 10 minutes
interval, set of 7 readings were taken three sustained reading were obtained. From this experiment,
the reaction rate constant for saponification of ethyl acetate sodium hydroxide at a fixed
temperature which is K 0.245 L/mol.min and the activation energy is 20.11 cal/mol thus this
experiment is achieved successfully. There were few errors occured during the experiment and so
there are some recommendations has been suggested in the conclusion. The entire objective have
been achieved and related to the theory of study.
2. INTRODUCTION
A stirred-tank reactor (STR) may be operated either as a batch reactor or as a steady-state flow
reactor (better known as Continuous Stirred-Tank Reactor (CSTR)).The key or main feature of this
reactor is that mixing is complete so that properties such as temperature and concentration of the
reaction mixture are uniform in all parts of the vessel reactor (CSTR).In a CSTR it is designed that,
one or more fluid reagents are introduced into a tank reactor (typically) equipped with an impeller
while the reactor effluent is removed. The impeller stirs the reagents to ensure proper mixing. Run
at steady state with continuous flow of reactants and products; the feed assumes a uniform
composition throughout the reactor, exit stream has the same composition as in the tank.
(Fogler,2013).
In application, simply dividing the volume of the tank by the average volumetric flow rate through
the tank gives the space time, or the average amount of time a discrete quantity of reagent spends
inside the tank. Chemical reactors often have significant heat effects, so it is important to be able to
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4
3. PRODEURE
3.1. Materials
1.
2.
3.
4.
5.
6.
7.
8.
Syringe
Measuring cylinders
Conical flasks
Stopwatch
Beakers
Burette
2L of 0.1M NaOH solution
2L of 0.1M ethyl acetate
V1
V2
V3
V4
V5
V6
V7
V8
V9
V10
V11
The flow of the feed was stop by closing the valve V2-V3 when the experiment is over
The heater and stirrer of the water bath was switch OFF
The stirrer of the reactor was switch OFF
Air pressure was reduced to 0kg/cm2 by pressure regulator and pressure gauge
Valve V1 was closed
The reactor, feed tanks and water bath was drained by valve V8-V11.
Valves
Air supply valve for feed tank
Flow Control Valve for Rotameter A
Flow Control Valve for Rotameter B
Feed Inlet Valve for Feed Tank A
Feed Inlet Valve for Feed Tank B
Air Vent Valve for Feed Tank A
Air Vent Valve for Feed Tank B
Drain Valve for Feed Tank A
Drain Valve for Feed Tank B
Drain Valve for Reactor
Drain Valve for Waterbath
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6
CAO = NNaOH
(1)
2. Concentrated of unreacted NaOH in the reactor, C A were calculated using equation;
t = (Vr ) /( V0)
(4)
5. The rate constant for individual run were calculated using equation;
(CAO
CA)
(5)
(6)
k= Ae-Ea/ RT
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7
CA2
T (C)
50
55.5
49
49.6
51.9
51.9
50.5
51.9
VA(LPH)
10
10
10
10
10
10
10
10
VB(LPH)
10
10
10
10
10
10
10
10
V1 (ml)
0
37
22.4
19.5
19.5
17
17
17
Table 1 shows the readings of volume of sodium hydroxide (NaOH) used for titration over time take
taken. The time taken was every 10 min intervals. The temperature changes as the time increase, its
Page
8
t (min)
0.231
0.231
0.231
0.231
0.231
0.231
0.231
XA
4.4
1.48
0.9
0.9
0.4
0.4
0.4
(1-XA)^2
11.56
0.2304
0.01
0.01
0.36
0.36
0.36
XA/(1-XA)^2
0.381
6.424
90
90
1.11
1.11
1.11
Table 2 shows the conversion of the reaction over the time taken. It can be seen that as the time
increases, the conversion decreases. This is because at the initial time the rate of reaction is faster.
The number of moles of reactants A reacted per mole of reactants. A fed decreases and it completely
changes to products as the time increases. In this non-catalytic homogenous reaction, the OH- ion is
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9
0.25
f(x) = 0.41x + 0
0.2
0.15
0.1
0.2
0.3
0.4
0.5
0.6
XA/(1-XA)^2
By analysing figure 2, it can be clearly seen that the conversion is directly proportional to the
residence time. The conversion increases along residence time throughout the experiment. From the
graph, the value of the slope is zero . The residence time is calculated by dividing the reactor volume
with the total flow rate. Since throughout the experiment the rotameter readings for tank A and B
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10
constant which is 0.231 minutes. Therefore, our solution of NaOH and Et(Ac) can be expect resides
in the reactor for 0.231 minutes. This is because the residence time in graph constant. From the graph,
it can conclude that the reactants being reproduce. This could happen due to reaction occurs in backward
direction. The relative corresponding equilibrium concentration have been achieved before the data is
taken. Based on the gradient equation on the graph.
Arrhenius equation represents the fraction of molecules having an energy equal to or greater than
the energy required for activation. Based on the Arrhenius equation, it can be calculated that the
activation energy, Ea is 20.11cal/mol. The overall activation energy calculated were in positive value.
Thus, can conclude that the rates of reaction increase with the increase in temperature. This support the
assumption that the reaction is already reached the relative corresponding equilibrium concentration and
reversed the reaction in backward direction, where NaOH is actually being produced back. The set
point temperature for reaction were set at 50C yet the temperature fluctuates from 49.6 C till 55.5
C because of the heat loss during the reaction thus the rate of reaction was not persistent and the
reaction went to the peak level and then it drop to the normal level. Thus, can conclude that the rates
of reaction increase with the increase in temperature.
There were some errors were observed which lead to defects in result towards the middle part of the
graphs where there might be some heat loss from the system to the surrounding which leads to
inaccurate temperature readings. Misinterpreting the colour of the indicator near the end point. This
will also affect the results. The other error is that the system is not of the same pressure causing the
flow rate to be not stable during the experiment conduction.
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11
6. REFERENCES
1. Fogler, H. (2013). Essentials of Chemical Reaction Engineering. Pearson Education
International.
2. Octave Levenspiel, (2008); chemical reaction engineering, 3 rd edition, Choudhary Press,
Delhi, India. Pg 27 -28
3. Coulson, J.M, Richardson, J.F (1996). "Chemical Reaction Engineering" Vol-1. 5th Ed.
ND: Asian Books Ltd. pp 349-350.
4. Holman, J.P (2008). "Chemical Engineering 9th Ed. ND: McGraw Hill. pp 25-27.
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7. APPENDIX
Data Table:
1.987 cal/mol K
r2 h * 1000
(0.07)2 (0.15) * 1000
= 2.31L
20ml
10ml
0.1 g eq/L
0.1 g eq/L
0.1 g eq/L
CAO = NNaOH
(1)
= 0.1mole/L
CA = (Cao - [(NV/ (1000) ]/0.03)
(2)
= (0.1-[(0.10 x 17) /1000 ]/0.03)
= 0.043mole/L
XA = (CA0 Ca) / CAO
(3)
= (0.1-0.043)/0.1
= 0.57
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13
(Vr
/(
V0)
(4)
= (2.31L) / 10LPH)
= 0.231 min
k= Ae-Ea/ RT
0.577= 1013 e-Ea/(1.987) (323)
Ea=20.11cal/mol
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(6)