SPM Trial 2014 Chemistry Qa Kedah SetB

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MODULE 2
CHEMISTRY 2014
KEDAH
PAPER 1 ANSWER
Question No.
Answer
Question No.
Answer
26
27
28
29
30
31
32
33
34
35
11
36
12
37
13
38
14
39
15
40
41
42
43
19
44
20
45
21
46
22
47
23
48
24
49
25
50
9
10
16
17
18
MARK SCHEME : PAPER 2 MODULE B: CHEMISTRY

Question
Mark Scheme
No
1 a) Empirical formula : formula that shows the simplest whole number ratio of atoms of
each element in a compound
b) To allow oxygen from the air to react with magnesium //
To prevent fumes of magnesium oxide from escaping
d)
(i) Mass of magnesium = 19.20 - 18.30 g = 0.9 g
(ii)
Mass of oxygen
Elements
No of mole
Ratio
(e)
= 19.80 - 19.20 g = 0.6 g

Mg
:
O
0.9
:
0.6
24
16
0.0375
0.0375
0.0375
0.0375
//
Total
(ii)
(iii) MgO
(i) Cu // Pb // Sn
(ii) To remove all the air in the combustion tube
(iii) To dry the hydrogen gas // as a drying agent
Question
No
2 (a)
(b)
(c)
(d)
(e)
(f)
(g) (i)
Marks
Mark Scheme
Marks
Contact Process
Oleum
SO3 + H2SO4 H2S2O7
450-500 OC
Air (udara)
Nitric acid
Acid rain corrodes the buildings made of calcium carbonate/limestone//
Acid rain corrodes concrete building
Reduce combustion of fossil fuels
Channel waste gases from factory through air filtering systems
(accept any suitable answers)
1
1
1
1
1
1
1
1
1
Total
1
1
1
1
9
(a)
(b)
Heat released when one mol of water produce from reaction between hydrochoric
acid // acid and sodium hydroxide// alkaline solution.
(i)
(ii)
(iii)
Heat change = mc
= 200 x 4.2 x 13
= 10 920 J = 10.92 kJ
No. of mol of H+ = 100 x 0.2

1000
= 0.02 mol
// No. of mol of OH- = 100 x 0.2
1000
= 0.02 mol
1
Heat of neutralisation = 10920
0.02
= 546 000
Heat of neutralization = - 546 kJ mol-1
1
(c)
H = - 546 kJmol-1
(d)
correct diagram
labelled
(i)
Between -533 kJ mol-1 to 542 kJ mol-1
(ii)
Ethanoic acid is a weak acid // ionise partially in water to produce hydrogen ion
Some heat is absorbed for ionization of ethanoic acid.
Total
10
(a)
(b)
(c)
(d)
(i)
(ii)
(i)
(ii)
(i)
(ii)
(iii)
Strong acid is an acid that ionises completely in water to produce high

concentration of hydrogen ions.
Ethanoic acid
Ionise partially in water //produce low concentration of hydrogen ions.
2
10 x X = 250 x 0.02
X = 0.5 mol dm-3
water
H+
Zn +2 HCl ZnCl2 + H2
1.correct formula and reactant
2.balancing
1
1
1
1
1
1
1
1
1
1
Total
(a)
Sulphuric acid
[r: H2SO4]
(b)
H2SO4 + 2KOH K2SO4 + 2H2O
Correct formula reactant and product

Balanced
(c)
(i)
10
1
1
Able to calculate the volume of Y(V1) acid used with unit

M1V1 = M 2V2
a
b
0.1 (V1) = 0.2(25)
1
2
V1 = 25 cm3 (r : without unit)

(ii)
Able to calculate the mass of salt formed with unit

Number of mol Y acid = MV
1000
= 0.1(25)
1000
=0.0025
Mass of salt formed= 0.0025 x 174
= 0.435 g (r : without unit)
(d)
The solution is heated until saturated /one third of its original volume
Cool the solution slowly
The salt are filtered and dried by pressing them between filter papers.
1
1
1
(e)
Sodium sulphate//Potassium nitrate//sodium nitrate//sodium chloride//potassium

chloride
11
6
(a)
(b)
Alkene / alkena
1
1
H H H
I I I
HCCCH
I I I
H H H
(c)
(i)
C3H6 + 9/2O2 3CO2 + 3H2O

2
(ii)
Correct formula of reactant and product

Balance equation
Propene produce more soot
% of C in propene is higher than that in propane
% of C in propene;
3 X 12 X 100 = 85.71%
42
% of C in propane:
1
1
3 X 12 X 100 = 81.82%
44
(d)
Propene is an unsaturated hydrocarbon but propane is saturated hydrocarbon //

Propene has double bond but propane has single bond
(e)
Glass wool
soaked with
propanol
Gambarajah berfungsi
label
anak panah : heat
1
1
1
TOTAL
11
Section B http://cikguadura.wordpress.com/
7
(a)
(i)
(ii)
(b)
(i)
1.No of mole of helium atoms= 4 mol //1 mol

4
2. No of mole of hydrogen atoms = 2 x 2mol //2 mol
2
1.No of atom of hydrogen is double/twice than helium

2.because no of mole of atom of hydrogen is double/twice than helium
Empirical formula = C5H7 N
Molecular Formula = C10 H14 N2
1
1
1
1
C5H7 N
C10 H14 N2
1
both contain element carbon,hidrogen and nitrogen
(ii)
(c)
(i)
(ii)
(iii)
Contain 5 carbon atoms,7

Contain 10 carbon atoms,17
hidrogen atoms and 1 nitrogen
hidrogen atoms and 2 nitrogen
atom
atom
Shows simplest whole number
Shows actual number of atom of
ratio of atom of each element
each element
1.brown bromine water decolourises
2.nicotine undergoes addition reaction with bromine//c=c react with bromine
1+1
1+1
1
1
Wrong formula
1. AgCl2
2. Mg NO3
2AgNO3 + MgCl2 2AgCl + Mg(NO3)2
1
1
1.correct formula of reactant and product

2.correct balancing
1
1
1. silver nitrate and magnesium chloride are reactants and silver chloride and
magnesium nitrate are products
2. silver nitrate , magnesium chloride and magnesium nitrate are in aqueous
solution but silver chloride in solid form
3. 2 mole of AgNO3 react with 1 mole of MgCl2 to form 2 mole of AgCl and
1mole of Mg(NO3)2
(Note : point 3 ecf from (c)(ii))
Total
1
1
20
8(a)
(i)
2H2O2 2H2O + O2
Correct formula
balanced
1
1
Correct curve
axis and units
label expt(A,B) and time (20,40)
1
1
1
i) Increase the concentration of hydrogen peroxide

ii) 0.1 mol dm-3 /
any suitable higher concentration
3
iii) Volume 25 cm /
any suitable volume to get that match the
concentration
iv) Any suitable application of concentration.
1
1
1
v) How the application is used.
(ii)
EkspB
Eksp A
20
(iii)
40
(iv)
functional diagram
Labelled
1
1
(c)
(c)
(i)
1. Rate of reaction of experiment B is higher
2. The presence of catalyst in experiment B
3. the reaction through the alternative path // lower activation energy
4. more colliding particle can achieve the lower activation energy
5. frequency of effective collision is higher.
(ii)
Eksp B
Activation
energy
Section C
9
a)
Eksp A
Correct graph
Label experiment (A,B)
Label activation energy
Total
20
i.
Ionic: Y and X// Y and Z// Y and W

Covalent: W and X//W and Z //X and Z
ii
Ionic:
Between Y and X
2-
1
1
X
or
Between Y and Z
ii.
Covalent
Correct no of shells and electron for each atoms involved
Correct no of atoms// charge for each compund
1x2
1x2
ii
Explain:
Between element Y and X(sample for ionic)
Atom Y has 1 valence electron and atom X has 6 valence electron
2 Atom of Y donate 1 electron each to form 2Y+ ion // 2Y 2Y+ + 2e
Atom X accept 2 electron to form X2- ion // X + 2e X2To achieve stable octet electron arrangement
+
22 ion Y and ion X attract each other by a strong electrostatic forces
// Y2X ionic compound is formed
1
1
1
1
1
Between element W and X (WX2)(sample for covalent)

One atom W contribute 4 electrons
Four atom Z contribute 1 electron to share.
One atom W share 4 pairs electron with four atom Z
Four single covalent bond are formed
WZ4 covalent compound is formed
1
1
1
1
1
Maximum mark 12
b)
Covalent Compound
Low melting and boiling points
Held by weak intermolecular
forces
Need more energy to overcome
the forces
Ionic Compound d
High melting and boiling points
Held by strong electrostatic
forces
Need less energy to overcome
the forces
1+1
1+1
1+1
or
Covalent Compound
Ionic Compound
Cannot conduct electricity in Cannot conduct electricity in
any state
solid state
1+1
10
Consist of molecules
Neutral particles
Can conduct electricity in

molten and aqueous state
Consist of ions
Charged particles//Move freely
in molten and aqueous state
1+1
1+1
mark 6
TOTAL 20
10
(a)
(b)
Metal R: magnesium//zinc
Reason: Metal R is more electropositive than iron// Iron nail does not
rust//prevent iron from rusting//inhibit rusting of iron nail
Metal S: copper//tin//lead//silver//aurum
Reason: Iron is more electropositive than metal S// Iron nail rusts//speed up
rusting
(accept any suitable metal R and S)
1
1
Metal: magnesium // zinc// lead // tin

Eg:
Oxidation nombor of Mg increases from 0+2 //Mg Mg2++2e
Magnesium undergoes oxidation
Oxidation nombor of copper(II) ion decreases from +2 0// Cu2+ +2e Cu
Copper undergoes reduction
Redox reaction occurs as oxidation of magnesium and reduction of copper(II)
ions occur simultaneously.
1
1
1
1
1
(c)
Carbon
electrode
Carbon
electrode
Bromine water
Potassium
iodide
solution
Sulphuric acid
Diagram:
1. label
2. functional apparatus
Suggested chemical:Potassium iodide solution
(or any suitable reducing agent)
1
1
11
Procedure:
1. Dilute sulphuric acid is poured into a U-tube.
2. Using a dropper, potassium bromide solution is added at one arm
and bromine water at another arm.
4. Carbon electrode is placed in each side of the U-tube.
5. The electrodes are connected to a galvanometer by using connecting
wires// The external circuit is completed.
6. Any changes that can be observed are recorded.
1
1
1
1
1
Half-equations:
2I- I2 + 2e
Br2 + 2e 2Br-
1
1
Max 10
Total
END OF MARK SCHEME

20
MODULE B :KIMIA PAPER 3: Mark Scheme
Questions
Mark Scheme
1(a)
Able to state the three variables correctly
Sample answer
- Manipulated Variable: metals in contact with Fe//P,Q,R
- Responding Variable: rusting//blue spots//pink spots
- Constant Variable: iron nail//electrolyte
Able to state any two variables correctly
1(b)
Mark
3
Able to state any one variables correctly
No response or wrong response
Able to state the relationship between the manipulated variable and the
responding variable and state the direction correctly.
Sample answer
The further the distance between two metals in electrochemical series,
When less electropositive metal in contact with iron, the higher is the
intensity/more of blue spots/rust
Able to state the relationship between the manipulated variable and the
responding variable without stating the direction
Sample answer
When different metal in contact with iron, the more blue spot/rust formed
Able to give an idea of hypothesis
Sample answer
Pair of metal willproduce rust.
Able to make inference correctly.
1(c)
Sample answer
1(d)
Inference
Set
I
Metal P is less elctropositive than iron
II
Metal Q is the most electropositive.
III
Metal R is more electropositive than iron
Able to state 2 inference correctly
Able to state 1 inference correctly
Able to give the operational definition for rusting correctly with the
following aspects:
i.what you do
ii.what you observe
Sample answer
When less electropositive metal in contact with iron, blue spot form
Able to give the operational definition for rusting incompletely with any
one of the following aspects:
i.what you do
ii.what you observe
Sample answer
Metal is put into jelly blue spot form
1(e)
Able to give an idea of operational definition for rusting
Sample answer
Metal rust
Able to compare the difference between 1 day and 2 days correctly
Sample answer
The size/quantity of blue spot increase with time
1(f)
1(g)
Able to compare the difference between 1 day and 2 days

Sample answer
More blue spot form
Sample answer
Blue spot form
Able to arrange the four metals correctly

Sample answer
P, Fe, R, Q
Able to arrange any three metals in sequence correctly
Sample answers
Fe, R, Q , // P, Fe, R
Able to arrange any two metals correctly
Sample answers
P, Fe// Fe, R// R, Q
Able to predict the metal correctly

Sample answer
Copper/Cu // Silver/Ag
Able to predict the metal less correctly
Sample answer
Gold/Au
1(h)
1(i)
Able to give an idea of predicting the metal

Sample answer
Mercury/Hg
Able to classify all the six metals correctly

Sample answer
Metal which are less
Metal which are more
electropositive than iron
electropositive than iron
Logam yang lebih elektropositif

daripada besi
Logam yang kurang elektropositif

daripada besi
Magnesium
Aluminium
Zinc
Copper
Tin
Silver
Able to classify any 4 metals correctly

Able to classify any two metals correctly
If reverse
2
1
Able to state all observations correctly

Sample answer
Electrode/Electrolyte
Observation
Elektrod/Elektrolit
Pemerhatian
Negative terminal
Becomes thinner//corrodes
Terminal negatif
Positive terminal
Terminal positif
Electrolyte
Elektrolit
1(j)
Becomes thicker// brown solid

deposited.
Intensity of blue colour
decreases//blue to light blue
Able to state any two observations correctly

Able to state any one observation correctly
2
1
0
Able to record all readings accurately with one decimal place and unit
Answer
Set I : 2.2 V
Set II : 3.4 V
Set III : 1.4 V
Able to record all readings correctly without unit or any two readings
correctly with unit.
Sample answer
Set I : 2.2 //2.20
Set II : 3.4 // 3.40
Set III : 1.4 // 1.40

Able to record at least one reading
1(k)
Able to construct a table that consists of:

1.Headings for manipulated and responding variables with unit
2. List all the variables
Sample answer
Pairs of Metal
Voltage (V)
Fe/P
2.2
Fe/Q
1.4
Fe/R
3.4

1.Headings for manipulated and responding variables without unit
Sample answer
Pairs of Metal
Voltage
Fe/P
2.2
Fe/Q
1.4
Fe/R
3.4

1.Headings for manipulated and responding variables
Sample answer
Pairs of Metal
2(a)
2(b)
1
0
Voltage
Able to give the problem statement correctly

Sample answer
Does soap more effective than detergent for cleansing action in hard water?
Able to give the problem statement
Sample answer
Does soap more effective than detergent ?
Able to give an idea of the problem statement.
Sample answer
Does soap more effective ?
Able to state all variables correctly

Sample answer
Manipulated variable: Detergent ,soap
Responding Variable: effectiveness of cleansing action
Fixed variable : hard water//mass/volume of detergent and
2(c)
2(d)
2(e)
soap//volume of water
Able to state any two variables correctly
Able to state any one variable correctly
Able to state the hypothesis correctly

Sample answer
Detergent is more effective than soap in hard water
Able to state the hypothesis
Sample answer
Detergent is more effective
Able to give an idea of the hypothesis
Sample answer
Detergent is for cleaning action
Able to list the materials and apparatus completely

Sample answer
Materials
1. dirty cloth/socks
2. soap and detergent
3. hard water
Apparatus
1. Beaker/basin
2. Measuring cylinder
3. Spoon/spatula
Able to list the materials and apparatus
Sample answer
Materials
1. cloth
2. soap and detergent
3. hard water
Apparatus
4. Beaker/basin/container
Able to give an idea of materials and apparatus

Sample answer
1. detergent/soap
2. cloth
3. water
Able to state all steps of procedure correctly

Sample answer
1.Pour 100-200 ml of hard water into a beaker
2. Add/put 1-2 spoon of detergent into the beaker
3. Soak/dip a dirty cloth in the beaker
4. Leave for 30 minutes
5.Record the observation
6. Repeat steps 1-5 using soap.
Able to state the steps 1,2,3 and 5
0
3
2(f)
Able to state steps 1.2 and 3

1
0

Sample answer
Observation/Effectiveness
Type of cleaning agent
Detergent
Soap
Sample answer
Type of cleaning agent
Observation
PERATURAN PEMARKAHAN TAMAT


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MARK SCHEME : PAPER 2 MODULE B: CHEMISTRY

= 19.80 - 19.20 g = 0.6 g

No. of mol of H+ = 100 x 0.2

Between -533 kJ mol-1 to 542 kJ mol-1

Some heat is absorbed for ionization of ethanoic acid.

Strong acid is an acid that ionises completely in water to produce high

H2SO4 + 2KOH K2SO4 + 2H2O

Correct formula reactant and product

Able to calculate the volume of Y(V1) acid used with unit

V1 = 25 cm3 (r : without unit)

Able to calculate the mass of salt formed with unit

= 0.435 g (r : without unit)

Sodium sulphate//Potassium nitrate//sodium nitrate//sodium chloride//potassium

C3H6 + 9/2O2 3CO2 + 3H2O

Correct formula of reactant and product

Propene is an unsaturated hydrocarbon but propane is saturated hydrocarbon //

1.No of mole of helium atoms= 4 mol //1 mol

1.No of atom of hydrogen is double/twice than helium

both contain element carbon,hidrogen and nitrogen

Contain 5 carbon atoms,7

1.correct formula of reactant and product

i) Increase the concentration of hydrogen peroxide

v) How the application is used.

1. Rate of reaction of experiment B is higher

2. The presence of catalyst in experiment B

3. the reaction through the alternative path // lower activation energy

4. more colliding particle can achieve the lower activation energy

5. frequency of effective collision is higher.

Label experiment (A,B)

Label activation energy

Ionic: Y and X// Y and Z// Y and W

Correct no of shells and electron for each atoms involved

Correct no of atoms// charge for each compund

Between element W and X (WX2)(sample for covalent)

Can conduct electricity in

Metal: magnesium // zinc// lead // tin

END OF MARK SCHEME

Able to state any one variables correctly

No response or wrong response

Able to make inference correctly.

Able to state 1 inference correctly

No response or wrong response

Able to give an idea of operational definition for rusting

Able to compare the difference between 1 day and 2 days correctly

Able to compare the difference between 1 day and 2 days

Able to arrange the four metals correctly

No response or wrong response

Able to predict the metal correctly

Able to give an idea of predicting the metal

No response or wrong response

Able to classify all the six metals correctly

Logam yang lebih elektropositif

Logam yang kurang elektropositif

Able to classify any 4 metals correctly

Able to state all observations correctly

Becomes thicker// brown solid

Able to state any two observations correctly

Set III : 1.4 // 1.40

Able to construct a table that consists of:

Able to construct a table that consists of:

Able to construct a table that consists of: