TEXTILE
COMPOSITE
PRODUCTION,
MATERIALS
APPLICATION
DEVELOPMENT,
N94-16853
Petr
Y.
Mikhailov,
Ph.D.,
Corresponding
Member
of
International
and
Russian
/ ....
Engineering
Academies,
Academician
of the Engineering
Academy
in St. Petersburg,
General Director of the Research
Institute of Chemical
Fibers and Composite
Materials
Works, Khimvolokno
RI, St. Petersburg,
195030, Russia.
branch
reconstructed
of the
Artificial
into a pilot
fibers works,
Fibers
industrial
Institute
enterprise
was
established
intended
to produce
laboratory
- creation
research
of pilot plants
- pilot industrial
which
production
of new
enable
new
of new fibers
and products
- manufacture
composites
of polymer-polymer
composites
twisting
of fiber structure
economy,
products
economic
trends,
and
based
and
cleaning,
and properties,
of the
the works
fibers.
in the creation
of fibers
based
Institute
of new types
on them
technologies
textile
marketing
on new
some
fibers
types
and sewage
field
based
on such
treatment
and composite
in the
of products
of the
materials
developed
materials
and
In Russia,
the Khimvolokno
RI is the leader in the development
and manufacture
of fibrous
composite
materials
having special properties,
including
the types of materials
(1-4) that follow:
- high-strength
and high-modulus
(para-polyesters)
- heat-resistant
fibers
made
fibers
of polyimides,
was
fibers
materials
gas emission
and in 1968
engaged
development
of textile
of chemicals,
complex
and production
- manufacture
- reclaiming
on the territory
independent:
the "Research
RI) in St. Petersburg.
polymers
of the developed
erected
in 1948,
was
made
of poly-para-aramides
and
and poly-para-arylates
polybenzimidazoles
125
/J
- fluorocarbon
polymer
- carbon
based
fibers
various
types
- porous
on viscose
of polyvinyl
and reinforced
- single-component
above-mentioned
cords,
ropes,
fibers
and polyacryionitrile
alcohol
films
precursors
fibers
for ultrafiltration
and multicomponent
(combined)
and other fibers: braids, ribbons,
textile fabrics
fabrics, knitted
etc.
polymer-polymer
composites
and products:
anti friction, electrical
and radio engineering
constructional,
products,
etc.
heat-shielding,
chemoresistant,
and
medical
applications
by Prof.
R. M. Levit
and
Prof.
L. 1. Fridman
in their papers.
SUPER-HIGH-STRENGTH,
AND MATERIALS
types
- polyvinyl
- para-aramid
SUPER-HIGH-MODULUS
MANUFACTURED
and super-high-modulus
organic fibers and filaments, and textile
them are available
in a wide range of products.
They play an
types
for MVM
for SVM
126
are as follows
(3-5,
9-11):
and terlon
Characteristics
MVM
Strength,
GPa
Modulus
of
Elongation,
sports, medical
and other applications:
rubber products,
composites,
etc.
vinol
Although
the fibers and filaments are available
in a wide
of 29.4 tex and 58.8 tex have the following
properties:
elasticity,
FIBERS,
FILAMENTS,
ON THEIR
BASIS
GPa
%
vinol
range
of linear
densities,
SVM
Terlon
1.2-1.6
4.2-4.5
3-3.3
25-35
120-130
125-140
5-6
3-3.5
2-3
the main
filaments
Should
the need
density
arise,
the thinner
Since
the
filaments
by splicing
above-mentioned
filaments
of 14.2 tex
filaments
feature
developed
for processing
them, allowing
almost unchanged,
i.e., to ensure efficient
high
are manufactured
of 58.8
and
the braids
with
linear
tex.
rigidity,
the corresponding
the maintenance
of their structure
use of 90% or more of their rated
conditions
have
and properties
strength (1-4,
been
to remain
13-15).
The super-high-strength
ropes are manufactured
from the teflon and SVM filaments
and braids on
cord-braiding
machines.
The rope core is composed
of parallel
super-high-strength
filaments
and is
braided with polyfen,
vinol, arimid and SVM filaments.
Those may be illustrated
by referring
to the
properties
of the 6 mm and
10 mm diameter
rope
dia, mm
10
rope
mass,
22
66
17-30
70--95
4-5
4-5
breaking
g/m
load,
elongation,
The
rope
strength
strength
of SVM
ropes
is 2-5
Nonwoven
fabrics
ropes.
GPa
times
that of polyamide
or oil products
are manufactured
from
does
not exceed
SVM
fibers
and
polyester
ropes.
The
annual
loss of
25-35%.
having
the above
properties
as well
as from
principal
MIP
MVP
consumer
characteristics
of the fabrics
Characteristics
Surface
density,
Punching
density,
are as follows:
MIP
MVP
15 0-200
g/m 2,
1/cm 2
Knitting
density
per 100 mm
40/36
knitted
(horizontal-vertical)
Because
nonwoven
of fibrillation
fabrics
When epoxide
of constructional
presents
of fibers
in carding,
the
resulting
web
fabric
is well
formed
and
production
of
no problem.
and epoxyphenol
binders are used, both types of nonwoven
fabrics
fabric-based
laminates
possessing
high mechanical
properties.
allow
production
127
Fiber content,%
50-75
Density,g/cm3
1.25-1.3
Strength,MPa:
450--480
Tensile strength
450-480
Bendingstrength
470-520
Shear strength
110-120
Super-high-modulus
filament-based
fabrics play an important
role in the manufacture of constructional
composite
materials.
High rigidity of the filaments calls for development
of special conditions to prepare
them for weaving
as well as for development
of the weaving process itself. In this case, the following
factors are important:
reduction
of an excessive
bend radius of filament-guiding
parts, reduction
of
filament
friction,
reduction
of filament tension,
and a change in the loom set-up scheme to reduce
dynamic
forces in the filaments.
Weaving
is performed
on shuttle and shuttleless
looms at reduced
speeds. The fabrics produced
have the characteristics
shown in Table 1.
Braids, fabrics and nonwoven
materials of super-high-modulus
fibers and filaments
form the basis for
production
of various types of composite
materials,
where epoxide and epoxy-phenol
binders are used,
by employing
molding methods.
The properties
of these materials
are given in Table 2 for illustration
only.
HEAT-RESISTANT
FILAMENTS
Among
the high-heat-resistant
Khimvolokno
RI in St. Petersburg,
- polyamide:
Arimid,
Their
128
principal
and nonflammable
fibers and
there are two main types:
Arimid
- polyamidobenzimidazole:
characteristics
AND NONFLAMMABLE
FIBERS,
AND TEXTILE
FABRICS
T
Togilen
are as follows:
filaments
designed
and
produced
by
Arimid,
filament,
Togilen,
filament,
11-100
11-200
O. 12-0.44
4O-450
40-60
30-50
6-12
10-15
20-25
Strength retention
at 300C
55-65
60-70
60-70
Strength retention
after heating at
300C, 100 h, %
60-80
Oxygen
42--45
13-15
13-15
Characteristics
Linear
density,
Strength,
tex
cN/tex
Elongation,
index
Moisture
content
Fibers
It should
the most
Woven
and filaments,
Based
2-3
arimid
Togilen,
fiber,
and togilen,
are classed
as heat-resistant
and
nonflammable
materials.
on Arimld
and Arlmid
togilen
is
T. Filaments.
are largely
properties.
- high-temperature
governed by thermal
These are
electrical
insulation
protective
clothing
for firemen,
decorative
transport,
finishing material,
and welfare rooms.
(filaments,
welders,
curtains,
yellow
characteristics,
ribbons,
nonflammability,
low hygroscopieity
fabrics)
etc.
fabrics
colouring
for aircrafts,
places
ships,
definite
automobile
restrictions
and
railway
on their application
as
120
Table
1.
Characteristics
of Reinforcing
on High-Modulus
Linear
density
of filaments,
MVM
tex
Weaver
Filament
vinol
Basket
2/2
Linen
SVM
of
filaments
per
10
Thickness,
crn
of
strip
mm
mm
25
wide,
g/m 2
Elongation,%
140/155
0.65
300
1450/1650
9/I0
29.4/29.4
150/160
0.30
110
1600/1800
14/12
29.4/29.4
300/250
0.35
180
2700/2400
ll/9
Sateen
8/3
29.4/29.4
255/235
0.40
160
2100/2600
12/9
58.8/58.8
178/142
0.42
130
2500/2100
Reinforcing
Filler
2.
Characteristics
of Composites
Made From High-Modulus
Density
g/era
;_
Unidirectional
braid, SVM
fabric
Nonwoven
SVM
Based on Textile
Filaments
Fabrics
MPa
Modulus
tensile
bending
1500-2500
280-300
in tension
GPa
Elongation
rupture
80-84
1.7-2.1
2.5-4.0
500-750
32-40
210-300
14-17.5
fabric,
Unidirectional
braid, Teflon
130
Strength
density
93.5/93.5
Strength,
Teflon
Surface
2/2
Table
SVM
Based
Basket
Linen
Teflon
Number
Fabrics
Filaments
fabric
1.27-1.30
1300-2000
400--600
280-300
-
90-100
1.5-2.0
35-42
2.0-3.0
at
Table3. Characteristicsof
Nonflammable
Characteristics
Types
of fabric
linen
Weave
Linear
density
Number
(stitches)
of filaments
per 10 cm
Thickness,
Surface
29.4/29.4
29.4/29.4
230/240
248/275
0.25
0.32
130
157
mm
density,
crepe
g/m 2
Strength of strip 25 mm
wide, N
Elongation,
Textile
facilities.
1500-1900
15113
and filaments
are readily manufactured
or chemical
fibers, the fibers are also
using
readily
standard
textile
processed.
The
assortment
comprises
various structures
of knitted and nonwoven
fabrics. The characteristics
of (knitted)
fabrics are given in Table 4 for illustration
only. Their applications
are largely governed
by high thermal
properties,
nonflammability,
- protective
- decorative
public
-
clothing
materials,
filtering
insulation,
be noted
metal-makers,
mats
These
are
welders,
for aircraft,
ships,
drivers,
pilot,
automobile
pilots,
and
etc.
railway
transport,
and rooms
high-temperature
It should
for firemen,
finishing
buildings
thermal
media
and some
that in mass
and
other products
as ready-made
Togilen
fibers and filaments
are distinguished
resistant
and nonflammable
fibers and materials
material,
togflen
can be coloured
in bright
hues.
131
Fabric
Weave
Knitted
twill
fabric
satin-stitch
2/2
Linear
density
Number
per
Thickness,
Surface
- ftorin
Table
200/220
120/90
mm
0.40
0.55
240
g/m 2
AND TEXTILE
FLUOROCARBON
FABRICS
BASED
POLYMERS
ON
RI (St. Petersburg)
is the leader in the development
and manufacture
on fluorocarbon
polymers.
The two main types of fibers and filaments
(manufactured
(manufactured
10 cm
density,
FIBERS
- polyfen
29.4
of filaments
(stitches)
In Russia
the Khimvolokno
of fibers and filaments
based
manufactured
are as follows:
58.8/58.8
from
polytetrafluoroethylene)
from a copolymer
5.
Characteristics
of tetrafluoroethylene
of Fabrics
Fluorocarbon
with hexaftuoropropylene)
and Filaments
Based
on
Polymers
Ftorin
Polyfen
Complex
filament
Characteristics
Linear
density,
tex
13--44
Monofilament
10-70
(0.13-0.5
filament
4-20
4MB
Staple fiber
3-5
mm)
Density,
g/cm 3
2.2-2
2.15-2.16
2.15-2.16
2.15-2.16
Strength,
MPa
250-820
150-180
170-210
130-180
15-30
15-30
15-35
20-50
up to +225
up to +200
up to +200
up to +200
Elongation
at rupture,%
Permissible
operating
temperature,
C
132
Complex
Textile
Fabrics
Based
on Polyfen
Filaments.
Antifriction
polymer
materials
based on fluoroplastic,
polyamides
and some other polymers
and
extensively
used in engineering,
are essentially
bonded
in their application
by the magnitude
of unit
pressure,
friction wear and other indicators.
Woven fabrics based on polyfen
filaments
made it possible
to avoid these disadvantages.
The designed
fabrics, such as naftlen,
aftlen, daclen, vsetal, etc., have
an original structure
with such an arrangement
of mutually
related filament systems that only polyfen
filaments
appear on the right side, thereby forming
an antifi-iction
layer.
The inside of the fabrics is
composed
of the filaments
of vinol, cotton yam and other materials
having a high friction
coefficient.
This side of the fabric can be bonded to any hard surface as may be required.
The structure
and surface
of naftlen and aftlen fabrics are smooth, and those of daclen fabric are corrugated.
The characteristics
of these fabrics are given in Table 6.
Special
features
units of machinery,
unit loads.
The above-mentioned
fabrics
offer the possibility
of carrying
large-sized
cargoes
and structures,
whose mass amounts to hundreds
and thousands
of tons, such as bridge bays and structures,
a largesized apparatus,
ships on building
berths, etc.
Table
6.
Characteristics
of Antifriction
Fabrics
Fabrics
Characteristics
Naftlen
Aftlen
Daclen
Vsetal
Combined
two-1 ayer
Weave
Right side and
inside layers
Ancotex
Combined
multi-layer
Polyfen
vinol
Polyfen
cotton
2.5
0.5
1.0
1.4
1500
500
and
lower
600
and
lower
1300
2800
Surface
smooth
smooth
Maximum
unit
load, MPa
600
600
600
Friction
coefficient
0.016
0.016
0.016
0.012-
For steel
0.032
0.032
0.028
0.022
Thickness,
mm
Surface density
g/m 2
Polyfen
arimid
corrugated
Polyfen
vinol
corrugated
1800
Polyfen
lavsan
corrugated
900
133
The composite
antifriction
material,
ataalen,
is produced
by combining
naftlen,
daclen and other
fabrics with the plates made of metal (aluminium
alloys), glass-reinforced
and organic
plastics that
are bonded together.
This material
is manufactured
in the form of sheets and offers the possibility
of
carrying
heavy
large-sized
structures
materials
where
have
and cargoes
no match
among
and average
textile
based
Chemoresistant
fabrics
up to 100-150
the antifriction
speed
on polyfen
and ftorin
phosphoric
Fabrics
of gases.
form
and sulphuric
acids,
chemical
the layers
Another
for trapping
important
splashes
application
tons.
materials
of movement
of filtering, protective
and nonwoven
fabrics designed
chemoresistance
allows these fully fluorinated
fibers
nitric,
thousand
used in various
plants
where
liquid
metal
of
are employed.
fibers
and filaments
include
a variety
agents,
fertilizers,
etc.
of concentrated
of polyfen
process
filament-based
gases.
fabrics
is reinforcement
of fluorocarbon
polymer
films employed
as ion-exchange
membrances
for electrolysis
(of sodium chloride
the manufacture
of caustic soda and chlorine)
and reinforced
ultrafiltration
films (described
The fabrics manufactured
are used in the manufacture
fields
solutions
below).
in
from polyfen and florin filaments may not be wetted with molten metal and
of working clothes
and protective
means for nuclear reactors
and similar
heat-transfer
agents
are employed.
Polyfen
and florin fibers and filaments
are also used in the manufacture
of packing
cords and
glands
for rotary shafts in chemical
equipment
(reactors,
pumps),
and gaskets
for various
devices
such as gate valves, etc. In these cases, braided cords of square, rectangular
and round cross sections
are manufactured
by combining
fluorine
filaments
with carbon,
asbestos
and other filaments.
High
chemoresistance,
heat resistance
and a low friction coefficient
ensure long service life for them.
DEVELOPMENTS
OF NEW TYPES
OF TEXTILE
COMPOSITE
MATERIALS
COMBINED
for organizations
and woven
fabrics
on para-aramid
and other
high-modulus
countries
(1-4,
AND
18, 19).
fibers.
134
linear
density,
modulus
of elasticity,
elongation,
cutting
The
100%
SVM
length,
of SVM fibers
and roving.
1-2
fibers yam
density,
Coefficient
for Linear
of variation
density, %
ensures
the
adequate
6--6.5
per
Relative
strength,
cN/tex
230-250
1 m
28-35
3-3.2
has designed
which
150-170
tex
of twists
the institute
in combing,
characteristics:
Number
Elongation,
time,
65
mm
machine.
Linear
At the same
3-33
by a spinning
apparatus
system that is similar to the one employed
to
comprises
the main equipment
that follows:
Befama
two-web
machine,
ring-spinning
A special feature
binding of the web
100-120
GPa
oil content,
3.5-4.2
tex
woolen
yarn
containing
10% of SVM
fibers.
Carbon
purposes.
Filament-Based
Fabrics.
The traditional
method of producing
carbon
ribbons, and knitted
goods is to manufacture
or polyacrylonitrile)
subsequently
carbonized
limitations:
fibrous materials
such as fabrics, nonwoven
materials,
them from fibers and filaments
of precursors
(viscose
and graphitized.
This method,
however,
has its own
- impossibility
of obtaining
dense structures
because
the fibers carbonized,
which results in an increase
of an abrupt reduction
of through porosity
135
impossibility
of producing
fibers and filaments, some
In order to create new types
carbon fibrous filaments
having
the combined
other types
of composite
the following
woven
materials,
properties:
fabrics
the institute
Types
Characteristics
Linear
density,
Modulus
GPa
along
has designed
1.3-1.5
a serious
conditions
the fabrics
based
on
YKH-5000
450
2.5
2.7
200
240
of elasticity,
150-170
with carbon
of filament
225
GPa
In processing
carbon filaments,
necessary
to development
special
for the weaving
include,
YKH-2500
Ural H
tex
Fiber strength,
which
itself.
In forming
packages
threads were treated with
the traditional
ones. The
filament-guiding
devices
The institute
has designed
the fabrics in which either warp filaments
or weft filaments
are of carbon
type, and the second system filaments
consists of any specified types of ordinary
chemical
fibers. Their
special feature is the choice
of such weaving
conditions
that the carbon
filaments
are laid without
bending as if they are braided with ordinary
chemical
filaments.
When tested for bending,
compression
and tension,
mentioned
fabrics had indices 15-20% higher than those
webs
of the same
filaments
were
employed.
ultrafiltration
film
membranes
have
been
developed
and
are
available
in two
main
types:
-the
type based
(FAM-PA):
- the type based
on
aliphatic
polyimides
on fluorocarbon
polymers
and
reinforced
and reinforced
by
polyimide
by fluorocarbon
filament
gauze
fiber or fabrics.
The
highly
FKM-PTFE
corrosive
material
media.
is used
The
principal
Table
7.
to filter
solutions
characteristics
of acids,
of these
alkalies,
materials
organic
are given
solvents
in Table
and
other
7.
Principal
Characteristics
of Reinforced
Ultrafiltration
Film Membranes
FKM-PIPE
Minimum
retain
0.2 type
0.5 type
1.0 type
3.0
0.2
0.5
1.0
2.0
0.1
0.25
0.6
0.02
0.09
0.05
0.02
FAM-PA
Characteristics
size of
particles,
_m
In conclusion,
pressure,
it should
be noted
Research
Institute
in St. Petersburg
attaches
great importance
to integration
with institutes,
works, and firms in Russia and other countries
(CSFR,
USA, Poland,
Japan, Germany,
Finland) that is accomplished
by establishing
two-sided
contacts
and
with the assistance
rendered
by the Russian concem Khimvolokno
and its organizations
and International
and Russian academies.
In St. Petersburg
especially
close relations were established
within the scope of the F_rlgineering
Academy,
the Institute of Light, and the Textile Industry (research
developments
in new types of fibers
and woven fabrics), Machine-Building
Production
Association
(development),
and the Integrated
Fine
and Industrial
Fabrics
Works
(production
of woven
fabrics).
137
REFERENCES
1. Mikhailow
P. Y., Nachinkin
2. Khimvolokno
O. I., Perepelkin
R.l, Booklet,
Leningrad,
K. E.: Chemical
Nauka,
Properties.
Collected
Chemical
Fibers, Fibrous and Composite
Materials
for Industrial
by Nachinkin
O. I. and Kuznetsova
G. B. Leningrad,
Khimvolokno
5. Perepelkin
K. E.: Structure
6. Reference
Book
Machinostroyenie,
7. Yang
of Composites,
1988. V.I,
H. H.: Aromatic
8. Jambrich
9. Perepelkin
and Properties
M., Pikler
A., Diavik
K. E.: Zbomik
of Fibers,
Moscow:
High-Strength
Fibers,
I.: Fizika
Fibrichem
New
Vlanien,
'89.
1990,
1991.
3. Production
and Application
of Fibers Having Specific
K. E. Mitishchy,
VNIV. Proyekt,
1980, pp. l l0
4.
Fibers,
Sekcia
York,
Bratislava,
Khimiya,
Alfa,
G.A.:
Chemical
Fibers,
1990,
11. Perepelkin
K.E.:
Chemical
Fibers,
Publ.,
Perepelkin
15. Andreyev
A. A. Mikhailov
pp. 36-38.
16. Kovalev
A. D., Mikhailov
CSVTS,
K. E., Andreyev
P. Y., Pershikov
19. Mikhailov
138
M. Y., Volkova
P. Y.: Antifriction
P. Y., Andreyev
N. S., Bunareva
A. A., Krasina
A. A.,
Rumyantseva
V. N., Andriyenko
17. Kovalev
A. D., Mikhailov
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