A,G= +960 kj.mol"! aA 7 Vapour pressure of chloroform (CHC1) and dichloromethane (CHCl) at 25°C are 200 mmHg and 41.5 mmFg respectively, Vapour pressure of the solution obtained by mixing 25.5 g of CHCl, and 40 g of CH,Cl, at the same temperature will be (Molecular mass of CHCi,=119.5 u and molecular mass of CH,Cly=85 u) Q) 2855 mmHg 2173.9 mmHg (3) 615.0 mmHg (@ ° 347.9 mtg The Gibbs’ energy for the decomposition of Al,O, at 500°C is as follows 2 4 3 ALO; ZAL+O, : 4 i ok ‘The potential difference needed for the electrolytic reduction of aluminium oxide (Al,O3) at 500°C is at least . weg a) 50v Q 45v 0 tem : @) sav ano ~ol ee, @y- 25V A a Four successive members of the first series “of the transition metals are listed below, For which one of them the standard potential (Fm ) value has a positive sign? () Fe (Z=26) Q) Co (Z=27) (@) Ni Z=28) aos ek eewinRoRE Sea B 25°C aeerl (CHCI,) Fen STRATA (CHCl) & arey are FAM: 200 meg TT 41.5 mmHg @1 25.5 g CHCl, # Ta 40g CH,Cl, & fre 7 wre faeraa 1 ary ara seh ae x eT, (CHCL #1 FY YR = 119.5 u 98 CHCl #1 ay wR=85 u 8 oo 74). &e ¥ 43 (2) 285.5 mmHg Q) 173.9 mmHg a 0 cae 500°C R Al,O, * fraer & fee fret sat 3) 615.0 mmHg (4) 347.9 mmHg ‘Freafefan et? : z ALO; 4 AL+0, ; cd) +4) 9) e A,G= +960 kj mol-? a SOOCR RaPTPTAH HATES (41,05) % fT, array & fora fara oft an an tar: () 50V ¥ 2) 45Vv ard hee @) 30V (@) 25V *~ arr urged st gem dof & un & are wa am ard ar ager a fora ore B) a fraé fea sé fara (Sheen) srere fare ater 8? (Q) Fe (Z=26) (2) Co (Z=27) (@) Ni (Z=28) (4) Cu (Z=29)B f 4, Which of the following exhibits only +3 oxidation state ? (ly) Pa @ U (3) Th Ac 5. Molar conductivities (Ay, ) at infinite dilution of NaCl/1Cl and EB COONF are 126.4, 425.9 and 91.0 S em? mol! respectively. A\,, for CH;COOH will be L-4ty 390.5 $ cm? mol~1 Het crigtooiBh 4255S em? mokeL cry coowes | (3) 1805Scm? mol"! & oye (4) 290.8 S cm? mol-? = es A eS 50 6. In which of the following arrangements the given sequence is not strictly according to the property indicated against it ? Sry « SiO, < SnO, < PbO, : increasing oxidising power. HF < HC! < HBr < HI: increasing acidic strength H,0 -coon 14. In the replacement reaction SCl+MF—+SCF+MI The reaction will be most favourable if M happens to be : Q) Li UP) Na @) K (4) Rb 13. 14. 280 qq 3 Fre es Fete ar A 278 fen ra to a ar a fre afafear yoy? SOayy tb Or) 50244 * A Orgy, 35 fer rea ere at ar wet Sh? @) 13x1075 Q) 18x«10-% AF @) 3.6x1073 ze (4) 60x17? fre aa a ae wre tahoe ager warm 2? qa - CH=CH, ak CH, =CH-CH=CH), (2) CH,=CH-CN ak CH) =CH CH=CH), (3) Hj,N-CH,-COOH az HN —(CH,);-COOH | (4) HO-CH)~CH)-OH ait Hooc- (>-coon wfrenaa aifaferat 3Cl+MF—+SCE+MI 4, safutaney fer arqge ert af M eh ze Qg ui (2) Na @) K (4) Rb15. 16. B Activation energy (F,) and rate constants | 45, 2 faim ara, 1, 3a Ty ww finn at (k; and k,) of a chemical reaction at two - ‘am a Praia different temperatures (T, and T;) are sal (E,) en (k, 71k) related by “eal Wa van wafer Ki A ; nd a) k Bfl oa a mite Bea) k E, 1 1 a2. Rfid aaa ( ty ) ko E, as eee (al eee 4) in ge =- Fa @ ingre- = (2 5 @ my R eu {i ats 7 &e 7 ra aeelln Bi 7h ne - ba bu aber lat = Ri, tM = ty - misf. kt Which one of the following does not | 16. Aan or am fefiaa yond correctly represent the correct order of the wa} aga orafeaa ae £2 property indicated against it ? (1) Ti< V< Mn < Cr: weet fete oey (1) Ti< V < Mn < Cr: increasing 24 Osa hae ionization enthalpy wae @) Ti CH= NE, BN | city Q® woe NH, (8) CHACH,~ NH~ CH (@) CH,CH,-NH- CH, (4) CHy- N -CHs (4) CH,-N -CH \ tHe : CH; CH ~ a nnn mii tat i : .Se se il Seskes r-atsaseees 9 i #29 4B 6 19. Structure of 2 mixed oxide is cubic close - | 19, war faa stgange at ear or AgfeTa (cp) 7 packed (c.c.p}. The cubic unit cell of mixed 41 fea otaes Hon afd aa sites : oxide is composed of oxide ion’. One i fourth of the tetrahedral voids at sored ar arn Gon Bh Szrege flea ware wT i by fent jand the Sctahedral we therg um fits eng A gro wa ee ‘are occupied by a fronovalenit metal wer afeertge faa ta wedi ng Ba b. The formula ofthe oxide is ft store war { (1) AB,0, 4 qav (1) AB,0, Pa We Q) ABO, » 1 Vt 2 ABO, QY -A,BO, at Bg R® @) A,B, EE "ayes : (A) AgB,O, ge? A) AQB;O, Fetieeitvee we Gere 20. The orbital angular momentum of a | 20, uh p - Faagia an aitfeeet wane p- electron is given as { err fem ora : h : b ya P 3 + (wy v6. oa Ae ¥ a vet wle : 7 2 Lab = ¢ ‘ yk oe h h 2) ene aa @ Fe 4 qh zh * @ Bs @ 8s (Ba ‘i (a) ® WF 21. Four diatomic species are listed below, | 21. Wh fercnmmfam wits 7a fra m3 1 aa Identify the correct order in which the wal oa Si ora aifre fore a ee sey bond order is increasing in them ae aad quRT ae: et 7 f kere mR AES Ait an beer CH,>H, 2) @) HesH,0,, (3) ().O)O,>CH, . Yo H,0,>H, 24. A certain gas takes three times as long to effuse out as helium. Its molecular mass will be gu ay 10 22. 23. 24, arttiratsa Ceri afer) ¢sted W afatio eo fra thal 88 ahs waa eee B (1) waa terete (2) Afra teaeie arate Fat & ford aa ee ores anit ca yer ferat orm [rn Jo-myen RT ve sel ‘a’ atte -b’ 2a et aren feria #1 tae dae: (1) Oy, CO, Hy 3 He (I) CHy, 0, 3 Hy, Be-18 dg tal sy} aed eR ae atk Be-19 8 ag tal aa ak ee A afer fan mae) ei a wel an TA wife (1) (@) HyCH,>H, (2) (I) HeH,>0,, (3) (1)0,0,>CH, (4) () HysHe<0,Hy ve tte difera af gern Preafta a a oe Tr aaa Set 8, ear ory goa aT Q) ou Q) 27u Q) 36u (4) 64025. Consider the following reaction viens a Hy ee Pd—BaSO, ‘The product ‘A’ is (1). CgHgCl \B- CgHsCHO BY GHOH (4) CgH;COCH, 26. Which of the following reagents will be able to distinguish between 1-butyne and 2-butyne () Bry (OY Nani, 3) HCl @) O, 27. Which of the following compounds will give a yellow precipitate with iodine and alkali ? an (1) 2-Hydroxypropane¥ te eee YETORYPFOPAME eco Q) Acetophenone A ‘ er, ; AT Methyl acetate ed (4) Acetamide youre Q Chloroamphenicol is an wr (2) 3) (Yr antiseptic and disinfectant antibiotic - broad spectrum antifertility drug antihistaminic " 25. 26. 27. 28. fre offen oy fran afar : s)-COCL OC oh Se BaSO, ) CgHgCl ) CgHyCHO ) CgHSOH ) CgHsCOCH, Lay oh 22 a st we & fet fre aftrercal Fa sta ara em? Q) 2) @) a) Bry NaNH, Hcl ©2 fre fiat a8 at otdts atk heat mre cet 1 amr sada Se? OQ) 2. aegterihit Q) te 3) | Afwe deze (4) Referee @)29, 30. 31. Given the reaction between 2 gases represented by Ap and B, to give the compound AB) Arg + Big =? AB At equilibrium, the concentration of Ay=3.0x10-> M of By=4.2x1075 M of AB=2.8x 10-4 M Ifthe reaction takes place in a sealed vessel at 527°C, then the value of K, will be wr 45 (2) 2.0 @) 19 (4) 0.62 Low spin complex of d°~cation in an octdtiedral field will have the following energy : aa (a) (4,= Crystal Field Splitting Energy in an octahedral field, P= Electron pairing energy) In the five-kingdom classification, Chlamydomonas and Chlorella have been included in + (1) Monera (2) Protista (3) Algae Plantae 12 29. 30. 31. Ag Wen 8 Bre snfreres wg Heil aa safitinar GA CABG tires aT A2gg) * Bag) =? Bay. WAT Ay, Bw AB Ft APRA FH FARR: A: &t WRM=3.0% 1077 M B, wt BrRa=4.2x 10-9 M AB Gram =2.8x1079 M ate src x ofuten ua ae wa ett ta Ka em: ay 45 2) 20 @) 19 7 (4) 0.62 dé— earn H oremeata vies Yh fer dar at oat fre er: 2 a) A,+P via-aurdta aniferen #, acton’staPara wen aeiiter fared afinfera Fare 7 2 a) a Bae 2) Wee 3) tei (4) eet32, Identify the likely organisms (a), (b), (c) and (d) in the food web shown below 2 ton rvs snakes ~~ i Rae NEN aaa pr \ (@sgarow 2 @) mice NY ‘Vegetation/seeds ~ Options : ere L@ | (2) [squirrel (2)} deer | (3)| @) (b) cat rabbit @ | @ pigeon| rat frog bat dog _| squirrel | deer rat_| dog _ [tortoise crow 33. A test cross is carried out to \@) determine whether two species or varieties will breed successfully. @ determine the genotype of a plant at F. 2 GB) predict whether two traits are linked, assess the number of alleles of a gene. 13 B 32. Aa feed oi ara ate A (a), (b), (c) FH (4) shauna aan ara & weenPe = x ante am Ey Noe { ‘\ aNd © @ \/ ow Ro ee = | freed: fa) (b) ) (@) ) | Freveat] faeet [ar | ae @ | fea [acta] few | ae 3) | apat | Frere] ferres| fet @) | ae | ae | Fee | stn 33. Utened waren fare fed farm sen 8? (a) ae Freitas aed & ferg fs St wena a anneal amaanga sore sth ang 2) we ane, 7 oir aren Frutti & fares 3) Yawn ea & fag fe. dt Aen (fats) sear Fon vat (4) fared aha & Oeil wen Fru aa & faq34, Read the following five statements (A - E) and answer as asked next to them, ~gX)__ In Equisetum the female gametophyte is retained on the parent sporophyte In Ginkgo male gametophyte is not independent, (Gy The sporophyte in Riccin is more developed than that in Polyéricinin. UA(D) Sexual reproduction in Volvox is 35. 36. isogamous. The spores of slime molds lack cell walls How many of the above statements are correct ? a (1) One 32) Two Of” Three (4) Four Which one of the following human organs is often called the “graveyard” of RBCs ? (Q) Liver (2) Gall bladder (3) Kidney Aa) Spleen Which one of the following generally acts as an antagonist to gibberellins ? @) IAA 2) Zeatin (3) Ethylene (ABA 14 34. 35. 36. aa fea aq via wierd (A - B) wo ie de art gore &, see Gifs (A) Fattaiew #, re aeraighre Se sdramy-zefirg oe aH ve BL (8) Foret a ae pereptefine eats eT Bie | (©) fever arany-sefire, rtiergarn ram-sefrg st gern a satire farefira ame (D) aieaan tt aire wer Egat ah a . (2) Tener > dampsi a shes fae ae ert suited eri a fet wate? a) Qa @) am (4) mR frafefea 2 8 at em ue wa sin t fart we: ae ce aftrastt ar “afaET" wer swan? Q) FRA (fare) (2) Framer @) we CR) (4) ter (fareeit) frafetas a ae aa a ce t st ferattert aa faite wa Fad a 8? (1) IAA (2) states (3) Rete (4) ABA ne mm4. 40. 37, » UR) 38. 39. 15 Tobacco plants resistant to a nematode | 37, have been developed by the introduction of DNA that produced (in the host cells), (1) a toxic protein both sense and anti-sense RNA @) +a particular hormone (4) an antifeedant How many plants in the list given below | 3g have marginal placentation ? Muttard, Glam, Tulip, asp&agus’ arker, hemp, Chilji, Colchicine, Qnion, M@ong, Rea, Tobacco, Lupin 8, Res, Tobgcco, Lap () Three (2) Four 6) Five Sin F ! 39. ‘or its activity, carboxypeptidase requires (1) Copper Q) Zine @) Tron (@. Niacin “ 140. ‘The sdcond stage of hydrosere is occupied | by plants like | Qy Vollismeria 2) Azolla () Typha (4) Salix | mearg & yaepha-afadet dei & aa A DNA waa aren rer fad Cri atfirats & stat) farwen ara ava gon? (1) Ge Frees sig Q) ae cen vft-aef eri war SIRNA 8) we fafire anita (4) we weiss (feria) ara dt ng aot Ff @ fad tel 2 star ‘arate=ra da 3? feats, ans, ah, Het, wang, wait a) a Q) aR @) oe @) Ee sare aya et gd aan F ga va eH vee Hz, a fe: (1) Meriter 2) teen (3) aR (4) afore41, 42, 43. 44. 16 Which one of the following structures is an organelle within an organelle ? ) Mesosome (2) Ribosome (8) Peroxisome (4) ER In gobar gas, the maximum amount is that of: (1) Carbon dioxide (2) Butane 8) Methane (4) Propane The first clinical gene therapy was given for treating 1) Adenosine-deaminase deficiency (2) _ Diabetes mellitus (3) Chicken pox (4) Rheumatoid arthritis Which one of the following biomolecules is correctly characterised ? (2) Alanine amino acid - Contains an amino group and an acidic group anywhere in the molecule -@J Lecithin - a phosphorylated phosphory glyceride found in cell membrane @) Palmitic acid - an unsaturated fatty acid with 18 carbon atoms (4) Adenylic acid - adenosine with a vl glucose phosphate molecule 42. 43, 44. Frafefaa 4 a sit di ee dor sine sie si tet 8? () Asie (2) Tsar (3) Fiat (4) ER irae tea A wa safer ar Revert eet #7 Q) Heh spats 2) aR 3) er @ we aad veel Safer ota fafeen free sree & forg ct oe oft? Q) ehh Stare seve 2) wee (3) Bret aren (4) BAe ate frsfafaa 2 3 fea we daar at wet fafercar a wet $7 Q) Bes Gist ave - geri us Oh aRE Bren 8 eT Ty sac ae she orate 7 wg erat Beets (2) Ofefert - ahve feet Yast aren we mteriitfers ralttags (3) wikis one - um ariga wet ana fared 1s ara venga e) (4) Uhfes ara - Rear free ore Ge yah ay arm. ata +45, Ae kK 46. 4 | 47, ‘ i i 4 \ : 1 SREP Green revolution in India eceurred during (1) 1950's (QB 1960's (3) 1970's (4) 1980's Cuscuta is an example of (1) Endoparasitism ) este wa feta spurt an a arta Hert a fara ae wate? Q) ow Qa GB) aa 4) a Presta 9 8 fare war ate & at art aa ar fa 79 seg, fe 2 eR ERR a eI (1) Ayet ter an seq Tet - vite eh (arama) Enos) 2) dew aen onttenttea ataraa (3) Sar fewseh (fitz) gen Aaoee - ai meta eee (4) Gebiy cen Cargcteeto - fawst ache VR wor lem #3 cm fen & ong & St viet wt WAN: -1% 107? C wen 5x 10-2 C ana Fenn tafe, sah us ares ae a sts fen ara ah, a8 sire ae oar are am; Txt? 4 Olen. = 2x10 @pe UE cee 3x10-2C wv oN (@) 4x10"? ¢ Qe oo ame Gis,