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CURVA CALIBRACIN PARA DETERMINACIN DE FSFORO (P2O5)

Longitud de Onda : 420 nm

Abs vs ppm P2O5

Abs orvancia

0.7

ppm P2O5
0
15.51
23.27
31.02
38.78

Transmit
100
46.9
32.7
23.7
22.3

absorv
0.000
0.329
0.485
0.625
0.652

0.6
0.5

f(x) = 0.02096813x
R = 0.9999457089

0.4
0.3

Peso MuestraFd
1.028

0.2192
0.3125

0.2

0.0125

0.1

0.0
%P2O5
ppm P2O5 Pendiente
0
22.64
18.62
0.020968

10

15

20

25

30

35

ppm P2O5

Fact. C celdaTransmitanc Absorvancia


7
40.7
0.390
Factor
correccin de
celdas

Fecha
2/18/2014
2/18/2014
2/18/2014
2/19/2014
2/19/2014
2/19/2014
2/21/2014
2/21/2014

Producto
Fecha Envasado
Patrn Fosfato Dipotasio
Mezclado F Plus parte 1
Mezclado F Plus parte 1 (duplicado)
Patrn Fosfato Dipotasio
Mezclado F Plus parte 1
Mezclado F Plus parte 1 (duplicado)
Patrn Fosfato Dipotasio
Mezclado F Plus parte 1

40

Lote

Fcc
6.4
6.4
6.4
6.4
6.4
6.4
8.1
8.1

Transm. W muestra
Fd
54.3
0.34
0.016
67.9
0.60
0.005
64.2
0.60
0.01
54.3
0.34
0.016
71.5
0.56
0.0025
64.2
0.60
0.01
60.9
0.34
0.02
51.9
0.50
0.01

Base seca
ppm P2O5 P2O5 Teri % P2O5
45.62
10.34
48.66
5.47
6.15
5.13
12.82
7.21
12.02
45.62
10.34
48.66
2.46
5.17
2.31
12.82
7.21
12.02
45.62
7.69
45.21
20.97
10.58
21.16

% Humedad
Total
Total
Total
Total
Total

0.34
0.40

Base
Hmeda
% Humedad % P2O5
11.00
11.00

4.87
11.41

11.00
3.94

2.19
12.31

11.00

18.66

W Muestra
Peso P2O5

0.34 gr
108.8 mg

error blanco :

ppm 1
ppm 2
ppm 3

1088 mg/L
44 mg/L
0.0 mg/L

0.25
f(x) = 0.008076004x
R = 0.9424530215

ppm P2O5 Absorvancia


tramitancia
0
0
98.5
2
4
76.5
5
10
69.3
10
19
62.5
15
29
55.8
20
39
25
48

0.20

94
76.9
69.8
62.6
55.9

a 420 nm
0.000
0.082
0.122
0.164
0.208

0.15

100
82.7
75.5
68.5
61.9

0.10

Column
F

0.05

0.00

10

0.599

0.230

10

15

0.2192021
400

20

25

4x
5

10

104.5
82.5
75.3
68.5
61.8

Column
F

15

20

25

30

34.215
16

100
82.9
75.8
68.6
61.9

W Muestra

error blanco :

0.1095 gr

0.08

f(x) = 0.0029211771x
R = 0.9996138113

0.07

1.5

0.06

ppm P2O5 Absorvancia


tramitancia
0
0
98.5
2
5
95.3
5
12
91.4
10
25
83.3
20
50
69.8
25
62
64.1

a 470 nm
0.000
0.014
0.032
0.072
0.147
0.183

0.05

100
96.8
92.9
84.8
71.3
65.6

0.04
0.03
0.02
0.01
0.00
0

10

15

20

11771x
8113

Column F
Linear
(Column F)

10

15

20

25

30

35

40

W Muestra
Peso P2O5

0.41 gr
254.61 mg

ppm 1 2546.1 mg/L


ppm 2
102 mg/L
ppm 3
0.0 mg/L

0.25

f(x) = 0.0065617544x + 0.0692460443


R = 0.9501635412

0.20

ppm P2O5 Absorvancia


a 470 nm
0
0
2
2
0.081
4
4
0.085
8
8
0.124
15
15
0.188
20
20
0.215
25
25
0.217
30
31

0.15

0.10

0.05

0.00

10

10

0.599

0.230

0 f(x) = 5
R = 0

10

15

20

25

7544x + 0.0692460443
412

Column D
Linear
(Column D)
Column E

10

15

20

25

30

Calibracin Pipeta Volumtrica :

W vaso

103.3 gr
128.2 gr
153.0 gr
177.8 gr
202.7 gr
227.6 gr

25 mL

0 gr
24.9 gr
49.7 gr
74.6 gr
99.4 gr
124.3 gr

Real
0.0 mL
25.0 mL
49.9 mL
74.8 mL
99.8 mL
124.7 mL

Teorico
0 mL
25 mL
50 mL
75 mL
100 mL
125 mL

140
120

f(x) = 1.0022462567x
R = 0.9999999431

100
80
60

Densidad del Agua: 996.59 gr/mL


Temperatura :

27 C

40
20

Column I

0
0

20

40

60

80

100

120

140

Column I
100

120

140

Calibracin Pipeta Volumtrica :

W vaso

112.3 gr
121.9 gr
131.8 gr
141.7 gr
151.6 gr
161.5 gr
171.3 gr

10 mL

0 gr
9.6 gr
19.5 gr
29.3 gr
39.2 gr
49.1 gr
59.0 gr

Real
0.0 mL
9.6 mL
19.5 mL
29.4 mL
39.4 mL
49.3 mL
59.2 mL

Teorico
0 mL
10 mL
20 mL
30 mL
40 mL
50 mL
60 mL

70
60

f(x) = 1.0154913871x
R = 0.9999864188

50
40
30

Densidad del Agua: 996.59 gr/mL


Temperatura :

27 C

20
10
0
0

20

40

70
60

f(x) = 1.0154913871x
R = 0.9999864188

50
40
30
20
10

Column I

0
0

20

40

60

80

Calibracin Pipeta Volumtrica :

W vaso

101.8 gr
106.7 gr
111.7 gr
116.7 gr
121.6 gr
126.6 gr
131.6 gr
136.62 gr

Densidad del Agua: 996.59 gr/mL


Temperatura :

27 C

5 mL

0 gr
5.0 gr
9.9 gr
14.9 gr
19.9 gr
24.9 gr
29.9 gr
34.9 gr

Real
0.0 mL
5.0 mL
10.0 mL
15.0 mL
19.9 mL
25.0 mL
30.0 mL
mL

Teorico
0 mL
5 mL
10 mL
15 mL
20 mL
25 mL
30 mL
35 mL

35
30

f(x) = 1.0019178439x
R = 0.9999989586

25
20
15
10
5
0
0

20

35
30

f(x) = 1.0019178439x
R = 0.9999989586

25
20
15
10
5

Column I

0
0

20

40

Calibracin Pipeta Volumtrica :

W vaso

106.3 gr
108.2 gr
110.2 gr
112.2 gr
114.1 gr
115.1 gr
116.1 gr
118.14 gr
120.14 gr
122.15 gr

2 mL

0 gr
1.9 gr
3.9 gr
5.9 gr
7.9 gr
8.9 gr
9.9 gr
11.9 gr
13.9 gr
15.9 gr

10

Real
0.0 mL
1.9 mL
3.9 mL
5.9 mL
7.9 mL
8.9 mL
9.9 mL
11.9 mL
13.9 mL
15.9 mL

Teorico
0 mL
2 mL
4 mL
6 mL
8 mL
10 mL
12 mL
14 mL
16 mL
18 mL

f(x) = 1.0184490991x
R = 0.999962315

6
4
2
0
0
18.0
16.0
14.0

Densidad del Agua: 996.59 gr/mL


Temperatura :

27 C

12.0
10.0
8.0

f(x) = 1.0034216679x
R = 1

6.0
4.0
2.0
0.0
0

10
8

f(x) = 1.0184490991x
R = 0.999962315

6
4
2

Column I

0
0

20

18.0
16.0

f(x) = 1.0034216679x
R = 1

14.0
12.0
10.0
8.0

f(x) = 1.0034216679x
R = 1

6.0
4.0

Column G

2.0
0.0
0

10

12

14

16

18