CHAPTER 4 SMITH AND

VAN NESS
Cpmonterola che123

Objectives

Learn how to simulate the production process for

propylene glycol using Aspen HYSYS

2012 Aspen Technology, Inc. All rights reserved

INTERNAL ENERGY, U

ENTHALPY, H

HEAT CAPACITY OF GAS MIXTURE

ASPEN HYSYS PROBLEM 4.1

SOLUTION MANUAL

CLAPEYRON EQN AT
PERRY PAGE 4-13

TROUTONS RULE AND RIEDEL:

PERRY PAGE 4-13

WATSON

Constant-Volume Calorimetry
26

qsys = qwater + qbomb + qrxn

qsys = 0

qrxn = - (qwater + qbomb)

qwater = m x s x Dt
qbomb = Cbomb x Dt

Reaction at Constant V
DH = qrxn
DH qrxn

No heat enters or leaves!

Hess law 1

Standard State

Stoichiometric coefficient and heat

of reactions

The standard enthalpy of reaction (DH0 ) is the enthalpy of a

rxn
reaction carried out at 1 atm.
aA + bB

cC + dD

DH0rxn = [ cDH0f (C) + dDH0f (D) ] - [ aDH0f (A) + bDH0f (B) ]

DH0rxn = S nDH0f (products) - S mDHf0 (reactants)

(Enthalpy is a state function. It doesnt matter how you get

there, only where you start and end.)

31

Calculation of heat of reaction

from heat of formations

product reactant

Calculation of heat of reaction

from heat of formations

Heat of combustion

example

Calculation of heat of reaction

from heat of formations

Calculation of heat of reaction

from heat of formations

Calculation of heat of reaction

from heat of formations

Hf,NH3 = -46,110 J/mole

Adiabatic flame temperature or

Theoretical flame temperature

HEAT EFFECTS
8.
A natural gas fuel contains 50 mol % methane, 40 mol %
ethane and 10 mol % nitrogen.
a.
What is the standard heat of combustion (kJ/mol) of the
fuel at 25C with H2O (l) as a product? 10 PTS
b.
The fuel is supplied to a furnace with 50% excess air,
both entering at 25C. The products leave at 300C. If
combustion is complete and if no side reaction occur. How
much heat (kJ/mol of fuel) is transferred in the furnace? 20
PTS

Heat requirement for Heating air