Perhitunngan

Basis perhitungan 1000 gram bahan baku CPO

dari pabrik produksi CPO PT. Tania selatan didapat komposisi CPO sbb:
komponen
trigeliserida
ALB
H2O
Total

%W
93.64
4
2.36
100

komponen

struktur

trioleat
tripalmitat
trilinoleat
tristearat
trimiristat
triekosanoat
trilaurat
trilinolenat

C92H104O6
C51H98O6
C92H98O6
C92H110O6
C45H86O6
C63H104O6
C39H24O6
C92H104O6

As. Oleat
As. Palmitat
As. Linoleat
As. Stearat
As. Miristat

C18H34O2
C16H32O2
C18H32O2
C18H36O2
C14H28O2

H2O
Total

Total

%W
gram
Trigliserida
37.3
373
41.8
418
9.1
91
4.2
42
0.9
9
0.2
2
0.1
1
0.04
0.4
Asam Lemak Bebas
1.6
16
1.79
17.9
0.39
3.9
0.18
1.8
0.04
0.4
Air
2.36
23.6
100
1000

Bahan Baku metanol 2,88 : 1 mol bahan baku CPO untuk kemurnian metanaol antara 9
jadi mol metanol yang dibutuhkan adalah
:
2.88
1000
komposisi bahan baku metanol dari PT. Mtanol Lampung adalah
komponen
%W
CH3OH
96
H2O
4
Total
100
Stream (2)bahan baku metanol adalah
komponen
gram
gram/mol
mol
CH3OH
8847.36
32
276.48

H2O
Total

368.64
9216

18

20.48
296.96

perhitungan stokiometri reaksi trioleat membentuk metil ester (biodiesel) (2)

Reaksi :
konversi reaksi 98%
C92H104O6 + 3 CH3OH
3 C19H36O2 +
mula-mula
0.421946
276.48
bereaksi
0.41350708
1.24052124
sisa
0.00843892
275.23947876
BM
884
32
massa
7.46000528
8807.66332032

Reaksi keseluruhan trigliserida membentuk biodiesel

C92H104O6 + 3 CH3OH
3 C19H36O2 +

C512H8O6 + 3 CH3OH

C92H8O6 + 3 CH3OH

C92H110O6 + 3 CH3OH

C45H86O6 + 3 CH3OH

C63H104O6 + 3 CH3OH

C39H24O6 + 3 CH3OH

C92H104O6 + 3 CH3OH

C3H8O3

3 C17H34O2 +
3 C19H34O2 +

C3H8O3
C3H8O3

3 C19H32O2 +
3 C15H30O2 +
3 C21H42O2 +
3 C13H26O2 +
3 C19H32O2 +

analog perhitungan stoikiometri dari reaksi satuan mol

Reaksi
1
2
3
4
5
6
7
8
Total

Bereaksi
(mol)
36.554
40.964
8.918
4.116
0.882
0.196
0.098
0.039
91.767

Bereaksi
(mol)
109.662
122.892
26.754
12.348
2.646
0.588
0.294
0.118
275.302

Terbentuk
(mol)
109.662
122.892
26.754
12.348
2.646
0.588
0.294
0.118
275.302

analog perhitungan stoikiometri dari reaksi satuan mol

Terbentuk
(mol)
36.554
40.964
8.918
4.116
0.882
0.196
0.098
0.039
91.767

C3H8O3
C3H8O3
C3H8O3
C3H8O3
C3H8O3

C3H

Reaksi
1
2
3
4
5
6
7
8
Total
Reaksi
1
2
3
4
5
6
7
8
Total

Trigeliserida
Bereaksi
(gram)
32313.736
33016.984
7830.004
3663.24
636.804
190.904
62.524
34.182
77748.378

Metanol
Bereaksi
(gram)
3509.184
3932.544
856.128
395.136
84.672
18.816
9.408
3.763
8809.651

Sisa
(gram)
659.464
673.816
159.786
74.76
12.996
3.896
1.276
0.698
1586.702

Sisa
(gram)

Metil Ester
Terbentuk
(gram)
32459.952
33180.84
7865.676
3679.704
640.332
191.688
62.916
34.339
78115.447

Gliserol
Terbentuk
(gram)
3362.968
3768.688
820.456
378.672
81.144
18.032
9.016
3.606
8442.582

37.709

37.709

Jumlah air dari bahan baku metanol dan CPO

Total H2O
: H2O dari CPO + H2O dari CH3OH
: 42,48 gram + 368,640 gram
: 411,120 gram

stream (5) komposisi produk Bottom Reaktor (R-01)

komponen Gugus Senyawa
m (gram)
BM (gram/mol)
mol
CH3OH
Metanol
37.709
32
1.17840625
H2O
Air
411.12
18
22.84
C19H36O2
32459.952
296
109.662
C17H34O2
33180.84
270
122.892
C19H34O2
7865.676
294
26.754
C19H32O2
3679.704
298
12.348
Biodiesel
C15H30O2
640.332
242
2.646
C21H42O2
191.688
326
0.588
C13H26O2
62.916
214
0.215465753
C19H32O2
34.339
292
0.117599315
C92H104O6
659.464
884
0.746

Trigliserida

C51H98O6
C92H98O6
C92H110O6
C45H86O6
C63H104O6
C39H24O6
C92H104O6
C18H34O2
C16H32O2
C18H32O2
C18H36O2
C14H28O2
C3H8O3
Total
komponen
CH3OH
H2O
C19H36O2
C17H34O2
C19H34O2
C19H32O2
C15H30O2
C21H42O2
C13H26O2
C19H32O2
C92H104O6
C51H98O6
C92H98O6
C92H110O6
C45H86O6
C63H104O6
C39H24O6
C92H104O6
C18H34O2
C16H32O2
C18H32O2
C18H36O2
C14H28O2
C3H8O3
Total

673.816
806
159.786
878
74.76
890
Trigliserida
12.996
722
3.896
974
1.276
638
0.698
872
451.2
282
458.24
256
ALB
109.2
280
51.12
284
9.12
228
Gliserol
8442.582
92
89672.44
NERACA MASSA REAKTOR (R-01)
Masuk (gram)
keluar (gram)
Stream 2
stream 4
Stream 5
8847.36
37.709
368.64
42.48
411.12
32459.952
33180.84
7865.676
3679.704
640.332
191.688
62.916
34.339
32973.2
659.464
33690.8
673.816
7989.8
159.786
3738
74.76
649.8
12.996
194.8
3.896
63.8
1.276
34.88
0.698
451.2
451.2
458.24
458.24
109.2
109.2
51.12
51.12
9.12
9.12
8442.582
9216
80456.44
89672.44
89672.44

0.836
0.18198861
0.084
0.018
0.004
0.002
0.000800459
1.6
1.79
0.39
0.18
0.04
91.76719565
396.96

si CPO sbb:

(gram/mol)

mol

884
806
878
890
722
974
638
872

0.421946
0.51861
0.103645
0.047191
0.012465
0.002053
0.001567
0.000459

282
256
280
284
228

0.056738
0.069922
0.013929
0.006338
0.001754

18

1.311111
2.56773

emurnian metanaol antara 90 - 98 %

gram

2880 gram

90 mol

ster (biodiesel) (2)

3 C19H36O2 +

6O2 +

O2 +

O2 +

2O2 +

O2 +

2O2 +

O2 +

2O2 +

C3H8O3

1.24052124
109.662
296
32459.952

C3H8O3
C3H8O3
C3H8O3
C3H8O3
C3H8O3
C3H8O3
C3H8O3
C3H8O3

Metil Ester
(gram/mol)
296
270
294
298
242
326
214
292

mol
0.413507 mol
36.554 mol
92 gr/mol
3362.968 gram