Anda di halaman 1dari 13

Lubribor

LUBRIBOR

Safety Data Sheet

Fuel Additives, Inc.

Section 1: Identification of the Substance/Mixture and of the Company/Undertaking


1.1 Product identifier
Lubribor
Product Name
1.2 Relevant identified uses of the substance or mixture and uses advised against
Relevant identified use(s)

Corrosion inhibitor

1.3 Details of the supplier of the safety data sheet


Manufacturer

Hammonds Fuel Additives, Inc.


910 Rankin Rd.
Houston, TX 77073
United States
www.biobor.com
sales@biobor.com
Telephone (General) (800) 548-9166

1.4 Emergency telephone number


Manufacturer

Chemtrec - US - (800) 424-9300


001-703-527-3887 - Chemtrec INT

Manufacturer

Section 2: Hazards Identification


EU/EEC

According to: Regulation (EC) No 1272/2008 (CLP)/REACH 1907/2006 [amended by 453/2010]


According to: EU Directive 67/548/EEC (DSD) or 1999/45/EC (DPD)

2.1 Classification of the substance or mixture


CLP

Carcinogenicity 2 - H351
Hazardous to the aquatic environment Chronic 2 - H411
Harmful (Xn)
Carcinogenic Substances - Category 3
Dangerous to the Environment (N)
R40, R51, R53

DSD/DPD

2.2 Label Elements


CLP

WARNING

Hazard statements H351 - Suspected of causing cancer.

H411 - Toxic to aquatic life with long lasting effects

Precautionary statements
Prevention P201 - Obtain special instructions before use.
Preparation Date: 01/January/2014
Revision Date: 03/August/2015

Page 1 of 13

Format: EU CLP/REACH Language: English (US)


WHMIS, EU CLP, EU DSD/DPD, OSHA HCS 2012

Lubribor

P202Donothandleuntilallsafetyprecautionshavebeenreadandunderstood.
P273Avoidreleasetotheenvironment.
P281Usepersonalprotectiveequipmentasrequired.
Response P308+P313IFexposedorconcerned:Getmedicaladvice/attention.
P391Collectspillage.
Storage/Disposal P405Storelockedup.
P501Disposeofcontentand/orcontainerinaccordancewithlocal,regional,
national,and/orinternationalregulations.
DSD/DPD

Riskphrases R40Limitedevidenceofacarcinogeniceffect.
R51Toxictoaquaticorganisms.
R53Maycauselongtermadverseeffectsintheaquaticenvironment.
Safetyphrases S36Wearsuitableprotectiveclothing.
S37Wearsuitablegloves.
S53Avoidexposureobtainspecialinstructionsbeforeuse.
S57Useappropriatecontainmenttoavoidenvironmentalcontamination.

2.3OtherHazards
CLP

AccordingtoRegulation(EC)No.1272/2008(CLP)thismaterialisconsidered
hazardous.
ThisproductisconsidereddangerousaccordingtotheEuropeanDirective
67/548/EEC.

DSD/DPD

UnitedStates(US)
Accordingto:OSHA29CFR1910.1200HCS

2.1Classificationofthesubstanceormixture
OSHAHCS2012

FlammableLiquids4
SkinIrritation2
GermCellMutagenicity2
Carcinogenicity2
ReproductiveToxicity2
SpecificTargetOrganToxicityRepeatedExposure1

2.2Labelelements
OSHAHCS2012

DANGER

Hazardstatements Combustibleliquid

Causesskinirritation
Suspectedofcausinggeneticdefects.
Suspectedofcausingcancer.
Suspectedofdamagingfertilityortheunbornchild.
Causesdamagetoorgansthroughprolongedorrepeatedexposure.

Precautionarystatements
Prevention Obtainspecialinstructionsbeforeuse.
Donothandleuntilallsafetyprecautionshavebeenreadandunderstood.
Keepawayfromheat,sparks,openflamesand/orhotsurfaces.Nosmoking.
Donotbreathemists,vapours,and/orspray.
Washthoroughlyafterhandling.
Donoteat,drinkorsmokewhenusingthisproduct.
Preparation Date: 01/January/2014
Revision Date: 03/August/2015

Page 2 of 13

Format: EU CLP/REACH Language: English (US)


WHMIS, EU CLP, EU DSD/DPD, OSHA HCS 2012

Lubribor

Wearprotectivegloves/protectiveclothing/eyeprotection/faceprotection.
Response Incaseoffire:Useappropriatemediaforextinction.
Ifonskin:Washwithplentyofwater.
Takeoffcontaminatedclothingandwashbeforereuse.
Specifictreatment,seesupplementalfirstaidinformation.
Ifskinirritationoccurs:Getmedicaladvice/attention.
IFexposedorconcerned:Getmedicaladvice/attention.
Getmedicaladvice/attentionifyoufeelunwell.
Storage/Disposal Storeinawellventilatedplace.Keepcool.
Storelockedup.
Disposeofcontentand/orcontainerinaccordancewithlocal,regional,national,and/or
internationalregulations.

2.3Otherhazards
OSHAHCS2012

UnderUnitedStatesRegulations(29CFR1910.1200HazardCommunication
Standard),thisproductisconsideredhazardous.

Canada
Accordingto:WHMIS

2.1Classificationofthesubstanceormixture
WHMIS

CombustibleLiquidsB3
ToxicD1B
OtherToxicEffectsD2A
OtherToxicEffectsD2B

2.2Labelelements
WHMIS

CombustibleLiquidsB3
ToxicD1B
OtherToxicEffectsD2A
OtherToxicEffectsD2B

2.3Otherhazards
WHMIS

InCanada,theproductmentionedaboveisconsideredhazardousunderthe
WorkplaceHazardousMaterialsInformationSystem(WHMIS).

Section3Composition/InformationonIngredients
3.1Substances

Materialdoesnotmeetthecriteriaofasubstance.

3.2Mixtures

Composition
ChemicalName

Identifiers
CAS:6474294
5
EC

Preparation Date: 01/January/2014


Revision Date: 03/August/2015

30%

ClassificationsAccordingto
Regulation/Directive

LD50/LC50
InhalationRatLC50
>590mg/m4Hour
Page 3 of 13

Comments

EUDSD/DPD: NotClassified
Format: EU CLP/REACH Language: English (US)
WHMIS, EU CLP, EU DSD/DPD, OSHA HCS 2012

Lubribor

Solventnaphtha

Number:265
1985
EUIndex:649
424003

TO
60%

(s)
SkinRabbitLD50>2
mL/kg

Naphthalene

CAS:91203
EC
Number:202
0495
EUIndex:601
052002

1%
TO
5%

SkinRabbitLD50
>20g/kg
Ingestion/OralRat
LD50490mg/kg

1,2,4
Trimethylbenzene

CAS:95636
EC
Number:202
4369
EUIndex:601
043003

1%
TO
5%

Ingestion/OralRat
LD505g/kg
InhalationRatLC50
18000mg/m4Hour
(s)

EUCLP: NotClassified
OSHAHCS2012: NotClassified

NDA

EUDSD/DPD: AnnexVI,Table3.2:Carc.Cat.3,
R40Xn,R22N,R50,R53
EUCLP: AnnexVI,Table3.1:Carc.2,H351Acute
Tox.4*,H302AquaticAcute1,H400Aquatic
NDA
Chronic1,H410
OSHAHCS2012: Flam.Sol.2AcuteTox.4(orl)
SkinIrrit.2Muta.2Carc.2Repr.2STOTSE3:
Narc.STOTRE1(Blood,EyesOrl,Inhl)
EUDSD/DPD: AnnexVI,Table3.2:R10Xn,R20
Xi,R36/37/38N,R51,R53
EUCLP: AnnexVI,Table3.1:Flam.Liq.3,H226
AcuteTox.4*,H332EyeIrrit.2,H319STOTSE3:
Resp.Irrit.,H335SkinIrrit.2,H315AquaticChronic NDA
2,H411
OSHAHCS2012: Flam.Liq.3SkinIrrit.2EyeIrrit.
2STOTSE3:NarcSTOTSE3:Resp.Irrit.(inhl)
Asp.Tox.1

SeeSection16forfulltextofHstatementsandRphrases.

Section4FirstAidMeasures
4.1Descriptionoffirstaidmeasures
Inhalation
Skin
Eye
Ingestion

Movevictimtofreshair.Administeroxygenifbreathingisdifficult.Giveartificial
respirationifvictimisnotbreathing.Getmedicalattentionifsymptomsoccur.
Incaseofcontactwithsubstance,immediatelyflushskinwithrunningwaterforat
least20minutes.Removeandisolatecontaminatedclothing.Washskinwithsoap
andwater.Ifirritationdevelopsandpersists,getmedicalattention.
Incaseofcontactwithsubstance,immediatelyflusheyeswithrunningwaterforat
least20minutes.Ifeyeirritationpersists:Getmedicaladvice/attention.
DoNOTinducevomiting.Rinsemouth.Drink24cupfulsofwater.Donotgive
anythingbymouthtoanunconsciousperson.Obtainmedicalattentionimmediatelyif
ingested.

4.2Mostimportantsymptomsandeffects,bothacuteanddelayed
RefertoSection11ToxicologicalInformation.

4.3Indicationofanyimmediatemedicalattentionandspecialtreatmentneeded
NotestoPhysician

Alltreatmentsshouldbebasedonobservedsignsandsymptomsofdistressinthe
patient.Considerationshouldbegiventothepossibilitythatoverexposuretomaterials
otherthanthisproductmayhaveoccurred.

Section5FirefightingMeasures
5.1Extinguishingmedia
SuitableExtinguishingMedia LARGEFIRES:Waterspray,fogoralcoholresistantfoam.
SMALLFIRES:Drychemical,CO2,watersprayoralcoholresistantfoam.
UnsuitableExtinguishing
Donotusestraightwaterstream.
Media

5.2Specialhazardsarisingfromthesubstanceormixture
UnusualFireandExplosion
Hazards
Preparation Date: 01/January/2014
Revision Date: 03/August/2015

Containersmayexplodewhenheated.
Vaporexplosionhazardindoors,outdoorsorinsewers.
Page 4 of 13

Format: EU CLP/REACH Language: English (US)


WHMIS, EU CLP, EU DSD/DPD, OSHA HCS 2012

Lubribor

HazardousCombustion
Products

HIGHLYFLAMMABLE:Willbeeasilyignitedbyheat,sparksorflames.
Manyliquidsarelighterthanwater.
Mostvaporsareheavierthanair.Theywillspreadalonggroundandcollectinlowor
confinedareas(sewers,basements,tanks).
Runofftosewermaycreatefireorexplosionhazard.
Vaporsmayformexplosivemixtureswithair.
Vaporsmaytraveltosourceofignitionandflashback.
HazardousdecompositionproductsareoxidesofcarbonandnitrogenincludingCO
andC02.

5.3Adviceforfirefighters
Structuralfirefighters'protectiveclothingwillonlyprovidelimitedprotection.
Wearpositivepressureselfcontainedbreathingapparatus(SCBA).
Movecontainersfromfireareaifyoucandoitwithoutrisk.
LARGEFIRES:Coolcontainerswithfloodingquantitiesofwateruntilwellafterfireis
out.

Section6AccidentalReleaseMeasures
6.1Personalprecautions,protectiveequipmentandemergencyprocedures
PersonalPrecautions
EmergencyProcedures

Ventilateenclosedareas.Donotwalkthroughspilledmaterial.Wearappropriate
personalprotectiveequipment,avoiddirectcontact.Donottouchdamagedcontainers
orspilledmaterialunlesswearingappropriateprotectiveclothing.

Asanimmediateprecautionarymeasure,isolatespillorleakareaforatleast50
meters(150feet)inalldirections.Iftank,railcarortanktruckisinvolvedinafire,
ISOLATEfor800meters(1/2mile)inalldirectionsalso,considerinitialevacuationfor
800meters(1/2mile)inalldirections.LARGESPILL:Considerinitialdownwind
evacuationforatleast300meters(1000feet)ELIMINATEallignitionsources(no
smoking,flares,sparksorflamesinimmediatearea).Keepunauthorizedpersonnel
away.Stayupwind.Keepoutoflowareas.

6.2Environmentalprecautions
Prevententryintowaterways,sewers,basementsorconfinedareas.

6.3Methodsandmaterialforcontainmentandcleaningup
Containment/Cleanup
Measures

Stopleakifyoucandoitwithoutrisk.
Absorborcoverwithdryearth,sandorothernoncombustiblematerialandtransferto
containers.
Usecleannonsparkingtoolstocollectabsorbedmaterial.
Avaporsuppressingfoammaybeusedtoreducevapors.
Allequipmentusedwhenhandlingtheproductmustbegrounded.
LARGESPILLS:Dikefaraheadofliquidspillforlaterdisposal.
LARGESPILLS:Waterspraymayreducevaporbutmaynotpreventignitionin
closedspaces.

6.4Referencetoothersections
RefertoSection8ExposureControls/PersonalProtectionandSection13Disposal
Considerations.

Section7HandlingandStorage
7.1Precautionsforsafehandling
Handling

Preparation Date: 01/January/2014


Revision Date: 03/August/2015

Useonlyinwellventilatedareas.Avoidcontactwithheatandignitionsources.Donot
usesparkingtools.Takeprecautionarymeasuresagainststaticcharges.All
equipmentusedwhenhandlingtheproductmustbegrounded.Donotpressurize,cut,
weld,braze,solder,drill,grind,orexposecontainerstoheat,flame,sparks,static
electricity,orothersourcesofignitiontheymayexplodeandcauseinjuryordeath.
Wearappropriatepersonalprotectiveequipment,avoiddirectcontact.Avoidbreathing
mist,vapoursand/orspray.Avoidcontactwithskin,eyes,andclothing.Wash
thoroughlywithsoapandwaterafterhandlingandbeforeeating,drinking,orusing
tobacco.Emptycontainersmaycontainresidualproduct.Donotreusecontainer
Page 5 of 13

Format: EU CLP/REACH Language: English (US)


WHMIS, EU CLP, EU DSD/DPD, OSHA HCS 2012

Lubribor

unlessproperlyreconditioned.

7.2Conditionsforsafestorage,includinganyincompatibilities
Storage

Keepcontainertightlyclosed.Storeinacool/lowtemperature,wellventilateddry
placeawayfromheatandignitionsources.Protectfromdirectsunlight.

7.3Specificenduse(s)
RefertoSection1.2Relevantidentifieduses.

Section8ExposureControls/PersonalProtection
8.1Controlparameters
ExposureLimits/Guidelines
Result
Naphthalene
(91203)
1,2,4
Trimethylbenzene
(95636)

TWAs

ACGIH
10ppmTWA

NIOSH

OSHA

10ppmTWA50mg/m3TWA

10ppmTWA50mg/m3TWA

STELs Notestablished

15ppmSTEL75mg/m3STEL

Notestablished

TWAs

25ppmTWA125mg/m3TWA

Notestablished

Notestablished

8.2Exposurecontrols
Engineering
Measures/Controls

Goodgeneralventilationshouldbeused.Ventilationratesshouldbematchedto
conditions.Ifapplicable,useprocessenclosures,localexhaustventilation,orother
engineeringcontrolstomaintainairbornelevelsbelowrecommendedexposurelimits.
Ifexposurelimitshavenotbeenestablished,maintainairbornelevelstoanacceptable
level.Useexplosionproofelectrical/ventilating/lighting/equipment.
PersonalProtectiveEquipment
Respiratory
Incaseofinsufficientventilation,wearsuitablerespiratoryequipment.Followthe
OSHArespiratorregulationsfoundin29CFR1910.134orEuropeanStandardEN149.
UseaNIOSH/MSHAorEuropeanStandardEN149approvedrespiratorifexposure
limitsareexceededorsymptomsareexperienced.
Eye/Face
Wearchemicalsplashsafetygoggles.
Skin/Body
EnvironmentalExposure
Controls

Wearappropriategloves.Wearlongsleevesand/orprotectivecoveralls.
Controlsshouldbeengineeredtopreventreleasetotheenvironment,including
procedurestopreventspills,atmosphericreleaseandreleasetowaterways.Follow
bestpracticeforsitemanagementanddisposalofwaste.

Keytoabbreviations
ACGIH = AmericanConferenceofGovernmentalIndustrialHygiene
NIOSH = NationalInstituteofOccupationalSafetyandHealth
OSHA = OccupationalSafetyandHealthAdministration

STEL = ShortTermExposureLimitsarebasedon15minuteexposures
TWA = TimeWeightedAveragesarebasedon8h/day,40h/weekexposures

Section9PhysicalandChemicalProperties
9.1InformationonPhysicalandChemicalProperties
MaterialDescription
PhysicalForm

Liquid

Appearance/Description

Darkamberliquidwithhydrocarbon
odor.

Color

Darkamber.

Odor

Hydrocarbon

OdorThreshold

Datalacking

Datalacking

MeltingPoint/FreezingPoint

GeneralProperties
BoilingPoint
Preparation Date: 01/January/2014
Revision Date: 03/August/2015

Page 6 of 13

Datalacking
Format: EU CLP/REACH Language: English (US)
WHMIS, EU CLP, EU DSD/DPD, OSHA HCS 2012

Lubribor

DecompositionTemperature

Datalacking

SpecificGravity/RelativeDensity

0.89to0.94@59F(15C)Water=1 Density

pH

Datalacking
7.6to7.8lbs/gal

WaterSolubility

Insoluble

Viscosity

20to40Centistoke(cSt,cS)or
mm2/sec@100F(37.7778C)

ExplosiveProperties

Datalacking

OxidizingProperties:

Datalacking

VaporPressure

1mmHg(torr)@75F(23.8889C)
1.6mmHg@100F/37.8C
3.6mmHg@125F/51.7C

VaporDensity

Datalacking

EvaporationRate

Datalacking

FlashPoint

151F(66.1111C)PMCC(Pensky
MartinsClosedCup)

UEL

Datalacking

LEL

Datalacking

Autoignition

Datalacking

Flammability(solid,gas)

Datalacking

Octanol/WaterPartitioncoefficient Datalacking

Volatility

Flammability

Environmental

9.2OtherInformation
Noadditionalphysicalandchemicalparametersnoted.

Section10:StabilityandReactivity
10.1Reactivity
Nodangerousreactionknownunderconditionsofnormaluse.

10.2Chemicalstability
Stableundernormaltemperaturesandpressures.

10.3Possibilityofhazardousreactions
Hazardouspolymerizationwillnotoccur.

10.4Conditionstoavoid
Excessheat,sparks,openflame.

10.5Incompatiblematerials
Avoidcontactwithstrongoxidizers(eg.chlorine,peroxides,chromates,nitricacid,
perchlorates,concentratedoxygen,permanganates)whichcangenerateheat,fires,
explosionsandthereleaseoftoxicfumes.

10.6Hazardousdecompositionproducts
IntheeventofcombustionCO,CO2,Noxmaybeformed.

Section11ToxicologicalInformation
11.1Informationontoxicologicaleffects
Components
Solventnaphtha
(30%TO60%)

AcuteToxicity: InhalationRatLC50>590mg/m4Hour(s) SkinRabbitLD50>2mL/kg


64742 Behavioral:Somnolence(generaldepressedactivity)Behavioral:Changesinmotoractivity(specific
945
assay)Behavioral:Irritability
Irritation: SkinRabbit500L24Hour(s)Mildirritation
AcuteToxicity: Ingestion/OralGuineaPigLD501200mg/kgBehavioral:Somnolence(generaldepressed
activity)Behavioral:Changesinmotoractivity(specificassay) Ingestion/OralRatLD50490

Preparation Date: 01/January/2014


Revision Date: 03/August/2015

Page 7 of 13

Format: EU CLP/REACH Language: English (US)


WHMIS, EU CLP, EU DSD/DPD, OSHA HCS 2012

Lubribor

Naphthalene(1%
TO5%)

1,2,4
Trimethylbenzene
(1%TO5%)

9120
3

9563
6

mg/kg Ingestion/OralMouseTDLo158mg/kgBrainandCoverings:OtherdegenerativechangesLiver:Other
changesBiochemical:Metabolism(intermediary):Lipids,includingtransport InhalationHumanTCLo250
mg/mSenseOrgansandSpecialSenses:Eye:LacrimationBehavioral:Headache SkinRabbitLD50>20g/kg
Irritation: SkinRabbit0.05mL24Hour(s)Severeirritation
MultidoseToxicity: Ingestion/OralRatTDLo500mg/kg10Day(s)IntermittentBehavioral:SleepLungs,
Thorax,orRespiration:Dyspnea Ingestion/OralRatTDLo4500mg/kg10Day(s)IntermittentBrainand
Coverings:Otherdegenerativechanges
Mutagen: SpecificlocustestInhalationRat30ppm13Week(s)Intermittent MicronucleustestUnreported
RouteHumanLymphocyte(Somaticcell)30mg/L
Reproductive: Ingestion/OralMouseTDLo2400mg/kg(714Dpreg)ReproductiveEffects:Effectson
Newborn:LivebirthindexReproductiveEffects:EffectsonNewborn:Viabilityindex(e.g.,#aliveatday4per
#bornalive) Ingestion/OralRatTDLo4500mg/kg(615Dpreg)ReproductiveEffects:EffectsonEmbryoor
Fetus:Fetotoxicity(exceptdeath,e.g.,stuntedfetus)ReproductiveEffects:SpecificDevelopmental
Abnormalities:Otherdevelopmentalabnormalities
Tumorigen/Carcinogen: InhalationMouseTCLo30ppm6Hour(s)2Year(s)Intermittent
Tumorigenic:NeoplasticbyRTECScriteriaLungs,Thorax,orRespiration:Tumors InhalationRatTCLo1575
mg/kg105Week(s)IntermittentTumorigenic:CarcinogenicbyRTECScriteriaSenseOrgansandSpecial
Senses:Olfaction:Tumors InhalationRatTCLo60ppm6Hour(s)105Week(s)Intermittent
Tumorigenic:CarcinogenicbyRTECScriteriaSenseOrgansandSpecialSenses:Olfaction:Tumors
AcuteToxicity: Ingestion/OralRatLD505g/kg InhalationRatLC5018000mg/m4Hour(s)
MultidoseToxicity: InhalationRatTCLo100ppm6Hour(s)20Day(s)IntermittentBehavioral:Changesin
motoractivity(specificassay)Behavioral:AnalgesiaBehavioral:Alterationofoperant
conditioning InhalationRatTCLo20mg/m16Week(s)ContinuousKidney,Ureter,andBladder:Other
changesinurinecomposition

GHSProperties

Classification

Respiratorysensitization

EU/CLP Datalacking
OSHAHCS2012 Datalacking

Seriouseyedamage/Irritation

EU/CLP Datalacking
OSHAHCS2012 Datalacking

Acutetoxicity

EU/CLP Datalacking
OSHAHCS2012 Datalacking

AspirationHazard

EU/CLP Datalacking
OSHAHCS2012 Datalacking

Carcinogenicity

EU/CLP Carcinogenicity2
OSHAHCS2012 Carcinogenicity2

Skincorrosion/Irritation

EU/CLP Datalacking
OSHAHCS2012 SkinIrritation2

Skinsensitization

EU/CLP Datalacking
OSHAHCS2012 Datalacking

STOTRE

EU/CLP Datalacking
OSHAHCS2012 SpecificTargetOrganToxicityRepeatedExposure1

STOTSE

EU/CLP Datalacking
OSHAHCS2012 Datalacking

ToxicityforReproduction

EU/CLP Datalacking
OSHAHCS2012 ToxictoReproduction2

GermCellMutagenicity

EU/CLP Datalacking
OSHAHCS2012 GermCellMutagenicity2

PotentialHealthEffects
Inhalation
Preparation Date: 01/January/2014
Revision Date: 03/August/2015

Page 8 of 13

Format: EU CLP/REACH Language: English (US)


WHMIS, EU CLP, EU DSD/DPD, OSHA HCS 2012

Lubribor

Acute(Immediate)

Maycauseirritation.
Nodataavailable.

Chronic(Delayed)

Skin
Acute(Immediate)

Causesskinirritation.
Prolongedorrepeatedcontactmaydrytheskinandleadtoirritation(i.e.dermatitis)

Chronic(Delayed)

Eye
Acute(Immediate)

Cancausemild,shortlastingirritation.
Nodataavailable.

Chronic(Delayed)

Ingestion
Acute(Immediate)

Maycausenausea,committing,painandstomachupset(e.g.,diarrhea)
Nodataavailable.

Chronic(Delayed)

Other
Chronic(Delayed)
MutagenicEffects

Chronicexposureofworkerstonaphthalenehasbeenreportedtocausecataractsand
retinalhemorrhage.Exposuretoalargeamountofnaphthalenemaycausehemolytic
anemia.
Repeatedandprolongedexposuremaycausemutageniceffects.

CarcinogenicEffects

Repeatedandprolongedexposuremaycausecancer.
CarcinogenicEffects
CAS

Naphthalene

91203

ReproductiveEffects

IARC

NTP

Group2BPossibleCarcinogen

ReasonablyAnticipatedtobeHumanCarcinogen

Repeatedandprolongedexposuremaycausereproductiveeffects.

Keytoabbreviations
LC = LethalConcentration
LD = LethalDose
TC = ToxicConcentration
TD = ToxicDose

Section12EcologicalInformation
12.1Toxicity
Lubribor
Dosage

Species

Duration Results

Exposure
Conditions

Comments

0.213mg/L

Fish:Melanotaeniafluviatilis(ChrimsonSpotted
Rainbowfish)

96Hour
(s)

LC50

NDA

Naphthalene(91203)

136mg/L

Crustacea:Daphniamagna(WaterFlea)

48Hour
(s)

EC50

NDA

Naphthalene(91203)

1mg/L

Crustacea:Daphniamagna(WaterFlea)

48Hour
(s)

NOEC

NDA

Naphthalene(91203)

4.15mg/L

AquaticPlant(s):Scenedesmussubspicatus
(GreenAlgae)

7Day(s)

NOEC

NDA

Naphthalene(91203)

7.72mg/L

Fish:Pimephalespromelas(FatheadMinnow)

96Hour
(s)

LC50

NDA

1,2,4Trimethylbenzene(95
636)

48Hour
(s)

EC50

NDA

1,2,4Trimethylbenzene(95
636)

3.6063mg/L Crustacea:Daphniamagna(WaterFlea)

Toxictoaquaticlifewithlonglastingeffects.
Preparation Date: 01/January/2014
Revision Date: 03/August/2015

Page 9 of 13

Format: EU CLP/REACH Language: English (US)


WHMIS, EU CLP, EU DSD/DPD, OSHA HCS 2012

Lubribor

12.2Persistenceanddegradability
Nodataisavailableonthisproduct.

12.3Bioaccumulativepotential
Nodataisavailableonthisproduct.

12.4MobilityinSoil
Nodataisavailableonthisproduct.

12.5ResultsofPBTandvPvBassessment
NoPBTandvPvBassessmenthasbeenconducted.

12.6Otheradverseeffects
Nostudieshavebeenfound.

Section13DisposalConsiderations
13.1Wastetreatmentmethods
Productwaste

Disposeofcontentand/orcontainerinaccordancewithlocal,regional,national,and/or
internationalregulations.
Disposeofcontentand/orcontainerinaccordancewithlocal,regional,national,and/or
internationalregulations.

Packagingwaste

Section14TransportInformation

14.1UN
number

14.2UNpropershipping
name

14.3Transport
hazardclass(es)

14.4Packing
group

14.5Environmental
hazards

DOT

NA1993

Combustibleliquid,n.o.s.(Contains
AromaticHydrocarbons)

Comb.Liq.

III

NDA

TDG

NDA

NotRegulated

NDA

NDA

NDA

IMO/IMDG

NDA

NotRegulated

NDA

NDA

NDA

IATA/ICAO

NDA

NotRegulated

NDA

NDA

NDA

14.6Specialprecautionsfor Nonespecified.
user
14.7Transportinbulk
Datalacking.
accordingtoAnnexIIof
MARPOL73/78andtheIBC
Code

Section15RegulatoryInformation
15.1Safety,healthandenvironmentalregulations/legislationspecificforthesubstanceor
mixture
SARAHazardClassifications Acute,Chronic,Fire
Inventory
Component

CAS

CanadaDSL

CanadaNDSL

EUEINECS

EUELNICS

TSCA

1,2,4
Trimethylbenzene

95636

Yes

No

Yes

No

Yes

Naphthalene

91203

Yes

No

Yes

No

Yes

Preparation Date: 01/January/2014


Revision Date: 03/August/2015

Page 10 of 13

Format: EU CLP/REACH Language: English (US)


WHMIS, EU CLP, EU DSD/DPD, OSHA HCS 2012

Lubribor

Solventnaphtha

64742945

Yes

No

Yes

No

Yes

Canada
Labor

CanadaWHMISClassificationsofSubstances
Naphthalene
1,2,4Trimethylbenzene
Solventnaphtha

CanadaWHMISIngredientDisclosureList
Naphthalene
1,2,4Trimethylbenzene
Solventnaphtha

91203
95636
64742945

B4,D2A
B3
NotListed

91203
95636
64742945

1%
0.1%
NotListed

91203
95636
64742945

NotListed
NotListed
NotListed

91203
95636
64742945

NotListed
NotListed
NotListed

91203
95636
64742945

NotListed
NotListed
NotListed

Environment

CanadaCEPAPrioritySubstancesList
Naphthalene
1,2,4Trimethylbenzene
Solventnaphtha

UnitedStates
Labor
U.S.OSHAProcessSafetyManagementHighlyHazardousChemicals
Naphthalene
1,2,4Trimethylbenzene
Solventnaphtha

U.S.OSHASpecificallyRegulatedChemicals
Naphthalene
1,2,4Trimethylbenzene
Solventnaphtha

Environment
U.S.CAA(CleanAirAct)1990HazardousAirPollutants
Naphthalene
1,2,4Trimethylbenzene
Solventnaphtha

U.S.CERCLA/SARAHazardousSubstancesandtheirReportableQuantities

91203
95636
64742945

NotListed
NotListed

Naphthalene

91203

1,2,4Trimethylbenzene
Solventnaphtha

95636
64742945

100lbfinalRQ45.4kgfinal
RQ
NotListed
NotListed

91203
95636
64742945

NotListed
NotListed
NotListed

91203
95636
64742945

NotListed
NotListed
NotListed

U.S.CERCLA/SARARadionuclidesandTheirReportableQuantities
Naphthalene
1,2,4Trimethylbenzene
Solventnaphtha

U.S.CERCLA/SARASection302ExtremelyHazardousSubstancesEPCRARQs
Naphthalene
1,2,4Trimethylbenzene
Solventnaphtha
Preparation Date: 01/January/2014
Revision Date: 03/August/2015

Page 11 of 13

Format: EU CLP/REACH Language: English (US)


WHMIS, EU CLP, EU DSD/DPD, OSHA HCS 2012

Lubribor

U.S.CERCLA/SARASection302ExtremelyHazardousSubstancesTPQs
Naphthalene
1,2,4Trimethylbenzene
Solventnaphtha

U.S.CERCLA/SARASection313EmissionReporting

91203
95636
64742945

64742945

0.1%deminimis
concentration
1.0%deminimis
concentration
NotListed

91203
95636
64742945

NotListed
NotListed
NotListed

91203
95636
64742945

carcinogen,initialdate4/19/02
NotListed
NotListed

91203
95636
64742945

NotListed
NotListed
NotListed

91203
95636
64742945

NotListed
NotListed
NotListed

91203
95636
64742945

5.8g/dayNSRL
NotListed
NotListed

91203
95636
64742945

NotListed
NotListed
NotListed

91203
95636
64742945

NotListed
NotListed
NotListed

Naphthalene

91203

1,2,4Trimethylbenzene

95636

Solventnaphtha

U.S.CERCLA/SARASection313PBTChemicalListing
Naphthalene
1,2,4Trimethylbenzene
Solventnaphtha

NotListed
NotListed
NotListed

UnitedStatesCalifornia
Environment
U.S.CaliforniaProposition65CarcinogensList
Naphthalene
1,2,4Trimethylbenzene
Solventnaphtha

U.S.CaliforniaProposition65DevelopmentalToxicity
Naphthalene
1,2,4Trimethylbenzene
Solventnaphtha

U.S.CaliforniaProposition65MaximumAllowableDoseLevels(MADL)
Naphthalene
1,2,4Trimethylbenzene
Solventnaphtha

U.S.CaliforniaProposition65NoSignificantRiskLevels(NSRL)
Naphthalene
1,2,4Trimethylbenzene
Solventnaphtha

U.S.CaliforniaProposition65ReproductiveToxicityFemale
Naphthalene
1,2,4Trimethylbenzene
Solventnaphtha

U.S.CaliforniaProposition65ReproductiveToxicityMale
Naphthalene
1,2,4Trimethylbenzene
Solventnaphtha

15.2ChemicalSafetyAssessment
NoChemicalSafetyAssessmenthasbeencarriedout.

15.3OtherInformation
Preparation Date: 01/January/2014
Revision Date: 03/August/2015

Page 12 of 13

Format: EU CLP/REACH Language: English (US)


WHMIS, EU CLP, EU DSD/DPD, OSHA HCS 2012

Lubribor

WARNING:ThisproductcontainsachemicalknowntotheStateofCaliforniato
causecancer.

Section16OtherInformation
RelevantPhrases(code&fulltext)
H226Flammableliquidandvapour
H302Harmfulifswallowed
H315Causesskinirritation
H319Causesseriouseyeirritation
H335Maycauserespiratoryirritation
H400Verytoxictoaquaticlife
H410Verytoxictoaquaticlifewithlonglastingeffects
R10Flammable.
R20Harmfulbyinhalation.
R22Harmfulifswallowed.
R36/37/38Irritatingtoeyes,respiratorysystemandskin.
R50Verytoxictoaquaticorganisms.
RevisionDate
03/August/2015
PreparationDate
01/January/2014
Disclaimer/Statementof
Liability

USERSRESPONSIBILITY:Abulletinsuchasthiscannotbeexpectedtocoverall
possibleindividualsituations.Astheuserhastheresponsibilitytoprovideasafe
workplace,allaspectsofanindividualoperationshouldbeexaminedtodetermineif,
orwhere,precautionsinadditiontothosedescribedhereinarerequired.Anyhealth
hazardandsafetyinformationhereinshouldbepassedontoyourcustomersor
employees,asthecasemaybe.DISCLAIMEROFLIABILITY:Theinformation
containedhereinis,tothebestofourknowledgeandbelief,accurate.However,since
theconditionsofhandlingandusearebeyondourcontrol,wemakenoguaranteeof
results,andassumenoliabilityfordamagesincurredbyuseofthismaterial.All
chemicalsmaypresentunknownhealthhazardsandshouldbeusedwithcaution.
Althoughcertainhazardsaredescribedherein,wecannotguaranteethattheseare
theonlyhazardswhichexist.Finaldeterminationofsuitabilityofthechemicalisthe
soleresponsibilityoftheuser.Norepresentationsorwarranties,eitherexpressedor
implied,ofmerchantability,fitnessforaparticularpurposeoranyothernatureare
madehereunderwithrespecttotheinformationcontainedhereinorthechemicalto
whichtheinformationrefers.Itistheresponsibilityoftheusertocomplywithall
applicablefederal,stateandlocallawsandregulations.

Keytoabbreviations
NDA = Nodataavailable

Preparation Date: 01/January/2014


Revision Date: 03/August/2015

Page 13 of 13

Format: EU CLP/REACH Language: English (US)


WHMIS, EU CLP, EU DSD/DPD, OSHA HCS 2012

Anda mungkin juga menyukai