Chemistry 322 Inorganic Chemistry Spring 2007 Problem Set 1 In solving the problems for this class, encourage you to work together using whatever resources you need. Please answer the questions fully; use prose, calculations, figures and references as appropriate to communicate your understanding. The organization and comprehensibility of your answer is one basis for its evaluation, As always, the written work that you hand in should be your own. 2, For trans-1,2-dibromo-1,2-dichloroethylene, of C2» symmetry, Determine the symmetry elements and assign the point group of the following molecules or ions. You will need to consult a general chemistry textbook if you do not remember how to use VSEPR to obtain the correct structure of the molecules. Naor Bpts totat (05 pts ech) PF. . PFs — fake of Upt oF ne Deck ) is Pe 3 om moeten alements PBrsF (mast show] Hale Some Symes 74 SF ChPO XeF, Tetrachloroallene ChC=C=CChy Eclipsed Ferrocene (assume the rings are static) (see pg. 526) NOz rrvrer me ae ge ose rk eae a. List all the symmetry operations for the molecule. : b. Write a set of transformation matrices that describe the effect of each symmetry operation in the C2, point group on a set of coordinates x, y, z for a point. (Your answer should consist of four 3 x 3 matrices.) c. Using the terms along the diagonal, obtain as many irreducible representations as possible from the transformation matrices. (You should be able to obtain three irreducible representations in this way, but two will be duplicates.) 4. Using the Cz, character table, verify that the irreducible representations are mutually orthogonal . ; mest 46 3. Problem 7.7 from Shriverand Atkins. ph fe pelt correct (ome) J yt fee al correc # (ea)+ Ja NHC a ae “eé | -G Cy N nig 7 Y b 3a, . K s. Bet + high Symmele feet 6g Gia nee F peeFELeD WaY To DLALD TEP dP Fr fe : y ; |e ov ae . ~G | ~h4. SE, (wessa) 2 mr (see -suw) hy C1; PO (wer = 3a) oN u € Pa - 4 awh" =H lew |h in e . Fe EF ke! G ° 6 (6H) (spare placse ) G reatecred cvey ts Sow a e UE / ob cz cre 1 (bard te see) } N a a Tay ce (alrobas Ly ) b. ¢ oO C7 : Lea's [Fn | Fa : (+60) (7 2. po, (ia ve.) 9 bas —— oy: z Nv = vis lice NZ A 0 CaF inan O& °410 es, itis Bb. dyhas Dy, symmetry ignoring the signs, itis Day. dz yshas Dy, symmetry. Ygporing the signs, itis Da. @ dz has Dig symmeny. Hl 4411 The superimposed octahedron and cube s IN 8c Sid 6C, 6c . Cyaxes. Although there are only three such re i sx axes, counting C,’. G ey through the centers of opposite faces are C, axes as well as C, axes. i ‘of the cube isthe inversion center. 65, The Gaxes are also S, axes. C, axes ate also S, axes. 30, These mirror planes are paralle to the faces of the cube, 6%, These mirror planes are through two opposite edges. w/ ip Czy mofecules have E, C;, i, and 0, operations. Q FBe / a be a bo E10 0G: -1 0 0 &-1 0 0 o1 0 0 Oo 10. 0-1 0 oO-+ 0 “010 004 oo7 00-1 0 0-1 & These matrices can be block diagonalized into three | x | matrices, with the representations shown inthe table. oo tA XG) x(n) ase ” Bot “1 “1 1 from the x and y coefficients (xy accidently the Ad 1-1-1 from the 2 coefficients Sank The total is = 28, +4,. 4, Mukiplying B, and 4,: 1141) 14-1) x (1) +1 * (-1)= 0, proving they are orthogonal.MR, Ss kK A ce hed rool, 6 “mM 7iN cms 7|Ne A A 8 Cay Gr F A . c e le so we ol. a am | 8 Mw 2 CAN we Zac iii oF! Nn 7 (De A A : c hie hk ' ft ce. | oA PRS lea Chiral | vu - trectontes i ee Galen ee : 6