art ic l e i nf o
a b s t r a c t
Article history:
Received 3 March 2015
Received in revised form
25 May 2015
Accepted 21 August 2015
Available online 22 September 2015
Fuel cell technology holds the combination of benets, which are barely offered by any other energy generating technology. Because the fuel used in this technology is found in abundance in nature and can also be
renewed/sustained. Pakistan is blessed with renewable energy resources which are suitable for fuel cell
technology. Therefore, fuel cell technology offers a great opportunity to meet the demand of energy and for
the sustainable development of Pakistan. The energy research group at COMSATS Institute of Information
Technology (CIIT), Lahore has made efforts to study the technical aspects of fuel cell technology and its
commercial benets. The research group is interested in nding ways and means of generating and storing
the energy produced by using fuel cells. In this paper, the research activities on fuel cell technology in
Pakistan have been reviewed and it is also discussed how this technology can resolve the current energy
crises in Pakistan and can be the source of sustainable energy. It has been also reviewed that the country
would greatly benet from fuel cells and fuel cell hybrid system (environmental friendly technology), which
could be the best solution for electricity production as well for automobile industry.
& 2015 Elsevier Ltd. All rights reserved.
Keywords:
Renewable energy
Sustainable development
Hydrogen fuels
Fuel cells
Electrodes
Contents
1.
2.
3.
Introduction . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
Vision of political entities for renewable energy technology in Pakistan . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
Fuel cells and its basics . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
3.1.
Types of fuel cells . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
3.2.
Applications and advantages of fuel cells . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
4. Fuel cell technology in Pakistan . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
5. Challenges and recommendations . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
6. R&D culture . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
7. Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
Appendix A.
Supplementary material. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
References . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
1. Introduction
The world is gradually moving towards serious power crises
due to increase in the demand of energy [1]. Currently, Pakistan is
facing worst energy crisis due to its growing population and poor
Corresponding author.
E-mail address: razahussaini786@gmail.com (R. Raza).
http://dx.doi.org/10.1016/j.rser.2015.08.049
1364-0321/& 2015 Elsevier Ltd. All rights reserved.
450
451
452
452
453
454
458
458
459
459
460
Supply
Demand
100
80
80
60
60
40
40
20
20
2004
2008
2012
2016
2020
2024
2028
Years
Fig. 1. Pakistan power sector need for reforms [77].
0
2032
120
100
0
2000
451
452
is fed continuously from the outside whereas in the lead accumulator, chemicals are stored in the chamber which can be
recharged through external sources of electricity [29]. In FCs, some
renewable fuels, e.g., hydrogen gas, natural gas, biogas etc., are
being used. It is renewable, because it is abundantly available in
the universe and thus can be renewed and replenished without
any end. The hydrogen can be obtained from water and many
other sources. Hydrogen is also available in sufcient quantities in
the earth's atmosphere which also contains oxygen [30]. These
two elements are used in the working of a fuel cell, where they
combine to produce heat, electricity, and water in the form of
vapors [31].
A fuel cell usually contains two porous electrodes that are
separated by a dense electrolyte/membrane. A catalyst, usually
platinum is employed to accelerate the process. Hydrogen and
oxygen are fed at anode and cathode respectively and oxidation
process takes place at the anode in the presence of a catalyst in
such a way that hydrogen splits into electron and proton. Both
charge carriers are now pushed, off course through separate
routes, towards the cathode and electrons travel along an external
path through a load whereas the protons through the electrolyte
where they recombine with oxygen to produce water and heat
[3132]. The basic fuel cell working principle is illustrated in Fig. 3.
In 1839, Sir William R. Grove proposed that if electricity can be
used to split water then it can also be possible to produce electricity by using hydrogen and oxygen in a reverse process. In 1889,
Carl Langer and Ludwig Mond proposed the term 'fuel cell'. In
1932, a fuel cell was made that employed nickel electrodes and
alloys as electrolytic material using used oxygen and hydrogen as
fuel. In 1959, a complete system capable of producing 5 kW electricity was launched [3135].
We may need to consider reactions taking place at each electrode separately for understanding, how the reactions between
hydrogen and oxygen generate an electric current and where the
electrons come from. The basic function of fuel cell is based on the
chemical reactions [36] as follows:
At the anode, hydrogen splits into proton and electron in the
presence of catalyst,
2H2 4H+ + 4e
At the cathode, the proton and electron recombine with oxygen
to produce water,
O2 + 4H+ + 4e 2H2 O
Thus, the overall reaction is:
2H2 + O2 2H2 O
453
454
Table 1
Comparison of fuel cell technologies.
Fuel
cell
type
Common electrolyte
Operating
temp. (C)
System
output
Electrical efciency
PEMFC
5080
1250 KW
5360%(Transportation)2535%
(Stationary)
AFC
Aqueous solutionof
potassium hydroxide
socked in a matrix
Applications
Advantages
Disadvantages
-Backup power
-Portable power
-Transportation
90100
10
100 KW
60%
-Military
-Space
PAFC
150200
50 KW
1 MW
4 40%
-Distributed
generation
MCFC
Liquid solution of
Lithium, sodium or
potassium carbonates
socked in a matrix
600700
1 KW
1 MW
4547%
-Electric utility
-Large distributed
generation
SOFC
6001000
o1 KW
3543%
-Auxiliary power
3 MW
long; however important ones are given below to show the signicance of fuel cell.
i. Effectiveness: temperature is an important parameter which
limits the efciency of a heat engine. Fuel cells do not involve
any combustion process and thus are free from such type of
limitation. For this reason, these are highly efcient with
respect to combustion engines [3335].
ii. Pollutions free: fuel cells do not pollute our environment
because they do not generate any contaminants. They produce
water and heat as a byproduct which can be used for other
purposes [3335].
iii) Simplicity: fuel cells are very simple, reliable, and noiseless
because their functioning is independent of any moving parts.
They have pretty long life which can be as large as 40,000 h.
Furthermore, these can be stacked in modular form to match any
power requirement [3335].
-Electric utility
-Large distributed
generation
-Fuel exibility
-Can use a variety of
catalysts
-Suitable for CHP
-Variety of fuels
455
456
457
458
6. R&D culture
For sustainable progress in FC technology, signicant research
is needed. For this, R&D projects play a pivotal role. A competitive
research culture will also help in low cost products and their
evaluation. All the R&D organization and universities need to be
459
7. Summary
Pakistan is trying to resolve its energy crisis through conventional energy resources but so far little success has been obtained.
To resolve this issue, an effective long term solution must be
adopted in terms of renewable energy technology in addition to
the conventional ways. Pakistan is blessed with several renewable
energy resources which can fulll its energy needs. But due to
certain social, economic, technical, institutional and bureaucratic
barriers, these resources have not been harvested. To strengthen
the renewable energy technologies in Pakistan, a holistic approach
must be employed. The public and private sector should invest in
renewable energy technologies for sustainable energy future. The
major necessities which are operated on non-renewable energy
resources must be converted to renewable ways. Fuel cell technology is one of most promising renewable energy technologies
due its compatibility/usefulness with several renewable energy
resources and being combustion free. In addition, the diverse
applications of FC technology make it the most suitable candidate
to justify our future energy demands and sustainable development
of Pakistan. The fuel used in FC Technology is cheap and has high
efciency as compared to the conventional fuels. However, presently the energy produced from FC is not cheap. The cost will be
dramatically reduced in future by the development of improved
fuel storage techniques and cheap electrolytes. It is not easy and
short term way to adopt fuel cell technology, if considered all
hurdles and issues. But it can be possible/successful, and sustained,
by long-term commitment from fundamental research to commercial development and effective policies. Therefore, FCs hybrid
systems are most suitable for Pakistan.
460
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