DB
N
-
V.,"
(4.03)'
'
(3)
so that
Fig.
Page 562
72% decomposition. The ethane content of the mixed stream varied from
7 to 22%.
EXPERIMENTAL
Apparatus
A.1.Ch.E. Journal
May, 1965
WENCH
H.
u
c2nG
sembly.
A.1.Ch.E. Journal
Page 563
INFORMATION RETRIEVAL*
Abstract: The method for predicting the viscosity of binary nonpolar gaseous
mixtures from pure component Lennard-Jones force parameters and composition
has been extended to multicomponent mixtures. The 136 mixtures examined
contained from three to seven components from sixteen different gases in the
temperature range from 5 " to 1,014"C. The predicted gaseous viscosities should
fall between -0.3 and -6.7% of the actual viscosities 9 5 % of the time. With
a slight modificotion of the constant in the viscosity expression, the viscosity can
be predicted to within It 3.2% of the experimental viscosity 9 5 % of the
time for mixtures containing three or more components.
Stagnation in a fluid interface: properties of the stagnant film, Merson, R. L., and
J . A. Quinn, A.1.Ch.E. Journal, 11, No. 3, p. 391 (May, 1965).
A. Stagnation-8, 7, Interface-9, Fluids-9, Water-9, Channel-9, Horizontal-0, Compressible-0, Incompressible-0, Stearic Acid-6, Oleic-6, 9, Dodecyltrimethylammonium Chloride-6, 9, Film-8, Contaminants-6, Monolayers-9, Surface
Active Agents-6, 9, Concentration-6, Surface Equation of State-8, Acids (Carboxylic)-6, 9, Fatty Acids-6, 9.
Key Words:
Gas analyses were done with a PerkinElmer Vapor Fractometer, Model 154B,
equipped with a Leeds & Northrup recorder Model G, provided with a Disc integrator. The column was two meters of
silica gel, operated at 50C. and 10 lb./sq.
in. gauge helium pressure. Good resolutions of hydrogen, nitrogen, methane,
ethylene, and ethane were obtained. The
chromatograph was calibrated with known
volumes of the pure components.
Materials
Experimental measurements have been performed for pulsed perforotedplate columns of different column geometry, to determine longitudinal dispersion
coefficient for each phase, droplet size, and droplet holdup. These quantities are
correlated with operating conditions and column geometry, including those published by different authors.
Abstroct:
* For details on the use of these Key Words and the A.1.Ch.E. Information Retrieval
Program, see Chem. Eng. Progr., Vol. 60, NO. 8, p. 88 (August, 1964). A free copy of
this article may be obtained by sending a post card, with the words "Key Word
Article" and your name and address (please print) to Publications Department, A.I.Ch.E.,
345 East 4 7 St., N.Y. N.Y., 10017. Price quotations for volume quantities on request.
Free tear sheets of the information retrieval entries may be obtained by writing to the
New York office.
Page 564
A.1.Ch.E. Journal
Mixing
Effective Length
$5 to members
$10 to nonmembers
A. I.Ch. E. Journal
Page 565
INFORMATION RETRIEVAL
Flow Regime
no
Abstract: This paper presents a study of flux, film thickness, and velocity profiles
in the drainage and withdrawal processes of non-Newtonian fluids on flat plates.
The flow equations for the drainage from a vertical plate are solved far an
Ellis model fluid. The withdrawal case i s solved for the power law fluid.
I
Coalescence of liquid drops in two-component-two-phase systems: Part 1. Effect
of physical properties on the rate of coalescence. Part II. Theoretical analysis of
coalescence rate, Jeffreys, G. V., and J. L. Hawksley, A.1.Ch.E. Journal, 11, NO.
3, p. 4 13 (May, 1965).
Key Words: Coalescence-8, Single Drops-8, Plane Interface-8, First Step Coalescence-8, Overall Coalescence-8, Benzene-5, Iso-Octane-5, Normal Heptane-5,
Liquid Poraffin-5, Interfacial Tension-6, Viscosity-6, Drop Size-6, Density-6,
Descent Distance-6, Temperature-6, Coalescence Time-7, Coalescence Time Distribution-7, Mathematical Model-] 0, Correlation-10, High-speed Photography-10.
Abstract: Experimental coalescence time and time distribution studies of a single
drop a t a plane interface are presented for four two-component-two-phase systems.
The experimental results have been analyzed by dimensional and statistical
analysis and a correlation of coalescence time and time distribution with physical
properties presented. This is followed with the presentation of a theoretical model
to estimate film drainage time and the pressure drop in the film which has
shown that the film is thinnest at i t s periphery. High-speed photographic studies
confirmed the theoretical model findings.
The mixed suspension, mixed product removal crystallizer as a concept in crystallizer design, Randolph, Alan D., A.1.Ch.E. Journal, 11, No. 3, p. 424 (May, 1965).
1965).
Key Words: A. Design-8, Crystallizers-9, 8, Crystallization-8, Kinetics-7, Crystal
Bounded and patched solutions for boundary value problems, Churchill, Stuart
A.1.Ch.E. Journal, 11, No. 3, p. 431 (Moy, 1965).
Key Words: A. Mathematical Model-8, Approximate Solutions-8,
W.,
Bounding-10,
B. Bounding-10, Conduction-9, Convection-9, Solution-8, Analytical-0. C. Patching- 10, Conduction-9, Solution-8, Analytical-0, Freezing-9.
Abstract: The technique of bounding, that i s of constructing general solutions for
all ranges of the variables and parameters from solutions for a few limiting
and special cases, is outlined and illustrated for problems in conduction and
convection. The technique of patching, that i s of constructing approximate solutions
for multiphase media by the combination of pseudo solutions for the different
regions, is also outlined and illustrated for problems in conduction and freezing.
The shortcomings and possible inaccuracies of these two techniques are indicated
as well.
- 205
t3
-3
OISTANCE FROM
&
t6
+9
A.1.Ch.E. Journal
t-
sL,,,P
1/2(n, %)RTA"g
(2)
0.8
0.6
0.4
00
0.5
1.0
15
20
ON TWO)
decompo-
A.1.Ch.E. Journal
Page 567
Significance of pressure gradients in porous materials: Part II. Diffusion and flow
in porous catalysts, Otani, Seiya, Noriaki Wakao, and J . M. Smith, A.1.Ch.E.
Journal, 11, No. 3, p. 439 (May, 1965).
Key Words: A. Flow-8, 9, Rate-8, 7, 2, Diffusion-8, 7, 9, 2, Pressure Gradient-6,
the conditions of finite pressure gradients for single- and two-component systems.
Alumina pellets and Vycor were used in the studies. The calculated and experimental results were compared.
a capillary whose wall surface acts as a catalyst and within a spherical, porous,
catalyst pellet. The influence on the effectiveness factor is studied for different
types of diffusion.
c, =
A matrix method for location of cycles of a directed graph, Norman, R. L., A.1.Ch.E.
Journal, 11, No. 3, p. 450 (May, 1965).
10, Nests-9, Cycles-9, Graph-9, Directed-0,
Matrices-10, Program-8, Computer-1 0, Heat Balances-10, 8, 9, Material Balances10, 8, 9, Recycling -1 0, 8, 9.
Page 568
A.1.Ch.E. Journal
Cl
which is approC"
the
first-order behavior
May, 1965
c,
CO
66,500
logo k = 14.19 - - ( 3 )
RTaug
This must be considered only an approximation.
The values were then refined by
computing T , with Equation (l), recomputing contact time with Equation
(2) using T,, recomputing k with this
new contact time, and correlating this
k with T,. The resulting refined relation for the temperature dependence is
64,100
2.3RTm
This is shown in Figure 5. It should
be noted that T, and T,,, differed by
only about 1.5%, and that the refined
Important Wiley
the
Plastics,
HERMANF. MARK,
NORMANG. GAYLORD,
NORBERTM. BIKALES.Latest of a twelve-volume treatment,
covering chemical substances, properties, processes, uses, and general background.
1965. 871 pages. $50 single volume, $40 series subscription price. An Interscience book.
Resins, Rubbers, Fibers. Vol. 2: Amino Resins-Casein.
Kirk-Othmer
Editorial Board:
Second Edition.
Edited by HERMAN
F. MARK,JOHNJ. MCKETTA,
JR., and DONALD
F. OTHMER.
Vol. 5:
Chlorine-Colors for Food, Drugs, Cosmetics. 884 pages. Vol. 6: Complexing AgentsDextrose and Starch Syrups. $45 the single volume. $35 subscription for the entire set.
An Interscience book.
GENERAL PRINCIPLES OF THERMODYNAMICS. By GEORGEN. HATSOPOULOS and JOSEPHH. KEENAN. Represents a new set of definitions and postulates
leading to a rigorous and widely applicable formulation of general principles of thermodynamics. 1965. 788 pages. $15.00
7;?R x 10
~~
A.1.Ch.E. Journal
Page 569
INFORMATION RETRIEVAL
k = Ae-B/RT
Values of log, A and E are compared in the following table:
logd
E,
cal./g. mole
16.06
77,700
14.1
15.33
69,800
77,000
14.02
69,700
14.02
69,700
15.66
74,010
14.19
14.7
70,200
79,300
13.5
64,100
(9)
Sachsse (10)
Kuchler and Thiele
(1)
Steacie and Shane
(12)
Hepp, Spessard, and
Randal ( 1 3 )
Kinney and Crowley
(14)
Vopor-liquid equilibria in hydrogen-benzene and hydrogen-cyclohexone mixtures,
Thompson, Richard E., and Wayne C. Edmister, A.1.Ch.E. Journol, 11, No. 3, p. 457
(May, 1965).
Key Words: A. Vapor-Liquid Equilibrium-8, 9, Binary Mixtures-9, Hydrogen-9,
Normal stress and viscosity measurements for polymer solutions in steody coneand-plote shear, Williams, Michael, C., A.1.Ch.E. Journol, 11, No. 3, p. 467
(May, 1965).
Key Words: A. Viscosity-8, 9, 7, Non-Newtonian-0, Stress-8, 9, 7, Shear Strain-8,
9, 7, Elastic Modulus-8, 9, 7, Measurement-8, Cone-and-Plate Instruments-10,
Temperature-6, Concentration-6, Molecular Weight-6, Chemical Structure-6, Ferry
Reduced Variables- 10, Liquids-9, Viscoelastic-0, Polymers-9, Solutions-9, Rheology-8, Polyethylene Oxide-9, Hydroxyethyl Cellulose-9, Polyvityl Alcohol-9,
Physical Properties-8, 9, 7.
A.1.Ch.E. Journal
Schutt ( 1 5 )
Skinner and Ball
(16)
This work
0 Souders Lecture
0 Hulburt Lecture
$5
$5 with filmstrip
ACKNOWLEDGMENT
(Name)
(Add=)
NOTATION
C
D
= concentration, moles/cc.
= diffusivity, sq.cm./sec.
(Signature)
pre-exponential factor
//
/
I
/
When your next design, engineering or
construction project is assigned, call on
Stearns-Roger for one reliable source.
Upon completion the plant is at the
point of production to run far into the
future, efficiently, economically.
Engineers, Constructors,
Manufacture- to INDUSTRY
A.1,Ch.E. Journal
Page 571
INFORMATION RETRIEVAL
1.:
k
The stability of nonlinear systems in the region of linear dominance: Parts I and
It, Gura, I. A., and D. D. Perlmutter, A.1.Ch.E. Journol, 11, No. 3, p. 474 (May,
1965).
L
= general length of reactor, in.
L,,, = effective length of this reactor,
5 in.
n
= number of g.-moles
P
= pressure, atm.
R
= gas constant
R , = radius of tube, cm.
s
= cross section of tube, sq.cm.
t
= general contact time, sec.
to = contact time of center streamline, sec.
= temperature, K. or C.
TnVu= average temperature deter-
T,
Subscripts
Local rates of mass transfer from spheres in ordered arroys, Rhodes, John M., and
Fred N. Peebles, A.1.Ch.E. Journal, 11, No. 3, p. 481 (May, 1965).
Key Words: Mass Transfer-8, 9, Local-0, Beds-9, 5, Packed-0, Spheres-9, Fluids-9,
Heat Transfer-8, Rate-8, 6, Benzoic Acid-9, Water-9, 5, Sherwood Number-8, 7,
Packing-6, Reynolds Number-6, Flow-9, 6, Carboxylic Acids-9.
Abstract: The local mass transfer rates from a sphere in a regular packing array
have been determined by measuring the local radius change of a benzoic acid
test sphere having been immersed in a water stream. Results in the form of
typical local Sherwood number profiles are reported for single spheres and for
spheres i n simple cubic packing and rhombohedra1 packing.
Pressure drop studies in a plate heat exchanger, Smith, Vernon C., and Ralph A.
Troupe, A.1.Ch.E. Journal, 11, No. 3, p. 487 (May, 1965).
Key Words: A. Pressure Drop-8, 7, Plate Heat Exchangers-9, Heat Exchangers-9,
Design-8, 4, Velocity-6, Water-9, Fluid-9, Chester-Jensen Exchanger-9, Entrance-9, Exit-9, Crossover-9, Ribs-9.
Abstract: This paper presents the results of experimental studies to obtain pressure
drop relationships useful in plate heater design. A plastic prototype of a commercial model (Chester-Jensen) exchanger was fabricated and used t o obtain
entrance, exit, crossover, ribbed section, and overall pressure drops as a function
of velocity with water as the fluid. These individual losses were combined into
an expression for overall pressure drop for a series plastic plate pack having
any number of plates and employing any fluid.
I
Page 572
A.1.Ch.E. Journal
o
= entrance of reactor
1
= exit of reactor
Prod = sum of gaseous products excluding nitrogen
LITERATURE CITED
May, 1965