Electrolysis: the decomposition of a chemical substance (in solution or the molten state) by the
application of electrical energy
Identify the difference between elements, compounds and mixtures in terms of particle
theory
Identify that the biosphere, lithosphere, hydrosphere and atmosphere contain examples
of mixtures of elements and compounds
Identify and describe procedures that can be used to separate naturally occurring
mixtures of:
Describe situations in which gravimetric analysis supplies useful data for chemists and
other scientists
Explain the relationship between the reactivity of an element and the likelihood of its
existing as an uncombined element
Account for the uses of metals and non-metals in terms of their physical properties
Identify that matter is made of particles that are continuously moving and interacting
Apply the periodic table to predict the ions formed by atoms of metals and non-metals
Describe the formation of ionic compounds in terms of the attraction of ions of opposite
charge
Distinguish between molecules containing one atom (noble gases) and molecules with
more than one atom
- Ions
- Atoms sharing electrons
Summarise the differences between the boiling and electrolysis of water as an example
of the difference between physical and chemical change
Boiling Electrolysis
No new substance converts liquid water to Produces 2 new substances
gaseous
Easily reversed cool the vapour to liquid Hard to reverse
Less energy required Much more energy required
- Boiling doesnt alter particles (molecule) only separates them from each other water
vapour contains same water molecules as liquid water
Identify light, heat and electricity as the common forms of energy that may be released
or absorbed during the decomposition or synthesis of substances and identify examples
of these changes occurring in everyday life
- Decomposition:
o Calcium carbonate (limestone) decomposed to make lime, cement, glass
o Aluminium extracted by electrolysing molten aluminium oxide
- Direct combination:
o Rusting of iron to form iron(III) oxide
o Lightning creates such high temp that N2 and O2 gases form nitric oxide
- Stronger the bonds/strength of attraction more energy needed to separate the atoms
- Stronger the chemical bonding the more energy released when the compound is formed
Physical Chemical
Elements - Metals - Metals: form cations/basic
- Non-metals oxides/ionic chlorides
- Semi-metals - Non-metals: form anions/acidic
oxides/covalent chlorides
Compound - Ionic - Different chemical properties to
s o Solid constituent elements
o Soluble - Can be decomposed to component
o Conduct electricity when elements/simpler compounds
dissolved in solution (not solid)
- Covalent molecule
o Dont conduct electricity
o Low MP
o Soft, brittle
- Covalent network
o Non-conductors
o Insoluble
o Very high MP
o Very hard/brittle
Mixtures - Heterogenous - Demonstrate chemical properties of
o Demonstrate physical properties constituent pure substances
of constituent substances
o Dont look same throughout
mixture
- Homogenous
o Physical properties of
constituent substances
o Looks same throughout
- Ionic
o Solid at room temp
o Hard/brittle
o Conduct electricity as liquid/dissolved
- Covalent molecular
o Gases/liquids
o Dont conduct electricity
- Covalent network
o Solid very high MP
o Hard
o Dont conduct electricity except graphite
- Delocalised electrons lost from valence shell of metal atom positive ions
- Attraction between positive metal ions/delocalised electrons is metallic bonding
- Ionic compounds: infinite 3D array of cations and anions bonded by electrostatic attraction
Explain the relationship between the properties of conductivity and hardness and the
structure of ionic, covalent molecular and covalent network structures
IONIC
COVALENT MOLECULAR
COVALENT NETWORK
Metal Use
Copper - Over 8000yrs
- Electrical wiring
- Pipes and plumbing fittings
- Electroplating, jewellery, household decorations
Iron and steel - History: tools/weapons
(alloy of iron) - Railways, bridges, buildings
- Motor car bodies, ships, trains, heavy machinery in industry
- Pipes, nails, nuts, bolts
- Fridge, washing machine, domestic appliances
Lead - Car batteries
- Plumbing and in solder
Aluminium - Buildings (window/door frames, panelling)
- Aeroplanes, motor car parts
- Domestic pots/pans, wrapping foil, drink containers
- High voltage transmission lines
Describe the use of common alloys including steel, brass and solder and explain how
these relate to their properties
Explain why energy input is necessary to extract a metal from its ore
- Most metals found in minerals and energy necessary to extract metal from
compound/mixture
- Energy required to break metal ion-oxide bonds in the ore to separate pure metal from
other substances
Identify why there are more metals available for people to use now than there were 200
years ago
Describe observable changes when metals react with dilute acid, water and oxygen
Describe and justify the criteria used to place metals into an order of activity based on
their ease of reaction with oxygen, water and dilute acids
Identify the reaction of metals with acids as requiring the transfer of electrons
- Reactions of metals with acids transfers electrons from metal metal becomes positive
ions
Outline examples of the selection of metals for different purposes based on their
reactivity, with a particular emphasis on current developments in the use of metals
Outline the relationship between the relative activities of metals and their positions on
the Periodic Table
Identify the importance of first ionisation energy in determining the relative reactivity
of metals
Identify an appropriate model that has been developed to describe atomic structure
- Daltons atomic theory (1803 and 1808):
o Matter composed of tiny invisible particles called atoms
o All atoms of one element identical but diff from atoms of other elements
o Chemical reactions consist of combining, separating, rearranging atoms in simple
whole number ratios
Outline the history of the development of the Periodic Table including its origins, the
original data used to construct it and the predictions made after its construction
- 1829 Dobereiner drew attention to groups of 3 elements (triads) with similar properties
o Lithium, sodium, potassium
o Calcium, strontium, barium
o Chlorine, bromine, iodine
- 1864 John Newlands proposed law of octaves elements arranged in order of increasing
atomic weight
o 8th element starting from given one is like the first
o Identified many similarities among elements but required similarities where there
were none works up to calcium
- 1869 Dmitri Mendeleev and Lothar Meyer produced forerunner of modern periodic table
o Elements arranged in increasing atomic weight similar elements placed under
one another
o Periodic law: properties of the elements vary periodically with atomic weight
o Mendeleev left gaps because recognised probs undiscovered elements
Predicted the properties of 6 undiscovered elements elements later
discovered with properties very similar to his predictions
- 1914 Henry Moseley determined atomic number of elements which he proposed was basic
feature to determine properties (instead of atomic weight)
o Modified periodic law: properties of elements vary periodically with atomic number
Once recognised properties dependent on atomic number tendencies
towards relating layout of table to electron configuration developed
current table developed
Explain the relationship between the position of elements in the Periodic Table and:
- Electrical conductivity
o Decreases across periods
- Ionisation energy
o Increase across periods (gaining another proton, electrons in same shell stronger
attraction)
o Decrease down group (gaining another shell electrons further from nucleus)
- Atomic radius
o Decrease across period (stronger attraction between electrons and protons)
o Increase down group (gaining another shell)
- Melting point
o Highest in middle of period (bonding and structure)
o Decreases down group (more outer shells attraction of electrons to nucleus
weaker)
- Boiling point
o Highest in middle of period (bonding and structure)
o Decreases down group (more outer shells attraction of electrons to nucleus
weaker)
- Combining power (valency)
o Increases across period to group 4 where it goes back down and increases again
o Same down a group
- Electronegativity
o Increase across periods (stronger attraction because more positive nucleus and
outer electrons added to same shell)
o Decrease down group (outer electrons further away as theyre added to new shell
big atoms with more shell)
- Reactivity
o Decrease across period
o Increase down period
Define the mole as the number of atoms in exactly 12g of carbon-12 (avogadros
number)
- A mole of substance contains as many elementary units as number of atoms in exactly 12g
of Carbon-12
- This number is Avogadros number = 6.02 x 10 23
Compare mass changes in samples of metals when they combine with oxygen
Recount Avogadros law and describe its importance in developing the mole concept
- At same temp and pressure, equal volumes of gases contain same number of molecules
(vice versa)
- (same as above) determined formulae + atomic masses for elements existence of
formulae/atomic weights + ability to write chemical equations essential for talking about
moles critically important
Define the terms mineral and ore with reference to economic and non-economic
deposits of natural resources
Describe the relationship between the commercial prices of common metals, their
actual abundances and relative costs of production
- They were formed when earth was formed and no way of forming more of them
Describe the separation processes, chemical reactions and energy considerations
involved in the extraction of copper from one of its ores
Chemical reactions
Energy considerations
Compare the state, percentage and distribution of water in the biosphere, lithosphere,
hydrosphere and atmosphere
Outline the significance of the different states of water on Earth in terms of water as:
- A constituent of cells and its role as both a solvent and a raw material in
metabolism
o Comprises approx. 70% of cells and keeps them turgid
o Solvent for life processes to occur (eg. metabolism)
o Raw material in chemical reactions essential for photosynthesis
o Transports nutrients to cells and remove waste products
o Thermal regulator by smoothing out sudden large temp change
o Metabolic water produced by respiration is important water source for living things
- A habitat in which temperature extremes are less than nearby terrestrial
habitats
o Water bodies have less temp. fluctuation (high heat capacity) than land/air
o Ice less dense than water float on surface of waterbody insulating layer allows
aquatic life to survive
- An agent of weathering of rocks both as liquid and solid
o Ocean waves and rains wear surface rocks
o Glaciers wear away rocks and cause significant erosion as they move down valleys
from mountain top to ocean
o Freeze-thaw mechanism of water freezing cracking rocks
o Chemically weather rocks by reacting with minerals converting them to more
easily eroded minerals
- A natural resource for humans and other organisms
o Drinking, food prep, washing, recreation
o Irrigating crops and watering livestock
o Fluid in electricity generating station and coolant in industries
o Hydro-electricity
o Reactant, solvent, cleaning agent in industry and waste disposal, settling dust
o Mode of transport
Construct Lewis electron dot structures of water, ammonia and hydrogen sulphide to
identify the distribution of electrons
Compare the molecular structure of water, ammonia and hydrogen sulphide, the
differences in their molecular shapes and in their melting and boiling points
- Polar molecules have a net dipole because electron pairs unevenly shared
o -> due to differences in electronegativity
o Molecules line up so that positive end of one attracts negative end of another
o Electrostatic attraction acting between opp.-charged poles of the molecules
Explain changes, if any, to particles and account for those changes when the following
types of chemicals interact with water:
- Polar nature allows for H-bonding, dipole-dipole or dispersion interactions between water
and substance
- Polar ends of water molecule surround the substance and break it apart by attracting
oppositely charged particles OR
- Hydrogen bonding which occurs because of polar nature and breaks apart the substance
Identify some combinations of solutions which will produce precipitates, using solubility
data
Describe a model that traces the movement of ions when solution and precipitation
occur
- Saturated solution of lead nitrate add some lead nitrate crystals with radioactive lead
- Half hour later amount of solid lead nitrate in solution is the same but some radioactivity
detected in solution previously no radioactivity in solution concentration of lead ions in
solution and mass of solid not changed
- Ions moving from solid into solution at the same time as ions moving from solution back
into solid
o Both occurring at equal rates so concentration of solution and mass of solid doesnt
change dynamic equilibrium
Describe the molarity of a solution as the number of moles of solute per litre of solution
using c=n/v
- Amount of heat required to raise temp of unit mass of substance by 1degree celcius (1
kelvin)
- Measured in joules per Kelvin per gram: J K-1 g-1
Compare the specific heat capacity of water with a range of other solvents
Explain and use the equation H = -mC T
Explain how waters ability to absorb heat is used to measure energy changes in
chemical reactions
- Because specific heart capacity of water known and if water mass known, temp change in
water observed to work out heat change in water hence energy change in chemical
reaction in/immersed in water
Explain why waters ability to absorb heat is important to aquatic organisms and to life
on earth generally
Explain what is meant by thermal pollution and discuss the implications for life if a body
of water is affected by thermal pollution
- Discharges into river/lake of quantities of hot water large enough to increase temp. of
water body
- When river/lake water used for cooling in industry/electricity generation discharged back
into river/lake but 10-15degrees hotter
- Oxygen less soluble in hotter water 5degree increase lowers O2 concentration but 10-
15%
o Causes stress to organisms
o Increased metabolism rates increases demand for oxygen (but less oxygen)
o Fish eggs dont develop/hatch if temp too high
o False temp. cues to aquatic life migration/spawning at wrong time of year
o Sudden temp. change kill fish eggs
o Lethal temp limits may be exceeded
ENERGY
Outline the role of photosynthesis in transforming light energy to chemical energy and
recall the raw materials for this process
Outline the role of the production of high energy carbohydrates from carbon dioxide as
the important step in the stabilisation of the suns energy in a form that can be used by
animals as well as plants
Identify the photosynthetic origins of the chemical energy in coal, petroleum and
natural gas
Identify the position of carbon in the periodic table and describe its electron
configuration
- Electron configuration is 2, 4
Describe the structure of diamond and graphite allotropes and account for their
physical properties in terms of bonding
Diamond Graphite
Structure - C atoms bonded to 4 other C atoms - C atom bonded to 3 other C
- Tetrahedrally arranged atoms
- Planar structure
Bonding - Covalent bonds/network - Covalent bonds/network
Physical properties - Doesnt conduct electricity - Conductor of electricity
- Transparent and brilliant (orderly - Slipperiness/lubricating (weak
arrangement of atoms throughout) intermolecular forces between
layers)
Identify that carbon can form single, double or triple covalent bonds with other carbon
atoms
Explain the relationship between carbons combining power and ability to form a variety
of bonds and the existence of a large number of carbon compounds
Describe the use of fractional distillation to separate the components of petroleum and
identify the uses of each fraction obtained
Identify and use the IUPAC nomenclature for describing straight-chained alkanes and
alkenes from C1 to C8
Alkanes Alkenes
- MP/BP/dispersion forces increases with - MP/BP/dispersion forces increase with
molecular weight molecular weight (but BP slightly lower
- Volatility decreases with increase than alkanes)
molecular weight - Insoluble (non-polar)
- Insoluble (non-polar) - Dont conduct electricity
- Dont conduct electricity
C1/C2 Gases Gases
C4
C5 C8 Colourless liquids Liquids
Explain the relationship between the melting point, boiling point and volatility of the
above hydrocarbons, and their non-polar nature and intermolecular forces (dispersion
forces)
Assess the safety issues associated with the storage of alkanes C1 to C8 in view of their
weak intermolecular forces (dispersion forces)
- Colour, production of energy (light, heat, noise etc), formation of new substances, process
cant be easily reversed
Explain that energy is required to break bonds and energy is released when bonds are
formed
- Ignition temp: of fuel/air mixture is min temp to which mixture must be heated for
combustion
- Higher activation energy higher ignition temp