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Selection Guide

Fluoroelastomers

Technical Information
Introduction Viton is characterized by its:
Viton fluoroelastomer was introduced in 1957 to Resistance to degradation by a greater variety of fluids
meet the needs of the aerospace industry for a high- and chemicals than any other non-fluorinated elastomer.
performance seal elastomer. Since then, the use of Excellent resistance to oils, fuels, lubricants, and most
Viton fluoroelastomer has expanded to many other mineral acids.
industries, especially in the automotive, fluid power,
Extremely low permeability to a broad range of
appliance, and chemical fields. With over half a century
substances, including particularly good performance in
of proven performance, Viton fluoroelastomer has
oxygenated automotive fuels.
developed a reputation for outstanding performance in
high temperature and extremely corrosive environments. Resistance to aliphatic, aromatic hydrocarbons that
dissolve other rubbers.
Valuable Properties of Viton Fluoroelastomer
Exceptionally good resistance to compression set, even at
Vulcanizates based on Viton provide an exceptional
high temperatures.
balance of physical property characteristics, including
the following features: Exceptionally good resistance to atmospheric oxidation,
sun, and weather. Excellent resistance to fungus and mold.
Resistance to Temperature Extremes
Good electrical properties in low voltage, low frequency
HeatCompared to most other elastomers, Viton
applications.
is better able to withstand high temperature, while
simultaneously retaining its good mechanical properties. Low burning characteristics; inherently more resistant to
Oil and chemical resistance are also essentially burning than other, non-fluorinated hydrocarbon rubbers.
unaffected by elevated temperatures. Compounds of
Safety and Handling
Viton remain substantially elastic indefinitely when
exposed to laboratory air oven aging up to 204 C As with many polymers, minute quantities of potentially
(399 F) or to intermittent exposures up to 316 C irritating or harmful gases may diffuse from uncured Viton,
(601 F). High temperature service limits are generally even at room temperature. Therefore, all containers should
considered to be: be opened and used only in well-ventilated areas. In case
of eye contact, immediately flush the eyes for at least 15
3,000 hr at 232 C (450 F)
minutes with water. Always wash contacted skin with soap
1,000 hr at 260 C (500 F) and water after handling Viton.

240 hr at 288 C (550 F) Potential hazards, including the evolution of toxic vapors,
may arise during compounding, processing, and curing
48 hr at 316 C (601 F)
of raw polymers into finished products or under high-
ColdViton low temperature performance is dependent temperature service conditions. Therefore, before handling
on type, with serviceability as low as 31 C (24 F) in or processing Viton, make sure that you read and follow
dynamic seals and 45 C (49 F) in static seals using the recommendations in the Chemours technical bulletin,
Viton GLT-S. Handling Precautions for Viton and Related Chemicals.

Compounding ingredients and solvents that are used with


Viton to prepare finished products may present hazards in
handling and use. Before proceeding with any compounding
or processing work, consult and follow label directions and
handling precautions from suppliers of all ingredients.
Viton Fluoroelastomers

The Various Families and Types of Viton Viton GLT-S provides the same excellent resistance
Fluoroelastomers to heat and fluids that is typical of the A types of
Standard types of Viton fluoroelastomer products Viton fluoroelastomer. Viton GFLT-S, like Viton
are designated as A, B, or F according to their relative GLT-S, exhibits significantly improved low temperature
resistance to attack by fluids and chemicals. The flex characteristics compared to standard types of
differences in fluid resistance are the result of different fluoroelastomer. In addition, Viton GFLT-S provides the
levels of fluorine in the polymer, which is determined same superior resistance to fluids that is typical of the
by the types and relative amounts of copolymerized F types of Viton fluoroelastomer.
monomers that comprise the polymer.
Types of Viton Extreme
In general, Viton exhibits outstanding resistance to Fluoroelastomers that contain copolymerized vinylidene
attack from a wide variety of fluids, including mineral fluoride (VF2) are subject to attack by high pH materials,
acids, and aliphatic and aromatic hydrocarbons. The including caustics and amines. In addition, standard
higher the fluorine content of the polymer, the less will be fluoroelastomers are not resistant to low molecular
the effect, as measured by volume increase for example. weight carbonyl compounds, such as methyl ethyl ketone,
The most significant differences between A, B, and F acetone, or methyl tertiarybutyl ether.
types of Viton, in terms of resistance to volume change
or retention of physical properties, are exhibited in low Viton Extreme ETP-600S is a copolymer of ethylene,
molecular weight, oxygenated solvents (such as methanol tetrafluoroethylene (TFE), and perfluoromethylvinyl ether
and methyl t-butyl ether). (PMVE). This unique combination of monomers provides
outstanding resistance to fluids and is an example of
As mentioned above, the fluid resistance of Viton A, B, an ETP polymer. The ETP types of Viton exhibit the
and F types improves with increasing fluorine levels. This same excellent resistance to acids and hydrocarbons
is shown in Table 1 (note the volume increase after aging typical of A, B, and F types of Viton. Unlike conventional
in methanol at 23 C [73 F]). As the fluorine content fluoroelastomers, however, ETP types of Viton also
increases, however, the low temperature flexibility of the provide excellent resistance to low molecular weight
polymer decreases, and a compromise must be made esters, ketones, and aldehydes. In addition, these unique
between fluid resistance and low temperature flexibility polymers are inherently resistant to attack by base and,
of the final vulcanizate. thus, provide excellent resistance to volume swell and
For those applications that require the best performance property loss in highly caustic solutions and amines.
in both fluid resistance and low temperature flexibility, a Additional information regarding performance differences
number of specialty types of Viton were developed that between the various families and types of Viton
contain a copolymerized fluorinated vinyl ether monomer. fluoroelastomer is presented in Tables 36 to assist
Polymers that contain this monomer exhibit significantly in selecting the particular grade of Viton that is best
improved low temperature flexibility, compared to suited for both a given end-use application and a specific
standard types of fluoroelastomer. manufacturing process.

Table 1. Polymer Fluorine Content Versus Fluid Resistance and Low Temperature Flexibility

Standard Types Specialty Types


A B F GLT-S GFLT-S ETP-S
Nominal Polymer Fluorine Content, wt% 66 68 70 64 67 67
Percent Volume Change in Fuel C, 168 hr at 23 C (73 F)* 4 3 2 5 2 4
Percent Volume Change in Methanol, 168 hr at 23 C (73 F)* 90 40 5 90 5 5
Percent Volume Change in Methyl Ethyl Ketone, 168 hr at 23 C (73 F)* >200 >200 >200 >200 >200 19
Percent Volume Change in 30% Potassium Hydroxide, 168 hr at 70 C (158 F)* (Samples too swollen and degraded to test) 14
Low Temperature Flexibility, TR-10, C* 17 13 6 30 24 12
*Nominal values, based on results typical of those obtained from testing a standard, 30 phr MT (N990) carbon black-filled, 75 durometer vulcanizate. These are not intended to serve as
specifications.

2
Viton Fluoroelastomers

Curing Systems for Viton Fluoroelastomer cross-linking systems. When properly formulated, peroxide
In addition to inherent differences between the various cross-linking provides enhanced resistance to aggressive
types and families of Viton fluoroelastomer, a number automotive lubricating oils, steam, mineral and organic
of compounding variables have major effects on the acids, and aggressive biodiesel. Generally, vulcanizates of
physical property characteristics of the final vulcanizates. Viton fluoroelastomers cured with peroxide do not show
One very important variable is the cross-linking or curing any significant difference in resistance to hydrocarbon
system that is used to vulcanize the elastomer. fluids compared to a polymer of similar fluorine content
cured with bisphenol.
Diamine curatives were introduced in 1957 for cross-
linking Viton A. While these diamine curatives are In 2003, a series of peroxide-cure types of Viton
relatively slow curing and do not provide the best possible made with Advanced Polymer Architecture (APA) was
resistance to compression set, they do offer unique introduced. These polymers, designated as APA polymers
advantages. For example, compounds cured with diamines by having an S suffix on the product name, incorporate a
exhibit excellent adhesion to metal inserts and high hot significantly improved cure site. As a result, they provide
tensile strength. substantially better processing and physical properties,
compared to the original, non-APA peroxide-cure types
Most fluoroelastomers are cross-linked with Bisphenol of Viton. A comparison of the various processing and
AF, a curative introduced in 1970 in the first commercial physical property characteristics of compounds using the
curative-containing precompound, Viton E-60C. various cure systems is shown in Table 2.
Compounds of Viton that use this curative exhibit fast
rates of cure and excellent scorch safety and resistance Selecting a Specific Type of Viton Fluoroelastomer
to compression set.
Inherent Physical Property Differences Between Types/
In 1987, an improved bisphenol curative was introduced, Families of Viton Products
which was made available in several different
The physical properties of vulcanizates based on Viton
precompounds. The modified system provides faster
fluoroelastomers are determined to a large extent by the
cure rates, improved mold release, and slightly better
type and amount of the filler(s) and curative(s) used in the
resistance to compression set, compared to the original
formulation and by the temperature and duration of the
bisphenol cure system used in Viton E-60C and E-430.
curing cycle used in their manufacture.
Additional precompounds of Viton, incorporating this
modified curative, were introduced in 1993, including In terms of resistance to compression set, low
Viton A-331C, A-361C, B-601C, and B-651C. A brief temperature flexibility, and resistance to certain classes
description of all these products can be found in Table 6. of fluids, however, some inherent differences exist among
the various families of Viton fluoroelastomers. These are
Peroxide cross-linking provides fast cure rates and
the result of differences in the relative amount and type of
excellent physical properties and allows cross-linking
monomers used in the manufacture of the various types
of polymers, such as GLT-S and GFLT-S, which cannot
of Viton fluoroelastomers.
be readily cured with either diamine or bisphenol

Table 2. A Comparison of Cure Systems Used in Cross-Linking Viton

Type of Cure System


Property, Processing Characteristic Diamine Bisphenol Peroxide
Processing Safety (Scorch) P-F E E
Fast Cure Rate P-F E E
Mold Release/Mold Fouling P G-E G-E
Adhesion to Metal Inserts E G G
Compression Set Resistance P E E
Steam, Water, Acid Resistance F G E
Flex Fatigue Resistance G G G
Rating: E=Excellent, G=Good, F=Fair, P=Poor

3
Viton Fluoroelastomers

The differences in physical property characteristics Selecting a Specific Type of Viton Fluoroelastomer
that exist between various types and families of Viton
Differences in Fluid Resistance Among Types of Viton Products
fluoroelastomer products are outlined in general terms
in Table 3. As in the case of physical properties, different polymer
compositions will result in inherent differences with regard
As an example, resistance to compression set is an
to fluid resistance.
important property for seals, and if this property were
considered to be the most important feature for a Table 4 outlines the differences that exist among types
particular part, then one of the A-types of Viton might of Viton products, in terms of their resistance to various
be the best choice for the application. However, if classes of fluids and chemicals.
resistance to the widest possible range of fluids is a Because as certain types of Viton products may exhibit
more important consideration, then an F-type Viton performance that is superior to other types in one
fluoroelastomer might be a better choice for that regard, but not quite as good in some other aspect, it
particular end-use application. Further, if both fluid is important to consider the requirements of the part
resistance and low temperature flexibility are equally to be manufactured, in terms of both physical property
important requirements for maximizing the end-use requirements and fluid or chemical resistance needs.
suitability of a given part, GFLT types of Viton would
represent the best overall choice. Using Tables 3 and 4, the compounder can select the best
type of Viton product for a given end-use application, based
on the best combination of physical property and fluid
resistance characteristics.

Table 3. Physical Property Differences Among Types/Families of Viton Products

Type of Viton Fluoroelastomer Resistance to Compression Set General Fluids/Chemical Resistance* Low Temperature Flexibility**
A 1 3 3
B, GBL-S 2 3 3
F, GF-S 3 2 3
GLT-S 2 3 1
GFLT-S 2 2 2
ETP-S 3 1 3
1=ExcellentBest performance capability of all types; 2=Very Good; 3=GoodSufficient for all typical fluoroelastomer applications
*See Table 4 for a detailed guide to choosing the best type of Viton fluoroelastomer relative to specific classes of fluids and chemicals.
**Flexibility, as measured by Temperature of Retraction (TR-10), Gehman Torsional Modulus, Glass Transition (Tg), or Clash-Berg Temperature. Brittle-Point tests are a measure of impact
resistance only and do not correlate at all with the low temperature sealing capability of a vulcanizate.

Table 4. Differences in Fluid Resistance Among Types of Viton Fluoroelastomer

Type of Viton Fluoroelastomer A B F GAL-S GBL-S GF-S GLT-S GFLT-S ETP-S


Cure System Bisphenol Peroxide
Hydrocarbon Automotive, Aviation Fuels 1 1 1 1 1 1 1 1 1
Oxygenated Automotive Fuels (containing MeOH, EtOH, MTBE, etc.) NR 2 1 NR 2 1 NR 1 1
Reciprocating Engine Lubricating Oils (SE-SF Grades) 2 1 1 1 1 1 1 1 1
Reciprocating Engine Lubricating Oils (SG-SH Grades) 3 2 2 1 1 1 1 1 1
Aliphatic Hydrocarbon Process Fluids, Chemicals 1 1 1 1 1 1 2 1 1
Aromatic Hydrocarbon Process Fluids, Chemicals 2 2 1 1 1 1 2 1 1
Aqueous Fluids: Water, Steam, Mineral Acids (H2SO4, HNO3, HCl, etc.) 3 2 2 1 1 1 1 1 1
Amines, High pH Caustics (KOH, NaOH, etc.) NR NR NR 3 3 3 3 3 1
Low Molecular Weight Carbonyls (MTBE, MEK, MIBK, etc.) NR NR NR NR NR NR NR NR 1
1=ExcellentBest choice of Viton type(s) for service in this class of fluid/chemical; minimal volume increase, change in physical properties.
2=Very GoodGood serviceability in this class of fluid/chemical; small amounts of volume increase and/or changes in physical properties.
3=GoodSuitable for use in this class of fluid/chemical; acceptable amounts of volume increase and/or changes in physical properties.
NR=Not RecommendedExcessive volume increase or change in physical properties.

4
Viton Fluoroelastomers

Viton Product Naming System 3rd Character (Number)


With the introduction of six improved processing Represents the relative level of curative in a precompound
precompounds in 1993, a new nomenclature system on a scale of 10 to 1 (10 is represented by 0);
was adopted for Viton fluoroelastomer products. The 0 = High curative level (for optimum compression set)
new system incorporates the following information in a
product name: 9 to 2 = Intermediate, decreasing levels of curative
(increased elongation at break, tear resistance)
Nominal Mooney Viscosity
1 = Low curative level (for optimum tear, flex resistance)
Family type (relative fluid resistance)
4th Character (Number)
Relative state of cure (relative level of cross-linking
Represents a slightly different version of a particular
agent present in curative-containing precompounds)
precompound
An indication of whether the product can be cross-
linked using a peroxide cure system 5th Character (Letter)

An indication of whether the product is a gum polymer Absence of a letter suffix indicates that the product
or a precompound, which contains a preset, carefully is a gum polymer only and contains no curatives (may
controlled amount of bisphenol cross-linking system. contain process aid)

Each character in the product name indicates a specific C indicates that the product is a precompound,
characteristic as outlined below: containing accelerator and curative

S indicates that the product incorporates Viton made


||
Character No.: 1st 3rd 5th
|
with APA technology

Viton A-401C Choosing a Viton Product for Use in a Particular Type


| | 2nd 4th
of Manufacturing Process
The Viton product line includes a wide variety of different
types of fluoroelastomer products, which exhibit some
1st Character (Letter)
inherent differences in their end-use capabilities (see
Represents the Viton fluoroelastomer familyA, B, F, Tables 3 and 4). In addition, a broad range of viscosities is
or ETP offered for most types of Viton, providing a wide degree
A G prefix, in addition to a family prefix, indicates that of utility in various manufacturing processes.
the polymer can be cross-linked with the peroxide cure Having selected a given class of Viton products for
system an end use, the compounder must then choose which
An L designation indicates that the A, B, or F type particular Viton product is best suited for use in a
polymer provides slightly improved low temperature specific manufacturing process.
flexibility characteristics versus other polymers The Viton Application Guide (Table 5) lists the Viton
within the same family; an LT designation indicates products that are recommended for particular end-use
a more significant improvement in low temperature applications, according to the various processes that are
performance criteria most commonly used in their manufacture.

2nd Character (Number) The Viton Product Listing (Table 6) provides more
specific information about the various individual Viton
Represents nominal Mooney Viscosity of the product
products. Contact your Chemours sales or technical
ML 1 + 10 at 121 C (250 F).
representative to obtain more detailed information or data
on specific Viton products.

5
Viton Fluoroelastomers

How to Use the Viton Application Guide Each general end-use category listed is divided into four
The Viton Application Guide (Table 5) has been designed
columns, each listing Viton products within a specific
to facilitate choice of the type of Viton that is best family or type of Viton fluoroelastomerA, B, F, and
suited for meeting both the property requirements of the specialty types.
intended end use and the needs of the production method The guide is further divided into the five major types of
used to manufacture the finished product. process (rows) by which these general end-use categories
The guide is divided into five general categories (columns) might be produced:
of end-use products, differentiated primarily by physical Compression molding
form:
Transfer molding
Sheet form goods, such as gaskets, diaphragms, etc.
Injection molding
Simple shapes, such as O-rings, V-rings, etc., which
Extrusion
do not typically require high levels of de-molding tear
resistance, but that generally require high states of Calendering
cure to obtain the best compression set possible.
Within the blocks formed by the intersection of a given
Complicated molded shapes, such as shaft seals or end-use category (column) and the process type by which
valve stem seals, which require good hot tear upon the end products will be manufactured (row), we have
de-molding due to the undercuts in the molds used to listed the types of Viton that we believe are appropriate
form such parts and good adhesion to metal inserts choices for meeting the physical property requirements
(obtained during the vulcanization of the parts). of the finished product and are best suited for the chosen
manufacturing process.
Complicated molded shapes that do not involve
adhesion to metal inserts during vulcanization, The Viton products we believe will provide the best
but which require good resistance to tear during combination of end-use physical properties, together with
de-molding. Carburetor roll-over cages, boots, and reed the best processing characteristics for given methods of
valves are examples of such parts. manufacture, are listed in bold type.
Extruded shapes, such as rod, tubing, or hose Additional details for specific types of Viton can be found
constructions. in the Viton Product Listing and in product-specific data
sheets.

6
Viton Fluoroelastomers

Table 5. Viton Fluoroelastomer Application Guide


Reinforced/Unreinforced Sheet Stock (Gaskets, Diaphragms, etc.) Molded (Non-Bonded), Simple Shapes (O-Rings, V-Rings, etc.)
Manufacturing
Viton Types
Process
A B F Specialty A B F Specialty
A-331C B-435C F-605C GLT-600S A-401C B-601C F-605C GLT-600S
A-361C B-601C GF-600S GFLT-600S A-331C B-651C GF-600S GFLT-600S
A-401C B-651C ETP-600S A-601C GBL-600S ETP-600S
Compression
A-601C GBL-600S A-500 B-600
Molding
A-500 B-600 A-HV
A-700 A-700
AL-600 AL-600
A-201C B-435C F-605C GLT-200S A-201C B-651C F-605C GLT-200S
A-331C GBL-200S GF-200S GFLT-200S A-331C GBL-200S GF-200S GFLT-200S
A-361C B-202 ETP-600S A-361C B-202 ETP-600S
Transfer Molding
A-401C A-200
A-200 AL-300
AL-300
A-201C B-435C GF-200S GLT-200S A-201C B-601C F-605C GLT-200S
A-331C GBL-200S GBLT-200S A-331C B-651C GF-200S GFLT-200S
A-361C B-202 GFLT-200S A-361C GBL-200S ETP-600S
Injection Molding A-200 A-100 B-202
AL-300 A-200
A-500
AL-300
A-201C B-435C F-605C GLT-200S
A-401C B-601C GF-200S GLT-600S
A-331C B-651C GF-600S GFLT-200S
Calendering A-361C GBL-200S GFLT-600S
AL-300 GBL-600S ETP-600S
B-202
B-600
Molded (Bonded), Complicated Shapes (Valve Stem, Shaft Seals, etc.) Molded (Non-Bonded), Complicated Shapes (Boots, Valves, etc.)
A-361C B-435C F-605C/GF-200S GLT-200S A-331C B-435C F-605C/GF-600S GLT-600S
A-500 B-651C GF-200S GLT-600S A-401C/A-500 B-651C GF-600S GFLT-600S
A-700 GBL-600S GF-600S GFLT-200S A-601C/A-200 GBL-600S ETP-600S
Compression
AHV B-600 GFLT-600S A-361C B-600
Molding
AL-600 ETP-600S A-700
AHV
AL-600
A-361C B-435C GF-200S GLT-200S A-200 B-435C F-605C/GF-200S GLT-200S
A-200 GBL-200S GFLT-200S A-331C B-651C GF-300 GFLT-200S
A-500 B-202 ETP-600S A-361C GBL-200S ETP-600S
Transfer Molding
AL-300 A-200 B-600
A-500
AL-300
A-361C B-435C F-605C/GF-200S GLT-200S A-200 B-435C F-605C/GF-200S GLT-200S
A-100 B-651C GF-200S GFLT-200S A-331C B-651C GF-200S GFLT-200S
A-200 GBL-200S A-361C GBL-200S
Injection Molding
A-500 B-202 A-200 B-202
AL-300 A-500
AL-300
Extruded Goods (Hose, Tubing, Extruded Profiles, etc.)
Manufacturing
Viton Types
Process
A B F Specialty
A-201C B-435C F-605C GLT-200S
A-401C B-651C GF-200S GFLT-200S
A-361C GBL-200S ETP-600S
Extrusion
A-200 B-202
A-500 B-600
AL-300

7
Viton Fluoroelastomers

Table 6. Viton Fluoroelastomer Product Listing

Polymer Properties Nominal Physical Properties*


Nominal Volume
Viscosity, Polymer Compression Temperature Increase, Viton Viton
Viton ML1 + 10 Fluorine Set, % of After 7 days/ Fluoroelastomer Fluoroelastomer
Product at 121 C Specific Content, 70 hr/200 C Retraction MeOH/23 C Product Product Suggested
Type (250 F) Gravity % (392 F) (TR-10), C (73 F) Description Uses/Applications
A-Types: Curative-Containing Precompounds
Fast cure rate, excellent FDA-compliant**: injection
A-201C 20 1.81 66.0 15 17 +75 to 105% injection molding molding, O-rings, gaskets,
rheology, mold release extruded shapes
Compressioninjection
Excellent mold flow,
molding of complex
A-331C 30 1.81 66.0 20 17 +75 to 105% high elongation/tear
shapes, requiring maximum
resistance
hot tear
Compressioninjection
Excellent mold flow, tear
molding of complex
A-361C 30 1.81 66.0 20 17 +75 to 105% resistance, bonding to
shapes, bonded metal
metal inserts
inserts
Excellent rheology
FDA-compliant**:
at high shear rates,
A-401C 40 1.81 66.0 15 17 +75 to 105% compression, transfer, or
excellent resistance to
injection molding of O-rings
compression set
High viscosity,
FDA-compliant**:
high state of cure;
A-601C 60 1.81 66.0 12 17 +75 to 105% compression molding of
optimum resistance to
O-rings, simple shapes
compression set
A-Types: Gum Polymers
Ultra-low viscosity:
Coatings, viscosity modifier
A-100 10 1.82 66.0 15 17 +75 to 105% excellent polymer
for higher viscosity types
rheology
FDA-compliant**, cured w.
Low viscosity: excellent
A-200 20 1.82 66.0 15 17 +75 to 105% VC-50: injection molding
polymer rheology
applications
Intermediate viscosity: FDA-compliant**, cured
A-500 50 1.82 66.0 15 17 +75 to 105% excellent polymer w. VC-50: compression,
rheology transfer, injection molding
FDA-compliant**, cured
High viscosity: excellent
A-700 70 1.82 66.0 15 17 +75 to 105% w. VC-50: compression,
physical properties
transfer, injection molding
FDA-compliant**, cured
Ultra-high viscosity:
w. VC-50: compression
A-HV 160 1.82 66.0 15 17 +75 to 105% excellent physical
molding, high strength
properties
vulcanizates
Transfer, or injection
Slightly improved low
molded goods, where
AL-300 30 1.77 66.0 25 19 +75 to 105% temperature flexibility.
A-types are marginal in
Low viscosity
low-temperature flexibility
General molded goods,
Slightly improved low
where A-types are marginal
AL-600 60 1.77 66.0 20 19 +75 to 105% temperature flexibility.
in low-temperature
Medium viscosity
flexibility
Excellent resistance to FDA-compliant**: injection,
GAL-200S 25 1.79 66.0 30 19 +75 to 105% automotive lubricating transfer, or compression
oils, aqueous fluids molded goods

8 continued
Viton Fluoroelastomers

Table 6. Viton Fluoroelastomer Product Listing (continued)

Polymer Properties Nominal Physical Properties*


Nominal Volume
Viscosity, Polymer Compression Temperature Increase, Viton Viton
Viton ML1 + 10 Fluorine Set, % of After 7 days/ Fluoroelastomer Fluoroelastomer
Product at 121 C Specific Content, 70 hr/200 C Retraction MeOH/23 C Product Product Suggested
Type (250 F) Gravity % (392 F) (TR-10), C (73 F) Description Uses/Applications
B-Types: Curative-Containing Precompounds
Improved processing/ Injectioncompression
B-435C 40 1.85 68.5 25 14 +35 to 45% mold release/bonding vs. molding of metal-bonded
B-641C, B-651C parts
FDA-compliant**:
Excellent balance
compressioninjection
B-601C 60 1.85 68.5 20 14 +35 to 45% of resistance to
molding of O-rings, simple
compression set/fluids
shapes
Compressioninjection
Excellent mold flow, very
molding of complex
B-651C 60 1.85 68.5 30 14 +35 to 45% good tear resistance,
shapes, bonded metal
bonding to metal inserts
inserts
B-Types: Gum Polymers
FDA-compliant**:
Excellent resistance to
transfercompression
GBL-200S 20-30 1.85 67.0 30 16 +40 to 50% automotive lubricating
molding auto lubricating oil,
oils, aqueous fluids
coolant system seals
FDA-compliant**:
Excellent resistance to
compression molding
GBL-600S 65 1.85 67.0 30 16 +40 to 50% automotive lubricating
automotive lubricating oil,
oils, aqueous fluids
coolant system seals
FDA-compliant**:
Excellent extrudability;
high shear extrusion
B-202 20 1.86 68.5 25 14 +35 to 45% lower MeOH permeability
applicationsfuel hose
than A-types
veneer, coatings
Intermediate viscosity,
FDA-compliant**:
excellent polymer
B-600 60 1.86 68.5 20 14 +35 to 45% compression, transfer, and
rheology, superior fluids
injection molding
resistance
F-Types: Curative-Containing Precompounds
Improved polymer base FDA-compliant**:
vs. F-601Cimproved compression molded
F-605C 60 1.90 69.5 30 8 +5 to 10%
rheology, compression goods requiring best fluids
set resistance
F-Types: Gum Polymers
FDA-compliant**: injection
Low viscosity version of transfer, or compression
GF-200S 2530 1.91 70.0 35 6 +3 to 5%
GF-600S molded goods requiring
best fluids resistance
Superior resistance to FDA-compliant**:
broad range of fluids compression molded
GF-600S 65 1.91 70.0 35 6 +3 to 5%
and chemicals, including goods requiring best fluids
MeOH resistance

continued

9
Viton Fluoroelastomers

Table 6. Viton Fluoroelastomer Product Listing (continued)

Polymer Properties Nominal Physical Properties*


Nominal Volume
Viscosity, Polymer Compression Temperature Increase, Viton Viton
Viton ML1 + 10 Fluorine Set, % of After 7 days/ Fluoroelastomer Fluoroelastomer
Product at 121 C Specific Content, 70 hr/200 C Retraction MeOH/23 C Product Product Suggested
Type (250 F) Gravity % (392 F) (TR-10), C (73 F) Description Uses/Applications
Low-Temperature Types of Viton Polymer
GLT Types
FDA-compliant**:
2030 Mooney GLT: best
injectiontransfer molded
GLT-200S 2530 1.78 64.0 30 30 +75 to 105% FKM low-temperature
automotive fuel, chemical,
flexibility
petroleum industry seals
FDA-compliant**:
transfercompression
Medium viscosity version
GLT-600S 65 1.78 64.0 35 30 +75 to 105% molded automotive fuel,
of GLT
chemical, petroleum
industry seals
GFLT Types
30 ML GFLT: best
Bonded fuel systems parts:
combination of low-
GFLT-200S 2530 1.86 66.5 35 24 +5 to 10% resistance to oxygenates,
temperature flexibility/
low-temperature flexibility
fluids resistance
65 ML GFLT: best
Bonded fuel systems parts:
combination of low-
GFLT-600S 65 1.86 66.5 40 24 +5 to 10% resistance to oxygenates,
temperature flexibility/
low-temperature flexibility
fluids resistance
Viton Extreme Types
Outstanding resistance
to fluids/chemicals, FDA-compliant**:
ETP-600S 60 1.82 67.0 40 12 +10 to 15% including low molecular transfercompression
weight acids, aldehydes, molded seals, gaskets
ketones
*Nominal physical properties typical of those that can be expected of vulcanizates based on the specific type of Viton noted, in a 70A hardness, MT carbon black-filled formulation.
These are not intended to serve as specifications.
**Various types of Viton curative-containing precompounds have been determined to be in compliance with FDA 21 CFR-177.2600Rubber Articles for Repeated Food Contact.

10
Viton Fluoroelastomers

Applications are used in the pipings swivel and telescoping joints.


When these joints were inspected after two years
Automotive
service, they were found to be as good as new.
Parts produced from Viton fluoroelastomer are widely
Valves lined with Viton reduce heat and corrosion
used in the automotive industry because of their
worries in many plants.
outstanding heat and fluid resistance. They are used in
the following areas: Hose made of Viton transfers solvents and reactive
petrochemicals to and from processing and distribution
Powertrain Systems
facilities. There are installations on ocean tankers as
Crankshaft seals, valve stem seals, transmission seals well as on highway trailers.
Air intake manifold gaskets Processing rolls for hot or corrosive service are covered
with Viton.
Fuel Systems
Flange gaskets for glass-bodied valves in a paper
Veneered fuel hose
bleaching plant are of Viton.
In-tank fuel hose and tubing
Viton replaced caulking on a process equipment
Pump seals, diaphragms and injector O-rings enclosure, previously plagued with hot solvent leaks,
Accelerator pump cups and saved $4,000 per year in maintenance costs.

Filter caps and filter seals Aerosol-propelled solvent solutions of Viton are
sprayed on chemical process equipment as multi-
Fuel sender seals, carburetor needle tips
purpose maintenance coatings.
Appliances
Industrial Use
The heat and fluid resistance of Viton fluoroelastomer,
The good mechanical properties of Viton fluoroelastomer
coupled with its good mechanical strength, makes it a
allows replacement of conventional elastomers in a range
natural choice for many appliance parts. The use of seals
of applications that cut across industry lines. To cite a few:
and gaskets of Viton has resulted in design of appliances
in challenging environments. Here are some typical Stable-dimensioned O-rings in the meters of automatic
success stories: gasoline blending pumps

In one commercial automatic dry cleaning machine, High vacuum seals for the worlds most powerful proton
no less than 107 components are made of Viton: accelerator
door seals, sleeve-type duct couplings, shaft seals, Heat- and corrosion-resistant expansion joints for a
O-rings, and various static gaskets. They perform utility companys stack gas exhaust ducts
in an atmosphere of perchloroethylene fumes at
Tubing and seals for a variety of top-quality industrial
temperatures up to 88 C (190 F), conditions that
instruments
would quickly degrade other elastomers.
Compression pads for heavy-duty vibration mounts
A fluid-activated diaphragm-type thermostat for gas
used for portable missile ground control apparatus
or electric ranges owes its success to the designers
choice of Viton for the actuator element. Because Conveyor rolls for a solvent cleaning machine
Viton adheres well to brass, it is virtually impermeable Packing rings for hydraulic activators on steel mill ladles
to and is not swelled or deteriorated by the fluids used,
Clamp cushions for parts dipped in 285 C (545 F)
can withstand operating temperatures of 149204 C
solder
(300399 F), and has the mechanical strength to
resist repeated flexing. Jacketing for steel mill signal cable
Deflector rolls on high-speed tinplating lines
Chemical Industry
Precision-molded balls for check valves in oil or
Viton fluoroelastomer is essentially a universal seal
chemical service
for chemical process equipment. Its application in the
chemical industry is illustrated by the following examples: O-ring seals for test equipment in an automotive
manufacturers experimental lab
In a pumping station that handles more than 80
different solvents, oils, and chemicals, seals of Viton

11
Viton Fluoroelastomers

Aerospace Fluid Power


Reliability of materials under extreme exposure conditions Designers and engineers are discovering that seals of
is a prime requisite in this field. Aircraft designers Viton fluoroelastomer work better and last longer than
report that O-rings of Viton fluoroelastomer provide any other rubber in most fluid power applications. Viton
outstanding performance over a broad thermal range, seals effectively up to 204 C (399 F) and is unaffected
from low to extremely high temperatures, and that Viton by most hydraulic fluids, including the fire-resistant
exhibits long and consistent life, even at the upper end types. Seals of Viton can also cut maintenance costs
of this range. Higher temperatures can be tolerated for under more moderate service conditions (below 121 C
short periods. Viton also resists the effects of thermal [250 F]) by providing longer, uninterrupted seal reliability.
cycling, encountered in rapid ascent to and descent from
Some applications in which seals of Viton can reduce
the stratosphere. Other desirable characteristics of
fluid loss and minimize downtime include the following:
Viton that are pertinent to aerospace applications are
its excellent abrasion resistance and its ability to seal Actuators are the hydraulic components most likely
against hard vacuum, as low as 109 mm Hg (133 nPa), to develop small, steady leaks when rubber seals wear
absolute. and lose resilience, which can be extremely expensive.
In a working year, day-to-day leakage from the average
The high-performance properties of Viton have been hydraulic system wastes enough fluid to completely
demonstrated in these typical aircraft and missile fill the system more than four times. Viton prevents
components:
or reduces leakage by maintaining its toughness and
O-rings and Manifold gaskets resilience longer than other rubber seal materials under
Coated fabric covers for jet engine exhausts between normal fluid power conditions.
flights In pumps, poor sealing performance increases
Firewall seals operating costs by wasting power. When internal seals
lose resilience and allow more slippage than the pump
Abrasion-resistant solution coating over braid- design permits, power is wasted. When seals swell
sheathed ignition cable and drag, power is wasted. Seals of Viton keep their
Clips for jet engine wiring harnesses resilience and dont swell, thus preventing power waste
and helping hold down operating costs.
Tire valve stem seals
Siphon hose for hot engine lubricants

12
Viton Fluoroelastomers

Test Procedures

Property Measured Test Procedure


Compression Set ASTM D3955, Method B (25% deflection)
Compression SetLow Temperature ASTM D1299, Method B (25% deflection)
Compression Set, O-Rings ASTM D1414
Hardness ASTM D2240, durometer A
ASTM D1646, using the small rotor. Minimum viscosity and time to a
Mooney Scorch
1-, 5-, or 10-unit rise are reported.
Mooney Viscosity ASTM D1646, ten pass 100 C (212 F) and 121 C (250 F)
ODR (vulcanization characteristics measured with an oscillating disk cure meter) ASTM D2084
Property Change After Oven Heat-Aging ASTM D573
Stress/Strain Properties
100% Modulus
ASTM D412, pulled at 8.5 mm/sec (20 in/min)
Tensile Strength
Elongation at Break
Stiffness, Torsional, Clash-Berg ASTM D1043
Temperature Retraction ASTM D1329
Volume Change in Fluids ASTM D471
Note: Test temperature is 24 C (75 F), except where specified otherwise.

For more information, visit Viton.com

The information set forth herein is furnished free of charge and based on technical data that Chemours believes to be reliable. It is intended for use by persons having technical skill, at their own
discretion and risk. The handling precaution information contained herein is given with the understanding that those using it will satisfy themselves that their particular conditions of use present
no health or safety hazards. Because conditions of product use are outside our control, Chemours makes no warranties, express or implied, and assumes no liability in connection with any use
of this information. As with any material, evaluation of any compound under end-use conditions prior to specification is essential. Nothing herein is to be taken as a license to operate under or a
recommendation to infringe any patents.
NO PART OF THIS MATERIAL MAY BE REPRODUCED, STORED IN A RETRIEVAL SYSTEM OR TRANSMITTED IN ANY FORM OR BY ANY MEANS ELECTRONIC, MECHANICAL, PHOTOCOPYING, RECORDING OR OTHERWISE
WITHOUT THE PRIOR WRITTEN PERMISSION OF CHEMOURS.

2016 The Chemours Company FC, LLC. Viton and any associated logos are trademarks or copyrights of The Chemours Company FC, LLC. Chemours and the Chemours Logo are
trademarks of The Chemours Company.
Replaces: VTE-H68134-00-G0710
C-11021 (10/16)

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