1.

Match correctly
OH
O
CH3

O
A) I) Salicylaldehyde
O

OH

B) II) Vanillin
O

C) III) Cinnamaldehyde
1) A-I, B-II, C-III 2) A-II, B-I, C-III 3) A-III, B-I,C-II 4) A-I, B-III, C-II
2. Match correctly
A) CH3CHO I) 4-Bromo 3-methyl heptanal
B) CH3CH2CH2CH(Br)CH(CH3)CH2CHO II) 3-methyl cycloheptanone
O

CH3
C) III) Cyclohexanecarbaldehyde
O

D) IV) Ethanal
1) A- IV, B-I, C-III, D-II 2) A-IV, B-I, C-II, D-III

3) A-I, B-IV, C-II, D-III 4) A-III, B-I, C-IV, D-II

3. The IUPAC name of Isobutyraldehyde
1) 2-methyl propanol 2) 1-methyl propanal
 3) methyl propanal 4) 2-methyl propanal

4. The IUPAC name of phthaldehyde

1) Benzene 1,3 dicarbaldehyde 2) Benzene 1, 2 dicarbaldehyde
3) Benzene 1, 4 dicarbaldehyde 4) Benzene 1, 3- dial
5. The IUPAC name of Diisopropyl ketone
1) Dimethyl pentan-3-one 2) 2, 4 dimethyl pentan-3-one
3) Pentan-3-one 4) Pentan 1, 3 dione
6. The IUPAC name of mesityl oxide
1) 4-methyl pent-3-en-2-one 2) 3-methyl pent-3-en-2-one
3) 2-methyl pent-3-en-2-one 4) pent-3-en-2-one
7. Which of the following can be used for the preparation of aldehydes and ketones both?
A) Oxidation of alcohols in presence of PCC
B) Dehydrogenation of primary alcohols
C) Ozonolysis of alkenes
D) Hydration of alkynes
1) A, B 2) C, D 3) A, C 4)A, B, C, D
8. The hybridisation and geometry of carbonyl carbon
1) Sp2, trigonal planar 2) sp3 , tetrahedral 3) sp3, square planar 4) sp2, linear
9. DIBAL-H is used for conversion of
1) Esters to carboxylic acids
2) Esters to aldehydes
3) Esters to ketones
4) Esters to ethers
10. In presence of strong oxidising agents which of the following produces aromatic carboxylic acids
CH3 CH3
CH3

CH3
A) B) C)
1) A, B 2) Only A 3) only C 4) A, B, C
11. The chromium complex formed on treating Toluene in presence of CrO2Cl2/CS2
1) C6H5CH(OCrOHCl2)2 2) C6H5CH(OCrOHCl)2 3) C6H5CH(OCrOH)2 4)
C6H5CH(OCrClH)2
12. Which of the following reagents can be used for conversion of Toluene to Benzaldehyde
A) K2Cr2O7/H2SO4 B) Cl2/hv followed by hydrolysis

C) CrO2Cl2/CS2 followed by hydrolysis D) CO+HCl/ CuCl+AlCl3

1) A, D 2) A, B, C 3) B, C, D 4) A, D

13. The reagent used in gattermann Koch reaction

1) CO+HCl 2) HCHO 3) CO+HCl/ CuCl+AlCl3 4) Co/373K
14. Acetyl chloride on treatment with dimethyl cadmium , the product formed is
1) Acetaldehyde 2) Acetic acid 3) Acetone 3) hexanone
15. Methane nitrile on treating with phenyl magnesium bromide and on further hydrolysis forms
1) Benzophenone 2) Acetophenone 3) Acetone 3) propiophenone
16. By which of the following methods Benzophenone can be prepared
 C6 H 6 C6 H 5COCl AlCl3

A)
C6 H 5CN C6 H 5 MgBr ether
H 3O

B)
C6 H 5COCl (CH 3 ) 2 Cd
C)
C6 H 5COCl C6 H 6
D)
1) A, B, D 2) A, B, C 3) A, B, C, D 4) A, D
17. The reagent used for the conversion of Hexan-1-ol to Hexanal
1) PCC 2) KMnO4/H+ 3) Con.HNO3 4) DIBAL-H
18. The reagent used for the conversion of Cyclohexanol to cyclohexanone
1) KMnO4/H+ 2) Anhydrous CrO3 3) Con.HNO3 4) DIBAL-H
19. The reagent used for the conversion of allyl alcohol to propenal
1) PCC 2) KMnO4/H+ 3) Con.HNO3 4) DIBAL-H
20. The reagent used for the conversion of But-2-ene to ethanol
1) PCC 2) KMnO4/H+ 3) Con.HNO3 4) O3/H2O-Zn dust
21. Which of the following statement is incorrect?
1) Methanal is gas at room temperature
2) Ethanal is liquid at room temperature
3) The boiling point of aldehydes and ketones are less than hydrocarbons of comparable molecular
masses
4) The boiling point of aldehydes and ketones are more than hydrocarbons of comparable molecular
masses
22. Which of the following statements are correct?
A) The boiling point of alochols are greater than aldehydes of comparable masses
B) The lower members of aldehydes and ketones are miscible in water as they form hydrogen bonds
with water
C) Lower aldehydes have sharp pungent odour
D) As the size of the aldehyde molecule increases , the odour becomes less pungent and more
fragrant
1) Only A 2) Only B, C 3) A, B, C, D 4) only A, C
23. The increasing order of boiling point of
A) n-butane B) Methoxy ethane C) Propanal D) Acetone E) Propan-1-ol
1) A, B, C, D, E 2) A, B, D, C, E 3) A, C, B, D, E 4) A, E, B, C, D
24. The increasing order of their boiling points
A) CH 3CH 2 CH 2 CHO B ) CH 3CH 2CH 2CH 2OH C ) H 5C 2 -O-C 2 H 5 D) CH 3CH 2CH 2CH 3

1) D,C,B,A 2) A, B, C, D 3) A, C, B, D 4) A, D, B, C
25. Consider the following sequence of reactions

CH 3 C CH HHg
3O
A 1.CH 3 MgI
H 2O
B
2

The final product (B) in the following reaction

CH 3C CCH 3 CH 3COCH 2CH 3 CH 3CH 2CHOHCH 3 (CH 3 )C OH

1) 2) 3) 4)
26. Which of the following reactions will give a satisfactory yield of aldehyde?

RCOOCH
3
1. LiAlH 4
2. H 3O
RCOCl 1.LiAlH 4
H 3O

1) 2)

RCOOCH 3 1.[( CH 3 ) 2 CHCH 2 ]2 Al

H 3O RCOCl NaH

3) 4)

27. What will be the end product in the following reaction?

OH Sn HCl

SOCl

2 KCN
H3C

O
H
H3C
O H3C CH3
1) 2)
H
O
H3C
H3C H O
3) 4)

28. Which of the following works best as the reaction steps to carry out conversion below?
O
CH2
?

1) Br2; NaNH2(excess); H2O, HgSO4/H2SO4

2) B2H6/H2O2,NaOH; PCC/CH2Cl2
3) H2O, H2SO4; CrO3/H2SO4
4) CH3CO3H; NaOH, H2O

29. What could be the reagent for the following conversion?

OH O

H H
Re agent

1) Br2/FeCl3 2) (COCl)2 3) MnO2 4) K2Cr2O7

30. The enol form of acetone for the selective reduction of a ketone in the presence of an ester is
 OD O OH OD
H3C CH2 D 3C CD 3 H2C CH 2D D2 C CD 3
1) 2) 3) 4)

31. Ozonolysis of C7H14 gave 2-methyl pentan-3-one . The alkene is

1) 2-ethyl-3-methyl but-1-ene
2) 2-methyl-3-ethyl but-3-ene
3) 2, 5 dimethyl -3, 4 diethyl hex-3-ene
4) 2-methyl-3-ethyl but-1-ene

32. In the reaction

CH 3CHO HCN CH 3CH (OH) CN HOH

CH 3CH (OH )COOH

An assymetric centre is generated . The acid obtained will be

1) (L)-isomer 2) (D)-isomer

3) 20% (D) + 80% (L)-isomer 4) 50% (D) + 50% (L) isomer

H 3O
(CH 3 ) 2 CO

NaCN
HCl
A
B
33.

In the above sequence of reactions , A and B are

(CH 3 ) 2 C (OH )CN , (CH 3 ) 2 C (OH )COOH (CH 3 ) 2 C (OH )CN , (CH 3 ) 2 C (OH ) 2
1) 2)

(CH 3 ) 2 C (OH )CN , (CH 3 ) 2 CHCOOH (CH 3 ) 2 C (OH )CN , (CH 3 ) 2 CO

3) 4)

34. Which one of the following can be oxidised to corresponding carbonyl compounds?

1) 2-hydroxy propane 2) ortho nitrophenol 3) phenol 4) 2-methyl 2-hydroxy propane

35.Which reagent is used in the Rosenmunds reduction?

1) H2/Pd-BaSO4 2) LiAlH4

3) NH2NH2/KOH/CH2OH-CH2OH 4) Zn-Hg/HCl

36. Which one of the following called as rosenmunds reduction?

1) aldehydes are reduced to alcohols 2) acids are reduced to hydrocarbons

3) alcohols are reduced to hydrocarbons 4) acid chlorides are reduced to aldehydes

CH 3CH 2C N X
CH 3CH 2CHO
37. the compound X is
 1) H2/Pd-BaSO4 2) SnCl2/HCl/H2O, boil

3) LiAlH4/ether 4) NaBH4/ether/H3O+

38.The compound which is not formed during the dry distillation of a mixture of a calcium formate
and calcium acetate is

1) Propanal 2) propanone 3) ethanal 4) methanal

39. Reaction of Grignard reagent with ---------gives alcohol

A) carbondioxide B) formaldehyde C) acetaldehyde D) acetone

1) A, B 2) B, C, D 3) A, B 4) A, D, C

40. Which are mixed ketones?

A) propan-2-one B) butan-2-one C) pentan-3-one D) pentan-2-one

1) A, B 2) B, C 3) C, D 4) A, C

41. Gem dihalides on hydrolysis form

A) alkenes B) aldehydes C)ketones D) alkynes

1) A, C 2) B, C 3) A, D 4) B, D

42. Which of the following methods can be used to prepare aldehydes?

A)By the reduction of acid chlorides in presence of Pd or Pt

B)By passing the vapours of fatty acids with formic acid

C)By interaction of formic ester with Grignard reagent

D)By the reduction of alkyl cyanide with SnCl2/HCl and hydrolysis

1) A, B, C, D 2) Only A, B 3) only B, C 4) Only C, D

43. Ketones can be prepared by

A)heating calcium propionate with calcium formate

B) dry distillation of fused calcium acetate

C) hydrolysis of propylidene chloride with alkali

D) action of dialkyl cadmium on acid chloride

1) A, B, C, D 2) Only A, B 3) only B, C 4) Only C, D


44. A Cyanohydrin of a compound (X) on hydrolysis gives an -hydroxy acid which shows optical
activity after resolution. The compound X is

1) Acetone 2) Formaldehyde 3) diethyl ketone 4) acetaldehyde

45. One mole of hydrocarbon (A) on ozonolysis gives two moles of dicarbonyl compound (A) is
H3C
H3C CH3
CH2

H2C CH3
1) 2) 3) 4)

I ) RCOCl Boiling
Pd / BaSO 4
xylene
R CHO
II ) R CN
SnClHOH
2 / HCl R CHO
46 .

Reactions (I) and (II) are ----------- and ------------- respectively

1) Oxoprocess, wackers process

2) Rosenmunds reduction, stephens reduction
3) Gattermann reaction, stephens reaction
4) Reimer Tiemann reaction, wacker process

47. The major product obtained from photochemical chlorinationof ethyl benzene(in excess) is
hydrolysed with aqueous KOH and the product is then oxidised with PCC. The final product formed is

PhCH 2CHO PhCOCH 3 PhCHO PhCOOH

1) 2) 3) 4)

48. Which one of the following alcohols cannot be oxidised by K2CrO4?

1) Ethanol 2) Tert butyl alcohol 3) Isopropyl alcohol 4) Allyl alcohol

49. Mark out the correct order of dipole moment for the following compounds

I ) HCHO II ) CH 3CHO III ) CH 3COCH 3

I II III II III I III II I III I II

1) 2) 3) 4)

50. Which of the following reactions will produce aldehydes?

 H3C CH3
O3
Zn H 2O
H3C
H3C
CO H 2
CH3 CH2 CO2 ( CO )8

A) B)

CH

B2 H 6
OH / H 2O
CH Hg 2 , H 2 SO4
H3C H3C
C) D)

1) A, B 2) B, C 3) C, D 4) A, D

1-10 2 2 4 2 2 1 4 1 2 4
11-20 1 3 3 3 1 3 1 2 1 4
21-30 3 3 1 1 3 3 3 2 3 1
31-40 1 4 1 1 1 4 2 1 2 3
41-50 2 1 3 4 4 2 2 2 3 2