Dry cleaning is any cleaning process for clothing and considered a potential carcinogen by the Environmental
textiles using a chemical solvent other than water. It is Protection Agency and the National Institute for Occu-
used to clean fabrics that degrade in water, and delicate pational Safety and Health (NIOSH).[4][5] In 1993, the
fabrics that cannot withstand the rough and tumble of California Air Resources Board adopted regulations to
a washing machine and clothes dryer. It can eliminate reduce PCE emissions from dry cleaning operations; the
labor-intensive hand washing. same year, the EPA did the same. The U.S. EPA up-
dated its regulation in 2006 to reect the availability of
Unlike what its name implies, dry cleaning is not actu-
ally a 'dry' process. Clothes are soaked in a dierent improved emission controls.
solvent other than water. The solvent used is typically The replacement of PCE with other solvents remains of
toxic tetrachloroethylene (perchloroethylene), which the interest as it will ultimately disappear from the market.
industry calls perc. Perc is the most widely used sol-
vent across the world, although new solvents have become
more popular in the United States and Europe, including 1.2 Infrastructure
hydrocarbons, Green Earth, and Solvon K4 .
Traditionally, the cleaning process was carried out at cen-
tralized factories. High street cleaners shops received
1 History garments from customers, sent them to the factory, and
then had them returned to the shop, where the customer
could collect them. This was due mainly to the risk of
Modern dry cleaning use of non-water-based solvents re or dangerous fumes created by the cleaning process.
to remove soil and stains from clothes was reported At this time, dry cleaning was carried out in two dierent
in 1855. The potential for using petroleum-based sol- machinesone for the cleaning process, and the second
vents such as gasoline and kerosene was recognized by to dry the garments.
French dye-works operator Jean Baptiste Jolly, who of-
fered a new service that became known as nettoyage Machines of this era were described as vented; their dry-
seci.e., dry cleaning.[1][2] Flammability concerns led ing exhausts were expelled to the atmosphere, the same as
William Joseph Stoddard, a dry cleaner from Atlanta, to many modern tumble-dryer exhausts. This not only con-
develop Stoddard solvent (white spirit) as a slightly less tributed to environmental contamination but also much
ammable alternative to gasoline-based solvents. The potentially reusable PCE was lost to the atmosphere.
use of highly ammable petroleum solvents caused many Much stricter controls on solvent emissions have ensured
res and explosions, resulting in government regulation that all dry cleaning machines in the Western world are
of dry cleaners. After World War I, dry cleaners be- now fully enclosed, and no solvent fumes are vented to
gan using chlorinated solvents. These solvents were much the atmosphere. In enclosed machines, solvent recov-
less ammable than petroleum solvents and had improved ered during the drying process is returned condensed and
cleaning power. distilled, so it can be reused to clean further loads or
safely disposed of. The majority of modern enclosed ma-
On March 3, 1821, Thomas L. Jennings became the rst chines also incorporate a computer-controlled drying sen-
African-American to be granted a United States patent, sor, which automatically senses when all detectable traces
for his cleaning process called dry scouring, which was of PCE have been removed. This system ensures that only
the precursor to dry cleaning.[3] small amounts of PCE fumes are released at the end of
the cycle.
1
2 3 PROCESS
3 Process
5 Symbols Dryclean,
tetrachloroethylene (PCE) only
The international GINETEX laundry symbol for dry
cleaning is a circle. It may have the letter P inside
it to indicate perchloroethylene solvent, or the letter
F to indicate a ammable solvent (Feuergefhrliches
Schwerbenzin). A bar underneath the circle indicates
that only mild cleaning processes is recommended. A
crossed-out empty circle indicates that dry cleaning is not
permitted.[6]
Gentle cleaning with PCE
6 Dry-cleaning waste
Wastes are potentially hazardous, and restrictions often
apply to disposal.
Gentle cleaning with hydro- Cooked powder residue is the name for the waste ma-
carbon solvents terial generated by cooking down or distilling muck. It
will contain solvent, powdered lter material (diatomite),
8.3 Dibutoxymethane 5
carbon, non-volatile residues, lint, dyes, grease, soils, Mobil's DF-2000 or Chevron Phillips' EcoSolv. These
and water. The waste sludge or solid residue from the petroleum-based solvents are less aggressive than PCE
still contains solvent, water, soils, carbon, and other non- and require a longer cleaning cycle. Although com-
volatile residues. Used lters are another form of waste bustible, these solvents do not present a high risk of re
as is waste water. or explosion when used properly. Hydrocarbon also con-
tains volatile organic compounds (VOCs) that contribute
to smog.[13] Pure Dry is another brand.
7 Toxicity and environmental ef-
fects 8.3 Dibutoxymethane
Further information: Tetrachloroethylene Health and Dibutoxymethane (SolvonK4) is a bipolar solvent that
safety removes water-based stains and oil-based stains. Dibu-
toxymethane is considered to be one of the best replace-
ments solvents for PCE as cleaning performance is very
PCE is classied as carcinogenic to humans by the United similar.
States Environmental Protection Agency[7] and must be
handled as a hazardous waste. To prevent it from getting
into drinking water, dry cleaners that use PCE must take 8.4 Liquid silicone
special precautions.
When released into the air, PCE can contribute to smog Liquid silicone (decamethylcyclopentasiloxane or D5) is
when it reacts with other volatile organic compounds.[8] gentler on garments than PCE and does not cause color
California declared perchloroethylene a toxic chemical loss. Though more environmentally friendly, it is more
in 1991, and its use will become illegal in that state in expensive. It degrades within days in the environment to
2023.[9] silicon dioxide and trace amounts of water and carbon
dioxide (CO2 ). It produces nontoxic, nonhazardous
The most popular alternative to PCE is
waste. Toxicity tests by Dow Corning show the solvent
decamethylcyclopentasiloxane (liquid silicone),
to increase the incidence of tumors in female rats (no ef-
called D5 for short. It is popularized by GreenEarth
fects were seen in male rats), but further research con-
Cleaning.[10]
cluded that the eects observed in rats are not relevant
CO2 represents an alternative to PCE, however CO2 is to humans because the biological pathway that results in
inferior in removing some forms of grime.[11] Research tumor formation is unique to rats.[14]
has pursued additive surfactants to improve the ecacy
of CO.[12]
8.5 Brominated solvents
8 Solvents used
8.1 Perchloroethylene
8.2 Hydrocarbons A modern dry cleaning machine for use with various solvents
Hydrocarbons are most like standard dry cleaning but Brominated solvents (n-propyl bromide, Fabrisolv, Dry-
the processes use hydrocarbon solvents such as Exxon- Solv) are solvents with a higher KB-values than PCE.
6 10 REFERENCES
This allows faster cleaning, but can damage some syn- solubility, 2-propanol has shown increased cleaning ef-
thetic beads and sequins if not used correctly. Health- fects for liquid carbon dioxide as it increases the ability
wise, there are reported risks associated with nPB such of the solvent to dissolve polar molecules while other an-
as numbness of nerves.[15] The exposure to the solvents tistatic agents are also being researched.[18]
in a typical dry cleaner is considered far below the lev- Furthermore, machinery is expensive up to $90,000
els required to cause any risk.[16] Environmentally, it is more than a PCE machine, making aordability dicult
approved by the U.S. EPA as an alternative to hazardous for small businesses. Some cleaners with these machines
solvents used in the past. It is among the more expensive keep traditional machines on-site for the heavier soiled
solvents, but due its faster cleaning, lower temperatures,
textiles, but others nd plant enzymes to be equally ef-
and quick dry times, its considered to have the same or fective and more environmentally sustainable.
lower costs overall for the entire process.
[4] http://www3.epa.gov/airtoxics/hlthef/tet-ethy.html
[5] http://www.cdc.gov/niosh/topics/cancer/npotocca.html#
t
11 External links
Hazard Summary provided by the United States En-
vironmental Protection Agency.
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